Material Safety Data Sheet

Transcription

1 Material Safety Data Sheet NFPA HMIS Personal Protective Equipment W 2 Health Hazard Fire Hazard 1 See Section 15. Section 1. Chemical Product and Company Identification Page Number: 1 Common Name/ Trade Name Manufacturer Commercial Name(s) Synonym Chemical Name Chemical Family Chemical Formula Supplier Titanium tetrachloride SPECTRUM LABORATORY PRODUCTS INC S. SAN PEDRO STREET GARDENA, CA 9248 Titanium Chloride (TiCl4) TiCl4 SPECTRUM LABORATORY PRODUCTS INC S. SAN PEDRO STREET GARDENA, CA 9248 Catalog Number(s). CAS# RTECS CI# CALL (1) T1625, T XR1925 TSCA T S C A 8 ( b ) i n v e n t o r y : Titanium tetrachloride IN CASE OF EMERGENCY CHEMTREC (24hr) Section 2.Composition and Information on Ingredients Name CAS # Exposure Limits TWA (mg/m ) STEL (mg/m ) CEIL (mg/m ) % by Weight 1) Titanium tetrachloride Toxicological Data on Ingredients Titanium tetrachloride: VAPOR (LC5): Acute: 1 mg/m 2 hours [Mouse]. Section. Hazards Identification Potential Acute Health Effects Potential Chronic Health Effects Very hazardous in case of skin contact (irritant), of eye contact (irritant), of ingestion, of inhalation. Hazardous in case of skin contact (corrosive), of eye contact (corrosive). Liquid or spray mist may produce tissue damage particularly on mucous membranes of eyes, mouth and respiratory tract. Skin contact may produce burns. Inhalation of the spray mist may produce severe irritation of respiratory tract, characterized by coughing, choking, or shortness of breath. Inflammation of the eye is characterized by redness, watering, and itching. Skin inflammation is characterized by itching, scaling, reddening, or, occasionally, blistering. CARCINOGENIC EFFECTS: MUTAGENIC EFFECTS: TERATOGENIC EFFECTS: DEVELOPMENTAL TOXICITY: The substance may be toxic to lungs, mucous membranes, upper respiratory tract, skin, eye, lens or cornea. Repeated or prolonged exposure to the substance can produce target organs damage. Repeated or prolonged contact with spray mist may produce chronic eye irritation and severe skin irritation. Repeated or prolonged exposure to spray mist may produce respiratory tract irritation leading to frequent attacks of bronchial infection.

2 Titanium tetrachloride Page Number: 2 Section 4. First Aid Measures Eye Contact Skin Contact Serious Skin Contact Inhalation Serious Inhalation Ingestion Serious Ingestion Check for and remove any contact lenses. In case of contact, immediately flush eyes with plenty of water for at least 15 minutes. Cold water may be used. Get medical attention immediately. In case of contact, immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Cover the irritated skin with an emollient. Cold water may be used.wash clothing before reuse. Thoroughly clean shoes before reuse. Get medical attention immediately. Wash with a disinfectant soap and cover the contaminated skin with an anti-bacterial cream. Seek immediate medical attention. If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical attention immediately. Evacuate the victim to a safe area as soon as possible. Loosen tight clothing such as a collar, tie, belt or waistband. If breathing is difficult, administer oxygen. If the victim is not breathing, perform mouth-to-mouth resuscitation. WARNING: It may be hazardous to the person providing aid to give mouth-to-mouth resuscitation when the inhaled material is toxic, infectious or corrosive. Seek immediate medical attention. Do NOT induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an unconscious person. If large quantities of this material are swallowed, call a physician immediately. Loosen tight clothing such as a collar, tie, belt or waistband. Section 5. Fire and Explosion Data Flammability of the Product Auto-Ignition Temperature Flash Points Flammable Limits Products of Combustion Fire Hazards in Presence of Various Substances Non-flammable. Explosion Hazards in Presence of Various Substances Risks of explosion of the product in presence of mechanical impact: Risks of explosion of the product in presence of static discharge: Fire Fighting Media and Instructions Fire Hazards Explosion Hazards When heated to decomposition it emits toxic fumes of hydrocgen chloride. Section 6. Accidental Release Measures Small Spill Large Spill Dilute with water and mop up, or absorb with an inert dry material and place in an appropriate waste disposal container. Corrosive liquid. Stop leak if without risk. Absorb with DRY earth, sand or other non-combustible material. Do not get water inside container. Do not touch spilled material. Use water spray curtain to divert vapor drift. Prevent entry into sewers, basements or confined areas; dike if needed. Call for assistance on disposal.

3 Titanium tetrachloride Page Number: Section 7. Handling and Storage Precautions Storage Keep container dry. Do not ingest. Do not breathe gas/fumes/ vapor/spray. Never add water to this product. In case of insufficient ventilation, wear suitable respiratory equipment. If ingested, seek medical advice immediately and show the container or the label. Avoid contact with skin and eyes. Keep away from incompatibles such as oxidizing agents, metals. Keep container tightly closed. Keep container in a cool, well-ventilated area. Air Sensitive Moisture sensitive. Section 8. Exposure Controls/Personal Protection Engineering Controls Personal Protection Personal Protection in Case of a Large Spill Exposure Limits Provide exhaust ventilation or other engineering controls to keep the airborne concentrations of vapors below their respective threshold limit value. Ensure that eyewash stations and safety showers are proximal to the work-station location. Face shield. Full suit. Vapor respirator. Be sure to use an approved/certified respirator or equivalent. Gloves. Boots. Splash goggles. Full suit. Vapor respirator. Boots. Gloves. A self contained breathing apparatus should be used to avoid inhalation of the product. Suggested protective clothing might not be sufficient; consult a specialist BEFORE handling this product. TWA:.5 (mg/m ) from AIHA [United States] Consult local authorities for acceptable exposure limits. Section 9. Physical and Chemical Properties Physical state and appearance Liquid. (Fuming liquid.) Odor Pungent. Penetrating acid odor (Strong.) Molecular Weight ph (1% soln/water) g/mole Taste Color Colorless to light yellow. Boiling Point 16.4 C (277.5 F) Melting Point C (-11.4 F) Critical Temperature 7 C (698 F) Specific Gravity (Water = 1) Vapor Pressure 1. kpa (@ 2 C) Vapor Density 6.6 (Air = 1) Volatility Odor Threshold Water/Oil Dist. Coeff. Ionicity (in Water) Dispersion Properties See solubility in water. Solubility Soluble in cold water. Section 1. Stability and Data Stability Instability Temperature Conditions of Instability Incompatibility with various substances Corrosivity The product is stable. Incompatible materials, water, moisture Reactive with oxidizing agents, metals. Slightly reactive to reactive with moisture. Non-corrosive in presence of glass.

4 Titanium tetrachloride Page Number: 4 Corrosivity Polymerization Air sensitive. Moisture sensitive. Readily hydrolyzed by moisture, with the liberation of hydrochloric acid (reacts with water to release Hydrochloric acid fumes and heat). Incompatible with Potassium, powdered metals, alcohols. Will not occur. Section 11. Toxicological Information Routes of Entry Toxicity to Animals Chronic Effects on Humans Other Toxic Effects on Humans Toxicity to Animals Chronic Effects on Humans other Toxic Effects on Humans Absorbed through skin. Eye contact. Inhalation. WARNING: THE LC5 VALUES HEREUNDER ARE ESTIMATED ON THE BASIS OF A 4-HOUR EXPOSURE. Acute toxicity of the vapor (LC5): 1 mg/m 2 hours [Mouse]. May cause damage to the following organs: lungs, mucous membranes, upper respiratory tract, skin, eye, lens or cornea. Very hazardous in case of skin contact (irritant), of ingestion,. Hazardous in case of skin contact (corrosive), of eye contact (corrosive), of inhalation (lung corrosive). Acute Potential Health Effects: Skin: Corrosive. Causes severe irritation and burns epecially if skin is wet or moist. Eyes: Corrosive. Direct contact with eyes causes severe irritation and burns. It can cause severe eye injury with permanent corneal opacity. Inhalation: Corrosive. Poison. Harmful if inhaled. Vapors are to the eyes, and respiratory tract. Symptoms may include irritation of the mucosa of the nose or throat, cough, bronchoconstriction with wheezing, chemical pheumonitis, edema of the pharynx,, vocal cords, and trachea, noncardiogenic pulmonary edema. Ingestion: Corrosive. Can cause mouth, throat, esophageal, and gastrointestnial tract irritation and burns. Can c aus e abdominal pai n, naus ea, vomiting, di ar r hea. May c aus e per f or at i on of t he digestive/gastrointestinal tract. Chronic Potential Health Effects: Inhalation: Corrosive to the tissues of the respiratory tract. Prolonged or repeated inhalation of low concentrations can cause pulmonary injury which may resemble silicosis in some cases. Symptoms may include upper respiratory tract irritation and acute or chronic bronchitis, and pulmonary complications such as reduced ventilatory capacity, pleural thickening and plaques. Section 12. Ecological Information Ecotoxicity BOD5 and COD Products of Biodegradation Toxicity of the Products of Biodegradation the Products of Biodegradation Possibly hazardous short term degradation products are not likely. However, long term degradation products may arise. The products of degradation are less toxic than the product itself. Section 1. Disposal Considerations Waste Disposal Waste must be disposed of in accordance with federal, state and local environmental control regulations.

5 Titanium tetrachloride Page Number: 5 Section 14. Transport Information DOT Classification Identification CLASS 6.1: Poisonous material. Class 8: Corrosive material UNNA: 188 : Titanium Tetrachloride PG: I Special Provisions for Transport DOT Poison inhalation hazard zone B Section 15. Other Regulatory Information and Pictograms Federal and State Regulations California Proposition 65 Warnings Other Regulations Other Classifications Pennsylvania RTK: Titanium tetrachloride Massachusetts RTK: Titanium tetrachloride Massachusetts spill list: Titanium tetrachloride New Jersey: Titanium tetrachloride New Jersey spill list: Titanium tetrachloride New Jersey toxic catastrophe prevention act: Titanium tetrachloride Louisiana RTK reporting list: Titanium tetrachloride Louisiana spill reporting: Titanium tetrachloride TSCA 8(b) inventory: Titanium tetrachloride SARA 2/4/11/12 extremely hazardous substances: Titanium tetrachloride SARA 1 toxic chemical notification and release reporting: Titanium tetrachloride CERCLA: Hazardous substances.: Titanium tetrachloride: 1 lbs. (45.6 kg) California prop. 65: This product contains the following ingredients for which the State of California has found to cause cancer which would require a warning under the statute: No products were found. California prop. 65: This product contains the following ingredients for which the State of California has found to cause birth defects which would require a warning under the statute: No products were found. OSHA: Hazardous by definition of Hazard Communication Standard (29 CFR ). EINECS: This product is on the European Inventory of Existing Commercial Chemical Substances (EINECS No ). Canada: Listed on Canadian Domestic Substance List (DSL). China: Listed on National Inventory. Japan: Listed on National Inventory (ENCS). Korea: Listed on National Inventory (KECI). Philippines: Listed on National Inventory (PICCS). Australia: Listed on AICS. WHMIS (Canada) DSCL (EEC) This classification of this product has not been validated yet by the Service du repertoire toxicologique. However, it might be classified as: CLASS D-1A: Material causing immediate and serious toxic effects (VERY TOXIC). CLASS D-2A: Material causing other toxic effects (VERY TOXIC). CLASS E: Corrosive liquid. R14- Reacts violently with water. R4- Causes burns. S7/8- Keep container tightly closed and dry. S26- In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S6/7/9- Wear suitable protective clothing, gloves and eye/face protection. S45- In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). HMIS (U.S.A.) Health Hazard Fire Hazard Personal Protection 1 National Fire Protection Association (U.S.A.) Health W 2 Flammability Specific hazard

6 Titanium tetrachloride Page Number: 6 WHMIS (Canada) DSCL (Europe) TDG (Canada) ADR (Europe) Protective Equipment Gloves. Full suit. Vapor respirator. Be sure to use an approved/certified respirator or equivalent. Wear appropriate respirator when ventilation is inadequate. Face shield. Section 16. Other Information MSDS Code References Other Special Considerations T67 Major Uses: Pure titanium and titanium salts; irridescent effects in glass; smoke screens; titanium pigments; polymerization catalyst; intermediate in the production of titanium metal and titanium pigments, titanium dioxide Validated by Sonia Owen on 6/7/212. Verified by Sonia Owen. Printed 6/7/212. CALL (1) Notice to Reader All chemicals may pose unknown hazards and should be used with caution. This Material Safety Data Sheet (MSDS) applies only to the material as packaged. If this product is combined with other materials, deteriorates, or becomes contaminated, it may pose hazards not mentioned in this MSDS. It shall be the user's responsibility to develop proper methods of handling and personal protection based on the actual conditions of use. While this MSDS is based on technical data judged to be reliable, Spectrum Quality Products, Inc. assumes no responsibility for the completeness or accuracy of the information contained herein.