SAFETY DATA SHEET CYCLO Pumice Citrus Lotion Hand Cleaner
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1 Revision Date March 2014 Supersedes date July 2012 SAFETY DATA SHEET CYCLO Pumice Citrus Lotion Hand Cleaner According to Regulation (EU) No 453/2010 SECTION 1: IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING 1.1. Product identifier Product name Product No. Synonyms, Trade Names CYCLO Pumice Citrus Lotion Hand Cleaner C178 C Relevant identified uses of the substance or mixture and uses advised against Identified uses Hand cleaner Details of the supplier of the safety data sheet Supplier Tri Continental Streliska 150/A 2000 Maribor, Slovenia E mail Address ehs@cyclo.com 1.4. Emergency telephone number SECTION 2: HAZARDS IDENTIFICATION 2.1. Classification of the substance or mixture Classification (EC 1272/2008) Classification (1999/45/EEC) Physical and Chemical Hazards Not classified. Human health Environment Xi;R36. Eye Irrit. 2 - H319 Not classified. The Full Text for all R-Phrases and Hazard Statements are Displayed in Section 16. Human health Splashes in the eyes may cause redness and irritation. The product contains a sensitising substance which may provoke an allergic reaction among sensitive individuals. Environment The product is not expected to be hazardous to the environment Label elements Label In Accordance With (EC) No. 1272/ / 20
2 Signal Word Hazard Statements Precautionary Statements Supplemental label information Warning H319 P102 P280 CYCLO Pumice Citrus Lotion Hand Cleaner Causes serious eye irritation. Keep out of reach of children. Wear eye and face protection. P IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P If eye irritation persists: Get medical advice/attention. EUH208 Contains ORANGE, SWEET, EXT.. May produce an allergic reaction Other hazards This product does not contain any PBT or vpvb substances. SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS 3.2. Mixtures PUMICE 5-10% CAS-No.: EC No.: Classification (EC 1272/2008) Eye Irrit. 2 - H319 STOT SE 3 - H335 Classification (67/548/EEC) Xi;R36/37. UNDECAN-1-OL, ETHOXYLATED 1-10% CAS-No.: EC No.: Classification (EC 1272/2008) Acute Tox. 4 - H302 Eye Dam. 1 - H318 Classification (67/548/EEC) Xn;R22. Xi;R41. 1, 2 -PROPANEDIOL 1-5% CAS-No.: EC No.: Classification (EC 1272/2008) Not classified. Classification (67/548/EEC) Not classified. GLYCEROL 1-5% CAS-No.: EC No.: Classification (EC 1272/2008) Not classified. Classification (67/548/EEC) Not classified. 2 / 20
3 TITANIUM DIOXIDE < 1% CAS-No.: EC No.: Substance with a Community workplace exposure limit. Classification (EC 1272/2008) Not classified. Classification (67/548/EEC) Not classified. ORANGE, SWEET, EXT. < 1% CAS-No.: EC No.: Classification (EC 1272/2008) Flam. Liq. 3 - H226 Skin Irrit. 2 - H315 Skin Sens. 1 - H317 Asp. Tox. 1 - H304 Aquatic Chronic 2 - H411 Classification (67/548/EEC) Xn;R65. Xi;R38. N;R51/53. R10,R43. POTASSIUM HYDROXIDE < 1% CAS-No.: EC No.: Classification (EC 1272/2008) Acute Tox. 4 - H302 Skin Corr. 1A - H314 Classification (67/548/EEC) C;R35 Xn;R22 The Full Text for all R-Phrases and Hazard Statements are Displayed in Section 16. SECTION 4: FIRST AID MEASURES 4.1. Description of first aid measures Inhalation Move the exposed person to fresh air at once. Rinse nose and mouth with water. Get medical attention if any discomfort continues. Ingestion NEVER MAKE AN UNCONSCIOUS PERSON VOMIT OR DRINK FLUIDS! Rinse mouth thoroughly. Get medical attention. Skin contact Remove affected person from source of contamination. Remove contaminated clothing. Wash the skin immediately with soap and water. Get medical attention if any discomfort continues. Eye contact Make sure to remove any contact lenses from the eyes before rinsing. Promptly wash eyes with plenty of water while lifting the eye lids. Continue to rinse for at least 15 minutes. Get medical attention if any discomfort continues Most important symptoms and effects, both acute and delayed General information The severity of the symptoms described will vary dependant of the concentration and the length of exposure. Inhalation No specific symptoms noted. Ingestion May cause stomach pain or vomiting. Skin contact May cause sensitisation by skin contact. The product contains a small amount of sensitising substance which may provoke an allergic reaction among sensitive individuals in contact with skin. Eye contact Irritation of eyes and mucous membranes. 3 / 20
4 4.3. Indication of any immediate medical attention and special treatment needed Treat Symptomatically. SECTION 5: FIREFIGHTING MEASURES 5.1. Extinguishing media Extinguishing media Fire can be extinguished using: Foam, carbon dioxide or dry powder. Dry chemicals, sand, dolomite etc. Water spray, fog or mist Special hazards arising from the substance or mixture Unusual Fire & Explosion Hazards No unusual fire or explosion hazards noted. Specific hazards In case of fire, toxic gases may be formed (COx, NOx) Advice for firefighters Special Fire Fighting Procedures Move container from fire area if it can be done without risk. Cool containers exposed to flames with water until well after the fire is out. Protective equipment for fire-fighters Self contained breathing apparatus and full protective clothing must be worn in case of fire. SECTION 6: ACCIDENTAL RELEASE MEASURES 6.1. Personal precautions, protective equipment and emergency procedures Wear protective clothing as described in Section 8 of this safety data sheet. In case of spills, beware of slippery floors and surfaces Environmental precautions Avoid discharge to the aquatic environment Methods and material for containment and cleaning up Stop leak if possible without risk. Absorb in vermiculite, dry sand or earth and place into containers. Collect spillage in containers, seal securely and deliver for disposal according to local regulations Reference to other sections Wear protective clothing as described in Section 8 of this safety data sheet. See section 11 for additional information on health hazards. SECTION 7: HANDLING AND STORAGE 7.1. Precautions for safe handling Avoid contact with eyes. Avoid eating, drinking and smoking when using the product. Persons susceptible to allergic reactions should not handle this product Conditions for safe storage, including any incompatibilities Store in tightly closed original container in a dry, cool and well-ventilated place. Protect from freezing and direct sunlight. Do not store near heat sources or expose to high temperatures Specific end use(s) The identified uses for this product are detailed in Section 1.2. SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION 8.1. Control parameters 4 / 20
5 Name STD TWA - 8 Hrs STEL - 15 Min Notes 1, 2 -PROPANEDIOL WEL 150 ppm 10 mg/m3 GLYCEROL WEL 10 mg/m3 POTASSIUM HYDROXIDE WEL 2 mg/m3 TITANIUM DIOXIDE WEL 10 mg/m3 WEL = Workplace Exposure Limit Exposure controls Engineering measures Provide adequate ventilation. Respiratory equipment No specific recommendation made, but respiratory protection may still be required under exceptional circumstances when excessive air contamination exists. Chemical respirator with organic vapour cartridge. Hand protection Hand protection not required. Eye protection If risk of splashing, wear safety goggles or face shield. Other Protection Wear suitable protective clothing as protection against splashing or contamination. Hygiene measures No specific hygiene procedures noted, but good personal hygiene practices are always advisable, especially when working with chemicals. When using do not eat, drink or smoke. SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES 9.1. Information on basic physical and chemical properties Appearance Emulsion. Colour White. Odour Citrus Solubility Soluble in water. Initial boiling point and boiling range ( C) Melting point ( C) Vapour density (air=1) Vapour pressure Evaporation rate ph-value, Conc. Solution 6.7 Viscosity Decomposition temperature ( C) Odour Threshold, Lower Odour Threshold, Upper Flash point ( C) 98.9 C PM Closed cup. Auto Ignition Temperature ( C) 5 / 20
6 Flammability Limit - Lower(%) Flammability Limit - Upper(%) Partition Coefficient (N-Octanol/Water) Explosive properties Oxidising properties 9.2. Other information CYCLO Pumice Citrus Lotion Hand Cleaner SECTION 10: STABILITY AND REACTIVITY Reactivity No specific reactivity hazards associated with this product Chemical stability Stable under normal temperature conditions and recommended use Possibility of hazardous reactions Not applicable Conditions to avoid There are no known conditions that are likely to result in a hazardous situation Incompatible materials Materials To Avoid No incompatible groups noted Hazardous decomposition products Thermal decomposition or combustion may liberate carbon oxides and other toxic gases or vapours. SECTION 11: TOXICOLOGICAL INFORMATION Information on toxicological effects Acute toxicity: Acute Toxicity (Oral LD50) Acute Toxicity (Dermal LD50) Acute Toxicity (Inhalation LC50) Skin Corrosion/Irritation: Serious eye damage/irritation: Irritating to eyes. 6 / 20
7 Respiratory or skin sensitisation: Respiratory sensitisation Skin sensitisation Germ cell mutagenicity: Genotoxicity - In Vitro Genotoxicity - In Vivo Carcinogenicity: Reproductive Toxicity: Reproductive Toxicity - Fertility Reproductive Toxicity - Development Specific target organ toxicity - single exposure: Not classified as a specific target organ toxicant after a single exposure. Specific target organ toxicity - repeated exposure: Not classified as a specific target organ toxicant after repeated exposure. Aspiration hazard: Inhalation In high concentrations, vapours may irritate throat and respiratory system and cause coughing. Ingestion May cause discomfort if swallowed. May cause stomach pain or vomiting. Skin contact May cause sensitisation by skin contact. The product contains a small amount of sensitising substance which may provoke an allergic reaction among sensitive individuals after repeated contact. Eye contact Splashes may irritate. Route of entry Skin and/or eye contact. Inhalation. Toxicological information on ingredients. 7 / 20
8 1, 2 -PROPANEDIOL (CAS: ) Acute toxicity: Acute Toxicity (Oral LD50) mg/kg Rat Acute Toxicity (Dermal LD50) > 2000 mg/kg Rabbit Acute Toxicity (Inhalation LC50) > mg/m³ air Rabbit 2 hours Skin Corrosion/Irritation: Dose 0.5 ml 4 hr Rabbit Primary dermal irritation index (PDI) 0 Serious eye damage/irritation: Respiratory or skin sensitisation: Respiratory sensitisation Data lacking. Skin sensitisation Guinea pig maximization test (GPMT): Guinea Pig Germ cell mutagenicity: Genotoxicity - In Vitro Chromosome aberration: Negative. Carcinogenicity: Carcinogenicity NOAEL 1700 mg/kg/day Oral Rat Reproductive Toxicity: Reproductive Toxicity - Fertility NOAEL mg/kg/day Oral Mouse P Reproductive Toxicity - Development Developmental toxicity: NOAEL mg/kg/day Oral Mouse 8 / 20
9 CYCLO Pumice Citrus Lotion Hand Cleaner Specific target organ toxicity - single exposure: Not classified as a specific target organ toxicant after a single exposure. Specific target organ toxicity - repeated exposure: Not classified as a specific target organ toxicant after repeated exposure. Aspiration hazard: 9 / 20
10 GLYCEROL (CAS: ) Acute toxicity: Acute Toxicity (Oral LD50) mg/kg Mouse Acute Toxicity (Dermal LD50) mg/kg Guinea Pig Acute Toxicity (Inhalation LC50) 4655 mg/l air Rat 7 hours Skin Corrosion/Irritation: Dose 0.5 ml 24 hr Rabbit Primary dermal irritation index (PDI) < 2 Serious eye damage/irritation: Respiratory or skin sensitisation: Respiratory sensitisation Data lacking. Skin sensitisation Data lacking. Germ cell mutagenicity: Genotoxicity - In Vitro DNA damage and/or repair: Negative. Carcinogenicity: This substance has no evidence of carcinogenic properties. Reproductive Toxicity: Reproductive Toxicity - Fertility Two-generation study: NOEC 2000 mg/kg/day Oral Rat P Reproductive Toxicity - Development Maternal toxicity: NOAEL 1310 mg/kg/day Oral Rat Specific target organ toxicity - single exposure: Not classified as a specific target organ toxicant after a single exposure. 10 / 20
11 Specific target organ toxicity - repeated exposure: Not classified as a specific target organ toxicant after repeated exposure. Aspiration hazard: 11 / 20
12 TITANIUM DIOXIDE (CAS: ) Acute toxicity: Acute Toxicity (Oral LD50) > 5000 ml/kg bw Rat Conclusive data but not sufficient for classification. Acute Toxicity (Dermal LD50) Acute Toxicity (Inhalation LC50) > 6.82 mg/l air Rat 4 hours Conclusive data but not sufficient for classification. Skin Corrosion/Irritation: Dose 0.5g 4 hr Rabbit Erythema\eschar score Very slight erythema -barely perceptible (1). Oedema score No oedema (0). Not irritating. Serious eye damage/irritation: Respiratory or skin sensitisation: Skin sensitisation Guinea pig maximization test (GPMT): Guinea Pig Not Sensitising. Germ cell mutagenicity: Genotoxicity - In Vitro Chromosome aberration: Negative. This substance has no evidence of mutagenic properties. Genotoxicity - In Vivo Chromosome aberration: Negative. This substance has no evidence of mutagenic properties. Carcinogenicity: Carcinogenicity NOAEC 5 mg/m ³ air Inhalation. Rat Conclusive data but not sufficient for classification. NTP - Carcinogenicity Reasonably anticipated human carcinogen. Reproductive Toxicity: Reproductive Toxicity - Fertility 12 / 20
13 CYCLO Pumice Citrus Lotion Hand Cleaner Specific target organ toxicity - single exposure: STOT - Single exposure Not applicable. Specific target organ toxicity - repeated exposure: STOT - Repeated exposure NOAEL mg/l/6hr/day Oral Not classified as a specific target organ toxicant after repeated exposure. Aspiration hazard: Not relevant, due to the form of the product. UNDECAN-1-OL, ETHOXYLATED (CAS: ) Toxicological information 13 / 20
14 ORANGE, SWEET, EXT. (CAS: ) Acute toxicity: Acute Toxicity (Oral LD50) > 5000 mg/kg Rat Acute Toxicity (Dermal LD50) > 5000 mg/kg Rabbit Acute Toxicity (Inhalation LC50) Data lacking. Skin Corrosion/Irritation: Dose 0.5 ml 4 hr Rabbit Erythema\eschar score Well defined erythema (2). Oedema score Slight oedema - edges of area well defined by definite raising (2). Irritating to skin. Serious eye damage/irritation: Respiratory or skin sensitisation: Respiratory sensitisation Data lacking. Skin sensitisation Local Lymph Node Assay (LLNA) Mouse May cause sensitisation by skin contact. Germ cell mutagenicity: Genotoxicity - In Vitro Gene Mutation: Negative. Carcinogenicity: Carcinogenicity NOAEL 150 mg/kg/day Oral Rat Reproductive Toxicity: Reproductive Toxicity - Fertility Data lacking. Specific target organ toxicity - single exposure: Not classified as a specific target organ toxicant after a single exposure. Specific target organ toxicity - repeated exposure: 14 / 20
15 Not classified as a specific target organ toxicant after repeated exposure. Aspiration hazard: Viscosity Kinematic viscosity <= 20.5 mm2/s. Harmful: may cause lung damage if swallowed. Toxicological information PUMICE (CAS: ) SECTION 12: ECOLOGICAL INFORMATION Ecotoxicity The product is not expected to be hazardous to the environment Toxicity Acute Fish Toxicity Not considered toxic to fish. 15 / 20
16 Ecological information on ingredients. CYCLO Pumice Citrus Lotion Hand Cleaner 1, 2 -PROPANEDIOL (CAS: ) The product is not expected to be toxic to aquatic organisms. Acute Toxicity - Fish LC50 96 hours mg/l Onchorhynchus mykiss (Rainbow trout) Acute Toxicity - Aquatic Invertebrates EC50 96 hours mg/l Mysidopsis bahia Acute Toxicity - Aquatic Plants EC50 72 hours mg/l Selenastrum capricornutum GLYCEROL (CAS: ) The product is not expected to be toxic to aquatic organisms. Acute Toxicity - Fish LC50 96 hours mg/l Onchorhynchus mykiss (Rainbow trout) Acute Toxicity - Aquatic Invertebrates LC50 48 hours 1955 mg/l Daphnia magna TITANIUM DIOXIDE (CAS: ) The product is not expected to be toxic to aquatic organisms. Acute Toxicity - Fish Acute Toxicity - Aquatic Invertebrates Acute Toxicity - Aquatic Plants EC50 72 hours 61 mg/l Freshwater plants UNDECAN-1-OL, ETHOXYLATED (CAS: ) There are no data on the ecotoxicity of this product. ORANGE, SWEET, EXT. (CAS: ) Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. Acute Toxicity - Fish 5.65 mg/l Brachydanio rerio (Zebra Fish) Acute Toxicity - Aquatic Invertebrates EL50 48 hours 1.1 mg/l Daphnia magna Acute Toxicity - Aquatic Plants EL50 72 hours 150 mg/l Freshwater algae PUMICE (CAS: ) There are no data on the ecotoxicity of this product Persistence and degradability Degradability There are no data on the degradability of this product. 16 / 20
17 Ecological information on ingredients. CYCLO Pumice Citrus Lotion Hand Cleaner 1, 2 -PROPANEDIOL (CAS: ) Phototransformation Air. DT days Biodegradation Water Degradation (81.7%) 28 days The substance is readily biodegradable. GLYCEROL (CAS: ) Biodegradation Water Degradation (94%) 24 hours The substance is readily biodegradable. TITANIUM DIOXIDE (CAS: ) Degradability There are no data on the degradability of this product. UNDECAN-1-OL, ETHOXYLATED (CAS: ) Degradability There are no data on the degradability of this product. ORANGE, SWEET, EXT. (CAS: ) Degradability There are no data on the degradability of this product. PUMICE (CAS: ) Degradability There are no data on the degradability of this product Bioaccumulative potential Bioaccumulative potential No data available on bioaccumulation. Partition coefficient Ecological information on ingredients. Bioaccumulative potential Will not bio-accumulate. Bioaccumulation factor BCF ~ 0.09 Bioaccumulative potential No data available on bioaccumulation. Bioaccumulative potential No data available on bioaccumulation. Bioaccumulative potential No data available on bioaccumulation. Bioaccumulative potential No data available on bioaccumulation. Bioaccumulative potential No data available on bioaccumulation. 1, 2 -PROPANEDIOL (CAS: ) GLYCEROL (CAS: ) TITANIUM DIOXIDE (CAS: ) UNDECAN-1-OL, ETHOXYLATED (CAS: ) ORANGE, SWEET, EXT. (CAS: ) PUMICE (CAS: ) 17 / 20
18 12.4. Mobility in soil Mobility: The product is soluble in water. Ecological information on ingredients. 1, 2 -PROPANEDIOL (CAS: ) Mobility: The product is miscible with water. May spread in water systems. Adsorption/Desorption Coefficient Soil log Koc ~ 0.46 Henry's Law Constant Pa 12 C GLYCEROL (CAS: ) Mobility: The product is miscible with water. May spread in water systems. Henry's Law Constant atm 25 C TITANIUM DIOXIDE (CAS: ) Mobility: The product is insoluble in water. UNDECAN-1-OL, ETHOXYLATED (CAS: ) Mobility: ORANGE, SWEET, EXT. (CAS: ) Mobility: The product is partly soluble in water. May spread in the aquatic environment. PUMICE (CAS: ) Mobility: Results of PBT and vpvb assessment This product does not contain any PBT or vpvb substances. Ecological information on ingredients. 1, 2 -PROPANEDIOL (CAS: ) Not Classified as PBT/vPvB by current EU criteria. GLYCEROL (CAS: ) Not Classified as PBT/vPvB by current EU criteria. TITANIUM DIOXIDE (CAS: ) Not Classified as PBT/vPvB by current EU criteria. UNDECAN-1-OL, ETHOXYLATED (CAS: ) Not Classified as PBT/vPvB by current EU criteria. ORANGE, SWEET, EXT. (CAS: ) Not Classified as PBT/vPvB by current EU criteria. PUMICE (CAS: ) Not Classified as PBT/vPvB by current EU criteria Other adverse effects None known. SECTION 13: DISPOSAL CONSIDERATIONS 18 / 20
19 General information CYCLO Pumice Citrus Lotion Hand Cleaner Waste to be treated as controlled waste. Disposal to licensed waste disposal site in accordance with local Waste Disposal Authority Waste treatment methods Recover and reclaim or recycle, if practical. Do not allow runoff to sewer, waterway or ground. Dispose of waste and residues in accordance with local authority requirements. SECTION 14: TRANSPORT INFORMATION General The product is not covered by international regulation on the transport of dangerous goods (IMDG, IATA, ADR/RID) UN number Not applicable UN proper shipping name Not applicable Transport hazard class(es) Not applicable. Transport Labels No transport warning sign required Packing group Environmental hazards Environmentally Hazardous Substance/Marine Pollutant No Special precautions for user Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code No information required. Not relevant SECTION 15: REGULATORY INFORMATION Safety, health and environmental regulations/legislation specific for the substance or mixture EU Legislation Regulation (EC) No 1907/2006 of the European Parliament and of the Council of 18 December 2006 concerning the Registration, Evaluation, Authorisation and Restriction of Chemicals (REACH), establishing a European Chemicals Agency, amending Directive 1999/45/EC and repealing Council Regulation (EEC) No 793/93 and Commission Regulation (EC) No 1488/94 as well as Council Directive 76/769/EEC and Commission Directives 91/155/EEC, 93/67/EEC, 93/105/EC and 2000/21/EC, including amendments. Regulation (EC) No 1272/2008 of the European Parliament and of the Council of 16 December 2008 on classification, labelling and packaging of substances and mixtures, amending and repealing Directives 67/548/EEC and 1999/45/EC, and amending Regulation (EC) No 1907/2006 with amendments. National Regulations The Chemicals (Hazard Information and Packaging for Supply) Regulations No Workplace Exposure Limits 2005 (EH40) Chemical Safety Assessment No chemical safety assessment has been carried out. 19 / 20
20 SECTION 16: OTHER INFORMATION Revision Date March 2014 Supersedes date July 2012 Risk Phrases In Full R35 Causes severe burns. R10 Flammable. R22 Harmful if swallowed. R65 Harmful: may cause lung damage if swallowed. R36/37 Irritating to eyes and respiratory system. R36 Irritating to eyes. R38 Irritating to skin. R43 May cause sensitisation by skin contact. NC Not classified. R41 Risk of serious damage to eyes. R51/53 Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. Hazard Statements In Full H226 Flammable liquid and vapour. H302 Harmful if swallowed. H304 May be fatal if swallowed and enters airways. H314 Causes severe skin burns and eye damage. H315 Causes skin irritation. H317 May cause an allergic skin reaction. H318 Causes serious eye damage. H319 Causes serious eye irritation. H335 May cause respiratory irritation. H411 Toxic to aquatic life with long lasting effects. Disclaimer Cyclo Industries Inc provides the information contained herein in good faith but makes no representation as to its comprehensiveness or accuracy. Individuals receiving this information must exercise their independent judgment in determining its appropriateness for a particular purpose. Cyclo Industries Inc. makes no representations or warranties either expressed or implied, of merchantability, fitness for a particular purpose with respect to the information set forth herein or to the product to which the information refers. Accordingly, Cyclo Industries Inc. will not be reponsible for damages resulting from use of or reliance upon this information. 20 / 20
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