MATERIAL SAFETY DATA SHEET FOR BORA-GUARD. INTRODUCTION Ist JANUARY 2006
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1 Page 1 of 5 INTRODUCTION Ist STATEMENT OF HAZARDOUS NATURE: NOT CLASSIFIED AS A HAZARDOUS SUBSTANCE NOT CLASSIFIED AS A DANGEROUS GOOD UNDER THE ADG CODE. COMPANY DETAILS: Mabon's Timber Protection Australia P/L, ACN STREET ADDRESS: 64 Whitby Street, BRACKEN RIDGE Q 4017 POSTAL ADDRESS: P.O. Box 3097, BRACKEN RIDGE Q 4017 TELEPHONE NO: (61) (07) FAX NO: (61) (07) EMERGENCY TELEPHONE NO: FREECALL: (Australia Only) Product Name: PRODUCT IDENTIFICATION Mabon's Product code BORA-- APVMA approval # 55851/5L/0905, 55851/10L/0905, 55851/200/0905 UN Number: None allocated Dangerous Goods Class: Subsidiary Risk: Toxic Substances Schedule: Caution Schedule 5 NFPA: (Health: 1) - (Flammability: 0) - (Reactivity: 0) Packing Group: IMDG: Use: Insecticide, termiticide, fungicide, algaecide, mouldicide and slimeacide for preventative and remedial treatment of timber, brick and other porous masonry finishes. Flame retardant PHYSICAL DESCRIPTION/PROPERTIES Appearance: Clear colourless liquid with a sweet smell. Form: Liquid Boiling Point: >100 C Melting Point: <0 C Vapour pressure: Relatively non-volatile Vapour density: Volatile Component: Not available Specific gravity: Flash Point: >110 C Flammability Limits: Autoignition Temp: >400 C Solubility in water: 100% INGREDIENTS:
2 Page 2 of 5 Chemical Entity CAS. # Proportion Disodium Octaborate Tetrahydrate % Benzalkonium Chloride <10% Mono Ethylene glycol % Water To 100% HEALTH HAZARD INFOPRMATION Acute Effects: Swallowed: Harmful if swallowed. May cause nausea, vomiting, diarrhoea and abdominal pain. Central nervous system stimulation followed by depression may occur following ingestion of large quantities. Eye: Skin: Inhaled: Irritating to eyes. Harmful in contact with skin. Irritant. Prolonged or repeated exposure may lead to defatting of the skin which could cause secondary dermatitis. Irritant. Inhalation of mist may cause headache, nausea and irritation of the throat and respiratory tract. Chronic Effects: Kidney and liver damage may result from chronic exposure. Chronic exposure may cause hair loss, weight loss and diarrhoea. Ethylene glycol is a suspected teratogen. Boraguard has a bittering agent included in the formulation. Repeated exposure to ethylene glycol may lead to skin allergy. First Aid: Swallowed: Never give anything by mouth to an unconscious person. If swallowed, and if more than 15 minutes for a hospital, induce vomiting, preferably using Ipecac syrup APF. If poisoning occurs, contact a doctor or Poisons Information Centre immediately Eye: In case of contact with eyes, rinse immediately with plenty of water and contact a doctor or Poisons Information Centre Skin: After contact with skin, wash immediately with plenty of warm soapy water. Seek medical assistance if large area involved. Inhaled: Remove victim to fresh air. Lay patient down and keep warm and rested. If breathing is shallow or has stopped, ensure airway is clear and apply resuscitation. Seek medical assistance. FIRST AID FACILITIES: Ensure an eye wash and safety showers are available and ready for use.
3 Page 3 of 5 ADVICE TO DOCTOR: Treat symptomatically. Early diagnosis and treatment of ingestion is important. Ensure emesis is satisfactory. Test for correct metabolic acidosis and hypocalcaemia. If evidence of renal insufficiency apply rapid and sustained diuresis with the use of hypertonic mannitol. Evaluate renal status and begin haemodialysis if indicated PRECAUTIONS FOR USE Exposure Standards: Workplace exposure standards: TWA WES-C Mono ethylene glycol - 50ppm (127mg/ m 3 ) Borax 1mg/ m 3 Engineering Controls: Good Ventilation required. Local exhaust should be provided if handled in confined areas. Personal Protection: Wear eye protection in the form of goggles, PVC or rubber gloves, PVC boots and overalls should be worn when manufacturing or handling the concentrated product. An organic vapour respirator should be used during any spraying operations. Flammability: Not flammable. SAFE HANDLING INFORMATION Storage and Transport: Road Transport: Not listed in Australia Sea Transport: Not listed in IMDG code 1990 Storage: Store in a dry place away from foodstuffs at all times. Store away from sources of heat or ignition. Spills and Disposal: Wear protective clothing as above. Do not allow into drains or water courses. Contain spill by absorbing with sand, earth or other absorbent material. Wash down spill area with copious quantities of water. Waste and empty containers must be disposed on it accordance with local government regulations. Dispose of by liaising with a waste disposal company or by disposing at a site approved by relevant local authorities.
4 Page 4 of 5 Prevent spillages from entering waterways. Reactivity Data: Stable. Avoid strong acids and oxidising agents. Fire/Explosion Hazard: Not flammable. Use water spray to cool containers threatened by fire. Use alcohol foam, water fog, dry chemical or carbon dioxide to extinguish. ADDITIONAL INFORMATION TOXICITY DATA: Product: Oral LD50 (rat) mg/kg Disodium octaborate Oral LD50 (rat) mg/kg tetrahydrate: Oral LD50 (guinea pig) mg/kg Benzalkonium chloride: Oral LD50 (rat) - 240ml/kg Skin LD50 (rat) mg/kg Human eye - 50μg SEV Mono ethylene glycol: Oral LD50 (rat) mg/kg Lower lethal dose (human) mg/kg ECOLOGICAL INFORMATION Phytotoxicity: Although boron is an essential micronutrient for healthy growth of boron-sensitive plants, it can be harmful to plants in higher quantities. Plants and trees can easily be exposed by root absorption to toxic levels of boron in the form of water-soluble borate leached into nearby soil or waters. Care should be taken to minimize the amount of borate product released to the environment. Fish Toxicity: Boron naturally occurs in seawater at an average concentration of 5 mg 13/liter. In laboratory studies the acute toxicity (96-hr LC.) for under-yearling Coho salmon (Onchorhynchus kisutch) in seawater was determined as 40 mg B/L (added as sodium metaborate). Boron concentrations in fresh surface waters are generally less than 1 mg B/L. Laboratory studies on the toxicity of freshwater fish were determined using early life (embryo larval) stages in natural water and Boric Acid as a test substance. The results were: Rainbow trout (S. gairdneri) 24-day LC50 =l50.0 mg B/L 36-day NOEC-LOEC= mg B/L Goldfish (Carassius auratus) 7-day NOEC-LOEC=26.50 mg B/L 3-day LC.0=178 mg B/L Invertebrate Toxicity: The acute toxicity (48-hour LC.) to Daphnia (Daphnia magna Straus) in natural water is reported to be 133 mg B/L (added as Boric Acid). Estimated chronic toxicity (21 -day NOEC-LOEC) values of 6-13 mg B/L (added as Boric Acid) have also been reported.
5 Page 5 of 5 ENVIRONMENTAL FATE DATA: Persistence/Degradation: Boron is naturally occurring and ubiquitous in the environment. Disodium Octaborate Tetrahydrate decomposes in the environment to natural borate. Soil Mobility: The product is soluble in water and is leachable through normal soil. NOTE: Boron (B) is the element in Disodium Octaborate Tetrahydrate which is used to characterize borate product ecological effects. To convert Disodium Octaborate Tetrahydrate data to Boron (B), multiply by Acknowledgements to US Borax and USA EPA CONTACT POINTS: Mabon's Timber Protection Australia Pty Ltd Mabon's 24 HOUR EMERGENCY NUMBERS Business hours FREECALL (Australia Only) After Hours: (61 7) FIRE OR POLICE IN AN EMERGENCY, DIAL hr Emergency No: Poisons Centre Phone: The information contained herein is based on data available to MABON S TIMBER PROTECTION from both our own technical sources and from recognised published references and is believed to be both accurate and reliable. Since we cannot anticipate or control the many different conditions under which this information and our products may be used, each user should review these recommendations in the specific context of the intended application and confirm whether they are applicable.
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