PRODUCT TECHNICAL DOSSIER SODIUM BENZOATE

Transcription

1 PRODUCT TECHNICAL DOSSIER SODIUM BENZOATE Product Code: P1916 Raw Material Full Name: Sodium Benzoate This material is Food Grade Assay: % CAS Number: EC/EINECS Number: Molecular Formula for the raw material: C 6H 5CO 2Na ph: Acidity & Alkalinity: Conforms Halogenated Compounds: Max 300ppm Chlorides: Max 60ppm Phenol Content: Max 2ppm Product Code: P1916 Version: 2 Page 1 of 17

2 Zinc & Copper: Max 50ppm Loss on Drying: Max 2% Country of Origin: China Country of Origin of the Manufacture: Europe Base Source/Start Material: Toluene Oxidation, Benzoic Acid, Benzaldehyde Benzyl Alcohol Origin of Product Synthetic, Plant, Mineral, Animal, Fish or Fermented: Synthetic Synthetic: What are the starting materials of the synthesis and their sources? Toluene Oxidation, Benzoic Acid, Benzaldehyde Benzyl Alcohol Material is: 100% Compound Ingredients: None Shelf Life from Date of Manufacture Minimum 2 Years (Batch Specific) Storage Conditions: Store in a cool and dry; product is slightly hygroscopic. Appearance: Crystalline/Granular Powder Colour: White to Off White Product Code: P1916 Version: 2 Page 2 of 17

3 Flavour/Taste: Characteristic Odour: Characteristic Metals Heavy Metals: Max 10ppm Arsenic (As): Max 2ppm There are no nuts in this recipe and are no nuts on site, however we cannot guarantee that the raw materials entering the site are nut free. Product Code: P1916 Version: 2 Page 3 of 17

4 INTOLERANCE DATA If No please give details Free from All Animal Products (Beef, Pork, Poultry or other) Free from Bovine Products or Derivatives by using hormones to increase milk yield in cows Free from Bone Meal Free from Peanuts and Peanut Derivatives (including possible cross contamination) Free from other Nut and Nut Derivatives Free from Nut Derived Oil Free from Sesame Seeds and Sesame Seed Derivatives Free from Poppy Seeds and Poppy Seed Derivatives Free from Sunflower Seeds and Sunflower Seeds Derivatives Free from other Seeds and Seed Derivatives Free from Milk and Milk Derivatives (including lactose) Free from Egg and Egg Derivatives Free from Cereals containing Gluten (wheat / rye / oats / barley/ spelt/ kamut or their hybridised strains) and Derivatives Free from Soya and Soya Derivatives Free from Maize and Maize Derivatives Free from Corn and Corn Derivatives Free from Lupin and Lupin Derivatives Free from Yeast and Yeast Derivatives Free from Cotton Seeds (Flour) and Cotton Seed Derivatives Free from Rice and Rice Derivatives Free from Mustard and Mustard Derivatives Free from Celery or Celery Derivatives Free from Celeriac or Celeriac Derivatives Free from Fruit and Fruit Derivatives Free from Vegetable and Vegetable Derivatives Free from Carrot and Carrot Derivatives Free from Legumes / Pulses Free from Fish and Fish Derivatives Free from Crustaceans / Molluscs and their Derivatives Free from Additives Free from Added Salt Free from Added Sugar Free from Antioxidants Free from Artificial Glutamates Free from Aspartame Free from Azo and Coal Tar Dyes Free from Benzoates (E210 / E219) NO <500ppm Free from BHA / BHT (E320 / E321) Free from Caffeine Free from Cinnamon Free from Cocoa Free from Colours (Artificial / Nature Identical / Natural / Smoked) Free from Dextrose Free from Dioxins Free from Ethanol Product Code: P1916 Version: 2 Page 4 of 17

5 INTOLERANCE DATA If No please give details Free from Ethylene Oxide Free from Flavourings (Artificial / Nature Identical / Natural / Smoked) Free from Garlic Free from Gelatine Free from Glutamates (E620 to E625) Free from Histamine Free from Hickory Free from Honey Free from Lactose Free from Latex Free from MSG (Added and Naturally Occurring E621) Free from Nucleotides (E627, E630, E631, E635) Free from Polyols Free from Preservatives Free from Starch Products (Including Maltodextrin) Free from Sorbic Acid (E200, E203) Free from Sulphur Dioxide and Sulphites at levels above 10mg/kg or 10mg/litre expressed as SO 2 Free from Sulphites (E220, E228) Free from Sweeteners Free from Vannillin Suitable for Diabetics Suitable for Coeliacs Suitable for Ovo-Lacto Vegetarians Suitable for Vegans Kosher Certified NO Not Certified Halal Certified NO Not Certified Product Code: P1916 Version: 2 Page 5 of 17

6 PRODUCT PROCESS FLOW DIAGRAM PRODUCT NAME: PRODUCT CODE: SODIUM BENZOATE P1916 Purification Purox B Liquid (Pure Grade Benzoic Acid) Toluene Oxidation Benzoic Acid Purox B Flakes (Pure Grade Benzoic Acid) Benzaidehyde Benzyl Alcohol NaOH Purox S Grains (Pure Grade Sodium Benzoate) Benzaldehyde Customer Purification Benzyl Alcohol Product Code: P1916 Version: 2 Page 6 of 17

7 CONFIRMATION OF BSE/TSE STATUS This is to certify that this product complies with all relevant current UK and EU Legislative requirements in regard to Transmissible Spongiform Encephalopathies (TSE) and Bovine Spongiform Encephalopathy (BSE) for human food, and so is free of TSE/BSE. This is also to certify that, during the course of their manufacture, the above-mentioned product did not come into contact with any materials, which could be derived from TSE/BSE risk materials. CONFIRMATION OF GM STATUS This is to certify that this product is not manufactured from GM raw materials and is therefore not subject to labelling under regulations 1829/2003/EC and 1830/2003/EC. CONFIRMATION OF NON IRRADIATION STATUS This is to certify that this product, whole or in part, has not been subjected to Ionising Radiation as per European Directives 1999/2/EC and 1000/3/EC. CONFIRMATION OF NANDROLONE STATUS This is to certify that this product, whole or in part, has not come into contact with Nandrolone or any of its precursors in any way. CONFIRMATION OF IOC PRODUCT STATUS This is to certify that this product, whole or in part, has not come into contact with any product/s, which is banned by the IOC (International Olympics Committee). CONFIRMATION OF ANIMAL TESTING STATUS This is to certify that all the products sold by Cambridge Commodities have not been tested on animals in any part of its manufacture in accordance with regulation 86/609/EEC. CONFIRMATION OF PESTICIDES STATUS This is to certify that the above-mentioned product complies with the regulation (EC) No.396/2005 of 23 rd February 2005 and commission Regulation (EU) No. 559/2011 of 7 th June 2011 amending annexes II and III of the above Regulation. Product Code: P1916 Version: 2 Page 7 of 17

8 MATERIAL SAFETY DATA SHEET Section 1 Identification of the Substance/Mixture and of the Company/Undertaking Product Name: Product Code: Supplier: SODIUM BENZOATE P1916 Cambridge Commodities Limited 78 Lancaster Way, Ely, Cambridgeshire, CB6 3NW. Tel: mail@c-c-l.com 1.1 Product Identifier Components CAS Number EC/EINECS Number REACH Registration No. Sodium Benzoate Synonyms Sodium Benzoic Acid, Benzoic Acid Sodium Salt 1.2 Relevant Identified Uses of the Substance or Mixture and Uses Advised Against 1.21 Relevant Identified Uses Main Use Category Use of the Substance/Preparation : Industrial use, Professional Use : ES1: Manufacturing of the substance and industrial use as auxiliary for polymerization in a closed continuous process, with occasional exposure, including sampling. ES2: Industrial use as an auxiliary in polymerization processes in a closed continuous process, no likelihood of exposure including storing and forwarding. ES3: Charging/ discharging at non-dedicated facilities in an industrial setting ES4: Charging/ discharging at dedicated facilities in an industrial setting. ES5: Transfer of substance into small containers in an industrial setting. ES6: Industrial use in closed batch process formulation and auxiliary in polymerization processes. ES7: Mixing and blending in batch processes for formulation or preparations and articles (multistage and/or significant contact). Product Code: P1916 Version: 2 Page 8 of 17

9 ES8: Use in batch and other process (synthesis) where opportunity for exposure arises. ES9: Professional use of laboratory chemicals. Most Common technical function of the substance: Additive Use Advised Against No additional information available. Section 2: Hazard Identification 2.1 Classification of the Substance or Mixture Classification According to Regulation (EC) No.1272/2008 [CLP] Eye irrit. 2 H319 Full text of H-phrases: see section 16. Classification According to Directive 67/548/EEC or 1999/45/EC Xi: R36 Full text of R-phrases: see section16. Adverse Physicochemical, Human Health and Environmental Effects Causes serious eye irritation. 2.2 Label Elements Labelling According to Regulation (EC) No.1272/2008 [CLP] Hazard Pictograms (CLP): CLP Signal Word Hazard Statements (CLP) Precautionary Statements (CLP) GHS07 :Warning :H319- Causes serious eye irritation :P264- Wash hands thoroughly after handling P280- Wear protective gloves/protective clothing/eye protection/face protection. P305 + P351 + P338 IF E: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P337 + P313 If eye irritation persists: get medical advice/attention. Product Code: P1916 Version: 2 Page 9 of 17

10 Section 3 Composition and ingredients Name Product Identifier % Classification According to Directive 67/548/EEC Sodium Benzoate (CAS no.) (EC No.) (REACH No.) Xi; R36 Name Product Identifier % Classification According to Regulation (EC) No. 1272/2008 [CLP] Sodium Benzoate (CAS no.) (EC No.) (REACH No.) Eye irrit. 2, H319 Full text of R-, H- and EUH-phrases: see section Mixtures N/A Section 4 First Aid Measures 4.1 Description of First Aid Measures First- Aid Measure General : Move the affected person away from the contaminated area and into the fresh air. First-Aid Measure After Inhalation : Remove to fresh air and keep at rest in position comfortable for breathing if irritation persists, consult a doctor. First- Aid Measures After Skin contact : Rinse with plenty of water. Remove all contaminated clothing and footwear. If case of redness or irritation, call a doctor. First- Aid Measures After Eye Contact : Rinse immediately and thoroughly, pulling the eyelids well away from the eye (15 minutes minimum). If irritation persists, consult an eye specialist. First- Aid Measures After Ingestion : Rinse mouth out with water. Never give anything by mouth to an unconscious person. Get medical advice and attention if feel unwell. 4.2 Most Important Symptoms and Effects, Both Acute and Delayed Symptoms/ Injuries After Inhalation : Dust from this product may cause irritation to the respiratory tract. Cough. Symptoms/ Injuries After Eye Contact : Eye irritation. Redness. 4.3 Indication of any immediate Medical Attention and Special Treatments Needed Treat symptomatically. Product Code: P1916 Version: 2 Page 10 of 17

11 Section 5 : Fire Fighting Media 5.1 Extinguishing Media Suitable Extinguishing Media Dry Powder Carbon Dioxide (CO2) For Significant Fire: Water Spray Foam Dry Powder 5.2 Special Hazards Arising From the Substance and Mixture Fire Hazard 5.3 Advice for Fire Fighters Fire Fighting Instructions Protection During Fire Fighting :Dust may form explosive mixture in air. During Combustion: Toxic fumes may be released (Carbon Oxide (CO and CO2), (Sodium Oxide). : Contain extinguishing fluids by bunding. : Do not attempt to take action without suitable protective equipment. Complete protective clothing. Section 6 : Accidental Release Measures 6.1 Person Precautions, Protective Equipment and Emergency Procedures For Non-Emergency Personnel Emergency Procedures For Emergency Responders Protective Equipment : Avoid raising powdered material due to explosive hazard. Keep away from ignition sources (including static discharges). Explosion-free electrical equipment and lighting with earth. : Do not attempt to take action without suitable protective equipment. For further information refer to section 8 Exposure Controls/Personal Protection. 6.2 Environmental Precautions Contain the spilled material by bunding. Do not discharge into drains or rivers. 6.3 Methods and Material for Containment and Cleaning up For containment Method of Cleaning Up 6.4 Reference to Other Sections For further information refer to section 13. Section 7 Handling and Storage : Sweep or vacuum up the product. Put into a labelled container and provide safe disposal. Flame proof, lighting, electrical equipment and ventilation. : Wash non-recoverable remainder with large amounts of water. Product Code: P1916 Version: 2 Page 11 of 17

12 7.1 Precautions for Safe Handling Precautions for Safe Handling Hygiene Measures 7.2 Conditions for Safe Storage, Including any Incompatibilities Storage Conditions Incompatible Products Packaging Materials 7.3 Specific End Use(s) N/A : Ensure good ventilation of the work station. Extraction to remove dust at its source. Do not breathe dust. Use personal protective equipment as required. Avoid raising powdered material due to explosive hazard. Flame proof, lighting, electrical equipment and ventilation. Keep away from ignition sources (including static discharge). : Do not drink, eat or smoke in the work place. Always wash your hands after handling this product. : Keep container tightly closed and dry. Keep in a cool, well-ventilated place away from heat. Take precautionary measures against static discharge. Keep away from incompatible materials. Avoid any contamination of the product by other substances. : None :Polyethylene Polypropylene. Section 8 Exposure Control/Personal Protection 8.1 Control Parameters Sodium Benzoate ( ) DNEL?DMEL (Workers) Long-term- Systemic Effects, Dermal Long-term- Local Effects, Dermal 4,5 mg/cm 2 Long-term- Systemic Effects, Inhalation 10,4 mg/m 3 34,7 mg/kg Bodyweight/Day Long-term- Local Effects, Inhalation 6,3 mg/m 3 DNEL/DMEL (General Population) Long-term- Systemic Effects, Oral 25 mg/kg Bodyweight/ Day Long-term- Systemic Effects, Inhalation 2,1mg/m 3 Long-term- Systemic Effects, Dermal 20,8 mg/kg Bodyweight/Day Long-term Local Effects, Dermal 2,7 mg/cm 2 Long-term- Local Effects, Inhalation 1,3 mg/m 3 Product Code: P1916 Version: 2 Page 12 of 17

13 8.2 Exposure Controls Appropriate Engineering Controls : Ensure good ventilation of the work station. Flame proof, lighting, electrical equipment and ventilation. Hand Protection Butyl-rubber protective gloves. Nitrile-rubber protective gloves. Neoprene protective gloves. Protective gloves mad of PVC. VITON gloves. Break through time (min): > 480 Eye Protection : Safety spectacles with side shields. Skin and Body Protection : Protective clothing. Respiratory Protection : Dust production: dust mask with filter type P2. Environmental Exposure Controls : Take all necessary precautions to avoid accidental release of the product outside, due to the rupture of container or transfer systems. Section 9 Physical and Chemical Properties Physical state : Solid Appearance : Solid. Pellet. Hygroscopic. Colour : White to Off White Odour : Odourless Odour Threshold : Not estimated. ph : 9 ph Solubility : 10% Melting Point : 436 o C (1013 hpa) (OECD 102) Boiling Point : 465 o C Flash Point : N/A o C Relat. Evapor. Rate Comp. to Butyl acetate : No Data Available Flammability (Solid, Gas) : Non-flammable. (Expert statement) Explosive Limits : No Data Available Vapour Pressure : Negligible.Pa Relative Vapour Density at 20 o C : No Data Available Relative Density : 1,5 (20 o C) (OECD 109) Solubility : Water. 556 g/l (20 o C)(Handbook) Log Pow : -2, 27 (Calculated Value) Self-Ignition Temperature : No Data Available Decomposition Temperature : No Data Available Product Code: P1916 Version: 2 Page 13 of 17

14 Viscosity, Kinematic Viscosity, dynamic Explosive Properties Oxidizing Properties 9.2 Other Information Minimum Ignition Energy Other Properties A.5) : No Data Available : No Data Available : N/A (Expert statement) : N/A (Expert statement) : mj Pellet. : Surface Tension: 72.9 mn/m (20 o C) (1 g/l) (OECD 115, EC Section 10 Stability and Reaction 10.1 Reactivity To our knowledge, the product does not present any risk Chemical Stability Stable at ambient temperature and under normal conditions of use Possibility of Hazardous Reactions None to our knowledge Conditions to Avoid No flames, No sparks. Eliminate all sources of ignition. Moisture Incompatible Materials Acids Oxidizing Materials Iron Salt Hazard Decomposition Products On Thermal Decompositions (Pyrolysis): Carbon Oxides (CO, CO2), Sodium oxide. Section 11 Toxicological Information 11.1 Information on Toxicological Effects Acute Toxicity Sodium Benzoate ( ) LD50 Oral Rat LD50 Dermal Rat LC50 Inhalation Rat : Not Classified >2000 mg/kg >2000 mg/kg (read- across) >12.2 mg/l (read- across) Skin Corrosion/Irritation : Not classified (OECD 404) Serious Eye Damage/Irritation : Cause serious eye irritation (OECD 405) Product Code: P1916 Version: 2 Page 14 of 17

15 Respiratory or Skin Sensitization Germ Cell Mutagenicity Carcinogenicity Reproductive Toxicity Specific Target Organ Toxicity (Single Exposure) Specific Target Organ Toxicity (Repeated Exposure) Aspiration Hazard : Not classified (Based on available data, the classification criteria are no met) : Not classified (Based on available data, the classification criteria are no met) : Not classified (Based on available data, the classification criteria are no met) : Not classified (Based on available data, the classification criteria are no met) : Not classified (Based on available data, the classification criteria are no met) : Not classified (Based on available data, the classification criteria are no met) Not classified (Technical impossibility to obtain the data) Section 12 Ecological Information 12.1 Toxicity Sodium Benzoate ( ) LC50 Fish >100 mg/l/96h (OECD 203) EC50 Daphnia >100 mg/l/48h (Daphnia Magna) (OECD 211) EC50 Other Aquatic Organisms >100 mg/l/24h (Achromobacter sp.)(inhibition of Microbial Activity) NOEC (Chronic) 51 mg/l/21 D (Daphnia Maga) (OECD 211) ErC50 >100 mg/l/72h (OECD 201) Persistence and Degradability Sodium Benzoate ( ) Persistence and Degradability Readily Biodegradable (OECD 301B) 12.3 Bioaccumulative Potential Sodium Benzoate ( ) Log Pow 12.4 Mobility in Soil Sodium Benzoate ( ) Mobility in Soil -2,27 (Calculated Value) No Data Available Product Code: P1916 Version: 2 Page 15 of 17

16 12.5 Results of PBT and vpvb Assessment Sodium Benzoate ( ) Results of PBT Assessment The product does not meet the PBT and vpvb classification criteria Other Adverse Effects No additional information available. Section 13 Disposal Considerations 13.1 Waste Treatment Methods Waste Treatment Method : Dispose of in accordance with relevant local regulations. Section 14 Transport Information No dangerous good in sense of transport regulations. Section 15 Regulatory Information 15.1 Safety, Health and Environmental Regulations/Legislation Specific for the Substance or Mixture EU- Regulations No additional information available National Regulations No additional information available Chemical Safety Assessment A chemical safety assessment has been carried out. Section 16 Other Information Data Sources Full Text of R-, H- and EUH- Phrases: : CSR (Chemical Safety Report) Eye Irrit. 2 Serious Eye Damage/Irritation Category 2 H319 Cause Serious Eye Irritation R36 Irritating to Eyes. This advice is given by Cambridge Commodities Ltd who accept no legal liability for it. The information contained herein is based on the present state of our knowledge and is intended to describe our products from the point of view of safety requirements. It should not therefore be construed as guaranteeing specific properties. Product Code: P1916 Version: 2 Page 16 of 17

17 Individuals working with chemicals should consider all chemicals to be potentially hazardous even if their individual hazards may be uncharacterised or unknown. We confirm that the information above is sourced from the original manufacturers/suppliers Specification To be used as per local legislation Change History Version Change Customer Notification required Yes / No 1 First Issue N/A 2 Shelf Life amended (Batch Specific) added No QA Approval Date: Signature: Checked By: Kelsey Martin Product Code: P1916 Version: 2 Page 17 of 17