Feasibility of Continuous Frying System to Improve the Quality Indices of Palm Olein for the Production of Extruded Product

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1 Journal of Oleo Science Copyright 2015 by Japan Oil Chemists Society doi : /jos.ess15131 Feasibility of Continuous Frying System to Improve the Quality Indices of Palm Olein for the Production of Extruded Product Azmil Haizam Ahmad Tarmizi * and Karimah Ahmad Malaysian Palm Oil Board (6, Persiaran Institusi, Bandar Baru Bangi, Kajang, Selangor, MALAYSIA) Abstract: Comparative frying studies on the processing of extruded product were conducted under intermittent and continuous frying conditions using two separate frying systems i.e batch and pilot scale continuous fryers, respectively. Thermal resistance of palm olein were assessed for a total of 5 days of frying operation at 155 the unconventional frying temperature gave the product moisture content of 3% after intermittent and continuous frying for 2.5 min and 2 min, respectively. The formation of free fatty acid in palm olein in the case of intermittent frying was more than 2-fold higher compared to its counterpart (0.66%). Smoke point inversely evolved with oil acidity: the value dropped progressively from 215 to 177 and from 219 to 188 when extruded product was intermittently and continuously fried, respectively. In the light of induction period, repeated frying exhibited a gradual decrease in the value after 5 days of frying (12.2 h). Interestingly, continuous frying gave somewhat similar induction period, as demonstrated by fresh palm olein, across frying time. Frying at lower temperature, to some extent, provides opportunity for palm olein to retain 74% of its initial vitamin E during continuous frying. This benefit, however, is somehow denied when extruded product was processed under intermittent frying conditions only 27% of vitamin E was remained at the end of frying session. Regardless of frying protocols, transient in polar compounds was minimal and hence comparable. The colour in the case of continuous frying appeared to be darker due to higher degree of oil utilisation for frying. The data obtained will provide useful information for food processors on how palm olein behaves when frying is undertaken under different frying protocols. Key words: comparative frying, extruded product, intermittent frying, continuous frying, thermal resistance 1 INTRODUCTION Frying is one of the ancient methods in cooking food since it has been extensively practiced for more than 4000 years 1. It essentially involves rapid heat and mass transfer when food is immersed in edible oil at temperatures above the boiling point of water in the presence of air and water emission. This cooking technique is likely to be the most preferable way to process food because of its versatility, convenience and economic viability that enable to produce fried products with unique sensory attributes 2. Frying may have similar fundamental as in baking a brownish crust layer is formed on the food surface that contributes to a distinctive fried flavour but it generally cooks faster due to higher efficiency of heat transfer 3. In spite of all this, the benefits of frying process seem to be meaningless if the quality aspects of the oil are not considered. Exposure of oil to excessive heating in the pres- ence of air and moisture stimulates complex pattern of thermolytic, oxidative and polymeric reactions 4. Such deleterious reactions are becoming more complicated when oil degradation components interact with food during the frying process. It is anticipated that the compositions of the food e.g. proteins, carbohydrates and lipids determine the degree of oil breakdowns 5. Destructive changes in oil not only affect the usability and fry life of the oil, but may also initiate health hazards in human body 6. Many studies were undertaken to investigate the strategies on how to protect and hence minimise frying oil deterioration. The strategies include alteration of fatty acids composition through blending, hydrogenation, plant breeding, and incorporation of additives and antioxidants. Nonetheless, the rate of oil degradation relies not only to oil properties alone but also the process conditions or protocols of which the oil being applied 4, 7. Exposure of frying * Correspondence to: Azmil Haizam Ahmad Tarmizi, Malaysian Palm Oil Board (6, Persiaran Institusi, Bandar Baru Bangi, Kajang, Selangor, MALAYSIA) azmil_haizam@mpob.gov.my Accepted September 29, 2015 (received for review June 1, 2015) Journal of Oleo Science ISSN print / ISSN online

2 A. H. Ahmad Tarmizi and K. Ahmad oil with air is minimal when the oil surface area to volume ratio is relatively small 8. Flushing the frying oil with inert gases like carbon dioxide and/or nitrogen helps to reduce the concentration of dissolved oxygen 9, 10. Frying at elevated pressure 11 and under vacuum 9 protects frying oil against deterioration. Ahmad Tarmizi et al. 12 observed that the shelf life of frying oil can be improved when applying vacuum during the post-frying stage. It is also worth noting that the initial quality of oil also plays a significant role in oil stability during frying 3. The performance of vegetable oils during frying is extensively discussed in the literatures. Most of these studies, however, were carried out under intermittent batch frying, and many of which involved frying of potato products e.g. potato chips and French fries and coated products e.g. fillets and nuggets. In fact, research works that simulate industrial continuous frying, are rather scanty, and only restricted to frying potato chips and/or pre-fried French fries It is believed that higher operation cost and/or trade policy of food industry are the main reasons for scanty publications related to continuous frying 13. By considering all this, it is essential to investigate on how the oil behaves when frying is undertaken for other products. This study, therefore, was designed to compare the physical and chemical changes occurring in palm olein when extruded product was processed under intermittent and continuous frying conditions. Unlike any other papers that distinguished both frying protocols using identical frying system batch fryer, we conducted the continuous frying studies using a pilot scale continuous fryer to reflect the actual practice of the industrial frying operation. The outcome of the study would provide information on the influence of frying systems on the physico-chemical changes occurring in oil during frying. From the nutrition perspective, oil stability is of major concern because significant amount of frying oil is being taken up by the fried food. 2 MATERIALS AND METHODS 2.1 Raw materials Refined, bleached and deodorised RBD palm olein was provided by MOI Foods Sdn. Bhd. Pulau Indah, Malaysia. Ingredients for dough formulation were purchased from local suppliers. Dough for the preparation of extruded product contained chickpea and tapioca flours, chicken and chilli powders, salt, icing sugar, palm olein and water. 2.2 Frying procedures and oil sampling Intermittent frying experiments were conducted using 23-L capacity stainless steel electrical open fryer Frymaster Corporation, Shreveport, USA with two split pots; each pot has the capacity of 11.5 L. Oil was poured into the fryers and conditioned at 155 for 30 min prior to frying. For each pot, a batch of 100 g of dough was manually kneaded into noodle-like strands and fried for 2.5 min. Every 100 g of dough produced an average of 90 g of extruded product. The extruded product was processed for every 20 min cycles across 8 h day 1 for 5 consecutive days. About 1 L of oil was sampled at the end of each day using two 500-mL dark amber bottles. The samples were flushed with nitrogen and stored at 20 for subsequent physico-chemical analyses. The lid was placed on the fryer and left overnight. Necessary amount of fresh oil 1.2 L was added into the fryer on the next day of frying operation to keep a constant level of 11.5 L. Contrariwise, continuous frying was conducted for 8 h daily over 5 consecutive days using a 200-L capacity pilot plant continuous fryer Heat and Control Inc., Brisbane, Australia. Oil was transferred from the fresh oil tank into the fryer and heated gradually until the oil temperature reached 155. The dough strands were allowed to fry for 2 min. By taking the oil turnover time of 10 h as a bench mark, 80 kg of dough was automatically kneaded on hourly basis to yield 60 kg of extruded product. Fresh oil was continuously compensated at the rate of 18 kg h 1 throughout the process. About 1 L of oil was collected at predetermined time intervals, and treated in identical manners upon storage. At the end of each frying day, the oil inside the fryer was pumped into the used oil tank and stored overnight before use on the next day of operation. Summary of the process conditions underpinning intermittent and continuous frying is tabulated in Table 1. It is important to note that the establishment of dough formulation and process conditions for the above frying protocols were initially carried out prior to execution of this study. Despite the frying temperature used was considerably low 155 as compared to the typical frying temperatures, the time needed for the product to achieve 3 moisture content which is generally the final moisture content of commercial extruded products was shorter 2.5 min for intermittent frying and 2 min for continuous frying. 2.3 Analytical methods for fresh and heated oils Identification of fatty acid composition was performed with reference to the AOCS Official Methods Ce 2-66 and Ce 1a whereas lipid component was determined using a method described in AOCS Official Methods Ce 5c-89 and Ce 5c Free fatty acid FFA, smoke point, peroxide value PV and p-anisidine value AnV were analysed by the AOCS Official Methods Cc 9a-48, Cd 8b-90 and Cd 18-90, respectively 19. Total oxidation or Totox correlates with PV and AnV according to the following equation: TV 2PV AnV. Tocols content, induction time measured at 110 and colour were evaluated using AOCS Official Methods Ce 8-89, Cd 12b-92 and Cc 5a-40 respectively

3 Behaviour of palm olein for continuous frying of extruded product Table 1 Summary of process conditions for intermittent and continuous frying. Parameters Intermittent frying Continuous frying Oil temperature Frying interval 20 min Continuously Frying time 2.5 min 2 min Fryer capacity 11.5 L 200 L Oil replenishment 1.2 L daily before frying session 18 kg h 1 Frying operation 40 h (8 h daily for 5 days) 40 h (8 h daily for 5 days) Production rate 0.3 kg h 1 60 kg h 1 Oil sampling At the end of frying day At the end of frying day Table 2 Fatty acid composition of fresh palm olein. Fatty acids Composition (%) C12:0 0.3±0.0 C14:0 1.1±0.0 C16:0 40.9±0.1 C16:1 0.2±0.0 C18:0 4.1±0.0 C18:1 42.6±0.1 C18:2 10.2±0.0 C18:3 0.2±0.0 C20:0 0.1±0.0 Others 0.4±0.0 Saturated fatty acids 46.7±0.1 Monounsaturated fatty acids 42.8±0.1 Polyunsaturated fatty acids 10.4±0.1 Quantification of polar compounds TPC was determined gravimetrically using silica column chromatography following IUPAC Statistical analysis Intermittent frying and continuous frying sessions were conducted in triplicate and duplicate, respectively reproducibility while the physico-chemical measurements of each oil sample were done in triplicate repeatability. One-way analysis of variance ANOVA was carried out using Minitab Version 14 Minitab Inc., State College, USA at confident level of 95. Results in tables and figures are presented as means standard deviation, calculated across frying period. Table 3 Lipid composition of fresh palm olein. Triacyclglycerols content Composition (%) OLL 0.5±0.0 PLL 2.5±0.0 MLP 0.6±0.0 OLO 2.0±0.1 PLO 10.5±0.1 PLP 9.9±0.2 MPP 0.1±0.0 OOO 4.4±0.3 POO 25.2±0.6 POP 29.1±1.0 PPP 0.4±0.1 SOO 2.6±0.1 POS 4.9±0.0 SOS 0.6±0.0 Total diacylglycerols 6.7±0.2 Note: M myristic acid; P palmitic acid; O oleic acid; S stearic acid; L linoleic acid 3 RESULTS AND DISCUSSION 3.1 Initial fatty acid and lipid compositions Fatty acid and lipid compositions are among the few indicators used to establish the authenticity of edible oils. Table 2 showed that palm olein contained equal levels of saturated and unsaturated fatty acids, and therefore imparts to the stability of the oil. Palm olein also exhibited trace amount of linolenic acid C18:3, which is well below the maximum allowance of 2 linolenic acid for use in the industrial frying 3. Higher level of linolenic acid not only releases unpleasant smell throughout the frying operation but also gives bitter taste to the fried product 13. In general, palm olein contains about 93 of triacylglycerols TAG Table 3. The most abundant TAG are POP 29.1 and POO 25.2 with comparable amounts of 1261

4 A. H. Ahmad Tarmizi and K. Ahmad PLO 10.5 and PLP 9.9. The remaining TAG are found to be no greater than 5. It is also interesting to note that equivalent concentrations between mono- and disaturated TAG which are 40.5 and 45.1, respectively were somewhat similar to that of saturated and monounsaturated fatty acids Table 2, and thus reflects the stability of palm olein. Appreciable amount of diacylglycerols DAG in palm olein of nearly 7 contributes to inherently higher level of polar compounds when compared to conventional liquid oils such as soybean, canola and sunflower oils 2 to Free fatty acid Determination of oil acidity which measures the formation of free fatty acid FFA is one of the principle markers used by many food manufacturers to monitor the oil quality during frying. The FFA is generally developed when frying oil interacts with the leached water from food, and partly through alteration of oil triacylglycerols TAG as a result of oxidative reaction 21. Figure 1 illustrates the evolution of FFA in palm olein throughout the course of intermittent and continuous frying. As expected, a linear increase in FFA from 0.12 to 0.66 was observed when extruded product was repeatedly fried for 5 days. The FFA of oil samples collected during continuous frying, however, evolved exponentially with the function of frying time: the oil acidity increased gradually for the first two days before achieving an equilibrium state between 0.24 and It is also evidenced from Fig. 1 that the level of FFA was significantly lowered by more than two folds when frying is performed under continuous frying conditions. Similar trend is also obtained by Ahmad Tarmizi and Ismail 13, 14 when produced potato chips under similar frying conditions. In this respect, it is plausible that the oil inside the fryer which is taken up by the extruded product and/or loss during frying is continuously compensated with the fresh oil of lower acidity and hence gives the consistency in FFA formation 14. Regardless of the frying protocols performed, the level of FFA in all oil samples was significantly below the maximum allowance defined by some countries: Czech Republic, Russia and Ukraine 1 ; Austria, Turkey and Finland 1.25 ; Poland 1.5 ; Germany 2 ; The Netherlands 2.25 ; Belgium, Argentina and Chile 2.5 ; and Panama Assuming 1 of FFA is taken as the bench mark, it is conjectured that palm olein, in the case of intermittent frying, can be utilised for another 4 days before discarded. Contrariwise, continuous frying, in a way, allows infinite use of palm olein throughout frying operation. 3.3 Smoke point Smoke point is a form of heating test that determines the temperature where consistent wisp of smoke starts to emanate from the oil. Theoretically, disintegration of triacylglycerols to low-molecular-weight constituents e.g. FFA, monoacylglycerols MAG, DAG and other volatile matters quantifies to the amount of smoke release from the heated oil 23. The results demonstrated in Fig. 2 indicate a progressive drop of smoke point across 5 days of frying, and this appears to inversely correlate with the acidity of palm olein. The smoke points were similar in both frying protocols for the first two days of frying before start to deviate significantly from one to another for the remaining days. At the end of frying session, continuous frying gave the smoke point of 11 higher than the otherwise 177. Nonetheless, all the smoke point values were greater than 20 above the frying temperature 155 and exceeded the lower limit of smoke point 170 allowed by many countries 3. Despite being one of the internationally recognised indicators to discard used oil, the implementation of smoke point to be one of the oil quality Fig. 1 Development of free fatty acid in palm olein during intermittent and continuous frying of extruded product. Means within the same frying interval marked with asterisks (*) are significantly different (p < 0.05). Fig. 2 Transient of smoke point in palm olein during intermittent and continuous frying of extruded product. Means within the same frying interval marked with asterisks (*) are significantly different (p < 0.05). 1262

5 Behaviour of palm olein for continuous frying of extruded product Table 4 Changes of peroxide, p-anisidine and Totox values, colour, and induction period in palm olein during frying. Parameters Peroxide value (meq O 2 kg 1 ) p-anisidine value (unit) Totox value (unit) Induction period (h) Colour (R) Frying Frying time (day) protocol Intermittent 1.3±0.0aA 8.3±1.9bA 8.1±0.9bA 7.8±0.4bA 7.9±0.5bA 7.9±0.3bA Continuous 1.0±0.1aB 7.4±2.0bA 5.2±1.2bcB 4.4±0.1cB 7.4±2.8bA 6.9±2.8A Intermittent 1.5±0.2aA 15.9±2.1bA 24.5±3.3cA 30.9±2.0dA 32.9±1.9dA 42.0±8.5eA Continuous 1.3±0.1aA 12.5±1.2bB 16.9±3.9bcB 14.5±3.5bcB 13.9±1.6bB 18.8±2.6cB Intermittent 3.9±0.3aA 32.5±5.3bA 40.6±4.6bcA 46.5±2.4cA 48.6±1.0cdA 57.8±9.0dA Continuous 3.3±0.2aB 27.2±5.0bcA 27.2±6.3bcB 23.2±3.6bB 28.7±7.2bcB 32.5±3.1cB Intermittent 26.5±0.3aA 18.6±1.7bA 16.6±2.1bcdA 14.3±1.8cdA 12.8±1.9cdA 12.2±1.4dA Continuous 27.4±1.7aA 25.4±1.5abB 24.7±2.1abB 23.5±1.7bB 25.6±1.6abB 26.6±0.8aB Intermittent 3.0±0.0aA 4.8±0.2bA 5.8±0.3cA 6.6±0.3dA 7.4±0.2eA 8.9±0.1fA Continuous 3.0±0.1aA 10.9±0.1bB 13.1±1.1cB 14.2±0.1cB 15.1±2.3cdB 17.1±2.1dB Means within a row for each parameter marked with different lowercase letters are significantly different (p < 0.05). Means within a column for each parameter marked with different uppercase letters are significantly different (p < 0.05). parameters is hardly reported in the literatures. 3.4 Total oxidation value Peroxide value PV is an expression of primary oxidation that measures the formation of hydroperoxides in oils. Despite being a useful tool in monitoring the initial stage of oxidation, PV is considered as unstable measurement for oils when they are subjected to excessive heat because peroxides have a tendency to decompose at high temperatures while the new ones are being produced during the cooling period 23. As expected, there was no apparent trend in the peroxides formation throughout the course of intermittent and continuous frying: PV was no greater than 9 meq O 2 kg 1 in both cases even after 5 days of frying Table 4. Fission of hydroperoxides further disintegrates into constituents such as aldehydes and ketones; this secondary oxidation stage is denoted as p-anisidine value AnV. Total oxidation Totox value correlates both primary and secondary oxidations to provide adequate information pertaining to the oxidative state of oil. When palm olein is exposed to frying temperatures, AnV seems more prominent than PV and thus governing the Totox value. Table 4 clearly shows that rapid increase in Totox value was demonstrated after first and second days of continuous and intermittent frying, respectively before starting to increase moderately thereafter. This could be due to the formation of higher molecular weight compounds with carbonyl group 24. Inevitably, the highest Totox value was registered during intermittent frying of nearly 40 more than the otherwise. This can be elucidated from the basis of the procedure involved during intermittent frying where hot oil was allowed to remain idle and exposed to air oxygen between frying cycles the oil was heated without loading for a total of 52.5 min for each hour of operation. 3.5 Vitamin E Vitamin E, which consists of tocopherols and/or tocotrienols, is one of the abundant natural antioxidants existing in oils and fats. Unlike majority of vegetable oils that define vitamin E as tocopherols, palm olein is one of the few that contains both tocopherols and tocotrienols homologues. Indeed, more than one third of vitamin E content in palm olein is sourced from tocotrienols. In this study, palm olein used for frying extruded product primarily contained 570 mg kg 1 of vitamin E for which tocotrienols constitute about three quarters of the total share 423 mg kg 1. The qualitative synergistic effects of vitamin E, including tocopherols and tocotrienols, are displayed in Fig. 3 a, b and c, respectively. Degradation of vitamin E in the case of intermittent frying was the most significant because 73 of its original content had disappeared after 5 days. Similar reduction trend was also observed in tocopherol and tocotrienol homologues: only 42 mg kg 1 of tocopherols and 98 mg kg 1 of tocotrienols were retained in the oil. Inversely for continuous frying, palm olein only experienced one stage reduction of vitamin E by 29 at the first day of frying, and achieved consistency within a narrow range of 394 to 423 mg kg 1 afterwards. This can be explained from the basis of the oil losses inside the fryer was continuously conditioned with fresh oil throughout the frying process. It is worth to mention that at least 70 of the initial vitamin E content 78 tocopherols and 67 tocotrienols was still persisted in the oil upon completion of continuous frying session. Ahmad Tarmizi and Ismail 14 observed that potato chips produced under continuous frying conditions have retained almost half of the initial vitamin E content in palm olein after 5 days of frying. In all the frying protocols performed, it is also noted from Fig. 3 that reduction in vitamin E content was predominantly caused by decomposition of tocotrienols. The presence of 1263

6 A. H. Ahmad Tarmizi and K. Ahmad Fig. 3 Amounts of remaining vitamin E (a), tocopherols (b) and tocotrienols (c) in palm olein during intermittent and continuous frying of extruded product. Means within the same frying interval marked with asterisks (*) are significantly different (p < 0.05). three double bonds at the side chain of tocotrienols is prone to degradation in comparison to their tocopherols counterparts 25. during storage and heating 26. The results showed in Table 4 exhibit a clear distinct for oil samples collected throughout the two frying protocols. Induction time dropped sharply by 30 just after one day of intermittent frying, and followed by a slow decrease for the remaining days. Surprisingly, the induction time regardless to frying intervals seemed comparable with that of fresh palm olein when frying was undertaken under continuous frying conditions. It is plausible that the frying temperature applied in this study was considerably low 155 in contrast to the conventional frying temperatures. Producing potato chips at 180 under continuous frying operation exhibited a decrease in the induction time during the first stage of frying before hovering within a constant value afterwards 13, 14. In fact, Ahmad Tarmizi and Ismail 14 even concluded that induction time has some relationship with the retention of vitamin E when palm olein is used for frying. 3.7 Polar compounds Quantification of polar compounds is recognised as the most reliable and accurate route to assess thermo-oxidative degradation in frying oils. This can be elaborated from the spectrum of non-volatility of the polar compound fractions i.e. polymerised and oxidised TAG, DAG and FFA developed during excessive heat treatment 25. Oils containing high level of polar compounds are potentially toxic and can be easily absorbed by human body 27. As such, many countries have opted to establish regulatory limits for polar compounds varying from 25 and 30 3, 22. The evolutions of polar compounds in palm olein across 5 days of intermittent and continuous frying are illustrated in Fig. 4. The level of polar compounds, in the case of the intermittent frying, increased linearly over frying time and the value was somewhat doubled at the end of frying session This trend, however, was only true for the first 2 days of continuous frying before the values pla- 3.6 Induction time Induction time is among the alternative methods used to examine the extent of oil to resist oxidation at elevated temperatures. Unlike PV and AnV which provide static measures of oils stability, the determination of induction time is dynamic and thus gives an insight on the fate of oil Fig. 4 Evolution of polar compounds in palm olein during intermittent and continuous frying of extruded product. Means within the same frying interval marked with asterisks (*) are significantly different (p < 0.05). 1264

7 Behaviour of palm olein for continuous frying of extruded product teaued between 9.2 and 9.3, which are significantly lower than the results obtained from the otherwise. Irrespective of frying protocols, none of the oil samples superseded the threshold value. Continuous frying of potato chips gave similar trends in polar compounds formation; the value peaked after 24 h of frying and remained constant within 10 to 11.4 until the end of 56 h of frying operation 13. It is also noted that fresh palm olein contained higher level of polar compounds because the oil is inherently enriched with DAG Table 3. Since DAG is one of the components of polar compounds, it could be sometimes misleading for judging the quality of palm olein albeit the oil is not even being introduced to high temperatures. 3.8 Colour Colour is a subjective and least preferred indicator for monitoring the quality of oils. Within all the frying protocols performed, oil colourisation was stimulated across frying times Table 4. It came to surprise that the oil collected during intermittent frying was the least coloured compared to continuous frying considering good frying performance in the latter protocol especially when the frying temperature was considerably low 155. At the end of frying session, the rate of colour pigmentation in palm olein in the case of continuous frying was somewhat double than the otherwise. This occurrence can be explained from the basis of frying load during the operation: the ratio between the product and the amount of oil inside the fryer was relatively much higher for continuous frying 0.3 kg L 1 as opposed to intermittent frying 0.02 kg L 1. Of course, higher production rate is likely to lead for higher degree of scorched product being generated and diffused into the oil, which in turns accelerates oil darkening. Palm olein appeared to be darker 21.2 R when potato chips were continuously fried for 56 h Ahmad Tarmizi and Ismail, The incidence of colour reversion in palm olein can be explained from the perspective of its inherent antioxidants content; trace pigments, tocopherols and particularly tocotrienols are susceptible to the formation of red-brown quinone polymer which can further cause oil colourisation upon exposure at elevated temperatures 25. Onal-Ulusoy et al. 28 relate colour reversion with the evolution of polarity in frying oil. 4 CONCLUSIONS The present study shows that the performance of palm olein was more pronounced when extruded product is processed under continuous frying conditions. This frying protocol significantly reduced the free fatty acid content and vitamin E loss whereas the induction period seemed unchanged over frying time. Consistent replenishment of fresh palm olein containing lower free fatty acid content and significant amount of vitamin E tocopherols and tocotrienols enabled the oil to reach an equilibrium state soon after two days of continuous frying. Contrariwise, compensation of oil for intermittent frying only took place on the next day of operation. Of course, lowering the acidity would results in oil with higher smoke point. The level of polar compounds in both cases was more or less similar and none of them surpassed the legislative limit for used oil. In consideration of the results above, the snack food manufacturers particularly from the small and medium industry can opt to shift from the conventional batch fryer to continuous frying system for processing snack food. ACKNOWLEDGEMENTS The authors express their appreciation to the Director General of Malaysian Palm Oil Board for permission to publish this research work. Sincere gratitude is also extended to the Director of Product Development and Advisory Services Division, Head of Protein and Food Technology Unit and members of the Innovative Products Group for their support and technical assistance. REFERENCES 1 Rossell, J. B. Factor affecting the quality of frying oils and fats. In Frying: Improving quality Rossell, J. B. ed. Woodhead Publishing Ltd., Cambridge, pp Velasco, J.; Marmesat, S.; Dobarganes, M. C. Chemistry of frying. In Advances in deep-fat frying of foods Sahin, S.; Sumnu, S. G. ed CRC Press, Boca Raton, pp Berger, K. G. The use of palm oil in frying. Malaysian Palm Oil Council, Selangor Romano, R.; Giordano, A.; Vitiello, S. L.; Grottaglie, L.; Musso, S. S. Comparison of the frying performance of olive oil and palm superolein. J. Food Sci. 77, C519- C Karoui, I. J.; Dhifi, W.; Jemia, M. B.; Marzouk, B. Thermal stability of corn oil flavoured with thymus capitatus under heating and deep-frying conditions. J. Sci. 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8 A. H. Ahmad Tarmizi and K. Ahmad Cont. 24, Negishi, H.; Nishida, M.; Endo, Y.; Fujimoto, K. Effect of a modified deep-fat fryer on chemical and physical characteristics of frying oil. J. Am. Oil Chem. Soc. 80, Aladedunye, F.; Przybylski, R. Protecting oil during frying: A comparative study. Eur. J. Lipid Sci. Technol. 111, Nazarbakhsh, V.; Ezzatpanah, H.; Tarzi, B. G.; Givianrad, M. H. Chemical changes of canola oil during frying under atmospheric condition and combination of nitrogen and carbon dioxide gases in the presence of air. J. Am. Oil Chem. Soc. 91, Pawar, D. P.; Boomathi, S.; Hathwar, S. C.; Rai, A. K.; Modi, V. K. Effect of conventional and pressure frying on lipids and fatty acid composition of fried chicken and oil. J. Food Sci. Technol. 50, Ahmad Tarmizi, A. H.; Niranjan, K.; Gordon, M. Physico-chemical changes occurring in oil when atmospheric frying is combined with post-frying vacuum application. Food Chem. 136, Ahmad Tarmizi, A. H.; Ismail, R. Use of pilot plant scale continuous fryer to simulate industrial production of potato chips: thermal properties of palm olein under continuous frying conditions. Food Sci. Nutr. 2, Ahmad Tarmizi, A. H.; Ismail, R. Comparison of the frying stability of standard palm olein and special quality palm olein. J. Am. Oil Chem. Soc. 85, Ismail, R. Palm oil and palm olein frying applications. Asia Pac. J. Clin. Nutr. 14, Kristott, J. Performance of high-oleic oils during frying in comparison with palm olein. Technical Communication 11, Britannia Food Ingredients Ltd., pp du Plessis, L. M.; Meredith, A. J. Palm olein quality parameter changes during industrial production of potato chips. J. Am. Oil Chem. Soc. 76, Sebedio, J. L.; Dobarganes, C.; Marquez, G.; Wester, I.; Christie, W. W.; Dobson, G.; Zwobada, F.; Chardigny, J. M.; Mairot, T. H.; Lahtinen, R. Industrial production of crisps and pre fried French fries using sunflower oils. Grasas Aceites 47, Firestone, D. Official methods and recommended practices of the AOCS. 6 th ed. American Oil Chemists Society. Champaign Dieffenbacher, A.; Pocillinton, W. D. Standard methods for the analysis of oils, fats and derivatives. 7 th ed. International Union of Pure and Applied Chemistry. Oxford Al-Khusaibi, M.; Ahmad Tarmizi, A. H.; Niranjan, K. On the possibility of non-fat frying using molten sugar. J. Food Sci. 80, E66-E Inturrisi, L. Regulatory and food safety requirements for frying oil quality. Presented at AAOCS Biennial Meeting Deep Frying Workshop, Newcastle Matthäus, B. Utilization of high-oleic rapeseed oil for deep-fat frying of French fries compared to other commonly used edible oils. Eur. J. Lipid Sci. Technol. 108, Tsaknis, J.; Lalas, S.; Protopapa, E. Effectiveness of the antioxidants BHA and BHT in selected vegetable oils during intermittent heating. Grasas y Aceites 53, Aladedunye, F.; Przybylski, R. Performance of palm olein and modified rapeseed, sunflower, and soybean oils in intermittent deep-frying. Eur. J. Lipid Sci. Technol. 116, Aladedunye, F.; Kersting, H. J.; Matthäus, B. Phenolic extract from wild rose hip with seed: Composition, antioxidant capacity, and performance in canola oil. Eur. J. Lipid Sci.Technol. 116, Petersen, K. D.; Jahreis, G.; Busch-Stockfisch, M.; Fritsche, J. Chemical an sensory assessment of deep-frying oil alternatives for the processing of French fries. Eur. J. Lipid Sci. Technol. 115, Onal-Ulusoy, B.; Tur, E.; Mutlu, M. Plasma modified membrane for daily recovery of oil from repeated frying operation with frequent oil replenishment. J. Am. Oil Chem. Soc. 90,

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