Buffered Ammonium Persulfate

Transcription

1 SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier Trade name or designation of the mixture Product application GE Analytical Instruments part number APF 90150XX, APF 90300XX GE Analytical Instruments kit number Date of first issue Version number Revision date Supersedes date 26/10/ /05/ /02/2014 Product name Buffered Ammonium Persulfate 1.2. Relevant identified uses of the substance or mixture and uses advised against Analytical reagent. Identified uses Uses advised against ne known Details of the supplier of the safety data sheet GE Analytical Instruments Inc 6060 Spine Road Boulder, CO 0301 T emea.productstewardship@ge.com GE Water & Process Technologies Hungary Kft. 200 Tatabánya, Vigadó utca 2011 hrsz. Hungary Tel: oro.ehs@ge.com 1.4. Emergency telephone number INFOTRAC (rth America) Outside of N.A., call collect: GE (00) National Poisons Information Centre NHS Direct on SECTION 2: Hazards identification 2.1. Classification of the substance or mixture Classification according to Regulation (EC) 1272/200 as amended Physical hazards Corrosive to metals Health hazards Skin corrosion/irritation Serious eye damage/eye irritation Respiratory sensitisation Skin sensitisation Category 1 Category 2 Category 2 Category 1 Category 1 H290 May be corrosive to metals. H315 Causes skin irritation. H319 Causes serious eye irritation. H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled. H317 May cause an allergic skin reaction Label elements Page: 1 / 9

2 Label according to Regulation (EC). 1272/200 as amended Contains: Ammonium persulphate, Disodium phosphate(sodium phosphate, dibasic), SODIUM PHOSPHATE, MONOBASIC, Water Hazard pictograms Signal word Hazard statements H290 H315 H317 H319 H334 Precautionary statements Prevention Response P302 + P352 P304 + P340 P305 + P351 + P33 P342 + P311 Storage P406 Disposal P501 Supplemental label information 2.3. Other hazards Danger May be corrosive to metals. Causes skin irritation. May cause an allergic skin reaction. Causes serious eye irritation. May cause allergy or asthma symptoms or breathing difficulties if inhaled. IF ON SKIN: Wash with plenty of water. IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If experiencing respiratory symptoms: Call a POISON CENTER/doctor. Store in corrosive resistant container with a resistant inner liner. Dispose of contents/container in accordance with local/regional/national/international regulations. ne. ne known. SECTION 3: Composition/information on ingredients Mixtures Chemical description Aqueous solution of inorganic salts Chemical name % CAS. / EC. REACH Registration. INDEX. tes Water 0, Classification: Ammonium persulphate Classification: Acute Tox. 4;H302, Skin Irrit. 2;H315, Skin Sens. 1;H317, Eye Irrit. 2;H319, Resp. Sens. 1;H334, STOT SE 3;H335 Disodium phosphate(sodium phosphate, dibasic) 2, Classification: SODIUM PHOSPHATE, MONOBASIC 1, Classification: Material name: Page: 2 / 9

3 The classification of the above substance(s) is given, including the hazard class, category code and hazard statements which are assigned in accordance with their physicochemical, health and environmental hazards. Please refer to section 16 where the full text of each relevant Hstatement is listed. SECTION 4: First aid measures 4.1. Description of first aid measures Inhalation Remove victim to fresh air and keep at rest in a position comfortable for breathing. Call a POISON CENTRE or doctor/physician if you feel unwell. Skin contact Eye contact Ingestion 4.2. Most important symptoms and effects, both acute and delayed 4.3. Indication of any immediate medical attention and special treatment needed SECTION 5: Firefighting measures 5.1. Extinguishing media Suitable extinguishing media Unsuitable extinguishing media 5.2. Special hazards arising from the substance or mixture 5.3. Advice for firefighters Special protective equipment for firefighters Special fire fighting procedures Remove contaminated clothing immediately and wash skin with soap and water. Get medical attention if irritation develops and persists. Immediately flush eye(s) with plenty of water. Get medical attention if irritation develops and persists. Rinse mouth. Do not induce vomiting. Do not give anything to eat or drink. Get medical attention if symptoms occur. Sensitisation. Irritant effects. Dry chemical, CO2, water spray or regular foam. ne. SECTION 6: Accidental release measures Oxides of carbon, nitrogen, phosphorus, and sulphur evolved in fire. Self contained breathing apparatus. (CEN : EN 137) Protective clothing (CEN : EN 469) Protective gloves (CEN : EN 659) Helmet (CEN : EN 443) Use standard firefighting procedures and consider the hazards of other involved materials. Prevent spillage and firefighting water from entering in public sewers or the immediate environment Personal precautions, protective equipment and emergency procedures For nonemergency Wear protective clothing, gloves and safety goggles. personnel For emergency responders 6.2. Environmental precautions 6.3. Methods and material for containment and cleaning up 6.4. Reference to other sections SECTION 7: Handling and storage 7.1. Precautions for safe handling 7.2. Conditions for safe storage, including any incompatibilities 7.3. Specific end use(s) Use personal protection recommended in Section of the SDS. Prevent from entering sewers or the immediate environment. Accidental release of large quantities into the aquatic environment may harm aquatic organisms. Spills of the product are very slippery. Remove small spills with plenty of water. Please refer also to section no. 'Exposure controls' for further information. Ensure good ventilation. Handle in accordance with good industrial hygiene and safety procedures. Wash contaminated skin promptly. Store in a closed container away from incompatible materials. Store in cool, well ventilated area. Store containers closed when not in use. Only for professional and industrial s Material name: Page: 3 / 9

4 SECTION : Exposure controls/personal protection.1. Control parameters Occupational exposure limits Biological limit values Recommended monitoring procedures Derived noeffect level (DNEL) exposure limits noted for ingredient(s). biological exposure limits noted for the ingredient(s). Predicted no effect concentrations (PNECs).2. Exposure controls Appropriate engineering controls Adequate ventilation to maintain air contaminants below exposure limits. Individual protection measures, such as personal protective equipment Eye/face protection Safety goggles. CEN : EN 166 Skin protection Hand protection Other Respiratory protection Thermal hazards Environmental exposure controls Neoprene gloves (Protection against unintentional shortterm contact) CEN : EN 3741/2/3/4; EN 420 Protective clothing. CEN : EN ISO 136; EN ISO 6529; EN In case of insufficient ventilation, use a breathing mask with filter type: B2P2 CEN : EN 140; EN 1437 SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties Appearance Colour Odour Physical state Odour threshold Prevent from entering in public sewers or the immediate environment. Colorless Liquid ne ph (concentrated product) 6,5 Melting point/freezing point 1 C Initial boiling point and boiling range Flash point 100 C > 100 C PM(CC) Evaporation rate < 1 (Ether = 1) Flammability (solid, gas) t applicable. Upper/lower flammability or explosive limits Flammability limit lower (%) Flammability limit upper (%) Vapour pressure 11 mm Hg Vapour density 1 (Air = 1) Relative density 1,09 Relative density temperature 21 C Solubility Solubility (water) 100 % Material name: Page: 4 / 9

5 Partition coefficient (noctanol/water) Autoignition temperature Decomposition temperature Viscosity Viscosity temperature 21 C Explosive properties Oxidising properties 9.2. Other information Percent volatile t applicable. t applicable. 1 (Estimated) SECTION 10: Stability and reactivity Reactivity Chemical stability Possibility of hazardous reactions Conditions to avoid Incompatible materials Hazardous decomposition products SECTION 11: Toxicological information Information on toxicological effects Material is stable under normal conditions. Hazardous polymerisation does not occur. special requirement. Avoid contact with strong reducing agents. Oxides of carbon, nitrogen, phosphorus, and sulphur evolved in fire. Product (Mixture) Components Disodium phosphate(sodium phosphate, dibasic) (755794) Ammonium persulphate ( ) Test results Acute Dermal LD50 Rabbit: > 5000 mg/kg (Calculated according to GHS additivity formula) Acute Inhalation LC50 Rat: > 5 mg/l 4 Hours (Calculated according to GHS additivity formula) Acute Oral LD50 Rat: 4667 mg/kg (Calculated according to GHS additivity formula) Test results Acute Dermal LD50 Rat: > 5000 mg/kg Acute Oral LD50 Rat: > 5000 mg/kg Acute Dermal LD50 Rabbit: > 2000 mg/kg Acute Inhalation LC50 Rat: > 5,1 mg/l 4 Hours Acute Oral LD50 Rat: 700 mg/kg Acute toxicity Skin corrosion/irritation Serious eye damage/irritation Respiratory or skin sensitisation Specific target organ toxicity repeated exposure Specific target organ toxicity single exposure Carcinogenicity Germ cell mutagenicity Reproductive toxicity Causes skin irritation. Causes serious eye irritation. May cause allergy or asthma symptoms or breathing difficulties if inhaled. May cause an allergic skin reaction. Material name: Page: 5 / 9

6 Information on likely routes of exposure Ingestion May cause irritation of the gastrointestinal tract. Inhalation Skin contact Eye contact Symptoms Aspiration hazard Mixture versus substance information Other information May cause allergy or asthma symptoms or breathing difficulties if inhaled. May cause an allergic skin reaction. Causes skin irritation. Causes serious eye irritation. ne known. SECTION 12: Ecological information Toxicity toxicity data noted for the ingredient(s) Persistence and degradability Bioaccumulative potential Partition coefficient noctanol/water (log Kow) Bioconcentration factor (BCF) Mobility in soil Results of PBT and vpvb assessment data available Other adverse effects SECTION 13: Disposal considerations Waste treatment methods Contaminated packaging t a PBT or vpvb substance or mixture. According to Hazardous Waste Regulations. Disposal methods/information EWC ( European Waste Code ) recommendation : Waste packaging; absorbents, wiping cloths, filter materials and protective clothing not otherwise specified Packaging (including separately collected municipal packaging waste) Packaging containing residues of or contaminated by dangerous substances. Depending on the origin and state of the waste, other EWC numbers may be applicable too. According to Hazardous Waste Regulations. SECTION 14: Transport information EWC ( European Waste Code ) recommendation : Wastes not otherwise specified in the list Offspecification batches and unused products Inorganic wastes containing dangerous substances. Depending on the origin and state of the waste, other EWC numbers may be applicable too. ADR UN proper shipping name Corrosive liquid, n.o.s. (15% Ammonium persulphate and Water) Transport hazard Subsidiary Environmental hazards Tunnel restriction code (E) Material name: Page: 6 / 9

7 RID UN proper shipping name Transport hazard Subsidiary Environmental hazards ADN UN proper shipping name Transport hazard Subsidiary Environmental hazards IATA UN proper shipping name Transport hazard Subsidiary Environmental hazards ERG Code IMDG UN proper shipping name Transport hazard Subsidiary Environmental hazards Marine pollutant EmS Transport in bulk according to Annex II of MARPOL and the IBC Code Corrosive liquid, n.o.s. (15% Ammonium persulphate and Water) Corrosive liquid, n.o.s. (15% Ammonium persulphate and Water) Corrosive liquid, n.o.s. (15% Ammonium persulphate and Water) Corrosive liquid, n.o.s. (15% Ammonium persulphate and Water) FA, SB This substance/mixture is not intended to be transported in bulk. Material name: Page: 7 / 9

8 ADN; ADR; IATA; IMDG; RID SECTION 15: Regulatory information Safety, health and environmental regulations/legislation specific for the substance or mixture EU regulations Regulation (EC). 1005/2009 on substances that deplete the ozone layer, Annex I and II, as amended Regulation (EC). 50/2004 On persistent organic pollutants, Annex I as amended Regulation (EU). 649/2012 concerning the export and import of dangerous chemicals, Annex I, Part 1 as amended Regulation (EU). 649/2012 concerning the export and import of dangerous chemicals, Annex I, Part 2 as amended Regulation (EU). 649/2012 concerning the export and import of dangerous chemicals, Annex I, Part 3 as amended Regulation (EU). 649/2012 concerning the export and import of dangerous chemicals, Annex V as amended Regulation (EC). 166/2006 Annex II Pollutant Release and Transfer Registry Regulation (EC). 1907/2006, REACH Article 59(10) Candidate List as currently published by ECHA Authorisations Regulation (EC). 143/2011 Annex XIV Substances Subject to Authorisation Restrictions on use Regulation (EC). 1907/2006, REACH Annex XVII Substances subject to restriction on marketing and use as amended Directive 2004/37/EC: on the protection of workers from the risks related to exposure to carcinogens and mutagens at work Directive 92/5/EEC: on the safety and health of pregnant workers and workers who have recently given birth or are breastfeeding t regulated. Other EU regulations Directive 2012/1/EU on major accident hazards involving dangerous substances Ammonium persulphate (CAS ) Directive 9/24/EC on the protection of the health and safety of workers from the risks related to chemical agents at work Ammonium persulphate (CAS ) Directive 94/33/EC on the protection of young people at work Ammonium persulphate (CAS ) National regulations Chemical safety assessment Material name: Page: / 9

9 Inventory status Country(s) or region Inventory name On inventory (yes/no)* Europe European Inventory of Existing Commercial Chemical Substances Yes (EINECS) Europe European List of tified Chemical Substances (ELINCS) *A "Yes" indicates that all components of this product comply with the inventory requirements administered by the governing country(s) A "" indicates that one or more components of the product are not listed or exempt from listing on the inventory administered by the governing country(s). SECTION 16: Other information List of abbreviations References Information on evaluation method leading to the classification of mixture Full text of any Hstatements not written out in full under Sections 2 to 15 Revision information Training information Based on EC Directive / Regulations Further information COD: Chemical Oxygen Demand EC: European Commission Number IATA: International Air Transport Association CAS: Chemical Abstract Service. CLP: Classification, Labeling and Packaging REGULATION (EC) 1272/200 on classification, labeling and packaging of substances and mixtures. CEN: European Committee for Standardization (Comité Européen de rmalisation). TWA: Time Weighted Average. STEL: Shortterm Exposure Limit. LD50: Lethal Dose 50%. LC50: Lethal Concentration 50%. EC50: Effective Concentration 50%. NOEL: observed effect level. BOD: Biochemical oxygen demand. TOC: Total Organic Carbon. ADR: European agreement concerning the international carriage of dangerous goods by road (Accord européen relatif transport des merchandises dangereuses par route). ADN: European Agreement concerning the International Carriage of Dangerous Goods by Inland Waterways (Accord européen relatif au transport international des marchandises dangereuses par voies de navigation intérieures). IMDG Code: International Maritime Dangerous Goods Code. RID: Regulations concerning the international carriage of dangerous goods by rail (Règlement International concernant le transport de marchandises dangereuses par chemin de fer). Safety data sheets of raw materials. The physical, health and environmental hazards of this mixture are assessed by applying the classification criteria for each hazard class or differentiation in Parts 2 to 5 of Annex I to Regulation (EC) 1272/200 (CLP). H302 Harmful if swallowed. H315 Causes skin irritation. H317 May cause an allergic skin reaction. H319 Causes serious eye irritation. H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled. H335 May cause respiratory irritation. This document has undergone significant changes and should be reviewed in its entirety. Provide training on safe handling while considering the type of application and exposure scenarios. (EC) 1907/2006 (REACH) (EC) 1272/200 (EU) 1357/2014 (EU) 2015/30 Correction in Section: 2,3,4,11,16 Material name: Page: 9 / 9