SAFETY DATA SHEET STYCCOBOND F81 HARDENER

Transcription

1 Revision Date 30/09/14 Revision 12 Supersedes date 17/01/13 SAFETY DATA SHEET SECTION 1: IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING 1.1. Product identifier Product name Internal Id SBF81H/ Relevant identified uses of the substance or mixture and uses advised against Identified uses Uses advised against Component of epoxy resin based system No specific uses advised against are identified Details of the supplier of the safety data sheet Supplier F.Ball and Co. Ltd. Churnetside Business Park, Station Road, Cheddleton, Leek, Staffordshire. ST13 7RS Tel: Mon-Fri 8.30am-5.00pm (Exc Bank Holidays) Fax: E.mail: 1.4. Emergency telephone number National Emergency Telephone Number Mon-Fri 8.30am pm (excluding Bank Holidays) SECTION 2: HAZARDS IDENTIFICATION 2.1. Classification of the substance or mixture Physical and Chemical Hazards Not classified. Human health Skin Irrit. 2 - H315;Eye Irrit. 2 - H319;Skin Sens. 1 - H317 Environment Not classified. Classification (1999/45/EEC) Xi;R36/38. R43. The Full Text for all R-Phrases and Hazard Statements are Displayed in Section 16. Human health The product is irritating to eyes and skin. Risk of sensitisation by skin contact Environment Not established. Product should not be released to ground or surface waters untreated Label elements Contains 2-PIPERAZIN-1-YLETHYLAMINE TETRAETHYLENEPENTAMINE TOFA REACTION PRODUCT WITH TEPA Label In Accordance With (EC) No. 1272/ / 8

2 Signal Word Hazard Statements Precautionary Statements Warning H315 H317 H319 P280 P264 Causes skin irritation. May cause an allergic skin reaction. Causes serious eye irritation. Wear protective gloves/protective clothing/eye protection/face protection. Wash contaminated skin thoroughly after handling. P IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P IF ON SKIN: Wash with plenty of soap and water. P Store in a dry place. Store in a closed container. P501 Supplementary Precautionary Statements 2.3. Other hazards P313 Dispose of contents/container in accordance with local regulations. Get medical advice/attention. SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS 3.2. Mixtures 2,4,6-TRIS(DIMETHYLAMINOMETHYL)PHENOL 1-5% CAS-No.: EC No.: Acute Tox. 4 - H302 Skin Irrit. 2 - H315 Eye Irrit. 2 - H319 Xn;R22 Xi;R36/38 2-PIPERAZIN-1-YLETHYLAMINE 1-5% CAS-No.: EC No.: Acute Tox. 4 - H302 Acute Tox. 4 - H312 Skin Corr. 1B - H314 Skin Sens. 1 - H317 Aquatic Chronic 3 - H412 C;R34 Xn;R21/22 R43 R52/53 BIS(DIMETHYLAMINOMETHYL)PHENOL 1-5% CAS-No.: EC No.: Skin Corr. 1B - H314 C;R34. TETRAETHYLENEPENTAMINE 1-5% CAS-No.: EC No.: Acute Tox. 4 - H302 Acute Tox. 4 - H312 Skin Corr. 1B - H314 Skin Sens. 1 - H317 Aquatic Chronic 2 - H411 C;R34 Xn;R21/22 R43 N;R51/53 2 / 8

3 TOFA REACTION PRODUCT WITH TEPA 30-60% CAS-No.: EC No.: Skin Sens. 1 - H317 R43. The Full Text for all R-Phrases and Hazard Statements are Displayed in Section 16. Composition Comments Amine curing agent SECTION 4: FIRST AID MEASURES 4.1. Description of first aid measures General information Remove affected person from source of contamination. Inhalation Move the exposed person to fresh air at once. Get medical attention if any discomfort continues. Ingestion Rinse mouth thoroughly. Drink plenty of water. Do not induce vomiting. Get medical attention immediately! Skin contact Remove contaminated clothing immediately and wash skin with soap and water. Get medical attention if irritation persists after washing. Eye contact Immediately rinse with water. Continue to rinse for at least 15 minutes and get medical attention Most important symptoms and effects, both acute and delayed General information The severity of the symptoms described will vary dependant of the concentration and the length of exposure. Inhalation This is unlikely to occur but symptoms similar to those of ingestion may develop. Ingestion May cause discomfort if swallowed. Skin contact Skin irritation. Mild dermatitis, allergic skin rash. Eye contact Irritating and may cause redness and pain Indication of any immediate medical attention and special treatment needed Treat Symptomatically. SECTION 5: FIREFIGHTING MEASURES 5.1. Extinguishing media Extinguishing media Extinguish with foam, carbon dioxide or dry powder. Do not use water jet as an extinguisher, as this will spread the fire. Unsuitable extinguishing media Do not use water jet as an extinguisher, as this will spread the fire Special hazards arising from the substance or mixture Hazardous combustion products In case of fire, toxic gases (CO, CO2, NOx) may be formed. Unusual Fire & Explosion Hazards No unusual fire or explosion hazards noted. Specific hazards Toxic gases/vapours/fumes of: Oxides of: Carbon. Nitrogen Advice for firefighters Special Fire Fighting Procedures No specific fire fighting procedure given. 3 / 8

4 Protective equipment for fire-fighters Self contained breathing apparatus and full protective clothing must be worn in case of fire. SECTION 6: ACCIDENTAL RELEASE MEASURES 6.1. Personal precautions, protective equipment and emergency procedures Avoid contact with skin and eyes. Provide adequate ventilation. Use protective gloves, goggles and suitable protective clothing Environmental precautions Do not allow to enter drains, sewers or watercourses. Avoid discharge onto the ground. Contain spillages with sand, earth or any suitable absorbent material Methods and material for containment and cleaning up Absorb with sand or other inert absorbent. Collect spillage in containers, seal securely and deliver for disposal as hazardous waste Reference to other sections For personal protection, see section 8. See section 11 for additional information on health hazards. For waste disposal, see section 13. SECTION 7: HANDLING AND STORAGE 7.1. Precautions for safe handling Avoid contact with skin and eyes. Provide good ventilation. Observe good chemical hygiene practices. Do not eat, drink or smoke when using the product Conditions for safe storage, including any incompatibilities Keep separate from food, feedstuffs, fertilisers and other sensitive material. Store in closed original container at temperatures between 5 C and 30 C. Store in a cool and well-ventilated place Specific end use(s) The identified uses for this product are detailed in Section 1.2. SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION 8.1. Control parameters 8.2. Exposure controls Process conditions Provide eyewash station. Engineering measures Provide adequate general and local exhaust ventilation. Respiratory equipment In case of inadequate ventilation use a respirator suitable for organic vapours. Consult respirator manufacturer for specific advice. Hand protection Protective gloves should be used if there is a risk of direct contact or splash. Nitrile gloves to BSEN374 are recommended. Break through times can vary depending on thickness, use and source. Change gloves regularly. Eye protection If there is a risk of splashing, wear chemical resistant goggles or visor approved to BS EN166. Other Protection Wear suitable protective clothing as protection against splashing or contamination. Hygiene measures Promptly remove any clothing that becomes contaminated. Wash promptly with soap & water if skin becomes contaminated. Wash contaminated clothing before reuse. Personal protection Always check applicability with your supplier of protective equipment. Skin protection Wear apron or protective clothing in case of splashes. Environmental Exposure Controls Residues and empty containers should be taken care of as hazardous waste according to local and national provisions. SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES 4 / 8

5 9.1. Information on basic physical and chemical properties Appearance Colour Odour Relative density ph-value, Conc. Solution Viscosity Flash point ( C) Viscous liquid. Blue. Amine degc N/A 250 approx 20 decc N/A 9.2. Other information None. Volatile By Vol. (%) N/A SECTION 10: STABILITY AND REACTIVITY Reactivity Reaction with: Acids. Strong alkalis. Strong oxidising substances Chemical stability Stable under normal temperature conditions Possibility of hazardous reactions Under normal conditions of storage and use, hazardous reactions will not occur. Hazardous Polymerisation Not relevant Conditions to avoid Considerable exothermic reaction can occur when mixed with epoxide resins Incompatible materials Materials To Avoid Strong acids. Strong alkalis. Strong oxidising substances Hazardous decomposition products During fire, toxic gases (CO, CO2, NOx) are formed. SECTION 11: TOXICOLOGICAL INFORMATION Information on toxicological effects General information No specific health warnings noted. Inhalation May cause some discomfort in poorly ventilated areas. Ingestion Irritating. May cause nausea, stomach pain and vomiting. Skin contact Prolonged or repeated exposure may cause severe irritation. May cause sensitisation by skin contact. Eye contact Irritating to eyes. Health Warnings Irritating to skin. Irritating to eyes. May cause sensitisation by skin contact. Route of entry Skin and/or eye contact. 5 / 8

6 Target Organs Eyes Skin Medical Symptoms Skin irritation. Irritation of eyes and mucous membranes. Medical Considerations Pre-existing eye problems. Skin disorders and allergies. Toxicological information on ingredients. TETRAETHYLENEPENTAMINE (CAS: ) 2-PIPERAZIN-1-YLETHYLAMINE (CAS: ) Acute toxicity: Acute Toxicity (Oral LD50) < 2140 mg/kg Rat Acute Toxicity (Dermal LD50) 880 mg/kg Rabbit BIS(DIMETHYLAMINOMETHYL)PHENOL (CAS: ) 2,4,6-TRIS(DIMETHYLAMINOMETHYL)PHENOL (CAS: ) Acute toxicity: Acute Toxicity (Oral LD50) 1670 mg/kg Rat Acute Toxicity (Dermal LD50) 1242 mg/kg Rabbit TOFA REACTION PRODUCT WITH TEPA (CAS: ) SECTION 12: ECOLOGICAL INFORMATION Ecotoxicity The product should not be allowed to enter drains, sewers or watercourses Toxicity Not available Acute Fish Toxicity Not measured. Do not allow to enter waterways or drains Ecological information on ingredients. 2-PIPERAZIN-1-YLETHYLAMINE (CAS: ) Acute Toxicity - Fish LC50 96 hours < 2460 mg/l Pimephales promelas (Fat-head Minnow) LC50 96 hours > 100 mg/l Onchorhynchus mykiss (Rainbow trout) Acute Toxicity - Aquatic Invertebrates EC50 48 hours < 58 mg/l Daphnia magna Acute Toxicity - Aquatic Plants EC50 72 hours < 1000 mg/l Selenastrum capricornutum 2,4,6-TRIS(DIMETHYLAMINOMETHYL)PHENOL (CAS: ) Acute Toxicity - Fish LC50 96 hours 718 mg/l Cyprinus carpio (Common carp) Persistence and degradability Degradability There are no data on the degradability of this product. Ecological information on ingredients. Degradability The product is not readily biodegradable. 2-PIPERAZIN-1-YLETHYLAMINE (CAS: ) 6 / 8

7 12.3. Bioaccumulative potential Bioaccumulative potential No data available on bioaccumulation. Ecological information on ingredients. Partition coefficient log Kow PIPERAZIN-1-YLETHYLAMINE (CAS: ) Mobility in soil Mobility: The product is non-volatile Results of PBT and vpvb assessment Not Classified as PBT/vPvB by current EU criteria Other adverse effects None known. SECTION 13: DISPOSAL CONSIDERATIONS Waste treatment methods Small quantities may be treated with an equivalent quantity of product resin, allowed to cure and disposed of as low hazard waste. Larger quantities should be disposed of as hazardous waste via a licensed waste operator. Product containers must not be re-used without commercial cleaning. Waste Class Hazardous Waste Codes: Product: * ; Contaminated empty container * SECTION 14: TRANSPORT INFORMATION General The product is not covered by international regulation on the transport of dangerous goods (IMDG, IATA, ADR/RID) UN number UN proper shipping name Transport hazard class(es) ADR/RID/ADN Class Transport Labels Not classified for transportation. No transport warning sign required Packing group Environmental hazards Environmentally Hazardous Substance/Marine Pollutant No Special precautions for user Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code 7 / 8

8 SECTION 15: REGULATORY INFORMATION Safety, health and environmental regulations/legislation specific for the substance or mixture Uk Regulatory References The Control of Substances Hazardous to Health Regulations 2002 (S.I 2002 No. 2677) with amendments. Environmental Listing No listing noted. Approved Code Of Practice Safety Data Sheets for Substances and Preparations. Guidance Notes Workplace Exposure Limits EH40. National Regulations Control of Substances Hazardous to Health Regulations 2002 (as amended) Authorisations (Title VII Regulation 1907/2006) No specific authorisations are noted for this product. Restrictions (Title VIII Regulation 1907/2006) No specific restrictions of use are noted for this product Chemical Safety Assessment No chemical safety assessment has been carried out. SECTION 16: OTHER INFORMATION General information F.Ball and Company Ltd Technical Datasheet. Information Sources Health and Safety Executive Guidance Note EH40 (amended annually). Workplace Exposure Limits. Revision Comments GHS version Revision Date 30/09/14 Revision 12 Supersedes date 17/01/13 Safety Data Sheet Status Approved. Risk Phrases In Full R34 Causes burns. R22 Harmful if swallowed. R21/22 Harmful in contact with skin and if swallowed. R52/53 Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment. R36/38 Irritating to eyes and skin. R43 May cause sensitisation by skin contact. R51/53 Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. Hazard Statements In Full H319 Causes serious eye irritation. H314 Causes severe skin burns and eye damage. H315 Causes skin irritation. H302 Harmful if swallowed. H312 Harmful in contact with skin. H412 Harmful to aquatic life with long lasting effects. H317 May cause an allergic skin reaction. H411 Toxic to aquatic life with long lasting effects. Disclaimer This information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process. Such information is, to the best of the company's knowledge and belief, accurate and reliable as of the date indicated. However, no warranty guarantee or representation is made to its accuracy, reliability or completeness. It is the user's responsibility to satisfy himself as to the suitability of such information for his own particular use. 8 / 8