SECTION 1: Identification of the substance/mixture and of the company/undertaking

Transcription

1 SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier Trade name or designation of the mixture Version number 5.2 Revision date 09/09/2014 Supersedes date 16/12/ Relevant identified uses of the substance or mixture and uses advised against Identified uses Membrane Deposit Control Agent Uses advised against None known Details of the supplier of the safety data sheet Lenntech bv Rotterdamseweg 402m 2629HH Delft the Netherlands Tel , Emergency telephone number Multilingual emergency number (24/7) Europe, Middle East, Africa, Israel (Europe and English language speaking countries): +44(0) Middle East & Africa (speaking Arabic): +44(0) National Poisons Information Centre (NVIC) Open 24 h / day Only for the purpose of informing medical personnel in cases of acute intoxications. SECTION 2: Hazards identification 2.1. Classification of the substance or mixture Classification according to Directive 67/548/EEC or 1999/45/EC as amended Hazard summary Physical hazards Health hazards Environmental hazards Not classified for physical hazards. Not classified for health hazards. Not classified for hazards to the environment. Classification according to Regulation (EC) No 1272/2008 as amended This mixture does not meet the criteria for classification according to Regulation (EC) 1272/2008 as amended Label elements Label according to Regulation (EC) No. 1272/2008 as amended None. Hazard pictograms Signal word Hazard statements None. The product does not need to be labelled in accordance with EC directives or respective national laws. Page: 1 / 8

2 Precautionary statements Prevention Response Storage Disposal Supplemental label information 2.3. Other hazards None known. EUH210 - Safety data sheet available on request. EUH208 - Contains Mixture of: 5-chloro-2-methyl-4-isothiazolin-3-one [EC no ] and 2-methyl-4-isothiazolin-3-one [EC no ] (3:1). May produce an allergic reaction. SECTION 3: Composition/information on ingredients Mixtures Chemical description Aqueous acidic solution of phosphonates and polymer Chemical name % CAS-No. / EC No. REACH Registration No. INDEX No. Notes Mixture of: 5-chloro-2-methyl-4-isothiazolin-3-one [EC no ] and 2-methyl-4-isothiazolin-3-one [EC no ] (3:1) < 0, M=10 - Classification: DSD: CLP: T;R23/24/25, C;R34, R43, N;R50/53 Acute Tox. 3;H301, Acute Tox. 2;H310, Skin Corr. 1B;H314, Skin Sens. 1;H317, Acute Tox. 2;H330, Aquatic Acute 1;H400, Aquatic Chronic 1;H410 SECTION 4: First aid measures 4.1. Description of first aid measures Inhalation Remove to fresh air. Skin contact Eye contact Ingestion 4.2. Most important symptoms and effects, both acute and delayed 4.3. Indication of any immediate medical attention and special treatment needed SECTION 5: Firefighting measures Wash with water. Flush immediately with plenty of running water. Rinse mouth with water Extinguishing media Suitable extinguishing media Carbon dioxide, dry chemicals, foam, water spray (fog). Unsuitable extinguishing media 5.2. Special hazards arising from the substance or mixture 5.3. Advice for firefighters Special protective equipment for firefighters Special fire fighting procedures Material name: None. Oxides of carbon, nitrogen, phosphorus, and sulphur evolved in fire. Self contained breathing apparatus. (CEN : EN 137) Protective clothing (CEN : EN 469) Protective gloves (CEN : EN 659) Helmet (CEN : EN 443) Use standard firefighting procedures and consider the hazards of other involved materials. Prevent spillage and fire-fighting water from entering in public sewers or the immediate environment. Page: 2 / 8

3 SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures For non-emergency Protective clothing personnel For emergency responders Use personal protection recommended in Section 8 of the SDS Environmental precautions Prevent from entering sewers or the immediate environment. Accidental release of large quantities into the aquatic environment may harm aquatic organisms Methods and material for containment and cleaning up Remove small spills with plenty of water. Absorb onto inert material and dispose of according to Controlled Waste Regulations Reference to other sections Please refer also to section no. 8 'Exposure controls' for further information. SECTION 7: Handling and storage 7.1. Precautions for safe handling Normal chemical handling Conditions for safe storage, including any incompatibilities Stored in original closed package, in dry and cool area. Store containers closed when not in use. Do not freeze. If frozen, thaw completely and mix thoroughly prior to use Specific end use(s) Only for professional and industrial users Shelf life 360 days SECTION 8: Exposure controls/personal protection 8.1. Control parameters Occupational exposure limits Biological limit values Recommended monitoring procedures Derived no-effect level (DNEL) No exposure limits noted for ingredient(s). No biological exposure limits noted for the ingredient(s). Predicted no effect concentrations (PNECs) 8.2. Exposure controls Appropriate engineering controls Adequate ventilation to maintain air contaminants below exposure limits. Individual protection measures, such as personal protective equipment Eye/face protection Safety goggles. CEN : EN 166 Skin protection - Hand protection Protective gloves (Plastic, impervious) (Protection against unintentional short-term contact) CEN : EN Other Protective clothing if splashing or repeated contact with product is likely. CEN : EN ISO Respiratory protection Thermal hazards Not required. Environmental exposure controls Prevent from entering in public sewers or the immediate environment. SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties Appearance Colour Odour Physical state Odour threshold Material name: Amber Liquid Slight Page: 3 / 8

4 ph (concentrated product) 4,7 ph in aqueous solution 5,6 (5% SOL.) Melting point/freezing point -5 C Initial boiling point and boiling range Flash point 100 C Evaporation rate < 1 (Ether = 1) Flammability (solid, gas) Upper/lower flammability or explosive limits Flammability limit - lower (%) Flammability limit - upper (%) Vapour pressure 18 mm Hg Vapor pressure temp. 21 C Vapour density < 1 (Air = 1) Relative density 1,13 Relative density temperature 21 C Solubility Solubility (water) 100 % Partition coefficient (n-octanol/water) Auto-ignition temperature Decomposition temperature Viscosity 12 cps Viscosity temperature 21 C Explosive properties Oxidizing properties 9.2. Other information Percent volatile Pour point -2 C Shelf life 0 (calculated) 360 days SECTION 10: Stability and reactivity Reactivity Chemical stability Material is stable under normal conditions Possibility of hazardous reactions Conditions to avoid Protect from freezing Incompatible materials Avoid contact with strong oxidisers Hazardous decomposition products SECTION 11: Toxicological information Information on toxicological effects Oxides of carbon, nitrogen, phosphorus, and sulphur evolved in fire. Product (Mixture) Material name: Test results Acute Dermal LD50 Rabbit: > 5000 mg/kg (Calculated according to GHS additivity formula) Acute Oral LD50 Rat: > 5000 mg/kg (Calculated according to GHS additivity formula) Page: 4 / 8

5 Components Mixture of: 5-chloro-2-methyl-4-isothiazolin-3-one [EC no ] and 2-methyl-4-isothiazolin-3-one [EC no ] (3:1) ( ) Test results Acute Dermal LD50 Rabbit: 90 mg/kg Acute Inhalation LC50 Rat: 0,33 mg/l 4 hour Acute Oral LD50 Rat: 67 mg/kg Acute toxicity Skin corrosion/irritation Respiratory sensitisation Specific target organ toxicity - repeated exposure Specific target organ toxicity - single exposure Carcinogenicity Germ cell mutagenicity Reproductive toxicity Information on likely routes of exposure Ingestion May cause slight gastrointestinal irritation. Inhalation Skin contact Eye contact Symptoms Mixture versus substance information Other information Prolonged or repeated exposure may cause transient irritation. Prolonged or repeated contact may cause transient irritation. Prolonged or repeated contact may cause transient irritation. None known. SECTION 12: Ecological information Toxicity Product (CAS Mixture) Species Test results 0% Mortality Fathead minnow 2000 mg/l, Static Bioassay with 48-Hour Renewal, 96 hour Crustacea 0% Mortality Daphnia magna 2000 mg/l, Static Acute Bioassay, 48 hour Other 0% Mortality Rainbow trout 2000 mg/l, Static Bioassay with 48-Hour Renewal, 96 hour Persistence and degradability - COD (mgo2/g) 205 (calculated data) - BOD 5 (mgo2/g) 1 (calculated data) - BOD 28 (mgo2/g) 1 (calculated data) - Closed Bottle Test (% Degradation in 28 days) - Zahn-Wellens Test (% Degradation in 28 days) 1 (calculated data) 1 (calculated data) - TOC (mg C/g) 64 (calculated data) Bioaccumulative potential Bioconcentration factor (BCF) Mobility in soil Results of PBT and vpvb assessment Material name: Not a PBT or vpvb substance or mixture. Page: 5 / 8

6 12.6. Other adverse effects SECTION 13: Disposal considerations Waste treatment methods Contaminated packaging Disposal methods/information According to Controlled Waste Regulations. EWC ( European Waste Code ) recommendation : Waste packaging; absorbents, wiping cloths, filter materials and protective clothing not otherwise specified Packaging (including separately collected municipal packaging waste) Plastic packaging. Depending on the origin and state of the waste, other EWC numbers may be applicable too. According to Controlled Waste Regulations. SECTION 14: Transport information ADR RID ADN IATA IMDG SECTION 15: Regulatory information EWC ( European Waste Code ) recommendation : Wastes not otherwise specified in the list Off-specification batches and unused products Organic wastes Depending on the origin and state of the waste, other EWC numbers may be applicable too Safety, health and environmental regulations/legislation specific for the substance or mixture EU regulations Regulation (EC) No. 1005/2009 on substances that deplete the ozone layer, Annex I Regulation (EC) No. 1005/2009 on substances that deplete the ozone layer, Annex II Regulation (EC) No. 850/2004 On persistent organic pollutants, Annex I as amended Regulation (EC) No. 689/2008 concerning the export and import of dangerous chemicals, Annex I, part 1 as amended Regulation (EC) No. 689/2008 concerning the export and import of dangerous chemicals, Annex I, part 2 as amended Regulation (EC) No. 689/2008 concerning the export and import of dangerous chemicals, Annex I, part 3 as amended Regulation (EC) No. 689/2008 concerning the export and import of dangerous chemicals, Annex V as amended Regulation (EC) No. 166/2006 Annex II Pollutant Release and Transfer Registry Regulation (EC) No. 1907/2006, REACH Article 59(1) Candidate List as currently published by ECHA Authorisations Material name: Page: 6 / 8

7 Regulation (EC) No. 143/2011 Annex XIV Substances Subject to Authorisation Restrictions on use Regulation (EC) No. 1907/2006, REACH Annex XVII Substances subject to restriction on marketing and use as amended Directive 2004/37/EC: on the protection of workers from the risks related to exposure to carcinogens and mutagens at work Directive 92/85/EEC: on the safety and health of pregnant workers and workers who have recently given birth or are breastfeeding Not regulated. Other EU regulations Directive 96/82/EC (Seveso II) on the control of major-accident hazards involving dangerous substances Not regulated. Directive 98/24/EC on the protection of the health and safety of workers from the risks related to chemical agents at work Mixture of: 5-chloro-2-methyl-4-isothiazolin-3-one [EC no ] and 2-methyl-4-isothiazolin-3-one [EC no ] (3:1) (CAS ) Directive 94/33/EC on the protection of young people at work Mixture of: 5-chloro-2-methyl-4-isothiazolin-3-one [EC no ] and 2-methyl-4-isothiazolin-3-one [EC no ] (3:1) (CAS ) National regulations Chemical safety assessment General Assessment Methodology Category of aquatic harmfulness: Slightly harmful to aquatic organisms Decontamination effort: B Inventory status Country(s) or region Inventory name On inventory (yes/no)* Europe European Inventory of Existing Commercial Chemical Substances Yes (EINECS) Europe European List of Notified Chemical Substances (ELINCS) *A "Yes" indicates that all components of this product comply with the inventory requirements administered by the governing country(s) A "No" indicates that one or more components of the product are not listed or exempt from listing on the inventory administered by the governing country(s). SECTION 16: Other information List of abbreviations References Information on evaluation method leading to the classification of mixture CAS: Chemical Abstract Service Registration Number TWA: Time Weighted Average STEL: Short Term Exposure Limit LD50: Lethal Dose, 50% LC50: Lethal Concentration, 50% EC50: Effect Concentration, 50% NOEL: No Observed Effect Level COD: Chemical Oxygen Demand BOD: Biochemical Oxygen Demand TOC: Total Organic Carbon CEN: European Committee for Standardisation EC-No: European Commission Number CLP: Regulation on classification, labeling and packaging of substances and mixtures DSD: Dangerous Substances Directive ADR: European Agreement concerning the International Carriage of Dangerous Goods by Road ADN: European Agreement concerning the International Carriage of Dangerous Goods by Inland Waterways IATA: International Air Transport Association IMDG: International Maritime Dangerous Goods Code RID: International Rule for Transport of Dangerous Substances by Railway Safety data sheets of raw materials. The physical, health and environmental hazards of this mixture are assessed by applying the classification criteria for each hazard class or differentiation in Parts 2 to 5 of Annex I to Regulation (EC) No 1272/2008 (CLP). No Material name: Page: 7 / 8

8 Full text of any statements or R-phrases and H-statements under Sections 2 to 15 Revision information Training information Based on EC Directive / Regulations R23/24/25 Toxic by inhalation, in contact with skin and if swallowed. R34 Causes burns. R43 May cause sensitisation by skin contact. R50/53 Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. H301 Toxic if swallowed. H310 Fatal in contact with skin. H314 Causes severe skin burns and eye damage. H317 May cause an allergic skin reaction. H330 Fatal if inhaled. H400 Very toxic to aquatic life. H410 Very toxic to aquatic life with long lasting effects. This document has undergone significant changes and should be reviewed in its entirety. Provide training on safe handling while considering the type of application and exposure scenarios. 1999/45/EC 2001/118/EC (EC) No 1907/2006 (REACH) (EC) No 453/2010 (EC) No 1272/2008 Further information Correction in Section: 1,2,3,8,9,15,16 Material name: Page: 8 / 8