HENKEL LOCTITE CORPORATION 10/28/02 ROCKY HILL, CONNECTICUT EMERGENCY PHONE: (860) MATERIAL SAFETY DATA SHEET Page 01 of 05
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1 CHEMICAL PRODUCT AND COMPANY IDENTIFICATION MATERIAL SAFETY DATA SHEET Page 01 of 05 Product Type: Aerosol lubricant 2. COMPOSITION, INFORMATION ON INGREDIENTS Ingredients CAS No. % STODDARD SOLVENT Mineral Oil TETRACHLOROETHYLENE* BUTANE ISOBUTANE PROPANE KEROSENE * This component is listed as a SARA Section 313 Toxic Chemical. Ingredients which have exposure limits Exposure Limits (TWA) ACGIH OSHA OTHER Ingredients (TLV) (PEL) STODDARD SOLVENT 100 ppm 100 ppm None 525 mg/m3 525 mg/m3 Mineral Oil 5mg/m3 TWA mist 5mg/m3 TWA mist None TETRACHLOROETHYLENE 25 ppm 25 ppm TWA None 170 mg/m3 170 mg/m3 BUTANE 800 ppm TWA 800 ppm TWA None 1900mg/M3 1900mg/M3 PROPANE 2500 ppm 1000 ppm None 1800 mg/m3 Exposure Limits (STEL) ACGIH OSHA Ingredients (TLV) (PEL) Mineral Oil 10 mg/m3 mist None TETRACHLOROETHYLENE 100 ppm None 685 mg/m3 PROPANE Asphyxiant Asphyxiant
2 MATERIAL SAFETY DATA SHEET Page 02 of HAZARDS IDENTIFICATION Toxicity: Primary Routes of Entry: Signs and Symptoms of Exposure: Existing Conditions Aggravated by Exposure: Skin and eye irritant. May irritate respiratory tract. Aspiration hazard if swallowed. May cause dizziness or narcosis in high vapor concentrations Will cause defatting of skin. Long term exposure to high concentrations of vapor may cause lung, liver, or kidney damage. The solvents listed have been reported to affect the central nervous system. Deliberately concentrating and inhaling the vapor of the contents may be harmful or fatal. Inhalation, skin, ingestion Inhalation - difficulty in breathing Skin - redness. Ingestion - vomiting Heart disease, respiratory disorders Literature Referenced Carcinogen Ingredients Target Organ and Other Health Effects NTP IARC OSHA STODDARD SOLVENT CNS IRR NO NO NO Mineral Oil NTO NO NO NO TETRACHLOROETHYLENE AC3 CNS IRR KID LIV SOM YES 2B NO BUTANE CAR CNS IRR LUN NO NO NO ISOBUTANE CAR CNS LUN NO NO NO PROPANE CAR CNS IRR NO NO NO KEROSENE BNM CNS IRR KID LIV LUN SPL NO NO NO Abbreviations 2B Possibly carcinogenic to humans BNM Bone Marrow CNS Central nervous system KID Kidney LUN Lung SOM Some evidence of carcinogenicity AC3 ACGIH animal carcinogen. CAR Cardiac IRR Irritant LIV Liver NTO No Target Organs SPL Spleen 4. FIRST AID MEASURES Ingestion: Inhalation: Skin Contact: Do not induce vomiting. Keep individual calm. Obtain medical attention. Remove to fresh air. Give oxygen. If symptoms persist, obtain medical attention. Wash with soap and water.
3 MATERIAL SAFETY DATA SHEET Page 03 of FIRST AID MEASURES (continued) Eye Contact: Flush at least 15 minutes with water. Obtain medical attention. 5. FIRE FIGHTING MEASURES Flash Point: -142 F Method: Tag CLosed Cup Recommended Extinguishing Agents: Water fog, carbon dioxide, dry chemical, foam. Special Firefighting Procedures: Keep containers cool. Use equipment or shielding required to protect against bursting or venting containers. Hazardous Products formed by Fire or Thermal Decomp Irritating organic vapors; carbon dioxide; halogen acids, phosgene Unusual Fire or Explosion Hazards: Explosive Limits: (% by volume in air)lower 1.8% (% by volume in air)upper 9.5% 6. ACCIDENTAL RELEASE MEASURES Heated cans may burst. Steps to be taken in case of spill or leak: Ventilate area and remove sources of ignition. Take up with an inert absorbent. Store in a closed container until disposal. 7. HANDLING AND STORAGE Safe Storage: Store below 100 F away from heat, sparks, or open flame. (Contact Loctite Customer Service for shelf life information) Handling: Avoid prolonged skin contact. Keep away from eyes. Avoid prolonged breathing of vapors. Keep away from heat, sparks or open flame. When spraying more than one half can continuously or more than one can consecutively, use NIOSH approved respirator. 8. EXPOSURE CONTROLS, PERSONAL PROTECTION Eyes: Skin: Ventilation: Safety glasses or goggles. Rubber or plastic gloves. Long sleeves and long pants. Sufficient local exhaust to maintain vapor
4 MATERIAL SAFETY DATA SHEET Page 04 of EXPOSURE CONTROLS, PERSONAL PROTECTION (continued) Respiratory concentration below TLV. NIOSH approved respirator if the vapor concentration exceeds the TLV. 9. PHYSICAL AND CHEMICAL PROPERTIES See Section 2 for Exposure Limits. Appearance: Clear liquid Odor: Solvent Boiling Point: -40 F to 500 F ph: Does not apply Solubility in Water: Nil Specific Gravity 0.8 Volatile Organic Compound (EPA Method 24) Not available Vapor Pressure: 44 psig at 70 F Vapor Density: 4.0 Evaporation Rate (Ether = 1) Slower than butyl acetate 10. STABILITY AND REACTIVITY Stability: Stable Hazardous Polymerization: Will not occur Incompatibility: Strong oxidizers, active metals Conditions to Avoid: Not available Hazardous Decomposition Products (non-thermal): None 11. TOXICOLOGICAL INFORMATION 12. ECOLOGICAL INFORMATION 13. DISPOSAL CONSIDERATIONS Recommended methods of disposal: See Section 3. No data available Incinerate following EPA and local regulations. Do not incinerate pressurized cans. EPA Hazardous Waste Number D001/D005 - Hazardous waste per 40CFR and a TCLP waste per 40CFR.24/Tetrachloroethylene.
5 MATERIAL SAFETY DATA SHEET Page 05 of TRANSPORTATION INFORMATION DOT (49 CFR 172) Domestic Ground Transport Proper Shipping Name: Consumer Commodity Hazard Class or Division: ORM-D Identification Number: None Marine Pollutant: Tetrachloroethylene (Perchloroethylene) IATA Proper Shipping Name: Consumer Commodity Class or Division: Class 9 UN or ID Number: ID REGULATORY INFORMATION CA Proposition 65: WARNING: This product contains a chemical known to the State of California to cause birth defects or other reproductive harm. 16. OTHER INFORMATION Estimated NFPA(R) Code: Health Hazard: 2 Fire Hazard: 4 Reactivity Hazard: 0 Specific Hazard: Does not apply Estimated HMIS(R) Code: Health Hazard: 1* Flammability Hazard: 4 Reactivity Hazards: 0 Personal Protection: See Section 8. NFPA is a registered trademark of the National Fire Protection Assn. HMIS is a registered trademark of the National Paint and Coatings Assn. Prepared By: Stephen Repetto Title: Research Chemist - Health & Regulatory Affairs Company: Henkel Loctite Corporation, Rocky Hill CT (24hr.) Phone: (860) Revision Date: January 27, 1999 Revision: 0002
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