Industrial : New Generation, Low Solvent, Thixotropic, Polyurethane liquid membrane for waterproofing and protection

Transcription

1 according to Regulation (EC) No. 1907/2006 (REACH) with its amendment Regulation (EU)2015/830 Date of issue: 29/4/2015 Revision date: 22/6/2018 Supersedes: 29/4/2015 Version: 1.1 SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier Product form : Mixture Product name Product code : Axiom Guard V+ : RS and RS Relevant identified uses of the substance or mixture and uses advised against Relevant identified uses Industrial/Professional use spec Use of the substance/mixture Uses advised against 1.3. Details of the supplier of the safety data sheet Visqueen Heanor Gate Road, Heanor Derbyshire DE75 7RG T: enquiries@visqueen.com : For professional use only Industrial : New Generation, Low Solvent, Thixotropic, Polyurethane liquid membrane for waterproofing and protection 1.4. Emergency telephone number Emergency number : Monday - Friday, 9am-5pm: For all other times please use the following number: SECTION 2: Hazards identification 2.1. Classification of the substance or mixture Classification according to Regulation (EC) No. 1272/2008 [CLP] Respiratory sensitisation, Category 1 Full text of H statements : see section 16 Adverse physicochemical, human health and environmental effects 2.2. Label elements H334 Labelling according to Regulation (EC) No. 1272/2008 [CLP]Extra labelling to displayextra classification(s) to display Hazard pictograms (CLP) : Signal word (CLP) Hazardous ingredients Hazard statements (CLP) Precautionary statements (CLP) EUH-statements 2.3. Other hazards GHS08 : Danger : m-tolylidene diisocyanate, toluene-diisocyanate : H334 - May cause allergy or asthma symptoms or breathing difficulties if inhaled. : P101 - If medical advice is needed, have product container or label at hand. P102 - Keep out of reach of children. P260 - Do not breathe spray, fume, vapours. P280 - Wear protective gloves, face protection. P233 - Keep container tightly closed. P210 - Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. P271 - Use only outdoors or in a well-ventilated area. P501 - Dispose of contents/container to hazardous or special waste collection point, in accordance with local, regional, national and/or international regulation. : EUH204 - Contains isocyanates. May produce an allergic reaction. SECTION 3: Composition/information on ingredients 3.1. Substances Not applicable EN (English) 1/7

2 3.2. Mixtures Name Product identifier % Classification according to Regulation (EC) No. 1272/2008 [CLP] xylene (CAS-No.) (EC-No.) (EC Index-No.) (REACH-no) m-tolylidene diisocyanate, toluene-diisocyanate (CAS-No.) (EC-No.) (EC Index-No.) (REACH-no) ,-0006, Specific concentration limits: < 5 Flam. Liq. 3, H226 Acute Tox. 4 (Dermal), H312 Acute Tox. 4 (Inhalation), H332 Skin Irrit. 2, H315 Eye Irrit. 2, H319 STOT SE 3, H335 STOT RE 2, H373 Asp. Tox. 1, H304 Carc. 2, H351 Acute Tox. 2 (Inhalation), H330 Eye Irrit. 2, H319 STOT SE 3, H335 Skin Irrit. 2, H315 Resp. Sens. 1, H334 Skin Sens. 1, H317 Aquatic Chronic 3, H412 Name Product identifier Specific concentration limits m-tolylidene diisocyanate, toluene-diisocyanate (CAS-No.) (EC-No.) (EC Index-No.) (REACH-no) ,-0006, Full text of H-statements: see section 16 (C >= 0,1) Resp. Sens. 1, H334 SECTION 4: First aid measures 4.1. Description of first aid measures First-aid measures general First-aid measures after inhalation First-aid measures after skin contact First-aid measures after eye contact First-aid measures after ingestion : Never give anything by mouth to an unconscious person. If you feel unwell, seek medical advice (show the label where possible). : If breathing is difficult, remove victim to fresh air and keep at rest in a position comfortable for breathing. : Remove affected clothing and wash all exposed skin area with mild soap and water, followed by warm water rinse. : Rinse immediately with plenty of water. Obtain medical attention if pain, blinking or redness persists. : Rinse mouth. Do NOT induce vomiting. Obtain emergency medical attention Most important symptoms and effects, both acute and delayed Symptoms/effects after inhalation : May cause allergy or asthma symptoms or breathing difficulties if inhaled Indication of any immediate medical attention and special treatment needed SECTION 5: Firefighting measures 5.1. Extinguishing media Suitable extinguishing media Unsuitable extinguishing media 5.2. Special hazards arising from the substance or mixture 5.3. Advice for firefighters Firefighting instructions Protection during firefighting : Foam. Dry powder. Carbon dioxide. Water spray. Sand. : Do not use a heavy water stream. SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures : Use water spray or fog for cooling exposed containers. Exercise caution when fighting any chemical fire. Prevent fire fighting water from entering the environment. : Do not enter fire area without proper protective equipment, including respiratory protection For non-emergency personnel Emergency procedures : Evacuate unnecessary personnel For emergency responders Protective equipment : Equip cleanup crew with proper protection. 29/4/2015 (Version: 1.0) EN (English) 2/7

3 Emergency procedures : Ventilate area Environmental precautions Prevent entry to sewers and public waters. Notify authorities if liquid enters sewers or public waters Methods and material for containment and cleaning up Methods for cleaning up : Soak up spills with inert solids, such as clay or diatomaceous earth as soon as possible. Collect spillage. Store away from other materials Reference to other sections See Heading 8. Exposure controls and personal protection. SECTION 7: Handling and storage 7.1. Precautions for safe handling Precautions for safe handling : Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work. Provide good ventilation in process area to prevent formation of vapour. Avoid breathing spray, fume, vapours Conditions for safe storage, including any incompatibilities Storage conditions : Keep only in the original container in a cool, well ventilated place away from : Heat sources. Keep container closed when not in use. Incompatible products Incompatible materials 7.3. Specific end use(s) SECTION 8: Exposure controls/personal protection 8.1. Control parameters 8.2. Exposure controls Personal protective equipment: Avoid all unnecessary exposure. Hand protection: Wear protective gloves. Eye protection: Chemical goggles or safety glasses Respiratory protection: In case of inadequate ventilation wear respiratory protection. Other information: Do not eat, drink or smoke during use. : Strong bases. Strong acids. water, amines and alcohol's. : Sources of ignition. Direct sunlight. SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties Physical state : Liquid Appearance Colour Odour Odour threshold ph Relative evaporation rate (butylacetate=1) Melting point Freezing point Boiling point : Viscous liquid. : white. : characteristic. Flash point : > 64 C Auto-ignition temperature Decomposition temperature Flammability (solid, gas) Vapour pressure Relative vapour density at 20 C Relative density Density,Non flammable. : 1,55 g/cm³ 29/4/2015 (Version: 1.0) EN (English) 3/7

4 Solubility Log Pow Viscosity, kinematic Viscosity, dynamic Explosive properties Oxidising properties Explosive limits 9.2. Other information VOC content : organic solvents. : > 20,5 mm²/s : 4500 cp : 70 g/l SECTION 10: Stability and reactivity Reactivity Chemical stability Stable under recommended handling and storage conditions (see section 7) Possibility of hazardous reactions Not established Conditions to avoid Direct sunlight. Extremely high or low temperatures Incompatible materials Strong acids. Strong bases. water, amines and alcohol's Hazardous decomposition products fume. Carbon monoxide. Carbon dioxide. SECTION 11: Toxicological information Information on toxicological effects Acute toxicity (oral) Acute toxicity (dermal) Acute toxicity (inhalation) Skin corrosion/irritation Serious eye damage/irritation Respiratory or skin sensitisation Germ cell mutagenicity Carcinogenicity Reproductive toxicity STOT-single exposure STOT-repeated exposure Aspiration hazard ph ph : May cause allergy or asthma symptoms or breathing difficulties if inhaled. Axiom Guard V+ Viscosity, kinematic Potential adverse human health effects and symptoms > 20,5 mm²/s. SECTION 12: Ecological information Toxicity Acute aquatic toxicity Chronic aquatic toxicity 29/4/2015 (Version: 1.0) EN (English) 4/7

5 12.2. Persistence and degradability Axiom Guard V+ Persistence and degradability Bioaccumulative potential Axiom Guard V+ Bioaccumulative potential Mobility in soil Results of PBT and vpvb assessment Other adverse effects No available data. No available data. : Avoid release to the environment. SECTION 13: Disposal considerations Waste treatment methods Product/Packaging disposal recommendations Ecology - waste materials : Dispose in a safe manner in accordance with local/national regulations. Dispose of contents/container to a hazardous or special waste collection point. : Avoid release to the environment. SECTION 14: Transport information In accordance with ADR / RID / IMDG / IATA / ADN UN number UN-No. (ADR) UN-No. (IMDG) UN-No. (IATA) UN-No. (ADN) UN-No. (RID) UN proper shipping name Proper Shipping Name (ADR) Proper Shipping Name (IMDG) Proper Shipping Name (IATA) Proper Shipping Name (ADN) Proper Shipping Name (RID) Transport hazard class(es) ADR Transport hazard class(es) (ADR) IMDG Transport hazard class(es) (IMDG) IATA Transport hazard class(es) (IATA) ADN Transport hazard class(es) (ADN) RID Transport hazard class(es) (RID) Packing group Packing group (ADR) Packing group (IMDG) Packing group (IATA) Packing group (ADN) Packing group (RID) Environmental hazards Dangerous for the environment Marine pollutant Other information Special precautions for user Overland transport : No : No : No supplementary information available 29/4/2015 (Version: 1.0) EN (English) 5/7

6 Transport by sea Air transport Inland waterway transport Rail transport Transport in bulk according to Annex II of Marpol and the IBC Code Not applicable SECTION 15: Regulatory information Safety, health and environmental regulations/legislation specific for the substance or mixture EU-Regulations Contains no REACH substances with Annex XVII restrictions Contains no substance on the REACH candidate list Contains no REACH Annex XIV substances VOC content Directive 2012/18/EU (SEVESO III) : 70 g/l National regulations Germany Reference to AwSV 12th Ordinance Implementing the Federal Immission Control Act - 12.BImSchV Netherlands SZW-lijst van kankerverwekkende stoffen SZW-lijst van mutagene stoffen NIET-limitatieve lijst van voor de voortplanting giftige stoffen Borstvoeding NIET-limitatieve lijst van voor de voortplanting giftige stoffen Vruchtbaarheid NIET-limitatieve lijst van voor de voortplanting giftige stoffen Ontwikkeling Denmark Classification remarks Danish National Regulations Chemical safety assessment : Water hazard class (WGK) 1, low hazard to waters (Classification according to AwSV, Annex 1) : Is not subject of the 12. BlmSchV (Hazardous Incident Ordinance) : xylene is listed : Emergency management guidelines for the storage of flammable liquids must be followed : Young people below the age of 18 years are not allowed to use the product Persons suffering from asthma or eczema and persons who have chronic lung diseases, skin or respiratory allergies to isocyanates should not work with the material The requirements from the Danish Working Environment Authorities regarding work with epoxy resins and isocyanates must be observed during use and disposal SECTION 16: Other information Data sources : REGULATION (EC) No 1272/2008 OF THE EUROPEAN PARLIAMENT AND OF THE COUNCIL of 16 December 2008 on classification, labelling and packaging of substances and mixtures, amending and repealing Directives 67/548/EEC and 1999/45/EC, and amending Regulation (EC) No 1907/2006. Other information Full text of H- and EUH-statements: : None. Acute Tox. 2 (Inhalation) Acute toxicity (inhal.), Category 2 Acute Tox. 4 (Dermal) Acute toxicity (dermal), Category 4 Acute Tox. 4 (Inhalation) Acute toxicity (inhal.), Category 4 Aquatic Chronic 3 Hazardous to the aquatic environment Chronic Hazard, Category 3 Asp. Tox. 1 Aspiration hazard, Category 1 29/4/2015 (Version: 1.0) EN (English) 6/7

7 Carc. 2 Carcinogenicity, Category 2 Eye Irrit. 2 Serious eye damage/eye irritation, Category 2 Flam. Liq. 3 Flammable liquids, Category 3 Resp. Sens. 1 Respiratory sensitisation, Category 1 Skin Irrit. 2 Skin corrosion/irritation, Category 2 Skin Sens. 1 Skin sensitisation, Category 1 STOT RE 2 Specific target organ toxicity Repeated exposure, Category 2 STOT SE 3 H226 H304 H312 H315 H317 H319 H330 H332 H334 H335 H351 H373 H412 EUH204 Specific target organ toxicity Single exposure, Category 3, Respiratory tract irritation Flammable liquid and vapour. May be fatal if swallowed and enters airways. Harmful in contact with skin. Causes skin irritation. May cause an allergic skin reaction. Causes serious eye irritation. Fatal if inhaled. Harmful if inhaled. May cause allergy or asthma symptoms or breathing difficulties if inhaled. May cause respiratory irritation. Suspected of causing cancer. May cause damage to organs through prolonged or repeated exposure. Harmful to aquatic life with long lasting effects. Contains isocyanates. May produce an allergic reaction. SDS EU (REACH Annex II) This information is based on our current knowledge and is intended to describe the product for the purposes of health, safety and environmental requirements only. It should not therefore be construed as guaranteeing any specific property of the product 29/4/2015 (Version: 1.0) EN (English) 7/7