Tomamine Ether Amines Product Guide

Transcription

1 Ether Amines Product Guide

2 About Us Evonik Corporation is the world s largest producer of ether amines and ether amine derivatives with an expertise in cationic and amphoteric surfactants. This market leading position starts from a strong commitment to invest in technology, research and people and is further developed through our strong relationships with customers. At the core of these strong relationships is our deeper understanding of our customer s needs and challenges. Our experienced technical team works hand-to-hand with customers to develop effective solutions. Whether it s an environmental benefit, improving the performance of an existing product, or making a production process more cost effective, customers are always looking for assistance and ways to do things better than others in their market. We have been providing that edge for over 40 years. Select product applications: Hard surface cleaning Laundry Emulsifiers Warewashing Foaming agents Solubilizers Metalworking Agricultural additives Formulating can be a complex process. This product guide offers a good starting point providing an overview of our ethoxylated alcohols and alkoxylated nonionic surfactants. For free samples or technical assistance please us at picus@evonik.com. 2

3 The Chemistry Ethoxylated Ether Amines Alcohols: Linear and Branched C 3 to C 20 Propoxylated Ether Amines Ether Nitriles Ether Diamines Ether Amine Quats Ether Amines Ether Amine Salts Ether Amine Oxides Ether Amine Amphoterics 3

4 General Product Overview Ether Amines aliphatic ether amines are a unique class of industrial chemicals with broad range properties. PA- and DAseries synthetic ether amines are produced by the reaction of an aliphatic alcohol with acrylonitrile. These unique primary ether amines can be used as additives or building blocks for many other surfactants with broad applications. Ether Amines (PA-Series) PA-10L Hexyloxypropyl amine PA-12EH 2-Ethylhexyloxypropyl amine PA-1214 Octyl/decyloxypropyl amine PA-14 Isodecyloxypropyl amine PA-1618 Dodecyl/tetradecyloxypropyl amine PA-17 Isotridecyloxypropyl amine PA-1816 Tetradecyl/dodecyloxypropyl amine PA-19 Linear alkyloxypropyl amine Ether Diamines (DA-Series) DA-1214 Octyl/decyloxypropyl-1,3-diaminopropane DA-14 Isodecyloxypropyl-1,3-diaminopropane DA-1618 Dodecyl/tetradecyloxypropyl-1, 3-diaminopropane DA-17 Isotridecyloxypropyl-1,3-diaminopropane Ethoxylated Amines (E-Series) E-14-2 bis-(2-hydroxyethyl) isodecyloxypropylamine E-14-5 poly (5) oxyethylene isodecyloxypropylamine E-17-2 bis-(2-hydroxyethyl) isotridecyloxypropylamine E-17-5 poly (5) oxyethylene isotridecyloxypropylamine E-T-2 bis-(2-hydroxyethyl) tallow amine (and 5 & 15-mole adducts) E-DT-3 N-tallow-poly (3) oxyethylene-1,3-diaminopropane Quaternary Amines Q % active isodecyloxypropyl bis-(2-hydroxyethyl) methyl ammonium chloride (Available in propylene glycol) Q % active isotridecyloxypropyl bis-(2-hydroxyethyl) methyl ammonium chloride (Available in propylene glycol) Q-S-70HG 70% active mono soya methyl ammonium chloride Q-DT-HG 50% active tallow diamine diquaternary Q-C % active coco poly (15) oxyethylene methyl ammonium chloride Emulsifier Four 75% active dialkyl quaternary designed for emulsification of non-polar hydrophobes, particularly mineral seal oil. Emulsifier Four HF A modified high-flash version of Emulsifier Four. The flash point is above 200 F Tomadry N-4 Drying Agent 100% active super-concentrated mineral seal oil-containing drying agent. Made with Emulsifier Four. 4

5 Tomadry N-3 Drying Agent 100% active non oil-containing super-concentrated drying agent. Contains ethylene glycol monobutyl ether. Tomadry N-5C Drying Agent 100% active non oil-containing drying agent. Designed for quick water break and water beading. Tomadry N-7 Drying Agent 100% active non oil-containing super-concentrated drying agent. Does not contain ethylene glycol monobutyl ether. Tomadry N-8 Drying Agent A high-flash version of Tomadry N-4. Made with Emulsifier Four HF. Emulsion C-340 A 18% active cationic emulsion of carnauba wax. Used for hot carnauba drying agents. Tomadry DAB Drying Additive A 100% active wax additive designed for formulation into a wide variety of transportation cleaning applications. Emulsifier 300 A balanced emulsifier for Mineral Seal Oil (MSO) and other hydrophobes in water used to optimize drying efficiency for vehicle care products. Emulsifier 300HF A high-flash version of Emulsifier 300. Amine Oxides (AO-Series) AO % active bis-(2-hydroxyethyl) isodecyloxypropylamine oxide AO % active linear alkyloxypropylamine oxide AO % active low-foam alkyloxypropylamine oxide AO % active low-foam alkyloxypropylamine oxide Amphoteric Surfactants Amphoteric L 37% active; high foaming hydrotrope Amphoteric SC 35% active; high foaming hydrotrope Amphoteric 16 33% active biodegradable; high foaming, hydrotroping surfactant Amphoteric LH 30% active; moderate foaming hydrotrope Alkali Surfactant 35% active; moderate foaming hydrotrope Amphoteric % active; low foaming hydrotrope Amphoteric 12 35% active biodegradable; low foaming, hydrotroping surfactant Acid Additives & Inhibitors Acid Foamer 100% active foaming additive for organic and inorganic acids. Acid Thickener 100% active thickener for organic and inorganic acids. Inhibitor 60S Acid inhibitor for hydrochloric acid and other acids. Inhibitor 60Q Acid inhibitor for many mineral acids. Asphalt & Coal Tar Sealant Additives PA-14 Acetate A patented 100% active cationic surfactant designed to wet various clays, fillers, and fibers resulting in a stable and desirable end-use viscosity for asphalt coatings and sealants. Tomadyne Surfactants Tomadyne 100 Surfactant 83% active; moderate-foaming degreaser Tomadyne 102 Surfactant 83% active; moderate-foaming, non-corrosive as classified by the DOT 5

6 PA-Series Ether Amines The PA-series synthetic ether amines are produced by the reaction of an aliphatic alcohol with acrylonitrile. These unique primary ether amines can be used as additives or building blocks for many other surfactants with broad applications. Ether amines have excellent low temperature liquidity. Some of the more popular uses for the PA-series products include: corrosion inhibitors, lubrication additives, fuel additives, and mineral flotation collectors. R-O- NH 2 Product R Equals Description PA-10L C 6 H 13 Hexyloxypropyl amine PA-12EH Branched C 8 H 17 2-Ethylhexyloxypropyl amine PA-1214 C 8 H 17 /C 10 H 21 Octyl/decyloxypropyl amine PA-14 Branched C 10 H 21 Isodecyloxypropyl amine PA-1618 C 12 H 25 /C 14 H 29 Dodecy/tetradecyloxypropyl amine PA-17 Branched C 13 H 27 Isotridecyloxypropyl amine PA-1816 C 14 H 29 /C 12 H 25 Tetradecyl/dodecyloxypropyl amine PA-19 C 12 H 25 /C 15 H 31 Linear alkyloxypropyl amine PA-Series Ether Amines TYPICAL PROPERTIES PA-10L PA-12EH PA-1214 PA-14 PA-1618 PA-17 PA-1816 PA-19 Molecular Wt Min. amine value Min. mole% primary amine Water content, %max Flash point, F 183 >200 >200 >200 >200 >200 >200 >200 SpG 25 C Gardner color, max Pour point, F Physical 25 C Liquid Liquid Liquid Liquid Liquid Liquid Paste Paste 6

7 DA-Series Ether Amines The DA-series synthetic ether diamines are produced by the reaction of an aliphatic alcohol with two moles of acrylonitrile. Like the PA-series, these unique ether diamines can be used as additives or building blocks for many other surfactants with broad applications use. The DA-series ether diamines have excellent low temperature liquidity. R-O- N H NH 2 Product R Equals Description DA-1214 C 8 H 17 /C 10 H 21 Octyl/decyloxypropyl-1,3-diaminopropane DA-14 Branched C 10 H 21 Isodecyloxypropyl-1,3-diaminopropane DA-1618 C 12 H 25 /C 14 H 29 Dodecyl/tetradecyloxypropyl-1, 3-diaminopropane DA-17 Branched C 13 H 27 Isotridecyloxypropyl-1,3-diaminopropane DA-Series Ether Amines TYPICAL PROPERTIES DA-1214 DA-14 DA-1618 DA-17 Molecular Wt Min. amine value Min. mole% primary amine Water content, %max Flash point, F >200 >200 >200 >200 SpG 25 C Gardner color, max Pour point, F Physical 25 C Liquid Liquid Paste Liquid 7

8 Ethoxylated Amines Evonik produces a wide range of ethoxylated ether amines and (CH ethoxylated fatty amines. These amines have been reacted with 2 O) x H various amounts of ethylene oxide to modify emulsification, R-O- N surface tension, solubility and cationic strength. Some of the ( O) n-x H more popular uses of the E-Series products include: acid thickening, microemulsification, detergent boosting, and textile processing aids. The E-Series ether amines are represented by the formula above, where R is the alkyl radical and n is the total number of moles of ethylene oxide. Product R Equals Description E-14-2 Branched C 10 H 21 bis-(2-hydroxyethyl) isodecyloxypropylamine E-14-5 Branched C 10 H 21 poly (5) oxyethylene isodecyloxypropylamine E-17-2 Branched C 13 H 27 bis-(2-hydroxyethyl) isotridecyloxypropylamine E-17-5 Branched C 13 H 27 poly (5) oxyethylene isotridecyloxypropylamine E-T-2 Stearic/Oleic bis-(2-hydroxyethyl) tallow amine Ethoxylated Amines TYPICAL PROPERTIES E-14-2 E-14-5 E-17-2 E-17-5 E-T-2 Molecular Wt Min. amine value % tertiary amine Flash point, F >200 >200 >200 >200 >200 SpG 25 C Gardner color, max Pour point, F Physical 25 C Liquid Liquid Liquid Liquid Paste Physical 25 C Liquid Liquid Liquid Paste Paste 8

9 E-series Ethoxylated Amines The E-Series amines have a broad range of applications. Some of the suggested uses include: Degreasers Anti-static agents Textile processing aids Cationic emulsification Detergent boosters Intermediates for the manufacture of quaternaries and amine oxides Ternary General Purpose Cleaner/Detergent Premium Laundry Detergent Terpene Microemulsion Degreaser Component Weight % Component Weight % Water 79.0 E-14-2 Surfactant 3.0 Tomadol 91-8 Surfactant 7.0 Alkali Surfactant 5.0 Tetrapotassium pyrophosphate 4.0 Sodium metasilicate pentahydrate 2.0 Total Component Weight % Dipentene E-14-5 Surfactant 6.4 E-14-2 Surfactant 0.8 Alkali Surfactant 0.8 Water 87.0 Total E-14-2 Surfactant 25.0 Q-17-2 PG Surfactant 25.0 Tomadol 91-6 Surfactant 50.0 Total Dilute 1 part of this blend with 99 parts of water. Lab studies have shown that the ternary blend is extremely effective without builders at high dilutions for degreasing hydrophobic paraffincontaining non-polar soils. 9

10 Quarternary Amines Evonik quaternary amines are based on the reaction of aliphatic tertiary amines with methyl chloride using isopropanol as a diluent. The Q-Series ether amine-based quats are represented by the formula, on page 11, where R is the alkyl R-O- N B ( O) x H ( O) n-x H CH 3 Cl v radical and n is the total number of moles of ethylene oxide. Q % active isodecyloxypropyl bis-(2-hydroxy-ethyl) methyl ammonium chloride (Available in propylene glycol as Q-14-2 PG) Q % active isotridecyloxypropyl bis-(2-hydroxyethyl) methyl ammonium chloride (Available in propylene glycol as Q-17-2 PG) Q-S-70HG 70% active mono soya methyl ammonium chloride in hexylene glycol Q-DT-HG 70% active tallow diamine diquaternary in hexylene glycol Q-C % active coco poly (15) oxyethylene methyl ammonium chloride Emulsifier Four 75% active dialkyl quaternary designed for emulsification of non-polar hydrophobes, particularly mineral seal oil. Emulsifier Four HF 75% active high flash version of Emulsifier Four. The flash point is above 200 F. Emulsifier 300 Balanced emulsifier for MSO and other hydrophobes in water used to optimize drying efficiency for vehicle care products. Emulsifier 300HF A high-flash version of Emulsifier 300. Quarternary Amines TYPICAL PROPERTIES Q-14-2 Q-17-2 Q-S-70HG Q-DT-HG Q-C-15 ph, 5% solution Molecular Wt Flash Point, F >200 >200 >200 SpG 25 C Gardner color, max Pour point, F Physical 25 C Liquid Liquid Liquid Liquid Liquid Emusifier TYPICAL PROPERTIES E-4 E-4HF HF lb/gal Active, % Diluent Ethylene Glycol Isopropanol Hexylene Glycol Color Amber Amber Physical Form Liquid Liquid 10

11 Q-series Quarternary Amines The Q-Series amines have broad range application. Some of the suggested uses include: Initial Foam Height vs. Foam Height after 5 Minutes 0.1% actives; 0 ppm 25 C ph 7.0 Ross-Miles Foam Height Corrosion inhibitors Anti-static agents Surfactants in non-butyl cleaning systems Cationic emulsification Detergent boosters Q-14-2 Q-17-2 Q-S-70HG Initial 5 Min. Q-DT-HG Q-C Foam Height (cm) Hard Surface Cleaning Performance Non-Butyl/Low VOC Formula vs. Other General Purpose Cleaners 1.0% active, 150 ppm 22 C Immersion Cleaning Performance Ternary General Purpose Cleaner/Detergent vs. d-limonene 0.1% active, 150 ppm 12 C Soil = lithium grease in motor oil Component SXS Formulations Evaluated: Q-14-2/ AO % Butyl d-limonene, 100% (solvent) Water 83.05% 88.00% 78.75% Q-14-2 Amine AO Amine Tomadol 91-6 Surfactant Sodium carbonate d-limonene, 1.0% (microemulsion) d-limonene, 0.1% (microemulsion) E-14-2/ Q-17-2/Tomadol 900 (1:1:2 ratio, 0.1%) % transmittance Sodium metasilicate (5H 2 O) EDTA Tetrasodium salt (39%) Tetrapotassium pyrophosphate Gardner Scrub Cleaning Performance Water SXS blend Sodium xylene sulfonate, 40% Ethylene glycol butyl ether Total % % % Q-14-2/ AO-14-2 blend 10% Butyl blend % Soil Removal 11

12 Amphoteric Surfactants Evonik amphoteric surfactants are designed for use in alkaline and acid cleaners. They offer exceptional coupling stability and wetting in a wide range of formulations that may contain other anionic, nonionic, and cationic surfactants. Scrub tests indicate improved detergency in formulations containing Amphoteric surfactants compared to formulations containing generic hydrotropes such as sodium xylene sulfonate. R-O- N O C O v Na B C OH O Amphoteric 12 35% active biodegradable; low foaming, hydrotroping surfactant Amphoteric % active; low foaming hydrotrope Alkali Surfactant 35% active; moderate foaming hydrotrope Amphoteric LH 30% active; moderate foaming hydrotrope Amphoteric 16 33% active biodegradable; high foaming, hydrotroping surfactant Amphoteric SC 35% active; high foaming hydrotrope Amphoteric L 37% active; high foaming hydrotrope % Hydrotrope Required to Couple an Alkaline Formulation Component Weight % NP KOH, 45% 20.0 Na Silicate 3.22/ Na Gluconate 2.0 Hydrotrope Water q.s. balance Amphoteric Surfactants Alkali TYPICAL PROPERTIES Surfactant LH SC L SpG 25 C Active, % Gardner color, max Flash point, F >212 >212 >212 >212 >212 >212 >212 >212 Pour point, F ph, 5.0% solution CMC,% (critical micelle conc.) Surface 0.1% (dynes/cm) in 2% NaOH

13 Amphoteric Surfactants Some of the suggested uses include: High & low foam alkaline cleaners Foamers for acid cleaners Hand & laundry soaps Mechanical foaming systems Shampoos & personal care products Amphoterics Caustic Solubility 1.0% active, 0 ppm 25 C Amphoteric 12 Amphoteric-400 Alkali Surfactant Amphoteric-LH Amphoteric 16 Amphoteric-SC SXS % Hydrotrope Required Amphoteric 12 Amphoteric-400 Alkali Surfactant Amphoteric-LH Amphoteric 16 Amphoteric-SC Amphoteric-L % NaOH Initial Foam Height vs. Foam height After 5 Minutes 0.1% actives; 150 ppm 25 C Ross-Miles Foam Height Hard Surface Cleaning Performance 2% Hydrotrope, 2% Soda Ash, 1.5% Na 2 SiO 3 5H 2 O, 1% Baypure CX-100 Amphoteric 12 Amphoteric-400 Alkali Surf Amphoteric-LH Amphoteric 16 Amphoteric-SC Amphoteric-L NP-9 Initial 5 Min. Amphoteric 12 Alkali Surfactant Amphoteric-LH Amphoteric 16 Amphoteric-SC Cocoimidazoline Dicarboxylate Immidzoline Carboxylate Cocoamphodipropionate Phosphate Ester SXS Foam Height (cm) % Soil Removed 13

14 Ether Amine Oxides Evonik ether amine oxides are excellent detergents, foam boosters and foam stabilizers. They are used in detergent formulations to provide grease emulsification and soil suspension. Amine oxides tend to act non-ionically in neutral and alkaline ph. Ether amine oxides are represented by the formula where R is the alkyl radical and n is the total number of moles of alkylene oxide. R-O- N O ( O) x H ( O) n-x H AO % active bis-(2-hydroxyethyl) isodecyl-oxypropylamine oxide AO % active linear alkyloxypropylamine oxide AO % active low-foam alkyloxypropylamine oxide AO % active low-foam alkyloxypropylamine oxide Ether Amine Oxides TYPICAL PROPERTIES AO-14-2 AO-728 AO-405 AO C Active, % Gardner Color, max Flash point, F >212 >212 Pour Point, F Physical form Liquid Liquid Liquid Liquid Surface 0.1% (dynes/cm)

15 Ether Amine Oxides The AO-Series has a broad range of applications. Some of the suggested uses include: Hard surface cleaning Foam stabilization Surfactants in non-butyl cleaning systems Grease emulsification Detergent Boosters Suggested Formulation Spray And Wipe Hard Surface Cleaner Component Weight % Water 96.5 Sodium Tripolyphosphate 1.0 Tomadol AO Initial Foam Height vs. Foam height After 5 Minutes 0.06% actives; 150 ppm 22 C, ph 7.0 Ross-Miles Foam Height AO-405 AO-455 AO-14-2 AO-728 Initial 5 Min Foam Height (cm) Component Hard Surface Cleaning Performance Non-Butyl/Low VOC Formula vs. Other General Purpose Cleaners 1.0% active, 150 ppm 22 C SXS Formulations Evaluated: Q-14-2/ AO % Butyl Water 83.05% 88.00% 78.75% Q-14-2 Surfactant AO Surfactant Tomadol 91-6 Surfactant Gardner Scrub Cleaning Performance Water Sodium carbonate Sodium metasilicate (5H 2 O) EDTA Tetrasodium salt (39%) SXS blend Q-14-2/ AO-14-2 blend 10% Butyl blend % Soil Removal Tetrapotassium pyrophosphate Sodium xylene sulfonate, 40% Ethylene glycol butyl ether Total % % % 15

16 Tomadry Drying Agents Tomadry N-4 Drying Agent Tomadry N-3 Drying Agent Tomadry N-5C Drying Agent Tomadry N-7 Drying Agent Tomadry N-8 Drying Agent Emulsion C-340 Tomadry DAB Drying Additive 100% active super-concentrated mineral seal oil-containing drying agent. Made with Emulsifier Four. 100% active non-oil containing super-concentrated drying agent. Contains ethylene glycol monobutyl ether. More biodegradable than mineral seal oil spraywax. 100% active non-oil containing drying agent. Designed for quick water break and water beading. Fast-acting and biodegradable. 100% active non-oil containing super-concentrated drying agent. Does not contain ethylene glycol monobutyl ether. More biodegradable than mineral seal oil spraywax. 100% active non-flammable drying agent. Made with Emulsifier Four HF. 18% active cationic emulsion of carnauba wax. 100% active wax additive designed for formulation into a wide variety of transportation cleaning applications to improve shine and protection. The Tomadry N-series are fully formulated super concentrates. Simply dilute 39 parts of concentrate with 61 parts of water. The resulting 39% active spraywax microemulsion is usually diluted 5 gallons to 50 gallons with water prior to use. Apply 4-6 ounces of the dilute spray wax per vehicle via a spray arch, wand or other delivery system. The Emulsifier Four, and Emulsifier Four HF, are dialkyl quaternary amine emulsifiers designed for formulating microemulsion concentrates. TYPICAL PROPERTIES Tomadry Dry Agent Emulsion N-4 N-3 N-5C N-7 N-8 DAB C-340 lb/gal Active, % None None None None None Water Diluent Ethylene Glycol Amber Amber Amber Amber Amber Black Color Liquid Liquid Liquid Liquid Liquid Liquid Physical Form Liquid Paste Liquid Liquid Liquid Liquid Liquid Suggested Formulation Drying Agent Concentrate Suggested Formulation On-Line Total Body Protectant Component Weight % Mineral Seal Oil 12.1 Emulsifier Ethylene glycol monobutyl ether 2.4 Water (cold, tap) 70.0 Total Component Weight % Emulsifier Mineral Seal Oil 9.3 Ethylene glycol monobutyl ether 1.8 Tomadry DAB 5.0 Water (cold, tap) 72.0 Total Charge the mineral seal oil, Emulsifier, and ethylene glycol monobutyl ether and mix until clear. Add the water slowly while mixing. When the water has been added, mix about 5 more minutes. Add dye & fragrance if desired. The carwash operator would use 1/3 to 1/2 oz. per car. Charge the Emulsifier 300, mineral seal oil, ethylene glycol monobutyl ether and Tomadry DAB and mix until clear. Add the water slowly while mixing. When the water has been added, mix about 5 more minutes. Add dye & fragrance if desired. The carwash operator would use 3/4 to 1 oz. per car. 16

17 Acid Additives and Inhibitors Evonik Acid Foamer and Acid Thickener are designed to foam and thicken most inorganic and organic acids. In addition to the acid additives, Evonik offers Inhibitors 60Q and 60S for corrosion protection of mild steel and stainless steel when exposed to inorganic and organic acids. Acid Foamer Acid Thickener Inhibitor 60Q Inhibitor 60S A cationic surfactant designed to provide dense, stable foam in strong acids such as hydrochloric, hydrofluoric and sulfuric acids. Acid Foamer provides 99% inhibition of HCl or H2SO4 on stainless steel. A cationic surfactant designed to thicken a variety of acids. A versatile and effective corrosion inhibitor for use in cleaning applications. It is designed to not darken in most acid solutions allowing for a lighter-colored acid-based product. A effective, less expensive version of Inhibitor 60Q. It can be used in acid cleaning applications where the acid color is not critical. TYPICAL PROPERTIES Acid Foamer Acid Additives and Inhibitors Acid Thickener Inhibitor 60Q Inhibitor 60S 25 C Active, % Gardner color, max Flash Point, F >212 > Physical 25 C Liquid Paste Liquid Liquid Suggested Formulation Acid Foamer Component HF Acid NH 4 Bifluoride Water 70.0% 64.0% Acid Foamer % Sulfuric Acid % Hydrofluoric Acid 17.0 Ammonium Bifluoride 13.0 Total 100.0% 100.0% Viscoity (cps) Acid Thickener with 9.0% HCl; 2.0% Phosphoric Acid Use Level vs. Viscosity Acid Thickener (Wt%) Suggested Formulation Acid Thickener Component Formulation #1 Formulation #2 Water 67.9% 77.7% 75% Phosphoric Acid Acid Thickener Tomadol 91-8 Surfactant Salt (NaCl) % Hydrochloric Acid 24.5 Perfume Total 100.0% 100.0% Formulation #1 25 C: 1750 cps Formulation #2 25 C: 1800 cps 17

18 Tomadyne Heavy-Duty Degreasers Tomadyne surfactants are designed for use in hard surface and industrial cleaning formulations including transportation cleaners for cars, trucks, buses, aircraft, as well as metal cleaning detergents for soak tanks and high-pressure spray systems. Tomadyne 100 Surfactant Tomadyne 102 Surfactant Tomakleen TFR II Surfactant Tomakleen G12 Designed to be affordable and efficient additives for use in water-based degreasing and hard surface cleaning applications. Both products are moderate-foaming surfactants. Tomadyne 100 Surfactant is classified as corrosive by the DOT while Tomadyne 102 Surfactant is classified as non-corrosive. Designed to be affordable and efficient. Reformulating aid for removing oxygenated solvents. Tomadyne 100 Tomadyne 102 TYPICAL PROPERTIES Surfactant Surfactant Color, Gardner 3 3 Active, % ph, 5% in Water Pour Point, F Cloud 1%, C SpG 25 C Flash Point, F >200 >200 Heavy-Duty Degreasers and Hard Surface Cleaners Ingredient Mild Formula Alkaline Formula Acid Formula Tomadyne 100 or 102 Surfactant 9.0% 9.0% 9.0% Tetrapotassium Pyrophosphate % Sodium Hydroxide % Phosphoric Acid Alkali Surfactant Sodium Metasilicate Pentahydrate Water Formulation Properties ph SpG 25 C

19 Global Regulatory Listings USA EMEA CaN Aus Jap South Korea China Philippines New Zealand Taiwan Product TSCA SaferChoice CleanGredients EINECS REACH EU Biodegradability* DSL Tomadry DAB Drying Additive Tomadry N-3 Drying Agent Tomadry N-4 Drying Agent Tomadry N-5C Drying Agent Tomadry N-7 Drying Agent Tomadry N-8 Drying Agent Tomadyne Tomadyne Tomadyne Acid Foamer Acid Thickener Alkali Surfactant Amphoteric Amphoteric Amphoteric Amphoteric L Amphoteric LH + Amphoteric SC Anticake AO AO AO AO DA DA DA DA E E E E E E-C E-C E-DT Emulsifier Emulsifier 300HF Emulsifier Four Emulsifier Four HF Emulsion C E-T Inhibitor 60Q Inhibitor 60S PA-10L** + + PA PA-12EH PA-14 Acetate PA PA PA PA Q Q Q-C Q-DT-HG Q-S-70HG Q-ST AICS ENCS ECL SEPA IECSC PICCS NZIoC CSNN *Biodegradable according to Annex III of Regulation (EC) No. 648/2004 **Not sold in the USA 19

20 Evonik Corporation 7201 Hamilton Blvd. Allentown, PA Outside U.S. and Canada For Technical Information and Support: Americas: picus@evonik.com EMEA: apcse@evonik.com For Samples: Americas: prodinfo@evonik.com Asia: picasia@evonik.com EMEA: apcse@evonik.com For Customer Service: US / Canada cspmd@evonik.com LASA lachem@evonik.com Japan pmdcsojp@evonik.com Asia PMD-Asia Customer Service: pmdcso@evonik.com APCS PMGP (Korea): apcskr@evonik.com EMEA: apcsepx@evonik.com The information contained herein is offered without charge for use by technically qualified personnel at their discretion and risk. All statements, technical information and recommendations contained herein are based on tests and data which we believe to be reliable, but the accuracy or completeness thereof is not guaranteed and no warranty of any kind is made with respect thereto. Evonik Corporation, US-AUG17 E