: SALLOSPHERE MOON. SECTION 1: Identification of the substance/mixture and of the company/undertaking. SECTION 2: Hazards identification
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1 SECTION 1 Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier Product form Mixtures Product name SALLOSPHERE MOON Product code P_12_516 Type of product Detergent 1.2. Relevant identified uses of the substance or mixture and uses advised against Relevant identified uses Main use category Use of the substance/mixture Professional use Machine dishwashing detergent Uses advised against 1.3. Details of the supplier of the safety data sheet Sallo Kyra, S.L. Compositor Bach, Nave 2, 3, 4 y Rubi - Spain T lab.sallo@sallo.es Emergency telephone number Emergency number Office hour from 830 to 1330 and 1430 to 1730 h SECTION 2 Hazards identification 2.1. Classification of the substance or mixture Classification according to Regulation (EC) No. 1272/2008 [CLP] Skin corrosion/irritation, Category 1A Full text of hazard classes and H-statements see section 16 H Label elements Labelling according to Regulation (EC) No. 1272/2008 [CLP] Extra labelling to displayextra classification(s) to display Hazard pictograms (CLP) Signal word (CLP) Hazardous ingredients Hazard statements (CLP) Precautionary statements (CLP) Extra phrases Security closing plug for children Tactile warning Danger GHS05 sodium hydroxide, caustic soda H314 - Causes severe skin burns and eye damage P102 - Keep out of reach of children P405 - Store locked up P280 - Wear eye protection, protective gloves, protective clothing P301+P330+P331 - IF SWALLOWED rinse mouth. Do NOT induce vomiting P303+P361+P353 - IF ON SKIN (or hair) Take off immediately all contaminated clothing. Rinse skin with water/shower P305+P351+P338 - IF IN EYES Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing P310 - Immediately call a POISON CENTER, a doctor Do not ingest 22/06/2017 EN (English) 1/9
2 2.3. Other hazards Adverse physicochemical, human health and environmental effects Causes severe skin burns and eye damage. SECTION 3 Composition/information on ingredients 3.1. Substances Not applicable 3.2. Mixtures Name Product identifier % Classification according to Regulation (EC) No. 1272/2008 [CLP] sodium hydroxide, caustic soda (CAS-No.) (EC-No.) (EC Index-No.) (REACH-no) (1-hydroxyethylidene)bisphosphonic acid, sodium salt (CAS-No.) (EC-No.) (REACH-no) disodium metasilicate (CAS-No.) (EC-No.) (EC Index-No.) (REACH-no) sodio pcumenesulphonate (CAS-No.) (EC-No.) (REACH-no) Skin Corr. 1A, H314 >= 7 Acute Tox. 4 (Oral), H302 Eye Irrit. 2, H Met. Corr. 1, H290 Skin Corr. 1B, H314 STOT SE 3, H Eye Irrit. 2, H319 Specific concentration limits Name Product identifier Specific concentration limits sodium hydroxide, caustic soda (CAS-No.) (EC-No.) (EC Index-No.) (REACH-no) Full text of H-statements see section 16 ( 0,5 =<C < 2) Eye Irrit. 2, H319 ( 0,5 =<C < 2) Skin Irrit. 2, H315 ( 2 =<C < 5) Skin Corr. 1B, H314 (C >= 5) Skin Corr. 1A, H314 SECTION 4 First aid measures 4.1. Description of first aid measures First-aid measures general First-aid measures after inhalation First-aid measures after skin contact First-aid measures after eye contact First-aid measures after ingestion Call a physician immediately. Remove person to fresh air and keep comfortable for breathing. Rinse skin with water/shower. Remove/Take off immediately all contaminated clothing. Call a physician immediately. Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Call a physician immediately. Rinse mouth. Do not induce vomiting. Call a physician immediately Most important symptoms and effects, both acute and delayed Symptoms/effects Symptoms/effects after inhalation Symptoms/effects after skin contact Symptoms/effects after eye contact Symptoms/effects after ingestion Causes severe skin burns and eye damage. May cause irritation to the respiratory tract, sneezing, coughing, burning sensation of throat with constricting sensation of the larynx and difficulty in breathing. Burns. Serious damage to eyes. Burns Indication of any immediate medical attention and special treatment needed Treat symptomatically. SECTION 5 Firefighting measures 5.1. Extinguishing media Suitable extinguishing media Water spray. Dry powder. Foam Special hazards arising from the substance or mixture Hazardous decomposition products in case of fire Toxic fumes may be released. 22/06/2017 EN (English) 2/9
3 5.3. Advice for firefighters Protection during firefighting Do not attempt to take action without suitable protective equipment. Self-contained breathing apparatus. Complete protective clothing. SECTION 6 Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures For non-emergency personnel Emergency procedures For emergency responders Protective equipment Ventilate spillage area. Avoid contact with skin and eyes. Do not breathe dust/fume/gas/mist/vapours/spray. Do not attempt to take action without suitable protective equipment. For further information refer to section 8 "Exposure controls/personal protection" Environmental precautions Avoid release to the environment Methods and material for containment and cleaning up Methods for cleaning up Mechanically recover the product. Other information Dispose of materials or solid residues at an authorized site Reference to other sections For further information refer to section 13. SECTION 7 Handling and storage 7.1. Precautions for safe handling Precautions for safe handling Hygiene measures Ensure good ventilation of the work station. Avoid contact with skin and eyes. Do not breathe dust/fume/gas/mist/vapours/spray. Wear personal protective equipment. Wash contaminated clothing before reuse. Do not eat, drink or smoke when using this product. Always wash hands after handling the product Conditions for safe storage, including any incompatibilities Storage conditions Store locked up. Store in a well-ventilated place. Keep cool Specific end use(s) SECTION 8 Exposure controls/personal protection 8.1. Control parameters 8.2. Exposure controls Appropriate engineering controls Ensure good ventilation of the work station. Hand protection protective gloves. EN 374 Eye protection Safety glasses. EN 166 Skin and body protection Respiratory protection Wear suitable protective clothing In case of insufficient ventilation, wear suitable respiratory equipment Environmental exposure controls Avoid release to the environment. SECTION 9 Physical and chemical properties 9.1. Information on basic physical and chemical properties Physical state Solid Colour white. Odour characteristic. Odour threshold 22/06/2017 EN (English) 3/9
4 ph ph solution % Relative evaporation rate (butylacetate=1) Melting point Freezing point Boiling point Flash point Auto-ignition temperature Decomposition temperature Flammability (solid, gas) Vapour pressure Relative vapour density at 20 C Relative density Solubility Log Pow Viscosity, kinematic Viscosity, dynamic Explosive properties Oxidising properties Explosive limits 9.2. Other information SECTION 10 Stability and reactivity Reactivity Non flammable soluble in water. The product is non-reactive under normal conditions of use, storage and transport Chemical stability Stable under normal conditions Possibility of hazardous reactions No dangerous reactions known under normal conditions of use Conditions to avoid None under recommended storage and handling conditions (see section 7) Incompatible materials Hazardous decomposition products Under normal conditions of storage and use, hazardous decomposition products should not be produced. SECTION 11 Toxicological information Information on toxicological effects Acute toxicity (1-hydroxyethylidene)bisphosphonic acid, sodium salt ( ) LD50 oral rat 1100 mg/kg disodium metasilicate ( ) LD50 oral rat LD50 dermal rat LC50 inhalation rat (mg/l) Skin corrosion/irritation Serious eye damage/irritation Respiratory or skin sensitisation Germ cell mutagenicity Carcinogenicity Reproductive toxicity STOT-single exposure > 1152 ( ) mg/kg > 5000 mg/kg > 2,06 g/m³ Causes severe skin burns and eye damage. Serious eye damage, category 1, implicit 22/06/2017 EN (English) 4/9
5 disodium metasilicate ( ) NOAEL (oral, rat) STOT-repeated exposure Aspiration hazard 227 mg/kg bodyweight SECTION 12 Ecological information Toxicity Ecology - general Before neutralisation, the product may represent a danger to aquatic organisms. (1-hydroxyethylidene)bisphosphonic acid, sodium salt ( ) LC50 fish mg/l EC50 Daphnia mg/l disodium metasilicate ( ) LC50 fish 1 EC50 Daphnia 1 ErC50 (algae) ErC50 (other aquatic plants) 210 mg/l 1700 mg/l 207 mg/l > 345,4 mg/l Persistence and degradability Bioaccumulative potential Mobility in soil Results of PBT and vpvb assessment Other adverse effects SECTION 13 Disposal considerations Waste treatment methods Waste treatment methods Dispose of contents/container in accordance with licensed collector s sorting instructions. SECTION 14 Transport information In accordance with ADR / RID / IMDG / IATA / ADN UN number UN-No. (ADR) 3262 UN-No. (IMDG) 3262 UN-No. (IATA) 3262 UN-No. (ADN) 3262 UN-No. (RID) UN proper shipping name Proper Shipping Name (ADR) Proper Shipping Name (IMDG) Proper Shipping Name (IATA) Proper Shipping Name (ADN) Proper Shipping Name (RID) Transport document description (ADR) Transport document description (IMDG) CORROSIVE SOLID, BASIC, INORGANIC, N.O.S. CORROSIVE SOLID, BASIC, INORGANIC, N.O.S. Corrosive solid, basic, inorganic, n.o.s. CORROSIVE SOLID, BASIC, INORGANIC, N.O.S. CORROSIVE SOLID, BASIC, INORGANIC, N.O.S. UN 3262 CORROSIVE SOLID, BASIC, INORGANIC, N.O.S. (sodium hydroxide, caustic soda), 8, III, (E) UN 3262 CORROSIVE SOLID, BASIC, INORGANIC, N.O.S. (sodium hydroxide, caustic soda), 8, III Transport hazard class(es) ADR Transport hazard class(es) (ADR) 8 22/06/2017 EN (English) 5/9
6 Danger labels (ADR) 8 IMDG Transport hazard class(es) (IMDG) 8 Danger labels (IMDG) 8 IATA Transport hazard class(es) (IATA) 8 Hazard labels (IATA) 8 ADN Transport hazard class(es) (ADN) 8 Danger labels (ADN) 8 RID Transport hazard class(es) (RID) 8 Danger labels (RID) Packing group Packing group (ADR) Packing group (IMDG) Packing group (IATA) Packing group (ADN) Packing group (RID) Environmental hazards Dangerous for the environment Marine pollutant Other information No No No supplementary information available 22/06/2017 EN (English) 6/9
7 14.6. Special precautions for user - Overland transport Classification code (ADR) C6 Special provisions (ADR) 274 Limited quantities (ADR) Excepted quantities (ADR) Packing instructions (ADR) Mixed packing provisions (ADR) Portable tank and bulk container instructions (ADR) Portable tank and bulk container special provisions (ADR) Tank code (ADR) Vehicle for tank carriage 5kg E1 P002, IBC08, LP02, R001 MP10 T1 TP33 SGAV, L4BN AT Transport category (ADR) 3 Special provisions for carriage - Bulk (ADR) Hazard identification number (Kemler No.) 80 Orange plates VC1, VC2, AP7 Tunnel restriction code (ADR) EAC code E 2X - Transport by sea Special provisions (IMDG) 223, 274 Limited quantities (IMDG) 5 kg Excepted quantities (IMDG) E1 Packing instructions (IMDG) P002, LP02 IBC packing instructions (IMDG) IBC08 IBC special provisions (IMDG) B3 Tank instructions (IMDG) T1 Tank special provisions (IMDG) TP33 EmS-No. (Fire) F-A EmS-No. (Spillage) S-B Stowage category (IMDG) A Properties and observations (IMDG) Reacts violently with acids. Causes burns to skin, eyes and mucous membranes. - Air transport PCA Excepted quantities (IATA) E1 PCA Limited quantities (IATA) Y845 PCA limited quantity max net quantity (IATA) 5kg PCA packing instructions (IATA) 860 PCA max net quantity (IATA) 25kg CAO packing instructions (IATA) 864 CAO max net quantity (IATA) 100kg Special provisions (IATA) A3 ERG code (IATA) 8L - Inland waterway transport Classification code (ADN) C6 Special provisions (ADN) 274 Limited quantities (ADN) 5 kg Excepted quantities (ADN) E1 Equipment required (ADN) PP, EP Number of blue cones/lights (ADN) 0 22/06/2017 EN (English) 7/9
8 - Rail transport Classification code (RID) C6 Special provisions (RID) 274 Limited quantities (RID) Excepted quantities (RID) Packing instructions (RID) Special packing provisions (RID) Mixed packing provisions (RID) Portable tank and bulk container instructions (RID) Portable tank and bulk container special provisions (RID) Tank codes for RID tanks (RID) 5kg E1 P002, IBC08, LP02, R001 B3 MP10 T1 Transport category (RID) 3 Special provisions for carriage Bulk (RID) Colis express (express parcels) (RID) TP33 SGAV, L4BN VC1, VC2, AP7 CE11 Hazard identification number (RID) Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code Not applicable SECTION 15 Regulatory information Safety, health and environmental regulations/legislation specific for the substance or mixture EU-Regulations Contains no REACH substances with Annex XVII restrictions Contains no substance on the REACH candidate list Contains no REACH Annex XIV substances Detergent Regulation Labelling of contents Component % phosphonates, non-ionic surfactants 15-30% National regulations Regulation (EC) No. 648/2004 of 31 March 2004 on detergents The surfactant(s) contained in this preparation complies(comply) with the biodegradability criteria as laid down in Regulation (EC) No. 648/2004 on detergents. Data to support this assertion are held at the disposal of the competent authorities of the Member States and will be made available to them, at their direct request or at the request of a detergent manufacturer Listed on the EEC inventory EINECS (European Inventory of Existing Commercial Chemical Substances)- Directive 79/831/EEC, sixth Amendment of Directive 67/548/EEC (dangerous substances) Chemical safety assessment No chemical safety assessment has been carried out SECTION 16 Other information Indication of changes According to Regulation (EC) No. 1907/2006 (REACH) with its amendment Regulation (EU) 2015/830. Other information This document is a translation of the original one issued in Spain. Full text of H- and EUH-statements Acute Tox. 4 (Oral) Acute toxicity (oral), Category 4 Eye Irrit. 2 Serious eye damage/eye irritation, Category 2 Met. Corr. 1 Corrosive to metals, Category 1 Skin Corr. 1A Skin corrosion/irritation, Category 1A Skin Corr. 1B Skin corrosion/irritation, Category 1B STOT SE 3 Specific target organ toxicity Single exposure, Category 3, Respiratory tract irritation H290 May be corrosive to metals H302 Harmful if swallowed H314 Causes severe skin burns and eye damage H319 Causes serious eye irritation 22/06/2017 EN (English) 8/9
9 H335 May cause respiratory irritation Classification and procedure used to derive the classification for mixtures according to Regulation (EC) 1272/2008 [CLP] Skin Corr. 1A H314 Calculation method applicable for regions GB - United Kingdom SDS EU (anexo II REACH) SALLO This information is based on our current knowledge and is intended to describe the product for the purposes of health, safety and environmental requirements only. It should not therefore be construed as guaranteeing any specific property of the product 22/06/2017 EN (English) 9/9
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