Material Safety Data Sheet

Transcription

1 Material Safety Data Sheet NFPA HMIS Personal Protective Equipment 3 1 Health Hazard Fire Hazard 3 1 See Section 15. Section 1. Chemical Product and Company Identification Page Number: 1 Common Name/ Trade Name Manufacturer Commercial Name(s) Synonym Chemical Name Chemical Family Chemical Formula Supplier Hydriodic Acid, 47% SPECTRUM LABORATORY PRODUCTS INC S. SAN PEDRO STREET GARDENA, CA 9248 Hydrogen Iodide solution SPECTRUM LABORATORY PRODUCTS INC S. SAN PEDRO STREET GARDENA, CA 9248 Catalog Number(s). CAS# RTECS CI# H125 CALL (31) TSCA T S C A 8 ( b ) i n v e n t o r y : Hydriodic Acid, 47% IN CASE OF EMERGENCY CHEMTREC (24hr) Section 2.Composition and Information on Ingredients Name CAS # Exposure Limits TWA (mg/m 3 ) STEL (mg/m 3 ) CEIL (mg/m 3 ) % by Weight 1) Water ) Hydrogen iodide Toxicological Data on Ingredients Hydrogen iodide LD5: LC5: Section 3. Hazards Identification Potential Acute Health Effects Potential Chronic Health Effects Very hazardous in case of skin contact (irritant), of eye contact (irritant), of ingestion. Hazardous in case of skin contact (corrosive), of eye contact (corrosive), of inhalation. Liquid or spray mist may produce tissue damage particularly on mucous membranes of eyes, mouth and respiratory tract. Skin contact may produce burns. Inhalation of the spray mist may produce severe irritation of respiratory tract, characterized by coughing, choking, or shortness of breath. Inflammation of the eye is characterized by redness, watering, and itching. Skin inflammation is characterized by itching, scaling, reddening, or, occasionally, blistering. CARCINOGENIC EFFECTS: Classified A4 (Not classifiable for human or animal.) by ACGIH [Hydriodic Acid, 47%]. MUTAGENIC EFFECTS: TERATOGENIC EFFECTS: DEVELOPMENTAL TOXICITY: The substance is toxic to lungs. Repeated or prolonged exposure to the substance can produce target organs damage. Repeated or prolonged contact with spray mist may produce chronic eye irritation and severe skin irritation. Repeated or

2 Hydriodic Acid, 47% Page Number: 2 Section 4. First Aid Measures prolonged exposure to spray mist may produce respiratory tract irritation leading to frequent attacks of bronchial infection. Eye Contact Skin Contact Serious Skin Contact Inhalation Serious Inhalation Ingestion Serious Ingestion Check for and remove any contact lenses. In case of contact, immediately flush eyes with plenty of water for at least 15 minutes. Cold water may be used. Get medical attention immediately. In case of contact, immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Cover the irritated skin with an emollient. Cold water may be used.wash clothing before reuse. Thoroughly clean shoes before reuse. Get medical attention immediately. Wash with a disinfectant soap and cover the contaminated skin with an anti-bacterial cream. Seek medical attention. If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical attention immediately. Evacuate the victim to a safe area as soon as possible. Loosen tight clothing such as a collar, tie, belt or waistband. If breathing is difficult, administer oxygen. If the victim is not breathing, perform mouth-to-mouth resuscitation. Seek medical attention. Do NOT induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an unconscious person. If large quantities of this material are swallowed, call a physician immediately. Loosen tight clothing such as a collar, tie, belt or waistband. Section 5. Fire and Explosion Data Flammability of the Product Auto-Ignition Temperature Flash Points Flammable Limits Products of Combustion Fire Hazards in Presence of Various Substances Explosion Hazards in Presence of Various Substances Fire Fighting Media and Instructions Fire Hazards Explosion Hazards Non-flammable. Non-explosive in presence of open flames and sparks, of shocks. When heated to decomposition it emits highly toxic fumes of Hydrogen Iodide. Section 6. Accidental Release Measures Small Spill Large Spill Dilute with water and mop up, or absorb with an inert dry material and place in an appropriate waste disposal container. Corrosive liquid. Stop leak if without risk. Absorb with DRY earth, sand or other non-combustible material. Do not get water inside container. Do not touch spilled material. Use water spray curtain to divert vapor drift. Prevent entry into sewers, basements or confined areas; dike if needed. Call for assistance on disposal.

3 Hydriodic Acid, 47% Page Number: 3 Section 7. Handling and Storage Precautions Storage Keep container dry. Do not breathe gas/fumes/ vapor/spray. In case of insufficient ventilation, wear suitable respiratory equipment. If you feel unwell, seek medical attention and show the label when possible. Avoid contact with skin and eyes. Keep away from incompatibles such as oxidizing agents, metals, acids. Keep container tightly closed. Keep container in a cool, well-ventilated area. Sensitive to light. Store in light-resistant containers. Section 8. Exposure Controls/Personal Protection Engineering Controls Personal Protection Personal Protection in Case of a Large Spill Exposure Limits Provide exhaust ventilation or other engineering controls to keep the airborne concentrations of vapors below their respective threshold limit value. Face shield. Full suit. Vapor respirator. Be sure to use an approved/certified respirator or equivalent. Gloves. Boots. Splash goggles. Full suit. Vapor respirator. Boots. Gloves. A self contained breathing apparatus should be used to avoid inhalation of the product. Suggested protective clothing might not be sufficient; consult a specialist BEFORE handling this product. Section 9. Physical and Chemical Properties Physical state and appearance Liquid. Odor Unpleasant. Sharp Molecular Weight ph (1% soln/water) Not available Taste Color Clear Colorless to light yellow. (Light.) Boiling Point 127 C (26.6 F) Melting Point -51 C (-59.8 F) Critical Temperature Specific Gravity 1.5 (Water = 1) Vapor Pressure Vapor Density Volatility Odor Threshold Water/Oil Dist. Coeff. Ionicity (in Water) Dispersion Properties Solubility The highest known value is 2.3 kpa (@ 2 C) (Water) (Air = 1) See solubility in water. Easily soluble in cold water. Section 1. Stability and Data Stability Instability Temperature Conditions of Instability Incompatibility with various substances Corrosivity The product is stable. Incompatible materials, light, water/moisture Reactive with oxidizing agents, metals, acids. Slightly reactive to reactive with water/moisture Non-corrosive in presence of glass. Sensitive to light. Will darken on exposure to light. Decomposes on exposure to light. Incompatible with Ethyl hydroperoxide, potassium, magnesium, potassium perchlorate, perchloric acid.

4 Hydriodic Acid, 47% Page Number: 4 Corrosivity Polymerization Will not occur. Section 11. Toxicological Information Routes of Entry Toxicity to Animals Chronic Effects on Humans Other Toxic Effects on Humans Toxicity to Animals Chronic Effects on Humans other Toxic Effects on Humans Absorbed through skin. Eye contact. Ingestion. LD5: LC5: CARCINOGENIC EFFECTS: Classified A4 (Not classifiable for human or animal.) by ACGIH [Hydriodic Acid, 47%]. Very hazardous in case of skin contact (irritant), of ingestion. Hazardous in case of skin contact (corrosive), of eye contact (corrosive), inhalation. Acute Potential Health Effects: Skin: Corrosive. Causes severe irritation and burns. It can be absorbed through the skin. Eyes: Causes severe irritation and burns. May cause eye damage. Inhalation: Causes respiratory tract irritation, cough, shortness of breath, headache, fall in blood pressure, chills and possible collapse. It can cause edema of the glottis, laryngeal edema, spasms of the windpipe which can be fatal. It may cause pulmonary edema. Chronic Potential Health Effects: Chronic exposure can cause kidney and spleen injury, hypotension, palpitation, ataxia and weakness, lung damage, skin rash, headache, irritation of the mucous membranes, bronchitis, cough, phlegm shortness of breath, and running nose. Section 12. Ecological Information Ecotoxicity BOD5 and COD Products of Biodegradation Toxicity of the Products of Biodegradation the Products of Biodegradation Possibly hazardous short term degradation products are not likely. However, long term degradation products may arise. The product itself and its products of degradation are not toxic. Section 13. Disposal Considerations Waste Disposal Waste must be disposed of in accordance with federal, state and local environmental control regulations. Section 14. Transport Information DOT Classification Identification Class 8: Corrosive material UNNA: 1787 : Hydroiodic acid, solution PG: II Special Provisions for Transport

5 Hydriodic Acid, 47% Page Number: 5 DOT Section 15. Other Regulatory Information and Pictograms Federal and State Regulations California Proposition 65 Warnings Other Regulations Rhode Island RTK hazardous substances: Hydriodic Acid, 47% Pennsylvania RTK: Hydriodic Acid, 47% Massachusetts RTK: Hydriodic Acid, 47% Massachusetts spill list: Hydriodic Acid, 47% New Jersey: Hydriodic Acid, 47% TSCA 8(b) inventory: Hydriodic Acid, 47% California prop. 65: This product contains the following ingredients for which the State of California has found to cause cancer which would require a warning under the statute: No products were found. California prop. 65: This product contains the following ingredients for which the State of California has found to cause birth defects which would require a warning under the statute: No products were found. OSHA: Hazardous by definition of Hazard Communication Standard (29 CFR ). EINECS: This product is on the European Inventory of Existing Commercial Chemical Substances (EINECS No ). Canada: Listed on Canadian Domestic Substance List (DSL). China: Listed on National Inventory. Japan: Listed on National Inventory (ENCS). Korea: Listed on National Inventory (KECI). Philippines: Listed on National Inventory (PICCS). Australia: Listed on AICS. Other Classifications WHMIS (Canada) CLASS E: Corrosive liquid. DSCL (EEC) R35- Causes severe burns. S9- Keep container in a well-ventilated place. S26- In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S36/37/39- Wear suitable protective clothing, gloves and eye/face protection. S45- In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). HMIS (U.S.A.) Health Hazard Fire Hazard Personal Protection 3 1 National Fire Protection Association (U.S.A.) Health 3 1 Flammability Specific hazard WHMIS (Canada) DSCL (Europe) TDG (Canada)

6 Hydriodic Acid, 47% Page Number: 6 ADR (Europe) Protective Equipment Gloves. Full suit. Vapor respirator. Be sure to use an approved/certified respirator or equivalent. Wear appropriate respirator when ventilation is inadequate. Face shield. Section 16. Other Information MSDS Code References Other Special Considerations H3275 Major Uses: Reducing agent; iodination reactions. Validated by Sonia Owen on 8/16/21. Verified by Sonia Owen. Printed 8/16/21. CALL (31) Notice to Reader All chemicals may pose unknown hazards and should be used with caution. This Material Safety Data Sheet (MSDS) applies only to the material as packaged. If this product is combined with other materials, deteriorates, or becomes contaminated, it may pose hazards not mentioned in this MSDS. It shall be the user's responsibility to develop proper methods of handling and personal protection based on the actual conditions of use. While this MSDS is based on technical data judged to be reliable, Spectrum Quality Products, Inc. assumes no responsibility for the completeness or accuracy of the information contained herein.