1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE COMPANY/UNDERTAKING space. ul.szturmowa 2A Warszawa, Polska
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1 1 IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE COMPANY/UNDERTAKING Identification of the preparation Use of the preparation Company identification Emergency telephone number Poison Information Centre telephone number C9384A Hewlett-Packard health effects line (Toll-free within the US) (Direct) Inkjet printing Hewlett-Packard Polska Sp z oo ulszturmowa 2A Warszawa, Polska General information telephone number HP customer care line (Toll-free within the US) (Direct) Date prepared May-2007 SDS number COMPOSITION/INFORMATION ON INGREDIENTS Component/substance Matte Black ink CAS number % by weight EU number Water > < R36/38 Ethyl alkyldiol Proprietary < 5 Proprietary 1,5-pentanediol < Yellow ink Water > Aliphatic diol Proprietary < 10 Proprietary < < R36/38 Substituted napthalenesulfonate salt #13 Proprietary < 5 Proprietary Composition comments EU classification This ink supply contains an aqueous ink formulation This product has been evaluated using criteria specified in the EU Directives 67/548/EEC and 1999/45/EC, as amended For the full text of the R phrases mentioned in this Section, see Section 16 3 HAZARDS IDENTIFICATION Classification Emergency Overview Acute health effects This product is not classified according to EU Directive 1999/45/EC Contact with skin and eyes may result in irritation Any potential hazards are presumed to be due to exposure to the components 1 / 6
2 Skin contact Eye contact Inhalation Ingestion Potential health effects Routes of exposure Chronic health effects Contact with skin may result in irritation 1,5-pentanediol Contact with skin may result in irritation Contact with skin may result in irritation Aliphatic diol Contact with skin may result in irritation Ethyl alkyldiol Contact with skin may result in mild irritation Substituted napthalenesulfonate salt #13 Contact with skin may result in irritation Contact with eyes may result in irritation 1,5-pentanediol Contact with eyes may result in irritation Contact with eyes may result in irritation Aliphatic diol Contact with eyes may result in irritation Ethyl alkyldiol Contact with eyes may result in mild irritation Substituted napthalenesulfonate salt #13 Contact with eyes may result in irritation Inhalation may result in respiratory irritation Inhalation may result in respiratory irritation Aliphatic diol Inhalation may result in respiratory irritation Substituted napthalenesulfonate salt #13 Inhalation may result in respiratory irritation Ingestion may result in nausea, vomiting and diarrhea Ingestion may result in nausea, vomiting and diarrhea Potential routes of overexposure to this product are skin and eye contact Inhalation of vapor and ingestion are not expected to be significant routes of exposure for this product under normal use conditions Complete toxicity data are not available for this specific formulation None known 2 / 6
3 Carcinogenicity Other information None of the components present in this formulation at concentrations equal to or greater than 01% are listed by EU, MAK, IARC, NTP or OSHA The black and yellow inks are not classified according to EU Directive 1999/45/EC 4 FIRST AID MEASURES First aid procedures Eye Skin Inhalation Ingestion Do not rub eyes Immediately flush with large amounts of clean, warm water (low pressure) for at least 15 minutes or until particles are removed If irritation persists get medical attention Wash affected areas thoroughly with mild soap and water If irritation persists get medical attention Move to fresh air If symptoms persist, get medical attention If ingestion of a large amount does occur, seek medical attention 5 FIRE-FIGHTING MEASURES Flash point and method Auto ignition temperature Lower explosion limit Hazardous combustion products Extinguishing media Unsuitable extinguishing media Unusual fire and explosion hazard Special firefighting procedures > 933 C (> 200 F); Setaflash Closed Tester Refer to section 10 Dry chemical, CO2, water spray or regular foam None known None known None established 6 ACCIDENTAL RELEASE MEASURES Personal precautions Environmental precautions Procedures if material is released or spilled Wear appropriate personal protective equipment Do not let product enter drains Do not flush into surface water or sanitary sewer system Soak up with inert absorbent material Slowly vacuum or sweep the material into a bag or other sealed container Dispose of in compliance with federal, state, and local regulations See also section 13 Disposal considerations 7 HANDLING AND STORAGE Handling Storage Avoid contact with skin, eyes and clothing Keep out of the reach of children Keep away from excessive heat or cold 8 EXPOSURE CONTROLS/PERSONAL PROTECTION Exposure limit values Exposure limits have not been established for this product Personal protective equipment General Use personal protective equipment to minimize exposure to skin and eye Hygiene measures Handle in accordance with good industrial hygiene and safety practice Exposure guidelines Use in a well ventilated area 3 / 6
4 9 PHYSICAL AND CHEMICAL PROPERTIES ph Vapour pressure Boiling point Solubility Soluble in water Specific gravity 1-12 VOC content < 3 % Flash point > 933 C (> 200 F) Viscosity > 2 cp Vapour density > 1 (Air = 10) Evaporation rate Flammability Oxidising properties Colour Black and Yellow 10 STABILITY AND REACTIVITY Stability Hazardous polymerisation Hazardous decomposition products Incompatibility Stable under recommended storage conditions Will not occur Upon decomposition, this product may yield gaseous nitrogen oxides, carbon monoxide, carbon dioxide and/or low molecular weight hydrocarbons Incompatible with strong bases and oxidizing agents 11 TOXICOLOGICAL INFORMATION This ink formulation has not been tested for toxicological effects Refer to Section 3 for potential health effects and Section 4 for first aide measures 12 ECOLOGICAL INFORMATION Aquatic toxicity Matte Black ink LC50/96h/fathead minnows => 750 mg/l Yellow ink LC50/96h/fathead minnows => 750 mg/l 13 DISPOSAL CONSIDERATIONS Disposal instructions 14 TRANSPORT INFORMATION General Dispose of in compliance with federal, state, and local regulations HP's Planet Partners (trademark) supplies recycling program enables simple, convenient recycling of HP original inkjet and LaserJet supplies For more information and to determine if this service is available in your location, please visit Not a regulated article under United States DOT, IATA, ADR, IMDG, or RID 4 / 6
5 IATA Proper shipping name Hazard class Packaging exceptions Identification number (UN) Packing group Not applicable Not applicable None None N/A 15 REGULATORY INFORMATION International regulations EU label All chemical substances in this HP product have been notified or are exempt from notification under chemical substances notification laws in the following countries: US (TSCA), EU (EINECS/ELINCS), Switzerland, Canada (DSL/NDSL), Australia, Japan, Philippines, South Korea, New Zealand, and China This product does not require a label according to EU Directive 1999/45/EC 16 OTHER INFORMATION Manufacturer information Ingredient risk phrase definition(s) Other information Issue date Revision 1 Disclaimer Hewlett-Packard Company 1000 NE Circle Boulevard Corvallis, OR US R36/38 Irritating to eyes and skin This MSDS was prepared in compliance with EU Directive 91/155/EEC as amended by 2001/58/EC May :41AM This Safety Data Sheet document is provided without charge to customers of Hewlett-Packard Company Data is the most current known to Hewlett-Packard Company at the time of preparation of this document and is believed to be accurate It should not be construed as guaranteeing specific properties of the products as described or suitability for a particular application This document was prepared to the requirements of the jurisdiction specified in Section 1 above and may not meet regulatory requirements in other countries 5 / 6
6 Explanation of abbreviations ACGIH CAS CERCLA CFR COC DOT EPCRA IARC NIOSH NTP OSHA PEL RCRA REC REL SARA STEL TCLP TLV TSCA VOC American Conference of Governmental Industrial Hygienists Chemical Abstracts Service Comprehensive Environmental Response Compensation and Liability Act Code of Federal Regulations Cleveland Open Cup Department of Transportation Emergency Planning and Community Right-to-Know Act (aka SARA) International Agency for Research on Cancer National Institute for Occupational Safety and Health National Toxicology Program Occupational Safety and Health Administration Permissible exposure limit Resource Conservation and Recovery Act Recommended Recommended Exposure Limit Superfund Amendments and Reauthorization Act of 1986 Short-Term Exposure Limit Toxicity Characteristics Leaching Procedure Threshold Limit Value Toxic Substances Control Act Volatile Organic Compounds 6 / 6
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