MATERIAL SAFETY DATA SHEET CEB74379

Transcription

1 MATERIAL SAFETY DATA SHEET CEB74379 Revision Number 6, Revision Date 10/9/06 1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND THE COMPANY/UNDERTAKING Product code A00169PL MSDS 1006 Product name Citrus All Purpose Cleaner CEB74379 Chemical characterization Aerosol Manufacturer, importer, supplier Manufactured For: Corporate Express, Inc. 1 Environmental Way Broomfield, CO EMERGENCY TELEPHONE CHEMTREC: NUMBER 2. HAZARD IDENTIFICATION Emergency Overview: CAUTION Pressurized container. Protect from sunlight and do not expose to temperatures exceeding 122ºF (50 C) Do not pierce or burn, even after use. Do not spray on naked flame or any incandescent material KEEP OUT OF REACH OF CHILDREN HMIS (Hazardous Material Information System) Eye contact Skin contact Principle Routes of Exposure General advice Aggravated Medical Conditions Health=1; Fire=1; Reactivity=0 Personal protective equipment = B Mild eye irritation. Substance may cause slight skin irritation. of high vapour concentrations may cause nasal & respiratory irritation and symptoms like headache, dizziness, tiredness, nausea, vomiting and possible unconsciousness. Aspiration may cause pulmonary oedema and pneumonitis. nausea. Skin contact Avoid breathing vapors or mists. May cause eye or skin irritation with susceptible persons. May cause irritation of respiratory tract. 3. COMPOSITION/INFORMATION ON INGREDIENTS (hazardous components 1% or greater; carcinogens 0.1% or greater) CAS Chemical Name % Weight OSHA* ACGIH TLV (ppm) D-Limonene < 5.0% N/E N/E Ethylene oxide-nonylphenol polymer < 5.0% N/E N/E Isobutane < 5.0% 800 ppm 800 ppm Propane < 5.0% 1000 ppm 1000 ppm Dipropylene glycol methyl ether < 5.0% 100 ppm 150 ppm * OSHA - PELs 4. FIRST AID MEASURES Eye contact Skin contact Immediately flush with plenty of water. After initial flushing, remove any contact lenses and continue flushing for at least 15 minutes. If eye irritation persists, consult a specialist Wash off with soap and water If skin irritation persists, call a physician 1 of 5

2 Aggravated Medical Conditions Move to fresh air If not breathing, cal 911 or an ambulance, then give artificial respiration, preferably by mouth. Obtain medical attention DO NOT INDUCE VOMITING Clean mouth with water and afterwards drink plenty of water Never give anything by mouth to an unconscious person Obtain medical attention May aggravate existing eye, skin, or upper respiratory conditions 5. FIRE-FIGHTING MEASURES NFPA (National Fire Protection Association) Health=1; Fire=1; Reactivity=0; Special = - Flammability as per USA Flame Projection Test The product is not flammable (aerosols) Flash point (non-aerosols) Suitable extinguishing media Foamy spray Dry chemical Carbon dioxide (CO2) Water spray Extinguishing media which must not be used for None safety reasons Specific Hazards Pressurized container. Protect from sunlight and do not expose to temperatures exceeding 122ºF (50 C) Special protective equipment for firefighters As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear Specific methods Water mist may be used to cool closed containers. 6. ACCIDENTAL RELEASE MEASURES Personal precautions Environmental precautions Methods for cleaning up Ensure adequate ventilation Use personal protective equipment No special environmental precautions required. Flush into sewer with plenty of water. 7. HANDLING AND STORAGE Handling Safe handling advice Storage Technical measures/precautions Ensure adequate ventilation, especially in confined areas. Wear personal protective equipment. KEEP OUT OF REACH OF CHILDREN. Pressurized container. Protect from sunlight and do not expose to temperatures exceeding 122ºF (50 C). 8. EXPOSURE CONTROLS / PERSONAL PROTECTION Engineering measures Hand protection Eye protection Respiratory protection Skin and body protection Hygiene measures Ensure adequate ventilation, especially in confined areas Latex gloves Safety glasses with side-shields When workers are facing concentrations above the exposure limit they must use appropriate certified respirators None under normal use. Handle in accordance with good industrial hygiene and safety practice 2 of 5

3 General Information Form Appearance Colour Odour Wash hands after using Keep away from food, drink and animal feeding stuffs Keep working clothes separately 9. PHYSICAL AND CHEMICAL PROPERTIES Aerosol Foamy spray White Citrus Important Health Safety and Environmental Information Specific Gravity ºF (20 C) 8.17 lbs/gal ph to Boiling point/range Flash point Vapour pressure 70ºF (Aerosols): Max. 60. Vapour density. Water solubility Soluble. Evaporation Rate <1.0 ( butyl acetate = 1) VOC Content(%) 8.2%; per US EPA Definition 10. STABILITY AND REACTIVITY Stability Conditions to avoid Materials to avoid Hazardous decomposition products Polymerization Stable under normal conditions Heat, flames and sparks Extremes of temperature and direct sunlight Avoid temperatures above 122ºF (50 C) Strong oxidizing agents Carbon oxides Hazardous polymerization does not occur 11. TOXICOLOGICAL INFORMATION Acute toxicity Component Information CAS Chemical Name % Weight NIOSH - Selected LD50s and LC50s D-Limonene < 5.0% Oral LD50 Rat: 4400 mg/kg; Dermal LD50 Rabbit: >5 g/kg Ethylene oxide-nonylphenol polymer < 5.0% Oral LD50 Rat: 1310 mg/kg; Dermal LD50 Rabbit: 2 ml/kg Isobutane < 5.0% LC50 Rat: 57 pph/15m Propane < 5.0% Dipropylene glycol methyl ether < 5.0% Oral LD50 Rat: 5400 µl/kg; Dermal LD50 Rabbit: 10 ml/kg Product Information LD50/oral/rat = LD50/dermal/rat = Local effects 3 of 5

4 Skin irritation Eye irritation Sensitization Chronic toxicity May cause skin irritation in susceptible persons. Contact with eyes may cause irritation. Excessive inhalation may cause irritation of respiratory tract. Ingestion may cause gastrointestinal irritation, nausea, vomiting and diarrhea. May cause sensitization of susceptible persons. Prolonged exposure may cause chronic effects such as. 12. ECOLOGICAL INFORMATION Ecotoxicity effects Component Information CAS Chemical Name % Weight EFFSD* D-Limonene < 5.0% 96 Hr LC50 fathead minnow: 702 mg/l (flow-through) Ethylene oxide-nonylphenol < 5.0% polymer Isobutane < 5.0% Propane < 5.0% Dipropylene glycol methyl ether < 5.0% * EFFSD - Ecotoxicity - Freshwater Fish Species Data Product Information Aquatic toxicity Other information:. Ozone depletion potential; ODP;. (R-11 = 1) Global warming potential (GWP). Additional ecological. information Mobility Bioaccumulative potential 13. DISPOSAL CONSIDERATIONS Waste from residues / unused products Contaminated packaging Dispose of in accordance with local regulations. Empty containers should be taken for local recycling, recovery or waste disposal. 14. TRANSPORT INFORMATION DOT Proper shipping name (Ground). Consumer Commodity ORM-D IATA UN1950 Proper shipping name Aerosols, Non-Flammable, of 5

5 TDG UN1950 Proper shipping name Aerosols, Non-Flammable, Class REGULATORY INFORMATION U.S. Inventories CAS Chemical Name % Weight CPCL* TSCA* CERCLA/S ARA* SARA III IARC* NTP* D-Limonene < 5.0% Present No Ethylene oxide- Nonylphenol polymer < 5.0% XU No Isobutane < 5.0% Present No Propane < 5.0% Present No Dipropylene glycol methyl < 5.0% T No ether * CPCL - California - Proposition 65 - Carcinogens List * TSCA - United States - Section 8 (b) Inventory (TSCA) * CERCLA/SARA - Hazardous Substances and their Reportable Quantities * IARC - Group 1 (Carcinogenic to humans) * NTP - Report on Carcinogens - Known Carcinogens International Inventories CAS Chemical Name % Weight DSL - Canada* WHMIS* D-Limonene < 5.0% Present Ethylene oxide-nonylphenol polymer < 5.0% Present Isobutane < 5.0% Present A, B Propane < 5.0% Present A, B Dipropylene glycol methyl ether < 5.0% Present * DSL - Canada - Domestic Substances List (DSL) * WHMIS - Canada - WHMIS - Classification of Substances1 16. OTHER INFORMATION Prepared By End of Safety Data Sheet D. Padovani (IB). Amrep Inc., Regulatory Department. The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. 5 of 5