SAFETY DATA SHEET STP PETROL INJECTOR CLEANER
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1 Revision Date Revision 7 Supersedes date SAFETY DATA SHEET According to Regulation (EU) No 453/2010 SECTION 1: IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING 1.1. Product identifier Product name Product No , Relevant identified uses of the substance or mixture and uses advised against Identified uses Uses advised against Fuel additive. No specific uses advised against are identified Details of the supplier of the safety data sheet Supplier Armored Auto UK Ltd Unit 16, Rassau Industrial Estate Ebbw Vale Gwent NP23 5SD UK Tel: Fax: euregulatory@armoredautogroup.com 1.4. Emergency telephone number Monday - Thursday: Friday: SECTION 2: HAZARDS IDENTIFICATION 2.1. Classification of the substance or mixture Classification (1999/45/EEC) Xn;R65. R52/53, R66. Human health Droplets of the product aspirated into the lungs through ingestion or vomiting may cause a serious chemical pneumonia. Repeated exposure may cause skin dryness or cracking Label elements Contains KEROSENE Labelling Harmful Risk Phrases Safety Phrases R52/53 Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment. R65 Harmful: may cause lung damage if swallowed. R66 Repeated exposure may cause skin dryness or cracking. S2 Keep out of the reach of children. S24 Avoid contact with skin. 1 / 25
2 S46 If swallowed, seek medical advice immediately and show this container or label Other hazards This product does not contain any PBT or vpvb substances. SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS 3.2. Mixtures KEROSENE % CAS-No.: EC No.: Classification (EC 1272/2008) EUH066 Asp. Tox. 1 - H304 Classification (67/548/EEC) Xn;R65. R66. SOLVENT NAPHTHA (PETROLEUM), HEAVY AROMATIC 1-5% CAS-No.: EC No.: Registration Number: Classification (EC 1272/2008) EUH066 STOT SE 3 - H336 Asp. Tox. 1 - H304 Aquatic Chronic 2 - H411 Classification (67/548/EEC) Xn;R65. N;R51/53. R66,R67. POLYOLEFIN ALKYL PHENOL ALKYL AMINE 1-5% CAS-No.: EC No.: Classification (EC 1272/2008) Skin Irrit. 2 - H315 Classification (67/548/EEC) Xi;R38. 1,2,4-TRIMETHYLBENZENE 1-5% CAS-No.: EC No.: Classification (EC 1272/2008) Flam. Liq. 3 - H226 Acute Tox. 4 - H332 Skin Irrit. 2 - H315 Eye Irrit. 2 - H319 STOT SE 3 - H335 Aquatic Chronic 2 - H411 Classification (67/548/EEC) R10 Xn;R20 Xi;R36/37/38 N;R51/53 SOLVENT NAPHTHA (PETROLEUM), LIGHT AROM. (<0.1% BENZENE) 1-5% CAS-No.: EC No.: Classification (EC 1272/2008) Flam. Liq. 3 - H226 EUH066 STOT SE 3 - H335, H336 Asp. Tox. 1 - H304 Aquatic Chronic 2 - H411 Classification (67/548/EEC) Xn;R65. Xi;R37. N;R51/53. R10,R66,R67. 2 / 25
3 NAPHTHALENE < 1% CAS-No.: EC No.: Classification (EC 1272/2008) Acute Tox. 4 - H302 Carc. 2 - H351 Aquatic Acute 1 - H400 Aquatic Chronic 1 - H410 Classification (67/548/EEC) Carc. Cat. 3;R40 Xn;R22 N;R50/53 MESITYLENE < 1% CAS-No.: EC No.: Classification (EC 1272/2008) Flam. Liq. 3 - H226 STOT SE 3 - H335 Aquatic Chronic 2 - H411 Classification (67/548/EEC) R10 Xi;R37 N;R51/53 PROPYLBENZENE < 1% CAS-No.: EC No.: Classification (EC 1272/2008) Flam. Liq. 3 - H226 STOT SE 3 - H335 Asp. Tox. 1 - H304 Aquatic Chronic 2 - H411 Classification (67/548/EEC) R10 Xn;R65 Xi;R37 N;R51/53 The Full Text for all R-Phrases and Hazard Statements are Displayed in Section 16. SECTION 4: FIRST AID MEASURES 4.1. Description of first aid measures Inhalation Provide fresh air, warmth and rest, preferably in a comfortable upright sitting position. Get medical attention if any discomfort continues. Ingestion Never give liquid to an unconscious person. Rinse mouth thoroughly. Do not induce vomiting. If vomiting occurs, the head should be kept low so that stomach vomit doesn't enter the lungs. Get medical attention immediately! Skin contact Remove contaminated clothing immediately and wash skin with soap and water. Get medical attention promptly if symptoms occur after washing. Eye contact Immediately flush with plenty of water for up to 15 minutes. Remove any contact lenses and open eyes wide apart. Get medical attention if any discomfort continues Most important symptoms and effects, both acute and delayed Inhalation Vapour may irritate respiratory system or lungs. Ingestion May cause discomfort if swallowed. Droplets of the product aspirated into the lungs through ingestion or vomiting may cause a serious chemical pneumonia. Skin contact Prolonged contact may cause redness, irritation and dry skin. Eye contact Irritating and may cause redness and pain Indication of any immediate medical attention and special treatment needed 3 / 25
4 The severity of the symptoms described will vary dependant of the concentration and the length of exposure. SECTION 5: FIREFIGHTING MEASURES 5.1. Extinguishing media Extinguishing media Extinguish with foam, carbon dioxide, dry powder or water fog. Use fire-extinguishing media appropriate for surrounding materials. Unsuitable extinguishing media Do not use water jet as an extinguisher, as this will spread the fire Special hazards arising from the substance or mixture Hazardous combustion products Thermal decomposition or combustion may liberate carbon oxides and other toxic gases or vapours. Unusual Fire & Explosion Hazards Solvent vapours may form explosive mixtures with air Advice for firefighters Special Fire Fighting Procedures Avoid water in straight hose stream; will scatter and spread fire. Cool containers exposed to flames with water until well after the fire is out. Keep run-off water out of sewers and water sources. Dike for water control. Protective equipment for fire-fighters Self contained breathing apparatus and full protective clothing must be worn in case of fire. SECTION 6: ACCIDENTAL RELEASE MEASURES 6.1. Personal precautions, protective equipment and emergency procedures Wear protective clothing as described in Section 8 of this safety data sheet Environmental precautions Avoid discharge to the aquatic environment Methods and material for containment and cleaning up Wear necessary protective equipment. Stop leak if possible without risk. DO NOT touch spilled material! Extinguish all ignition sources. Avoid sparks, flames, heat and smoking. Ventilate. Ventilate well. Absorb in vermiculite, dry sand or earth and place into containers. Flush with plenty of water to clean spillage area. Do not let washing down water contaminate ponds or waterways. Containers with collected spillage must be properly labelled with correct contents and hazard symbol Reference to other sections Wear protective clothing as described in Section 8 of this safety data sheet. See section 11 for additional information on health hazards. Collect and dispose of spillage as indicated in section 13. SECTION 7: HANDLING AND STORAGE 7.1. Precautions for safe handling Read and follow manufacturer's recommendations. NOT for personal cleansing. Good personal hygiene is necessary. Wash hands and contaminated areas with water and soap before leaving the work site Conditions for safe storage, including any incompatibilities Keep away from heat, sparks and open flame. Store in tightly closed original container in a dry, cool and well-ventilated place Specific end use(s) The identified uses for this product are detailed in Section 1.2. SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION 8.1. Control parameters 4 / 25
5 Name STD TWA - 8 Hrs STEL - 15 Min Notes 1,2,4-TRIMETHYLBENZENE WEL 25 ppm 125 mg/m3 KEROSENE SUP 1000 mg/m3 MESITYLENE WEL 25 ppm 125 mg/m3 NAPHTHALENE WEL 10 ppm 53 mg/m3 15 ppm 80 mg/m3 WEL = Workplace Exposure Limit. Ingredient Comments SUP = Supplier's recommendation. 5 / 25
6 MESITYLENE (CAS: ) DNEL Worker Inhalation. Short Term Systemic Effects 100 mg/m3 Worker Inhalation. Short Term Local Effects 100 mg/m3 Worker Dermal Long Term Systemic Effects mg/kg/day Worker Inhalation. Long Term Systemic Effects 100 mg/m3 Worker Inhalation. Long Term Local Effects 100 mg/m3 Consumer Inhalation. Short Term Systemic Effects 29.4 mg/m3 Consumer Inhalation. Short Term Local Effects 29.4 mg/m3 Consumer Dermal Long Term Systemic Effects 9512 mg/kg/day Consumer Inhalation. Long Term Systemic Effects 29.4 mg/m3 Consumer Oral Long Term Systemic Effects 15 mg/kg/day Consumer Inhalation. Long Term Local Effects 29.4 mg/m3 PNEC Freshwater mg/l Marinewater mg/l Intermittent release mg/l STP 2.02 mg/l Sediment (Freshwater) 7.86 mg/kg Sediment (Marinewater) 7.86 mg/kg Soil 1.34 mg/kg 1,2,4-TRIMETHYLBENZENE (CAS: ) DNEL Worker Inhalation. Short Term Systemic Effects 100 mg/m3 Worker Inhalation. Short Term Local Effects 100 mg/m3 Worker Dermal Long Term Systemic Effects mg/kg/day Worker Inhalation. Long Term Systemic Effects 100 mg/m3 Worker Inhalation. Long Term Local Effects 100 mg/m3 Consumer Inhalation. Short Term Systemic Effects 29.4 mg/m3 Consumer Inhalation. Short Term Local Effects 29.4 mg/m3 Consumer Dermal Long Term Systemic Effects 9512 mg/kg/day Consumer Inhalation. Long Term Systemic Effects 29.4 mg/m3 Consumer Dermal Long Term Systemic Effects 9512 mg/kg/day Consumer Inhalation. Long Term Systemic Effects 29.4 mg/m3 Consumer Oral Long Term Systemic Effects 15 mg/kg/day Consumer Inhalation. Long Term Local Effects 29.4 mg/m3 PNEC Freshwater 0.12 mg/l Marinewater 0.12 mg/l Intermittent release 0.12 mg/l STP 2.41 mg/l Sediment (Freshwater) mg/kg Sediment (Marinewater) mg/kg Soil 2.34 mg/kg NAPHTHALENE (CAS: ) DNEL Consumer Dermal Long Term Systemic Effects 3.57 mg/kg/day Worker Inhalation. Long Term Systemic Effects 25 mg/m3 Worker Inhalation. Long Term Local Effects 25 mg/m3 PNEC Freshwater mg/l Marinewater mg/l Intermittent release 0.02 mg/l STP 2.9 mg/l Sediment (Freshwater) mg/kg Sediment (Marinewater) mg/kg Soil mg/kg 8.2. Exposure controls Protective equipment Process conditions Use engineering controls to reduce air contamination to permissible exposure level. 6 / 25
7 Engineering measures Provide adequate ventilation. Observe Occupational Exposure Limits and minimise the risk of inhalation of vapours. Hand protection For prolonged or repeated skin contact use suitable protective gloves. The most suitable glove must be chosen in consultation with the gloves supplier, who can inform about the breakthrough time of the glove material. Eye protection Wear approved, tight fitting safety glasses where splashing is probable. Hygiene measures Wash promptly if skin becomes contaminated. DO NOT SMOKE IN WORK AREA! When using do not eat, drink or smoke. No specific hygiene procedures noted, but good personal hygiene practices are always advisable, especially when working with chemicals. SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES 9.1. Information on basic physical and chemical properties Appearance Clear liquid. Colour Light (or pale). Yellow. Odour Hydrocarbon. Solubility Insoluble in water Melting point ( C) Data lacking. Relative density Vapour density (air=1) Data lacking. Vapour pressure Data lacking. Evaporation rate Data lacking. Evaporation Factor Data lacking. ph-value, Conc. Solution Data lacking. Viscosity Not determined. Solubility Value (G/100G H2O@20 C) Data lacking. Decomposition temperature ( C) Data lacking. Odour Threshold, Lower Data lacking. Flash point ( C) 70.5 C Auto Ignition Temperature ( C) Data lacking. Explosive properties Data lacking. Oxidising properties Not known Other information Not determined. SECTION 10: STABILITY AND REACTIVITY Reactivity Reaction with: Acids. Strong oxidising substances Chemical stability Stable under normal temperature conditions and recommended use Possibility of hazardous reactions 7 / 25
8 Hazardous Polymerisation Will not polymerise Conditions to avoid Avoid heat, flames and other sources of ignition Incompatible materials Materials To Avoid Strong oxidising substances Hazardous decomposition products Thermal decomposition or combustion may liberate carbon oxides and other toxic gases or vapours. SECTION 11: TOXICOLOGICAL INFORMATION Information on toxicological effects Acute toxicity: Skin Corrosion/Irritation: Serious eye damage/irritation: Germ cell mutagenicity: Carcinogenicity: Reproductive Toxicity: Specific target organ toxicity - repeated exposure: Repeated exposure may cause skin dryness or cracking. Aspiration hazard: Harmful: may cause lung damage if swallowed. Toxicological information on ingredients. PROPYLBENZENE (CAS: ) Acute toxicity: Acute Toxicity (Oral LD50) 6040 mg/kg Rat Miscellaneous information sources. Acute Toxicity (Inhalation LC50) ppm (vapour) Rat 2 hours Miscellaneous information sources. Specific target organ toxicity - single exposure: STOT SE 3 May cause respiratory irritation. Aspiration hazard: Asp. Tox. 1 May be fatal if swallowed and enters airways. 8 / 25
9 MESITYLENE (CAS: ) Acute toxicity: Acute Toxicity (Oral LD50) 6000 mg/kg Rat Read across data. Acute Toxicity (Dermal LD50) > 4 ml/kg Rat Read across data. Acute Toxicity (Inhalation LC50) mg/m³ (vapour) Rat 4 hours Read across data. Skin Corrosion/Irritation: Dose 0.5 ml 4 hr Rabbit Erythema\eschar score Well defined erythema (2). Irritating. Serious eye damage/irritation: Not Irritating. Respiratory or skin sensitisation: Skin sensitisation Guinea pig maximization test (GPMT): Guinea Pig Read across data. Not Sensitising. Germ cell mutagenicity: Genotoxicity - In Vitro Gene Mutation: Negative. Genotoxicity - In Vivo Chromosome aberration: Negative. Reproductive Toxicity: Reproductive Toxicity - Fertility Multigeneration study: NOAEC 500 ppm Inhalation. Rat F1 Read across data. Reproductive Toxicity - Development Developmental toxicity: NOAEC 1470 mg/m3 Inhalation. Rat Specific target organ toxicity - repeated exposure: STOT - Repeated exposure NOAEL 600 mg/kg Oral Rat Not classified as a specific target organ toxicant after repeated exposure. 9 / 25
10 1,2,4-TRIMETHYLBENZENE (CAS: ) Acute toxicity: Acute Toxicity (Oral LD50) 6000 mg/kg Rat Acute Toxicity (Dermal LD50) 4 ml/kg Rat Read across data. Acute Toxicity (Inhalation LC50) mg/m³ (vapour) Rat 4 hours Read across data. Skin Corrosion/Irritation: Dose 0.5 ml 4 hr Rabbit Erythema\eschar score Well defined erythema (2). Read across data. Irritating. Serious eye damage/irritation: Not Irritating. Read across data. Respiratory or skin sensitisation: Skin sensitisation Guinea pig maximization test (GPMT): Guinea Pig Read across data. Not Sensitising. Germ cell mutagenicity: Genotoxicity - In Vitro Gene Mutation: Negative. Genotoxicity - In Vivo Chromosome aberration: Negative. Reproductive Toxicity: Reproductive Toxicity - Fertility Multigeneration study: NOAEC 500 ppm Inhalation. Rat F1 Read across data. Reproductive Toxicity - Development Developmental toxicity: NOAEC 1470 mg/m3 Inhalation. Rat Specific target organ toxicity - repeated exposure: STOT - Repeated exposure NOAEL 600 mg/kg Oral Rat Read across data. Not classified as a specific target organ toxicant after repeated exposure. 10 / 25
11 NAPHTHALENE (CAS: ) Acute toxicity: Acute Toxicity (Oral LD50) > 2000 mg/kg Rat Acute Toxicity (Dermal LD50) > 2500 mg/kg Rat Acute Toxicity (Inhalation LC50) > 0.4 mg/l (vapours) Rat 4 hours Skin Corrosion/Irritation: Dose 0.5 g 24 hr Rabbit Primary dermal irritation index (PDI) 1.75 Erythema\eschar score Very slight erythema -barely perceptible (1). Oedema score Very slight oedema -barely perceptible (1). Not irritating. Serious eye damage/irritation: Not Irritating. Respiratory or skin sensitisation: Skin sensitisation Guinea pig maximization test (GPMT): Guinea Pig Not Sensitising. Germ cell mutagenicity: Genotoxicity - In Vitro Genome mutation: Negative. Genotoxicity - In Vivo Chromosome aberration: Negative. Carcinogenicity: Carcinogenicity Inhalation. Rat Limited evidence of a carcinogenic effect. IARC Carcinogenicity IARC Group 2B Possibly carcinogenic to humans. Reproductive Toxicity: Reproductive Toxicity - Development Developmental toxicity: NOAEC 150 mg/kg Oral Rat 11 / 25
12 Specific target organ toxicity - repeated exposure: STOT - Repeated exposure NOAEL 133 mg/kg Oral Mouse Not classified as a specific target organ toxicant after repeated exposure. 12 / 25
13 KEROSENE (CAS: ) Acute toxicity: Acute Toxicity (Oral LD50) > 5000 mg/kg Rat Acute Toxicity (Dermal LD50) > 2000 mg/kg Rabbit Acute Toxicity (Inhalation LC50) > 5.28 mg/l (vapours) Rat 4 hours Skin Corrosion/Irritation: Dose 0.5 ml 24 hr Rabbit Erythema\eschar score Moderate to severe erythema (3). Oedema score Slight oedema - edges of area well defined by definite raising (2). Irritating. Serious eye damage/irritation: Not Irritating. Respiratory or skin sensitisation: Skin sensitisation Buehler test: Guinea Pig Not Sensitising. Germ cell mutagenicity: Genotoxicity - In Vitro Gene Mutation: Negative. Genotoxicity - In Vivo Chromosome aberration: Negative. Carcinogenicity: Carcinogenicity LOAEL 250 mg/kg Dermal Mouse No evidence of carcinogenicity in animal studies Reproductive Toxicity: Reproductive Toxicity - Fertility Fertility: NOAEL 750 mg/kg Oral Rat P Reproductive Toxicity - Development Maternal toxicity: NOAEC >= 364 ppm Inhalation. Rat 13 / 25
14 Specific target organ toxicity - repeated exposure: STOT - Repeated exposure NOAEL 750 mg/kg Oral Rat Not classified as a specific target organ toxicant after repeated exposure. 14 / 25
15 SOLVENT NAPHTHA (PETROLEUM), HEAVY AROMATIC (CAS: ) Acute toxicity: Acute Toxicity (Oral LD50) > 5000 mg/kg Rat Acute Toxicity (Dermal LD50) > 2000 mg/kg Rabbit Acute Toxicity (Inhalation LC50) > 5.28 mg/l (vapours) Rat 4 hours Skin Corrosion/Irritation: Dose 0.5 ml 24 hr Rabbit Erythema\eschar score Moderate to severe erythema (3). Oedema score Slight oedema - edges of area well defined by definite raising (2). Irritating. Serious eye damage/irritation: Not Irritating. Respiratory or skin sensitisation: Skin sensitisation Buehler test: Guinea Pig Not Sensitising. Germ cell mutagenicity: Genotoxicity - In Vitro Gene Mutation: Negative. Genotoxicity - In Vivo Chromosome aberration: Negative. Carcinogenicity: Carcinogenicity LOAEL 250 mg/kg/day Dermal Mouse No evidence of carcinogenicity in animal studies Reproductive Toxicity: Reproductive Toxicity - Fertility Fertility: NOAEL 750 mg/kg/day Oral Rat P Reproductive Toxicity - Development Maternal toxicity: NOAEC >= 364 ppm Inhalation. Rat 15 / 25
16 Specific target organ toxicity - repeated exposure: STOT - Repeated exposure NOAEL 750 mg/l/6hr/day Oral Rat Aspiration hazard: Viscosity Kinematic viscosity <= 20.5 mm2/s. Harmful: may cause lung damage if swallowed. POLYOLEFIN ALKYL PHENOL ALKYL AMINE Acute toxicity: Irritating to eyes and skin. 16 / 25
17 SOLVENT NAPHTHA (PETROLEUM), LIGHT AROM. (<0.1% BENZENE) (CAS: ) Acute toxicity: Acute Toxicity (Oral LD50) > 5000 mg/kg Rat Acute Toxicity (Dermal LD50) > 2000 mg/kg Rabbit Acute Toxicity (Inhalation LC50) > 5610 mg/m³ (vapour) Rat 4 hours Skin Corrosion/Irritation: Dose 0.5 ml 4 hr Rabbit Erythema\eschar score Well defined erythema (2). Oedema score Slight oedema - edges of area well defined by definite raising (2). Irritating. Serious eye damage/irritation: Not Irritating. Respiratory or skin sensitisation: Skin sensitisation Buehler test: Guinea Pig Not Sensitising. Germ cell mutagenicity: Genotoxicity - In Vitro Gene Mutation: Negative. Genotoxicity - In Vivo Chromosome aberration: Negative. Carcinogenicity: Carcinogenicity NOAEL 0.05 ml Dermal Mouse This substance has no evidence of carcinogenic properties. IARC Carcinogenicity Not listed. Reproductive Toxicity: Reproductive Toxicity - Fertility Screening: NOAEL mg/m3 Inhalation. Rat F1 17 / 25
18 Reproductive Toxicity - Development Maternal toxicity: NOAEL mg/m3 Inhalation. Rat SECTION 12: ECOLOGICAL INFORMATION Toxicity Acute Fish Toxicity Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment. 18 / 25
19 Ecological information on ingredients. PROPYLBENZENE (CAS: ) Acute Fish Toxicity Toxic to aquatic organisms. Acute Toxicity - Fish LC50 96 hours 1.55 mg/l Onchorhynchus mykiss (Rainbow trout) MIscellaneous information sources. Acute Toxicity - Aquatic Invertebrates EC50 24 hours 2 mg/l Daphnia magna MIscellaneous information sources. MESITYLENE (CAS: ) Acute Toxicity - Fish LC50 96 hours mg/l Carassius auratus (Goldfish) Acute Toxicity - Aquatic Invertebrates LC50 48 hours 6 mg/l Daphnia magna Acute Toxicity - Aquatic Plants EC50 48 hours 25 mg/l Desmodesmus subspicatus Chronic Toxicity - Aquatic Invertebrates NOEC 21 days 2 mg/l Daphnia magna 1,2,4-TRIMETHYLBENZENE (CAS: ) Acute Toxicity - Fish LC50 96 hours 7.72 mg/l Pimephales promelas (Fat-head Minnow) Acute Toxicity - Aquatic Invertebrates EC50 48 hours 3.6 mg/l Daphnia magna Acute Toxicity - Aquatic Plants EC50 96 hours mg/l Freshwater algae Estimated Value NAPHTHALENE (CAS: ) Acute Toxicity - Fish LC50 96 hours 6.08 mg/l Pimephales promelas (Fat-head Minnow) Acute Toxicity - Aquatic Invertebrates EC50 48 hours 2.16 mg/l Daphnia magna Acute Toxicity - Microorganisms IC50 24 hours 29 mg/l Nitrosomonas sp. KEROSENE (CAS: ) Acute Toxicity - Fish LL50 96 hours 2-5 mg/l Onchorhynchus mykiss (Rainbow trout) Acute Toxicity - Aquatic Invertebrates EL50 48 hours 1.4 mg/l Daphnia magna Acute Toxicity - Aquatic Plants EL50 72 hours 1-3 mg/l Pseudokirchnerella subcapitata Chronic Toxicity - Aquatic Invertebrates EL50 21 days 0.89 mg/l Daphnia magna SOLVENT NAPHTHA (PETROLEUM), HEAVY AROMATIC (CAS: ) Acute Toxicity - Fish LL50 96 hours 2-5 mg/l Onchorhynchus mykiss (Rainbow trout) Acute Toxicity - Aquatic Invertebrates 19 / 25
20 EL50 48 hours 1.4 mg/l Daphnia magna Acute Toxicity - Aquatic Plants EL50 72 hours 1-3 mg/l Pseudokirchnerella subcapitata Acute Toxicity - Microorganisms NOEL 72 hours mg/l Tetrahymena pyriformis Estimated Value Chronic Toxicity - Fish Early life Stage NOEL 28 days mg/l Onchorhynchus mykiss (Rainbow trout) Estimated Value Chronic Toxicity - Aquatic Invertebrates EL50 21 days 0.89 mg/l Daphnia magna NOEL 21 days 0.48 mg/l Daphnia magna POLYOLEFIN ALKYL PHENOL ALKYL AMINE Acute Fish Toxicity Not considered toxic to fish. SOLVENT NAPHTHA (PETROLEUM), LIGHT AROM. (<0.1% BENZENE) (CAS: ) Acute Toxicity - Fish LL50 96 hours 8.2 mg/l Onchorhynchus mykiss (Rainbow trout) Acute Toxicity - Aquatic Invertebrates EL50 48 hours 4.5 mg/l Daphnia magna Acute Toxicity - Aquatic Plants EL50 72 hours 3.1 mg/l Pseudokirchnerella subcapitata Acute Toxicity - Microorganisms EC50 40 hours mg/l Tetrahymena pyriformis Persistence and degradability Degradability There are no data on the degradability of this product. 20 / 25
21 Ecological information on ingredients. PROPYLBENZENE (CAS: ) Degradability May cause long-term adverse effects in the aquatic environment. MESITYLENE (CAS: ) Biodegradation Water Degradation (50%) 4.4 days Estimated Value The substance is readily biodegradable. 1,2,4-TRIMETHYLBENZENE (CAS: ) Degradability There are no data on the degradability of this product. NAPHTHALENE (CAS: ) Biodegradation Soil Degradation (90%) 10 days Water Degradation (99.9%) 15.2±8.4 days The substance is readily biodegradable. KEROSENE (CAS: ) Degradability There are no data on the degradability of this product. SOLVENT NAPHTHA (PETROLEUM), HEAVY AROMATIC (CAS: ) Degradability No data available. POLYOLEFIN ALKYL PHENOL ALKYL AMINE Degradability There are no data on the degradability of this product. SOLVENT NAPHTHA (PETROLEUM), LIGHT AROM. (<0.1% BENZENE) (CAS: ) Degradability There are no data on the degradability of this product Bioaccumulative potential Bioaccumulative potential No data available on bioaccumulation. 21 / 25
22 Ecological information on ingredients. PROPYLBENZENE (CAS: ) Bioaccumulative potential No data available on bioaccumulation. MESITYLENE (CAS: ) Bioaccumulation factor BCF 161 Pimephales promelas (Fat-head Minnow) Estimated Value Partition coefficient log Pow ,2,4-TRIMETHYLBENZENE (CAS: ) Bioaccumulation factor BCF 243 Pimephales promelas (Fat-head Minnow) Estimated Value Partition coefficient log Pow 3.63 NAPHTHALENE (CAS: ) Bioaccumulative potential Will not bio-accumulate. Bioaccumulation factor BCF Partition coefficient log Pow 25 C KEROSENE (CAS: ) Bioaccumulative potential No data available on bioaccumulation. SOLVENT NAPHTHA (PETROLEUM), HEAVY AROMATIC (CAS: ) Bioaccumulative potential No data available on bioaccumulation. POLYOLEFIN ALKYL PHENOL ALKYL AMINE Bioaccumulative potential No data available on bioaccumulation. SOLVENT NAPHTHA (PETROLEUM), LIGHT AROM. (<0.1% BENZENE) (CAS: ) Bioaccumulation factor BCF Estimated Value Mobility in soil Mobility: No data available. 22 / 25
23 Ecological information on ingredients. PROPYLBENZENE (CAS: ) Mobility: No information available. MESITYLENE (CAS: ) Adsorption/Desorption Coefficient Soil log Koc 2.87 Estimated Value 1,2,4-TRIMETHYLBENZENE (CAS: ) Adsorption/Desorption Coefficient Soil log Koc 3.04 Estimated Value NAPHTHALENE (CAS: ) Adsorption/Desorption Coefficient Soil Koc 10 C KEROSENE (CAS: ) Mobility: No data available. SOLVENT NAPHTHA (PETROLEUM), HEAVY AROMATIC (CAS: ) Mobility: The product is insoluble in water. POLYOLEFIN ALKYL PHENOL ALKYL AMINE Mobility: No information available. SOLVENT NAPHTHA (PETROLEUM), LIGHT AROM. (<0.1% BENZENE) (CAS: ) Adsorption/Desorption Coefficient Soil log Koc Estimated Value Results of PBT and vpvb assessment Not determined Other adverse effects Not determined. SECTION 13: DISPOSAL CONSIDERATIONS Waste treatment methods Dispose of waste and residues in accordance with local authority requirements. Recover and reclaim or recycle, if practical. SECTION 14: TRANSPORT INFORMATION General The product is not covered by international regulation on the transport of dangerous goods (IMDG, IATA, ADR/RID) UN number Not applicable UN proper shipping name Not applicable Transport hazard class(es) Transport Labels No transport warning sign required Packing group Not applicable. 23 / 25
24 14.5. Environmental hazards Environmentally Hazardous Substance/Marine Pollutant No Special precautions for user Not applicable Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code Not applicable. SECTION 15: REGULATORY INFORMATION Safety, health and environmental regulations/legislation specific for the substance or mixture Statutory Instruments The Chemicals (Hazard Information and Packaging for Supply) Regulations 2009 (S.I 2009 No. 716). Guidance Notes Workplace Exposure Limits EH40. EU Legislation Regulation (EC) No 1272/2008 of the European Parliament and of the Council of 16 December 2008 on classification, labelling and packaging of substances and mixtures, amending and repealing Directives 67/548/EEC and 1999/45/EC, and amending Regulation (EC) No 1907/2006 with amendments. Water hazard classification WGK Chemical Safety Assessment No chemical safety assessment has been carried out. SECTION 16: OTHER INFORMATION Revision Comments Modification to substance classification due to new information from raw material supplier. No change to product classification. Revision Date Revision 7 Supersedes date Risk Phrases In Full R10 R20 R22 R52/53 R65 R36/37/38 R37 R38 R40 R66 R51/53 R67 R50/53 Flammable. Harmful by inhalation. Harmful if swallowed. Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment. Harmful: may cause lung damage if swallowed. Irritating to eyes, respiratory system and skin. Irritating to respiratory system. Irritating to skin. Limited evidence of a carcinogenic effect. Repeated exposure may cause skin dryness or cracking. Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. Vapours may cause drowsiness and dizziness. Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. 24 / 25
25 Hazard Statements In Full EUH066 H226 H302 H304 H315 H319 H332 H335 H336 H351 H400 H410 H411 H412 Repeated exposure may cause skin dryness or cracking. Flammable liquid and vapour. Harmful if swallowed. May be fatal if swallowed and enters airways. Causes skin irritation. Causes serious eye irritation. Harmful if inhaled. May cause respiratory irritation. May cause drowsiness or dizziness. Suspected of causing cancer. Very toxic to aquatic life. Very toxic to aquatic life with long lasting effects. Toxic to aquatic life with long lasting effects. Harmful to aquatic life with long lasting effects. Disclaimer The information supplied here is accurate to the best knowledge and belief of Armored Auto UK Ltd, it is however, not intended as a warranty or representation, and should not be construed as such, for which Armored Auto UK Ltd assumes any legal responsibility. Any information or advice obtained from Armored Auto UK Ltd other than by means of this publication, and whether relating to Armored Auto UK Ltd's products or other materials is also given in good faith. It remains at all times the sponsibility of the customer, and user, to ensure that the materials are suitable for the particular purpose intended. Materials not manufactured, or supplied, by Armored Auto UK Ltd when used instead of, or in conjunction with materials supplied by Armored Auto UK Ltd, it is the customer's responsibility to ensure that all technical, and other information related to such materials is obtained from the manufacturer or supplier. Armored Auto UK Ltd accepts no liability for the data contained within this document, as the information herein may be applied under conditions beyond our control, and in situations with which we may be unfamiliar. The information contained within this document is furnished upon condition that the customer and user of this product makes his own determination of the suitability of the product for his particular purpose. 25 / 25
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