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1 Newer Processing Methods for the Extraction & Refining of Rice Bran Oil By S. M. Javed Husain MUEZ-HEST INDIA PVT. LTD. Global Rice Bran Oil Conference 2015 August 7-8 th 2015 Trident Hotel, Mumbai, India

2 Rice Bran Seed Rice is the seed of the monocot plants Oryza sativa (Asian rice) or Oryza Glaberrima (African rice). As a cereal grain, it is the most important staple food for a large part of the world's human population, especially in East Asia, Southeast Asia, South Asia, the Middle East, and the West Indies.

3 Global Rice Paddy Production & Area Source- Food & Agriculture Organization of United Nations

4 Extraction of Rice Bran Oil Raw Material Conditioning Hydraulic Pressing Meal Cooling Value Addition De Sludging Sludge Crude Oil By Products Refining RBD Oil

5 Characteristics Composition of Rice Bran Full Fat Rice Bran Semifat Rice Bran Defatted Rice Bran Whole Wheat Flour Moisture (%) Fat Content (%) Total Carbohydrate (%) Protein (%) Crude Fiber (%) Ash Content Silica Content (%) P Content (mg/g) γ- Oryzanol (%) Energy (kcal/100gm)

6 Physical & Chemical Properties of Crude & RBD Rice Bran Oil Characteristics Unit Value Crude Oil Refined Oil Iodine Value (gl 2 /100g) Peroxide Value (Meq/kg) Max Moisture (%) Max Colour Tintometer 20Y+2.8R 10Y+1.0R Acid Value (mg KoH/gm) Free Fatty Acid (As oleic Acid) (%) Max Saponification Value (mg KoH/gm) Unsaponifiable Matter % Oryzanol ppm Total Tocopherol mg/kg (0.02%) Smoke Point (Degree C) Fire Point (Degree C) Cloud Point (Degree C) Refractive Index at 25 0 C Specific Gravity at 25 0 C Density

7 Glyceride & Fatty Acid Composition of Rice Bran Oil Glycerides Content (%) Fatty Acid Content (%) Boiling Point (ºC/ 10 mmhg) Monoglycerides 5-6 Myristic Acid Diglyceride 2-3 Palmitic Acid Triglycerides Steric Acid Oleic Acid Linoleic Acid Linolenic Acid Archidic Acid

8 Physical Refining of Crude Rice Bran Oil with Value Addition Crude RBO Water Degumming Gums (Rice Lecithin ) Value Addition Degumming Agent (Enzyme) Enzymatic Assisted Conditioning Bleaching Agents Bleaching High Purity Fatty Acid Distillate Value Addition Filtration Dewaxing & Filtration Physical Refining Winterization & Filtration Spent Bleaching Agents Crude Wax Value Addition Fatty Acid with high content of tocopherol Value Addition Crude Wax Value Addition Refined RBO

9 Data Generated at Pilot Scale Processing Step Color Acid Number Phosphorous (ppm) Oryzanol wt % Crude Oil 44* Water Degumming 44* Enzymatic Conditioning 51* Bleaching 32** Dewaxing 27** *¼ cell ** 1 cell

10 Water Degumming

11 Enzymatic Dry Degumming

12 Factors affecting Enzymatic Degumming Enzyme Dosage Temperature ph Time

13 Steam Bleaching with PLF

14 PLC Automated Dewaxing ( Crystallization) PLC DISPLAY

15 Features of Crystallizer Muez Hest s Specialty Crystallizer. PLC Automated Dewaxing brings down Cloud Point below 6ºC.

16 Deodorization with Short Path Distillation

17 Features of Deodorizer with Short Path Distillation Controlled Temperature and Pressure High Vacuum Low Heat Transfer No Polymerization of Oil Low Trans Fat Formation in Oil High Retention of Oryzanol Content in Oil Low Mechanical Damage to Oil Optimum Steam Utilization Thermic Fluid can be used for longer time due to low temperature.

18 Winterization (Crystallization) for Cloud Point 0ºC

19 Lecithin Plant New Technology

20 Phospholipid Content & Composition of some selected Vegetable Oils Source % in Oil PC (%) PE (%) PI (%) *Soybean **Rice Bran Rapeseed Sunflower Groundnut Cottonseed Palm * Issue of GMO and Non GMO ** Free from issue of GMO Phospholipid Composition of both Soybean and Rice Bran Lecithins are almost similar Note :- PC : Phosphotidal Choline PE : Phosphotidal Ethanolamine,PI : Phosphotidal Inositol

21 Why Rice Bran Lecithin is Superior to Soya Lecithin? Fatty acid Soya lecithin Rice bran lecithin Rice bran lyso lecithin 14: : : : : : Acid Value of Rice Bran and Soya Lecithin: Rice Bran Lecithin More Oxidative Stability due to less content of Linoleic and Linolenic acids Rice Bran Lecithin contains Oryzanol and Tocotrienols which enhances its Value, hence very useful as efficient emulsifier, growth promoter and so on

22 Phospholipid Composition of Lyso Rice Lecithin Crude Rice Bran Oil Phosphatidyl Choline Phosphatidyl Etyhanolamine Dewaxed Rice Bran Oil Phosphatidyl Inositol Other Phospholipids Triglycerides Wax Carbohydrates, sterols, FFA Moisture

23 Properties & Uses of lecithin Emulsifiers Wetting Agents Viscosity Modifiers Release Agents Separating Agents Extrusion Aids Anti-Dusting Agents Shelf- Life Aids Nutritional Supplements

24 RICE BRAN OIL SAMPLES

25 Rice Bran Oil Samples Crude Rice bran Oil Rice Bran Bleached Oil Winterized Refined Rice Bran Oil COLOUR 1-20 UNITS FFA 0.07% COLOUR 1 -<8 UNITS CLOUD POINT- 0ºC

26 Facilities R&D Centre Drawing & Design Proto validation

27 MUEZ-HEST S Strategic Initiatives Drawing & Design Laboratory Pilot Plant

28 R & D Centre

29 R & D Lab

30 Pilot Plant

31 Recognition and Approvals

32 Thank You MUEZ-HEST INDIA PVT. LTD

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