FLEKSIBILNO PODRUČJE AKREDITACIJE / FLEXIBLE SCOPE OF ACCREDITATION Služba za zaštitu okoliša i zdravstvenu ekologiju

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1 Popis ispitnih metoda u fleksibilnom području akreditacije, status The valid list of the test methods in the flexible scope of accreditation, status Ovaj popis odnosi se na Prilog potvrdi o akreditaciji broj: 1040 koji je dostupan na This list is related to Annex to Accreditation Certificate Number: 1040 which is available at www. akreditacija.hr FLEKSIBILNO PODRUČJE AKREDITACIJE / FLEXIBLE SCOPE OF ACCREDITATION Služba za zaštitu okoliša i zdravstvenu ekologiju Red br./ No. Oznaka/ Identification Materijali/Proizvodi Materials/Products Vrsta ispitivanja/svojstvo Type of test/property Raspon/Range Tehnika / Technique Metoda ispitivanja / Test method I Hrana i hrana za životinje Aditivi (A) Sladila (A1), Kofein i konzervansi (A2), Nitriti (A3), Kontaminanti (B) Ostaci pesticida (B1), Metali (B2) AAS: PAAS, MHS,, DMA, (B2-1), ICP- MS (B2-2), Mikotoksini (B3), Nitrati (B4) i Kvaliteta (C) U primjeni od / In use from I Food and Feed Additives (A) Sweeteners (A1), Caffeine and preservatives (A2), Nitrites (A3), Contaminants (B) Pesticide residues (B1), Metals (B2) AAS: PAAS, MHS,, DMA, (B2-1), ICP- MS (B2-2), Mycotoxins (B3), Nitrates (B4) and Quality (C) Aditivi (A) Sladila (A1) Additives (A) Sweeteners (A1) 1. I A1-1 Osvježavajuća bezalkoholna pića Soft Drinks Acesulfam / Acesulfame K 0,1-150 mg L -1 Saharin / Saccharine 0,1-150 mg L -1 Aspartam / Aspartame 0,1-150 mg L -1 HPLC-UV HRN EN 12856:2000 (EN 12856:1999) I A1-2 Dijetetski proizvodi Dietary Products Acesulfam / Acesulfame K mg kg -1 Saharin / Saccharine mg kg -1 Aspartam / Aspartame mg kg -1 HPLC-UV HRN EN 12856:2000 (EN 12856:1999) I A1-3 Osvježavajuća bezalkoholna pića Soft Drinks Određivanje ciklamata / Determination of cyclamate 0,8-230 mg L -1 HPLC-UV HRN EN 12857:2000 (EN 12857:1999) Aditivi (A) Kofein i konzervansi (A2) Additives (A) Caffeine and preservatives (A2) Popis ispitnih metoda u fleksibilnom području akreditacije 1(12)

2 4. I A2-1 Osvježavajuća bezalkoholna pića Soft Drinks Kofein / Caffeine 0, mg L -1 Benzojeva kis. / Benzoic acid 0, mg L -1 Sorbinska kis. / Sorbic acid 0, mg L -1 HPLC-UV SOP / I A2-2 Alkoholna pića Vino Alcoholic Beverages Wine Sorbinska kis. / Sorbic acid 0, mg L -1 HPLC-UV SOP / I A3-1 Hrana Foodstuff Mesni proizvodi Meat products Aditivi (A) Nitriti (A3) Additives (A) Nitrites (A3) Određivanje nitrita/ Determination of nitrites Nitriti/nitrites mg kg -1 HPLC-UV SOP /2009 Red.br. / No. Oznaka/ Identification Materijali/Proizvodi Materials/Products Vrsta ispitivanja/svojstvo Type of test/property Raspon/Range Tehnika / Technique Metoda ispitivanja / Test method U primjeni od / In use from Kontaminanti (B) Ostaci pesticida (B1) Contaminants (B) Pesticide residues (B1) Popis ispitnih metoda u fleksibilnom području akreditacije 2(12)

3 7. I B1-1 HRANA BILJNOG PORIJEKLA FOOD OF PLANT ORIGIN Voće i povrće Visoki udio vode Visoki udio ulja Visoki udio kiseline Voćni sokovi Fruits and vegetables High water content High oil content High acid content Fruit Juices 0,01 mg kg -1 Aldrin/Aldrin, Alfa-HCH/Alpha-HCH, Azinfos-etil/Azinphos-ethyl, Azinfos-metil/Azinphos-methyl, Bioaletrin/Bioallethrin, Beta- HCH/Beta-HCH, Bromofos-metil/Bromophos-ethyl,Karbaril/Carbaryil, Klorfevinfos/Chlorfevinphos, Klorpirifos/Chlorpyrifos, Klorpirifos-metil/Chlorpyrifos-methyl, Ciflutrin-beta izomer 1/Cyfluthrin-beta isomer1, Ciflutrin-beta izomer 2/Cyfluthrin-beta isomer 2, Ciflutrin beta izomer 3/Cyflutrin-beta isomer 3, p-p'-dde/p-p'-dde,p-p'-ddd/ p-p'-ddd, p-p'-ddt/p-p'-ddt, Diazinon/Diazinone, Diklorvos/Dichlorvos, Dieldrin/Dieldrine, Dimetoat/Dimethoate, Disulfoton/Disulfoton, Disulfotonsulfon/Disulfoton-sulfon, Disulfoton-sulfoksid/Disulfoton-sulfoxid, Heptaklor/Heptachlor, Heptaklor epoksid/heptachlor epoxid, Endrin/Endrin Endosulfan alfa/endosulfan alpha,endosulfan beta/ Endosulfan beta, Endosulfan sulfat/endosulfan sulphate, Etion/Ethion, Etrimfos/Etrimfos, Fenamifos/Fenamiphos, Fenklorfos/Fenchlorphos, Fenitrotion/Fenitrothion, Fenpropratrin/Fenpropathrin, Fensulfotion/Fensulfothion, Fention/Fenthion,Lindan/ Lindane, Imazalil/Imazalil, Malaokson/Malaoxon, Malation/Malathion, Metamidofos/Methamidophos, Metakrifos/Methacrifos, Metidation/Methidathion, Mevinfos/Mevinphos, Paraoksonmetil/Paraoxon-methyl,Paration/Parathion, Paration-metil/Parathionmethyl, Forat/Phorate, Fosfamidon/Phosphamidon, Pirimifos metil/pirimifos methyl,tetrametrin/tetramethrin,kvinalfos/quinalphos, Klortalonil/Chlortalonil,Fosalon/Phosalone, Prokimidon/Procymidone, Tetradifon/Tetradifon, Trifloksistrobin/Trifloxystrobin GC-MS HRN EN 15662:2008 (EN 15662:2008) ,05 mg kg -1 Cis-permetrin/Cis-permethrin, Cipermetrin izomer 1/Cypermethrin isomer 1, Cipermetrin izomer 2/Cypermethrin isomer 2, Cipermetrin izomer 3/Cypermethrin isomer, Azoksistrobin/Azoxystrobin, Boskalid/Boscalid, Klorporpam/Chlorpropham,Cis-klordan/Cis- Chlordane, Fludioksonil/Fludioxonil, Miklobutanil/Myclobutanyl, Pirimikarb/Pirimicarb, Pirazofos/Pyrazophos,Pirimitanil/Pyrimethanil, Resmetrin/Resmethrin,Trans-Klordan/Trans-Chlordane, Tolkofosmetil/Tolclofos-methyl Popis ispitnih metoda u fleksibilnom području akreditacije 3(12)

4 8. I B1-2 HRANA BILJNOG PORIJEKLA FOOD OF PLANT ORIGIN Žitarice i proizvodi od žita (uključujući tjestenine) Visoki udio proteina ili visoki udio škroba Cereals and products there of (including pasta) High protein content or high starch content 0,01 mg kg -1 Aldrin/Aldrin,alfa-HCH/alpha HCH, Bioaletrin/Bioallethrin, Bromofosmetil/Bromophos-ethyl, Klorpirifos/Chlorpyrifos, Klorpirifos metil/chlorpyrifos methyl, Diazinin/Diazinone,Disulfoton sulfoksid/disulfoton sulfoxid, DDT (p,p, DDT+p,p DDE+p,p, DDD)/DDT (p,p, DDT+p,p DDE+p,p, DDD), Endosulfan alfa/ Endosulfan alpha, Endosulfan beta/endosulfan beta, Endosulfan sulfat/endosulfan sulphate, Heptaklor/ Heptachlor, Heptaklor epoksid/heptachlor epoxid, Malaokson/Malaoxon, Malation/Malathion,Pirimifos metil/pirimiphos methyl, Forat/Phorate, Fosalon/Phosalone, Prokimidon/Procymidone, Tetrametrin/Tetramethrin, Trifloksistrobin/Trifloksistrobin, Vinklozolin/Vinklozolin, Kvinalfos/Quinalphos, 0,05 mg kg -1 Boskalid/Boscalid, Cis-Klordan/Cis-Chlordane, Trans-Klordan/Trans- Chlordane, Pirazofos/Pyrazophos, Pirimetanil/Pyrimethanil, Resmetrin/Resmethrin, Tolkofos-metil/Tolclofos-methyl GC-MS HRN EN 15662:2008 (EN 15662:2008) Popis ispitnih metoda u fleksibilnom području akreditacije 4(12)

5 Red br./ No. Oznaka/ Identification Materijali/Proizvodi Materials/Products Vrsta ispitivanja/svojstvo Type of test/property Raspon/Range Kontaminanti (B) Metali (B2) AAS: PAAS, MHS,, DMA, (B2-1), ICP- MS (B2-2) Contaminants (B) Metals (B2) AAS: PAAS, MHS,, DMA, (B2-1), ICP- MS (B2-2) Tehnika / Technique Metoda ispitivanja / Test method U primjeni od / In use from 9. I B2-1-1 Bezalkoholna pića Soft Drinks As 0,5 10,0 µg L -1 Pb 2,0 50,0 µg L -1 Cd 0,2 2,0 µg L -1 AAS MHS I B I B2-1-3 Ribe Fish Lignje Squids Ribe i hrana za životinje Fish and feed Pb 0,05 1,25 mg kg -1 Cd 0,005 0,05 mg kg -1 Cd 0,005 0,05 mg kg -1 Hg 0,02-6,0 mg kg -1 AAS Amalgamiranje Amalgamation SOP / I B2-1-4 Konzerve voća i povrća Canned Fruits and Vegetables Sn 0,25 2,5 mg kg -1 Fe 2,5-100 mg kg -1 PAAS Popis ispitnih metoda u fleksibilnom području akreditacije 5(12)

6 13. I B2-1-5 Voće i povrće Fruits and Vegetables Cd 0,005 0,05 mg kg -1 Pb 0,05-1,25 mg kg -1 As 0,012 0,25 mg kg -1 Hg 0,005 0,20 mg kg -1 MHS I B2-1-6 Dodaci prehrani Food Supplements Propolis Propolis Cd 0,01 0,1 mg kg -1 Pb 0,1 2,5 mg kg -1 As 0,025 0,50 mg kg -1 Hg 0,01 0,40 mg kg -1 MHS I B2-1-7 Dječja hrana na bazi žitarica Cereal based Infant Food Cd 0,004 0,04 mg kg -1 Pb 0,04 1,0 mg kg I B2-1-8 Proizvodi od voća i povrća Fruits and Vegetables Products Cd 0,01-0,1mg kg -1 Pb 0,1 2,5 mg kg I B2-2-1 Hrana za životinje Feed Pb 0,2 10 mg kg -1 Cd 0,02 2,0 mg kg -1 As 0,1 6 mg kg -1 ICP-MS SOP / Popis ispitnih metoda u fleksibilnom području akreditacije 6(12)

7 Kontaminanti (B) Mikotoksini (B3) Contaminants (B) Mycotoxins (B3) 18. I B3 Orašasti proizvodi, bademi, pistacije, kikiriki Tree nuts, Ground nuts Almond, Pistachio, Peanuts Aflatoksin B1/Aflatoxin B1 0,5 10 μg kg -1 Aflatoksin B2/Aflatoxin B2 0,5 10 μg kg -1 Aflatoksin G1/Aflatoxin G1 0,5 10 μg kg -1 Aflatoksin G2/Aflatoxine G2 0,5 10 μg kg -1 LC- MS/MS SOP / Kontaminanti (B) Nitrati (B4) Contaminants (B) Nitrates (B4) 19. I B4 Voće i povrće Fruits and Vegetables Nitrati/Nitrates mg kg -1 HPLC UV HRN EN :1998 (EN :1997) Kvaliteta (C) Određivanje ugljikohidrata Quality (C) Determination of carbohydrates 20. I C1-1 Sokovi, sirupi i sirupi sa smanjenom količinom šećera Juices, Juice Concentrates and Reduced Sugar Juice Concentrates Fruktoza / Fructose 0,35 21 g L -1 Glukoza / Glucose 0,35 21 g L -1 Saharoza / Sucrose 0,35 21 g L -1 HPLC RID SOP / I C1-2 Med Honey Fruktoza / Fructose g kg -1 Glukoza / Glucose g kg -1 Saharoza / Sucrose g kg -1 HPLC RID SOP / Popis ispitnih metoda u fleksibilnom području akreditacije 7(12)

8 Red br./ No. Oznaka/ Identification 22. II A Materijali/Proizvodi Materials/Products Voda za ljudsku potrošnju, površinska, podzemna i otpadna voda Water for human consumption, surface water, ground and waste water Vrsta ispitivanja/svojstvo Type of test/property Raspon/Range II Voda Odabrani elementi (A) II Water Selected elements (A) Cu 0,02 2,0 mg L -1 Cr 0,001 0,05; 0,05 5,0 mg L -1 Mn 0,02 2,0 mg L -1 Zn 0,005 0,05; 0,05 5,0 mg L -1 Cd 0,001 0,05; 0,05 5,0 mg L -1 Ni 0,02 2,0 mg L -1 Pb 0,02 2,0 mg L -1 Ba 0,001-0,05; 0,05-5,0 mg L -1 Tehnika / Technique ICP OES Metoda ispitivanja / Test method HRN EN ISO 11885: 2010 (ISO 11885:2007; EN ISO 11885:2009) U primjeni od / In use from III - Predmeti opće uporabe Ftalati (A); Prijelaz (otpuštanje) određenih metala (B) AAS: PAAS, MHS,, DMA (B1), ICP- MS (B2) III - Objects of common use Phtalates (A); Migration of certain metals (B) AAS: PAAS, MHS,, DMA (B1), ICP- MS (B2) 23. III A Dječje igračke od omekšane i poliuretanske umjetne mase Toys made of softened polymer materials dietil ftalat/dietyl phthalate (0,01%-0,15%) dibutil ftalat/dibutyl phthalate (0,01%-0,15%), benzil butil ftalat/benzyl butyl phthalate (0,01%- 0,15%), dietilheksil ftalat/ bis(2-ethylhexyl) phthalate (0,01%-0,15%), di-n-oktiil ftalat/ di-n-octyl phthalate (0,01%-0,15%), diizononil ftalat/ di-isononyl phthalate (0,02%- 0,20%), diizodecil ftalat/di-isodecyl phthalate (0,02%-0,20%) GC MS HRN EN 14372:2004 (EN 14372:2004) točka/clause 5.4 za kemijske zahtjeve/ for chemical requirements Popis ispitnih metoda u fleksibilnom području akreditacije 8(12)

9 24. III B1-1 Dječje igračke izrađene od materijala Kategorija III Toys made of softened polymer materials made of materials Category III Pb 10,0 50,0 mg kg -1 Cd 1,5 50,0 mg kg -1 Ba mg kg -1 As 0,025 0,50 mg kg -1 Hg 0,01 0,4 mg kg -1 Se 0,05 0,50 mg kg -1 Sb 0,1 0,50 mg kg -1 PAAS MHS HRN EN 71-3:2013 (EN 71-3:2013) SOP / III B1-2 Igračke Toys Školski pribor za pisanje i crtanje Kategorija I i Kategorija II School accessories for drawing and writing Category I and Category II Pb 10,0 50,0 mg kg -1 Cd 1,5 50,0 mg kg -1 Ba mg kg -1 As 0,025 0,50 mg kg -1 Hg 0,01 0,4 mg kg -1 Se 0,05 0,50 mg kg -1 Sb 0,1 0,50 mg kg -1 PAAS MHS HRN EN 71-3:2013 (EN 71-3:2013) SOP / III B2-1 Igračke Toys Kategorija III Category III Cd 0,1 1,0 mg kg -1 Pb 1,0 5,0 mg kg -1 Ba 1,0 5,0 mg kg -1 As 1,0 5,0 mg kg -1 Se 1,0 5,0 mg kg -1 Sb 1,0 5,0 mg kg -1 ICP- MS HRN EN 71-3:2013 (EN 71-3:2013) SOP / Popis ispitnih metoda u fleksibilnom području akreditacije 9(12)

10 27. III B2-2 Plastični materijali i proizvodi koji dolaze u kontakt s hranom Plastic materials and articles intended to come into contact with food Ba µg L -1 Co µg L -1 Zn µg L -1 ICP- MS SOP / HRN EN :2000 (EN :1995) keramika/ceramic 28. III B2-3 Keramika i staklo Ceramic and glass Pb 0,2-20,0 µg L -1 Cd 2, µg L -1 ICP- MS HRN EN :2000 (EN :2000) staklo/glass modificirana/modification SOP / III B2-4 Posuđe i pribor od nehrđajućeg čelika / Disches and kitchen utensils from stainless steel Ni µg L -1 Mn µg L -1 ICP- MS SOP / Popis ispitnih metoda u fleksibilnom području akreditacije 10(12)

11 IV - Otpad, voda, tlo, muljevi i eluati -Odabrani elementi (A) IV - Waste, water, soil, sludges and eluate -Selected elements (A) 30. IV A-1 Tlo, mulj, kruti i tekući otpad Soil, sludge, solid and liquid waste Pb mg kg -1 Cd mg kg -1 AAS HRN EN 13657:2008 Cr mg kg -1 (EN 13657:2002) IV A-2 Eluati tla i otpada Soil and waste eluates Cd 0,3-10 mg kg -1 Cu 0,4-20 mg kg -1 Ni 2-40 mg kg -1 Hg 0,02-0,08 mg kg -1 AAS HRN ISO 8288:1998 (ISO ) Popis ispitnih metoda u fleksibilnom području akreditacije 11(12)

12 Napomene / Notes HPLC- RID: tekućinska kromatografija visoke djelotvornosti s refraktometrijskom detekcijom (engl. High performance liquid chromatography with refractometric detection, HPLC-RID) HPLC- UV: tekućinska kromatografija visoke djelotvornosti s detekcijom u ultraljubičastom području (engl. High performance liquid chromatography with ultraviolet detection, HPLC- UV) AAS: atomska apsorpciona spektrometrija ( engl. Atomic absorption spectrometry, AAS ) : grafitna tehnika (engl. Graphite furnace technique, GFAAS) PAAS: plamena tehnika (engl. Flame technique, FAAS ) MHS: hidridna tehnika (engl. Hydride technique or metal hydrid system, MHS) GC-MS: plinska kromatografija-spektrometrija masa (engl. Gas chromatography-mass spectrometry, GC-MS) ICP MS: induktivno spregnuta plazma i spektrometrija masa (engl. Inductively coupled plasma mass spectrometry, ICP-MS) ICP OES: induktivno spregnuta plazma i optička emisijska spektroskopija (engl. Inductively coupled plasma - optical emission spectroscopy, ICP OES) LC-MS/MS: tekućinska kromatografija i višestruka spektrometrija masa (engl. Liquid chromatography tandem mass spectrometry, LC-MS/MS) Fleksibilnim područjem akreditacije dopušta se laboratoriju primjena metoda ispitivanja na materijale/proizvode, vrstu ispitivanja/svojstvo i raspone unutar područja, u skladu s dokumentiranim i odobrenim postupcima laboratorija. Flexible scope allows laboratory application test methods in materials/products, type of test/property and ranges within the scope, in accordance with the laboratory s documented and approved procedures. Važeći popis akreditiranih metoda iz fleksibilnog područja akreditacije dostupan je na The valid list of accredited methods in the flexible scope is available on Ažurirano: , A.Devčić Jeras / A.Galić / J.Šabarić Popis ispitnih metoda u fleksibilnom području akreditacije 12(12)