Material Safety Data Sheet Attached

Transcription

1 Canada Colors and Chemicals Limited 152 Kennedy Road South Brampton, Ontario Canada L6W 3G4 General Inquiry Number: (905) Material Safety Data Sheet Attached

2 1. PRODUCT AND COMPANY IDENTIFICATION Product name : This product is distributed by Canada Colors and Chemicals Limited General Inquiry: (416) (905) Hour Emergency: (416) CCC: Product Code: CCC: Product Name: Product Use Description : Surfactant Manufacturer/Importer/Distribu tor : Air Products and Chemicals, Inc 7201 Hamilton Blvd. Allentown, PA GST No RT0001 QST No TQ0001 Telephone : Corporate Chemicals Cust Serv Gases/Electronics Cust Serv Emergency telephone number (24h) : USA International 2. HAZARDS IDENTIFICATION Emergency Overview Corrosive Keep away from heat and sources of ignition. Components of the product may affect the nervous system. Flammable. Severe eye irritant. Severe respiratory irritant. Severe skin irritant. Potential Health Effects Inhalation : Can cause severe eye, skin and respiratory tract burns. Risk of serious damage to the lungs (by inhalation). May cause nose, throat, and lung irritation. Inhalation of aerosol may cause irritation to the upper respiratory tract. May cause central nervous system effects, such as headache, nausea, dizziness, confusion, breathing difficulties. Severe cases of overexposure can result in respiratory failure. Inhalation of vapors and/or aerosols in high concentration may cause irritation of respiratory system. May cause headache and dizziness. Eye contact : Causes eye burns. May cause blindness. Severe eye irritation. Skin contact : Causes skin burns. If absorbed through the skin, may cause central nervous system effects, such as headache, nausea, dizziness, confusion, breathing difficulties. 1/9

3 Ingestion : If ingested, severe burns of the mouth and throat, as well as a danger of perforation of the oesophagus and the stomach. Chronic Health Hazard : This product contains no listed carcinogens according to IARC, ACGIH, NTP and/or OSHA in concentrations of 0.1 percent or greater. Prolonged contact may result in chemical burns and permanent damage. Exposure Guidelines Target Organs : Skin. Eyes. Respiratory system. Central nervous system. Blood. Symptoms : Repeated and/or prolonged exposure to low concentrations of vapors and/or aerosols may cause: Sore throat. Aggravated Medical Condition Eye disease. Skin disorders and Allergies. Asthma. Neurological disorders 3. COMPOSITION/INFORMATION ON INGREDIENTS Components CAS Number Concentration (Weight) Poly(oxy-1,2-ethanediyl), % a,a'-[[methyl[3-(tridecyloxy)propyl]iminio]di-2,1-ethanediyl] bis[w-hydroxy-, branched, chlorides % CHEMICAL FAMILY: Quaternary Ammonium Compound 4. FIRST AID MEASURES General advice : Seek medical advice. If breathing has stopped or is labored, give assisted respirations. Supplemental oxygen may be indicated. If the heart has stopped, trained personnel should begin cardiopulmonary resuscitation immediately. Eye contact : Hold eyelids apart, initiate and maintain gentle and continuous irrigation until the patient receives medical care. If medical care is not promptly available, continue to irrigate for one hour. Skin contact : Immediately remove contaminated clothing, and any extraneous chemical, if possible to do so without delay. Initiate and maintain continuous irrigation until the patient receives medical care. If medical care is not promptly available, continue to irrigate for one hour. Cover wound with sterile dressing. Ingestion : If a person vomits when lying on his back, place him in the recovery position. Never give anything by mouth to an unconscious person. Prevent aspiration of vomit. Turn victim's head to the side. 2/9

4 Inhalation : If breathing has stopped or is labored, give assisted respirations. Supplemental oxygen may be indicated. If the heart has stopped, trained personnel should begin cardiopulmonary resuscitation immediately. Move to fresh air. 5. FIRE-FIGHTING MEASURES Suitable extinguishing media : Alcohol-resistant foam. Carbon dioxide (CO2). Dry chemical. Dry sand. Limestone powder. Specific hazards : Incomplete combustion may form carbon monoxide. Burning produces noxious and toxic fumes. In the event of fire, cool tanks with water spray. Downwind personnel must be evacuated. Fire or intense heat may cause violent rupture of packages. May form explosive mixtures in air. Special protective equipment for fire-fighters : Avoid contact with the skin. A face shield should be worn. Use personal protective equipment. Wear self contained breathing apparatus for fire fighting if necessary. Further information : Do not allow run-off from fire fighting to enter drains or water courses., Fire residues and contaminated fire extinguishing water must be disposed of in accordance with local regulations. 6. ACCIDENTAL RELEASE MEASURES Personal precautions : Wear suitable protective clothing, gloves and eye/face protection. Use self-contained breathing apparatus and chemically protective clothing. Remove all sources of ignition. Evacuate personnel to safe areas. Environmental precautions : Construct a dike to prevent spreading. Shut off or remove all ignition sources. Construct a dike to prevent spreading. Methods for cleaning up : Contact Air Products' Emergency Response Center for advice. Approach suspected leak areas with caution. Absorb with inert absorbent materials such as: Dry sand. Vermiculite. Activated charcoal. Place in appropriate chemical waste container. Additional advice : Open enclosed spaces to outside atmosphere. Prevent from entering sewers, basements and workpits, or any place where its accumulation can be dangerous. If possible, stop flow of product. 7. HANDLING AND STORAGE Handling Use only in well-ventilated areas. Avoid breathing vapors and/or aerosols. Avoid contact with skin and eyes. Emergency showers and eye wash stations should be readily accessible. Adhere to work practice rules established by government regulations. Avoid contact with eyes. See "Flammable and Combustible Liquid Code" NFPA No. 30, National Fire Protection Association, Boston, MA. Use personal protective equipment. When using, do not eat, drink or smoke. 3/9

5 Storage Keep containers tightly closed in a dry, cool and well-ventilated place. To avoid ignition of vapors by static electricity discharge, all metal parts of the equipment must be grounded. Keep away from heat and sources of ignition. Keep in a dry, cool place. Keep away from oxidizers. Technical measures/precautions Keep away from open flames, hot surfaces and sources of ignition. Storage Temperature : < 120 F (< 48.9 C) 8. EXPOSURE CONTROLS / PERSONAL PROTECTION Engineering measures Use explosion-proof equipment. Apply process controls to ensure safe operating conditions. Assess potential flammability hazards based on flashpoint and potential ignition sources. Provide readily accessible eye wash stations and safety showers. Provide natural or explosion-proof ventilation adequate to ensure concentrations are kept below exposure limits. Personal protective equipment Respiratory protection : Wear appropriate respirator when ventilation is inadequate. Hand protection : Neoprene gloves. Nitrile rubber. Impervious gloves. Chemical-resistant, impervious gloves complying with an approved standard should be worn at all times when handling chemical products if a risk assessment indicates this is necessary. Eye protection : Full face shield with goggles underneath. Chemical resistant goggles must be worn. Skin and body protection : Impervious clothing. Full rubber suit (rain gear). Rubber or plastic boots. Long sleeve shirts and trousers without cuffs. Slicker Suit. Environmental exposure controls Special instructions for protection and hygiene : Construct a dike to prevent spreading. Shut off or remove all ignition sources. : Provide readily accessible eye wash stations and safety showers. Wash hands at the end of each workshift and before eating, smoking or using the toilet. Provide readily accessible eye wash stations and safety showers. Exposure limit(s) 4/9

6 Time Weighted Average (TWA): (QUE) 400 ppm 985 mg/m3 Short Term Exposure Limit (STEL): (QUE) 500 ppm 1,230 mg/m3 Time Weighted Average (TWA): CAD AB 400 ppm 983 mg/m3 Short Term Exposure Limit (STEL): CAD AB 500 ppm 1,230 mg/m3 Time Weighted Average (TWA): CAD BC 200 ppm - Short Term Exposure Limit (STEL): CAD BC 400 ppm - Time Weighted Average (TWAEV): CAD ON 200 ppm - Short Term Exposure Limit (STEV): CAD ON 400 ppm - Time Weighted Average (TWA): (QUE) 400 ppm 983 mg/m3 Short Term Exposure Limit (STEL): (QUE) 500 ppm 1,230 mg/m3 Time Weighted Average (TWA): (QUE) 400 ppm 983 mg/m3 Short Term Exposure Limit (STEL): (QUE) 500 ppm 1,230 mg/m3 Time Weighted Average (TWA): CAD AB 200 ppm 492 mg/m3 Short Term Exposure Limit (STEL): CAD AB 400 ppm 984 mg/m3 8 hour average contamination limit: CAD SK 200 ppm - 15 minute average contamination limit: CAD SK 400 ppm - Time Weighted Average (TWA): CAD MB 200 ppm - Short Term Exposure Limit (STEL): CAD MB 400 ppm - Time Weighted Average (TWAEV): CAD ON 200 ppm - Short Term Exposure Limit (STEV): CAD ON 400 ppm - 9. PHYSICAL AND CHEMICAL PROPERTIES Form : Liquid. Color : Colorless. Odor : Irritating. Relative density : 0.97 Vapor pressure : mmhg at 68 F (20 C) Melting point/range : 2 F (-16.7 C) Flash point : 23.9 C Viscosity : 350 mpa.s at 68 F (20 C) 5/9

7 10. STABILITY AND REACTIVITY Chemical Stability : Stable under normal conditions. Conditions to avoid : Heat, flames and sparks. Materials to avoid : Reactive metals (e.g. sodium, calcium, zinc etc.). Materials reactive with hydroxyl compounds. Oxidizing agents. Acids. Alkalies. Alkali and alkaline earth metals - powdered aluminum, zinc, etc. Reacts with water to form corrosive acids. Hazardous decomposition products : Carbon monoxide. Carbon dioxide (CO2). Aldehydes Flammable hydrocarbon fragments. 11. TOXICOLOGICAL INFORMATION Acute Health Hazard Ingestion : No data is available on the product itself. Ingestion - Components LD50 : 4,710 mg/kg Species : Rat. Inhalation : No data is available on the product itself. Inhalation - Components LC50 (8 h) : ppm Species : Rat. Female Dermal : No data is available on the product itself. Dermal- Components LD50 : 6,290 mg/kg Species : Rabbit. Eye irritation/corrosion : Severe eye irritation., Risk of serious damage to eyes. Skin irritation/corrosion : Severe skin irritation. 12. ECOLOGICAL INFORMATION Ecotoxicity effects Aquatic toxicity : LC50 (96 h) : 11 mg/l Species : Fathead minnow (Pimephales promelas). Toxicity to other organisms : No data available. 6/9

8 Persistence and degradability Biodegradability : Inherently biodegradable. Mobility : No data available. Bioaccumulation : No data is available on the product itself. 13. DISPOSAL CONSIDERATIONS Waste from residues / unused products : Contact supplier if guidance is required. Contaminated packaging : Dispose of container and unused contents in accordance with federal, state, and local requirements. 14. TRANSPORT INFORMATION DOT UN/ID No. : UN2733 Proper shipping name : Amines, flammable, corrosive, n.o.s., (Quaternary amines, 2-Propanol) Class or Division : 3 Packing group : III Label(s) : 3 (8) Marine Pollutant : No IATA UN/ID No. : UN2733 Proper shipping name : Amines, flammable, corrosive, n.o.s., (Quaternary amines, 2-Propanol) Class or Division : 3 Packing group : III Label(s) : 3 (8) Marine Pollutant : Yes ** NOTE: This product contains a substance that: 1) is regulated as a Marine Pollutant, or 2) meets the definition of toxic to the aquatic environment. IMDG UN/ID No. : UN2733 Proper shipping name : AMINES, FLAMMABLE, CORROSIVE, N.O.S., (Quaternary amines, 2-Propanol) Class or Division : 3 Packing group : III Label(s) : 3 (8) Marine Pollutant : Yes ** NOTE: This product contains a substance that: 1) is regulated as a Marine Pollutant, or 2) meets the definition of toxic to the aquatic environment. 7/9

9 TDG UN/ID No. : UN2733 Proper shipping name : AMINES, FLAMMABLE, CORROSIVE, N.O.S., (Quaternary amines, 2-Propanol) Class or Division : 3 Packing group : III Label(s) : 3 (8) Marine Pollutant : No Further Information The transportation information is not intended to convey all specific regulatory data relating to this material. For complete transportation information, contact an Air Products customer service representative. 15. REGULATORY INFORMATION OSHA Hazard Communication Standard (29 CFR ) Hazard Class(es) Corrosive. Flammable. Country Regulatory list Notification USA TSCA Included on Inventory. EU EINECS Included on EINECS inventory or polymer substance, monomers included on EINECS inventory or no longer polymer. Canada DSL Included on Inventory. Australia AICS Included on Inventory. Japan ENCS Not on Inventory. South Korea ECL Not on Inventory. China SEPA Not on Inventory. Philippines PICCS Not on Inventory. EPA SARA Title III Section 312 (40 CFR 370) Hazard Classification Fire Hazard. Acute Health Hazard EPA SARA Title III Section 313 (40 CFR 372) Component(s) above 'de minimus' level WHMIS Hazard Classification Flammable Liquid, Toxic Material Causing Other Toxic Effects, Corrosive Material WHMIS Ingredient Disclosure List. 16. OTHER INFORMATION HMIS Rating Health : 3 Flammability : 3 8/9

10 Physical hazard : 0 REVISION NOTES : 14. TRANSPORT INFORMATION Prepared by : Air Products and Chemicals, Inc. Global EH&S Product Safety Department Telephone : Corporate Chemicals Cust Serv Gases/Electronics Cust Serv Preparation Date : 09/06/2014 For additional information, please visit our Product Stewardship web site at 9/9