Jan 2016 AEROSOL SOLVENTS. Solstice PF Solvent for Aerosol Applications

Transcription

1 Jan 2016 AEROSOL SOLVENTS Solstice PF Solvent for Aerosol Applications

2 Solstice PF (HFO-1233zd(E)) 1 Honeywell's Solstice Performance Fluid (PF) is a highly effective solvent that is non-flammable, has favorable toxicity properties and a low GWP. Cl H Environmentally preferred Improved safety VOC exempt, GWP = 1 Superior performance with flexible compatibility H C C CF 3 Nomenclature INCI - Chlorotrifluoropropene Trans- 1-chloro-3,3,3-trifluoropropene 1-chloro-3,3,3-trifluoroprop-1-ene,(1E) HFO-1233zd

3 2 Performance Low pressure: 1.4 PSIG at 70 F (21 C) Liquid density: 1.3 g/cc at 70 F (21 C) High degree of solvency: KB Value 25 Excellent solvency in a wide variety of solutes: Mineral oil and other hydrocarbon oils Silicone oils, silicone greases Soy lecithin Fluorinated oils, refrigerant oils Acrylics Cutting oils, hydraulic fluids Essential oils Very low surface tension provides excellent wetting Surface tension of 12.7 dynes/cm is lower than most other halogenated solvents Useful as a Cleaning Solvent and a Carrier Solvent

4 Safety and Environmental Impact 3 Notable Properties GWP = 1 (100yr ITH) Very low MIR and POCP values VOC Exempt by US EPA & SCAQMD Non-flammable according to ASTM-E 681 Very low order of Toxicity: OEL 800 ppm Widespread adoption of Solstice PF could save about 18 million metric tons per year of CO 2 equivalent emissions Favorable Environmental Properties

5 Regulatory Needs 4 Meets and Exceeds Government Regulations TSCA Inventory (2012) Added to the US EPA SNAP list as an Aerosol solvent (2012) US EPA VOC Exempt (August 2013), SCAQMD (2014) Solstice PF has an MIR value of 0.04 g O2/g VOC, which is approximately 85% lower than the value for ethane. California CARB VOC Exemption submitted and under review Registered in Canada, Japan, South Korea, China, Australia EU REACH: Registered for volumes > 1,000 tons Favorable Regulatory Landscape

6 Stability and Miscibility 5 Thermally stable Hydrolytically stable Does not mix with water but stable in the presence of water High dielectric strength (18 KV; 0.1 gap) Miscible with many formulation ingredients: All commonly-used propellants: Solstice Propellant (HFO-1234ze) HFC-152a HFC-134a DME Hydrocarbons propane, butane, isobutane Alcohols and ketones Hydrocarbon solvents Halocarbon solvents Mixes Well with a Variety of Other Common Ingredients

7 TEAS Solubility Diagrams 6 TEAS Diagram Quick Explanation H Hydrogen Bonding P Polarity D Dispersion Tendency for greater cleaning effectiveness with soils located close to the solvents on the chart* *Must be experimentally validated 6

8 HANSEN Solubility Diagram 7 Solstice PF delivers superior blending and miscibility

9 8 Solstice PF Materials Compatibility Compatible with most plastics tested except Acrylic and HIPS Compatible with Neoprene, Viton B and Other Elastomers Aerosol valve compatibility studies by Precision and Aptar show good results with grades of Buna and Butyl Compatible with Stainless Steel 304, aluminum, cold rolled steel, copper, galvanized steel, titanium Compatible with tinplate cans and lined cans 2015 Honeywell International Flexible Compatibility

10 Toxicological Properties AIHA WEEL Value: 800 ppm Acute Toxicity: Low Toxicity Inhalation (rats): 4-hr LC 50 > 120,000 ppm (12%) Skin Sensitization (humans): Not a skin irritant or sensitizer in a repeated insult patch test (RIPT) Cardiac Sensitization to Adrenalin (dogs): No cardiac sensitization observed; threshold 35,000 ppm Repeat Exposure Toxicity: Slight Toxicity 2-week study (rat): NOAEL 2,000 ppm 4-week study (rat): NOAEL 4,500 ppm 13-week study (rat): NOAEL 4,000 ppm Developmental Toxicity: No significant adverse developmental effects Developmental toxicity study (rat): NOAEL 10,000 ppm Developmental toxicity study (rabbit): NOAEL 15,000 ppm Reproduction Toxicity: No adverse reproductive effects observed 2-Generation Reproduction (rat): NOEL ppm (reproductive/developmental effects) NOAEL 5000 ppm (systemic effects) Genetic Toxicity: Does not cause genetic toxicity Ames Assay: No mutagenicity observed at 76% (highest concentration tested) No chromosome aberration in human lymphocytes tested at 5% (highest concentration tested) In vivo micronucleus: Mice 4-hr exposures up to 50,000 ppm not active Rats 4 week exposure up to 10,000 ppm not active In vivo UDS w 4-wk exposure at 10,000 ppm: not active Metabolism: < 0.1% metabolized 9 Extensive Testing Supports Solstice PF Safety

11 10 Solstice PF Environmental Tests Aquatic Toxicity: Slightly practically nontoxic Fresh water algal growth inhibition test: 72-hr NOEC >215 mg/l (growth rate) Acute immobilization in Daphnia magna: 48-hr EC50 = 82 mg/l Acute toxicity in rainbow trout: 96-hr NOEC = 38 mg/l Environmental Fate: Not readily biodegradable 2015 Honeywell International Preferable Environmental Impact

12 11 Solstice PF KEY PROPERTIES Property Solstice PF Molecular Weight 130 Boiling Point ( F) 66 (19 C) Heat of Vaporization (BTU/lb) at NBP 83.4 Vapor Pressure 70 F (21 C) 1.4 Liquid Density 70 F (21 C) 1.3 Flash Point/Vapor Flame Limits NONE KB Value 25 Surface Tension (dynes/cm), 25 C 12.7 Atmospheric Life 26 days ODP ~0 GWP100 1 Flammable No VOC No Color Colorless Odor Faint-None Solvent Efficacy is Based on a Mosaic of Properties

13 Solstice PF Applications 12 Paints, Varnishes and Coatings Household Products (some examples listed below) - Cleaners (glass, rug, fabric, wall) - Laundry products, Waxes and Polishes - Bug sprays and insecticides Personal Care (some examples listed below) - Hair Products - Sprays, Mousse, Styling Gels, Shampoo & Conditioners - Medicinal and Pharmaceutical uses - Deodorants, Antiperspirants, Perfumes and Colognes - Cosmetics - Face, Color, Nail polishes, coatings, and protectants - Foaming products - Cleansers - Sun care - Body & Facial Care - Lotions, Creams Miscellaneous - Engine and parts cleaners - Keyboard and electronics cleaners

14 13 More Information Thank You!