SAFETY DATA SHEET according to 1907/2006/EC, Article 31

Transcription

1 SAFETY DATA SHEET according to 1907/006/EC, Article 31 SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier Product name 1.3. Details of the supplier of the safety data sheet Company Address Web SEAL IT SERVICES LTD T/A BOND IT Unit G16 Riverbank Way, Lowfields Business Park, Elland, West Yorkshire HX5 9DN Telephone Fax Emergency telephone number Emergency telephone number AM PM Mon-Fri date Page 1/7 SECTION : Hazards identification.1. Classification of the substance or mixture.1.1. Classification - 67/548/EEC Main hazards.1.. Classification - EC 17/008.. Label elements Hazard pictograms F; R11 Xn; R48/ Xi; R38-43 N; R51/53 R67 Symbols: F: Highly flammable. Xn: Harmful. N: Dangerous for the environment. Highly flammable. Irritating to skin. May cause sensitisation by skin contact. Harmful: danger of serious damage to health by prolonged exposure through inhalation. Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. Possible risk of harm to the unborn child. Harmful: may cause lung damage if swallowed. Vapours may cause drowsiness and dizziness. EUH08; Flam. Liq. : H5; Asp. Tox. 1: H304; Skin Irrit. : H315; Skin Sens. 1: H317; Eye Irrit. : H319; STOT SE 3: H336; Repr. : H361; STOT RE : H373; Aquatic Chronic : H411; Signal Word Hazard Statement Danger EUH08 - Contains rosin. May produce an allergic reaction. Flam. Liq. : H5 - Highly flammable liquid and vapour. Asp. Tox. 1: H304 - May be fatal if swallowed and enters airways. Skin Irrit. : H315 - Causes skin irritation. Skin Sens. 1: H317 - May cause an allergic skin reaction. Eye Irrit. : H319 - Causes serious eye irritation.

2 .. Label elements Prevention Response Storage Disposal date STOT SE 3: H336 - May cause drowsiness or dizziness. Repr. : H361 - Suspected of damaging fertility or the unborn child. STOT RE : H373 - May cause damage to organs through prolonged or repeated exposure. Aquatic Chronic : H411 - Toxic to aquatic life with long lasting effects. Page /7 P01 - Obtain special instructions before use. P0 - Do not handle until all safety precautions have been read and understood. P10 - Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. P33 - Keep container tightly closed. P40 - Ground/bond container and receiving equipment. P41 - Use explosion-proof electrical/ventilating/lighting// equipment. P4 - Use only non-sparking tools. P43 - Take precautionary measures against static discharge. P60 - Do not breathe dust/fume/gas/mist/vapours/spray. P61 - Avoid breathing dust/fume/gas/mist/vapours/spray. P64 - Wash thoroughly after handling. P71 - Use only outdoors or in a well-ventilated area. P7 - Contaminated work clothing should not be allowed out of the workplace. P73 - Avoid release to the environment. P80 - Wear protective gloves/protective clothing/eye protection/face protection. P301+P310 - IF SWALLOWED: IF SWALLOWED: Immediately call a POISON CENTER/doctor/. P30+P35 - IF ON SKIN: Wash with plenty of water/. P303+P361+P353 - IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower. P304+P340 - IF INHALED: Remove person to fresh air and keep comfortable for breathing. P305+P351+P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P308+P313 - IF exposed or concerned: Get medical advice/attention. P31 - Call a POISON CENTER/doctor/ /if you feel unwell. P314 - Get medical advice/attention if you feel unwell. P31 - Specific treatment (see on this label). P331 - Do NOT induce vomiting. P33+P313 - If skin irritation occurs: Get medical advice/attention. P333+P313 - If skin irritation or rash occurs: Get medical advice/attention. P337+P313 - If eye irritation persists: Get medical advice/attention. P370+P378 - In case of fire: Use to extinguish. P391 - Collect spillage. P403+P33 - Store in a well-ventilated place. Keep container tightly closed. P403+P35 - Store in a well-ventilated place. Keep cool. P405 - Store locked up. P501 - Dispose of contents/container to meet National Legislation and Environmental Regulations SECTION 3: Composition/information on ingredients 3.1. Substances 67/548/EEC / 1999/45/EC Chemical Name Index No. CAS No. EC No. REACH Registration Number Conc. (%w/w) Classification Toluene F; R11 Repr. Cat. 3; R63 Xn; R48/0-65 Xi; R38 R67 M-factor.

3 Page 3/7 date 3.1. Substances EC 17/008 Chemical Name Index No. CAS No. EC No. REACH Registration Number Conc. (%w/w) Classification Toluene Flam. Liq. : H5; Repr. : H361d; Asp. Tox. 1: H304; STOT RE : H373; Skin Irrit. : H315; STOT SE 3: H336; low boiling point hydrogen treated naphtha (petroleum), hydrotreated light. Acetone Flam. Liq. : H5; Eye Irrit. : H319; STOT SE 3: H336; Rosin (Rosin-based solder flux fume) M-factor. SECTION 4: First aid measures 4.1. Description of first aid measures Inhalation Eye contact Skin contact Ingestion Move the exposed person to fresh air. Rinse immediately with plenty of water for 15 minutes holding the eyelids open. Wash off immediately with plenty of soap and water. Remove contaminated clothing. DO NOT INDUCE VOMITING. 4.. Most important symptoms and effects, both acute and delayed Inhalation Eye contact Skin contact Ingestion Harmful by inhalation. Inhalation may cause nausea and vomiting. May cause dizziness and headache. May cause irritation to eyes. May cause dermatitis. May cause irritation to skin and eyes. Harmful by inhalation and if swallowed. Ingestion may cause nausea and vomiting. Ingestion is irritating to the respiratory tract and may cause damage to the central nervous system Indication of any immediate medical attention and special treatment needed Inhalation Eye contact Skin contact Ingestion SECTION 5: Firefighting measures 5.1. Extinguishing media Seek medical attention. 5.. Special hazards arising from the substance or mixture 5.3. Advice for firefighters SECTION 6: Accidental release measures Seek medical attention if irritation or symptoms persist. Seek medical attention if irritation or symptoms persist. If swallowed, seek medical advice immediately and show this container or label. Use as appropriate: Carbon dioxide (CO), Dry chemical, Foam. Highly flammable. Burning produces irritating, toxic and obnoxious fumes. Self-contained breathing apparatus. Wear protective clothing Personal precautions, protective equipment and emergency procedures 6.. Environmental precautions 6.3. Methods and material for containment and cleaning up SECTION 7: Handling and storage Ensure adequate ventilation of the working area. Eliminate all sources of ignition. Wear suitable protective equipment. Do not allow product to enter drains. Prevent further spillage if safe. Absorb with inert, absorbent material. Transfer to suitable, labelled containers for disposal. Clean spillage area thoroughly with plenty of water.

4 7.1. Precautions for safe handling 7.. Conditions for safe storage, including any incompatibilities SECTION 8: Exposure controls/personal protection 8.1. Control parameters date Page 4/7 Avoid contact with eyes and skin. Ensure adequate ventilation of the working area. Use explosion proof equipment. Keep away from sources of ignition - No smoking. Adopt best Manual Handling considerations when handling, carrying and dispensing. Keep in a cool, dry, well ventilated area. Keep containers tightly closed Exposure Limit Values Toluene WEL 8-hr limit ppm: 50 WEL 8-hr limit mg/m3: Exposure controls WEL 15 min limit ppm: 100 WEL 15 min limit mg/m3: 384 WEL 8-hr limit mg/m3 total - WEL 15 min limit mg/m3 total - inhalable dust: inhalable dust: WEL 8-hr limit mg/m3 total - WEL 15 min limit mg/m3 total - respirable dust: respirable dust: Appropriate engineering controls 8... Individual protection measures Eye / face protection Skin protection - Handprotection Respiratory protection Ensure adequate ventilation of the working area. Wear chemical protective clothing. Approved safety goggles. Chemical resistant gloves (PVC). Self-contained breathing apparatus. Wear protective clothing. SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties Appearance Liquid Colour Amber Odour Characteristic Flammability (solid, gas) No data available Vapour pressure No data available Vapour density No data available Relative density (HO = 0 C) Autoignition temperature No data available Explosive properties Product is not explosive, formation of explosive air/vapour mixtures are possible. Oxidising properties No data available Partition coefficient No data available Viscosity No data available Fat Solubility No data available ph No data available Initial boiling point 55 C Melting point Not determined Flash point = -19 C Evaporation rate No data available Freezing Point No data available Solubility Immiscible in water 9.. Other information

5 Page 5/7 date 9.. Other information Conductivity No data available Surface tension No data available Gas group No data available VOC (Volatile organic No data available compounds) Benzene Content No data available Lead content No data available SECTION 10: Stability and reactivity 10.. Chemical stability Stable under normal conditions Possibility of hazardous reactions Oxidising agents Conditions to avoid Heat, sparks and open flames. SECTION 11: Toxicological information Toxicological Information CONTACT ADHESIVE WITH TOLUENE CLP Oral Rat LD50: 5000 mg/kg Dermal Rabbit LD50: 114 mg/kg Inhalation Mouse LC50/4 h: 530 mg/l SECTION 1: Ecological information 1.1. Toxicity No data available Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment Bioaccumulative potential Partition coefficient SECTION 13: Disposal considerations General information SECTION 14: Transport information Hazard pictograms CONTACT ADHESIVE WITH No data available TOLUENE CLP Dispose of in compliance with all local and national regulations UN number UN UN proper shipping name ADHESIVES Transport hazard class(es) ADR/RID 3

6 14.3. Transport hazard class(es) Subsidiary risk - IMDG 3 Subsidiary risk - IATA 3 Subsidiary risk Packing group Packing group Environmental hazards Environmental hazards Marine pollutant ADR/RID II Yes Yes Hazard ID 33 Tunnel Category IMDG EmS Code IATA (D/E) Packing Instruction (Cargo) 364 Maximum quantity Packing Instruction (Passenger) Maximum quantity F-E S-D 60L 353 5L date Page 6/7 SECTION 15: Regulatory information Safety, health and environmental regulations/legislation specific for the substance or mixture Regulations SECTION 16: Other information Other information Text of risk phrases in Section 3 Text of Hazard Statements in Section 3 COMMISSION REGULATION (EU) No 453/010 of 0 May 010 amending Regulation (EC) No 1907/006 of the European Parliament and of the Council on the Registration, Authorisation and Restriction of Chemicals (REACH), establishing a European Chemicals Agency, amending Directive 1999/45/EC and repealing Council Regulation (EEC) No 793/93 and Commission Regulation (EC) No 1488/94 as well as Council Directive 76/769/EEC and Commission Directives 91/155/EEC, 93/67/EEC, 93/105/EEC and 000/1/EC. REGULATION (EC) No 1907/006 OF THE EUROPEAN PARLIAMENT AND OF THE COUNCIL of 18 December 006 concerning the Registration, Evaluation, Authorisation and Restriction of Chemicals (REACH), establishing a European Chemicals Agency, amending Directive 1999/45/EC and repealing Council Regulation (EEC) No 793/93 and Commission Regulation (EC) No 1488/94 as well as Council Directive 76/769/EEC and Commission Directives 91/155/EEC, 93/67/EEC, 93/105/EC and 000/1/EC. This document differs from the previous version in the following areas:. - Hazard pictograms ADR/RID IMDG. R11 - Highly flammable. R38 - Irritating to skin. R48/0 - Harmful: danger of serious damage to health by prolonged exposure through inhalation. R63 - Possible risk of harm to the unborn child. R65 - Harmful: may cause lung damage if swallowed. R67 - Vapours may cause drowsiness and dizziness. Flam. Liq. : H5 - Highly flammable liquid and vapour. Asp. Tox. 1: H304 - May be fatal if swallowed and enters airways. Skin Irrit. : H315 - Causes skin irritation.

7 Other information Further information date STOT SE 3: H336 - May cause drowsiness or dizziness. Repr. : H361d - Suspected of damaging the unborn child. STOT RE : H373 - May cause damage to organs through prolonged or repeated exposure. EUH066 - Repeated exposure may cause skin dryness or cracking. Eye Irrit. : H319 - Causes serious eye irritation. Page 7/7 The information supplied in this Safety Data Sheet is designed only as guidance for the safe use, storage and handling of the product. This information is correct to the best of our knowledge and belief at the date of publication however no guarantee is made to its accuracy. This information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any other process.