Material Safety Data Sheet Revision Date: 12/22/11

Transcription

1 Restek Corporation 110 Benner Circle Bellefonte, PA (814) (800) Fax: (814) I. PRODUCT IDENTIFICATION Catalog Number / Product Name: / Aromatics Mix Revision Number: 2 Intended use: For Laboratory use only II. HAZARD INDENTIFICATION Emergency Overview: Physical Hazards: Health Hazards: F - Highly flammable Xn - Harmful T - Toxic Repr. Cat 3 Xi - Irritant Routes of Entry: Inhalation, Skin Contact, Eye Contact, Ingestion Target Organs Potentially Affected By Exposure: Eyes, skin, respiratory tract, liver, kidneys, blood, CNS Chemical Interactions That Change Toxicity: None Known Immediate (Acute) Health Effects by Route of Exposure: Inhalation Irritation: Can cause moderate respiratory irritation, dizziness, weakness, fatigue, nausea and headache. Skin Contact: Can cause moderate skin irritation, defatting, and dermatitis. Not likely to cause permanent damage. Eye Contact: Contact with the eyes may cause moderate to severe eye injury. Eye contact may result in tearing and reddening, but not likely to permanently injure eye tissue. Temporary vision impairment (cloudy or blurred vision) is possible. Ingestion Irritation: Severely irritating to mouth, throat, and stomach. Can cause abdominal discomfort, nausea, vomiting and diarrhea. Long-Term (Chronic) Health Effects: Carcinogenicity: Reproductive and Developmental Toxicity: Inhalation: Skin Contact: Skin Absorption: Contains a probable or known human carcinogen. Contains a known human reproductive and/or developmental hazard. Upon prolonged and/or repeated exposure, can cause moderate respiratory irritation, dizziness, weakness, fatigue, nausea and headache.harmful! Can cause systemic damage upon prolonged and/or repeated exposure (see "Target Organs) Upon prolonged or repeated contact, can cause moderate skin irritation, defatting, and dermatitis. Not likely to cause permanent damage. Upon prolonged or repeated exposure, toxic if absorbed through the skin. Likely to cause systemic damage / Aromatics Mix Page 1 of 12

2 III. COMPOSITION / INFORMATION ON INGREDIENTS Chemical Name CAS # EINEC # % Composition Toluene Benzene Ethylbenzene phenylhexane isopropyltoluene (pcumene) t-butyl-3,5- dim o-xylene m-xylene isobutylbenzene Propylbenzene sec-butylbenzene m o-cymene ,2-Dim3- M2-propylbenzene, isopropylbenzene (cumene) M4- propylbenzene butylbenzene M3-propylbenzene, tert-butyl-2- m Benzene, 1,4-dim2- tert-butyl m ,2,4-trim pentylbenzene / Aromatics Mix Page 2 of 12

3 tert-butylbenzene ,3,5-tri m m-cymene p-xylene ,2,4-tri Benzene, 1,2-dim4-1,2,4,5- tetram ,2-di ,3-Dim ,3,5-trim Dim5-, 1, Methylbutylbenzene, IV. FIRST-AID MEASURES Inhalation: Remove to fresh air. If breathing is difficult, have a trained individual administer oxygen. If not breathing, give artificial respiration and have a trained individual administer oxygen. Get medical attention immediately Eyes: Immediately flush eyes with plenty of water for at least 20 minutes retracting eyelids often. Tilt the head to prevent chemical from transferring to the uncontaminated eye. Get immediate medical attention and monitor the eye daily as advised by your physician. Skin Contact: Wash with soap and water. Remove contaminated clothing and launder. Get medical attention if irritation develops or persists. Ingestion: Severely irritating. Do not induce vomiting. Seek medical attention immediately. Drink 2 glasses of water or milk to dilute. V. FIRE FIGHTING MEASURES Extinguishing Media: Fire and/or Explosion Hazards: Fire Fighting Methods and Protection: Hazardous Combustion Products: Use alcohol resistant foam, carbon dioxide, or dry chemical extinguishing agents. Water spray or fog may also be effective for extinguishing if swept across the base of the fire. Water can also be used to absorb heat and keep exposed material from being damaged by fire. Vapors may be ignited by heat, sparks, flames or other sources of ignition at or above the low flash point giving rise to a Class B fire. Vapors are heavier than air and may travel to a source of ignition and flash back Do not enter fire area without proper protection including self-contained toxic breathing apparatus and full protective equipment. Fight fire from a safe distance and a protected location due to the potential of hazardous vapors and decomposition products. Flammable component(s) of this material may be lighter than water and burn while floating on the surface. Use water spray/fog for cooling. Carbon dioxide, Carbon monoxide VI. ACCIDENTAL RELEASE MEASURES / Aromatics Mix Page 3 of 12

4 Personal Precautions and Equipment: Methods for Clean-up: Exposure to the spilled material may be irritating or harmful. Follow personal protective equipment recommendations found in Section 8 of this SDS. Additional precautions may be necessary based on special circumstances created by the spill including; the material spilled, the quantity of the spill, the area in which the spill occurred. Also consider the expertise of employees in the area responding to the spill. Prevent the spread of any spill to minimize harm to human health and the environment if safe to do so. Wear complete and proper personal protective equipment following the recommendation of Section 8 at a minimum. Dike with suitable absorbent material like granulated clay. Gather and store in a sealed container pending a waste disposal evaluation. VII. HANDLING AND STORAGE Handling Technical Measures and Precautions: Storage Technical Measures and Conditions: Harmful or irritating material. Avoid contacting and avoid breathing the material. Use only in a well ventilated area. Use spark-proof tools and explosion-proof equipment Store in a cool dry ventilated location. Isolate from incompatible materials and conditions. Keep container(s) closed. Keep away from heat, sparks, and flame VIII. EXPOSURE CONTROLS / PERSONAL PROTECTION United States: Chemical Name CAS No. IDLH ACGIH STEL ACGIH TLV- OSHA Exposure Limit Toluene ppm IDLH 50 ppm ; 188 mg/m3 200 ppm ; C 300 ppm Benzene ppm IDLH 2.5 ppm STEL; ppm ; 1.6 mg/m3 10 ppm (apply only mg/m3 STEL to exempt industry segments) Ethylbenzene ppm IDLH 125 ppm STEL; 100 ppm ; 434 mg/m3 100 ppm ; mg/m3 STEL mg/m3 phenylhexane ND No TLV No PEL established 4-isopropyltoluene (pcumene) ND No TLV No PEL established t-butyl-3,5- ND No TLV No PEL established dim o-xylene ppm IDLH 150 ppm STEL 100 ppm No PEL established m-xylene ppm IDLH 150 ppm STEL 100 ppm No PEL established isobutylbenzene ND No TLV No PEL established Propylbenzene ND No TLV No PEL established sec-butylbenzene ND No TLV No PEL established 3-m ND No TLV No PEL established o-cymene ND No TLV No PEL established 1,2-Dim ND No TLV No PEL established M2-propylbenzene, ND No TLV No PEL established isopropylbenzene ppm IDLH 50 ppm 50 ppm ; 245 mg/m3 (cumene) (10% LEL) M4-propylbenzene ND No TLV No PEL established butylbenzene ND No TLV No PEL established M3-propylbenzene, ND No TLV No PEL established tert-butyl-2- ND No TLV No PEL established m Benzene, 1,4-dim ND No TLV No PEL established tert-butyl-4- ND No TLV No PEL established m ND No TLV No PEL established 1,2,4-trim ND No TLV No PEL established pentylbenzene ND No TLV No PEL established tert-butylbenzene ND No TLV No PEL established 1,3,5-tri ND No TLV No PEL established 2-m ND No TLV No PEL established m-cymene ND No TLV No PEL established p-xylene ppm IDLH 150 ppm STEL 100 ppm No PEL established 1,2,4-tri ND No TLV No PEL established Benzene, 1,2-dim ND No TLV No PEL established / Aromatics Mix Page 4 of 12

5 1,2,4,5-tetram ND No TLV No PEL established 1,2-di ND No TLV No PEL established 1,3-Dim2- ND No TLV No PEL established 1,3,5-trim ND No TLV No PEL established Dim5-, ND No TLV No PEL established 1,3- Methylbutylbenzene, ND No TLV No PEL established United Kingdom: dim o-xylene m-xylene ppm STEL; 441 mg/m3 STEL 100 ppm STEL; 441 mg/m3 STEL isobutylbenzene Propylbenzene sec-butylbenzene m o-cymene ppm ; 220 mg/m3 50 ppm ; 220 mg/m3 Chemical Name CAS No. EINEC No. WEL-STEL WEL- Toluene ppm STEL; 384 mg/m3 STEL 50 ppm ; 191 mg/m3 Benzene ppm STEL (calculated); ppm ; 3.25 mg/m3 mg/m3 STEL (calculated) Ethylbenzene ppm STEL; 552 mg/m3 STEL 100 ppm ; 441 mg/m3 phenylhexane isopropyltoluene (pcumene) t-butyl-3,5-1,2-dim M2-propylbenzene, isopropylbenzene (cumene) ppm STEL; 250 mg/m3 STEL 25 ppm ; 125 mg/m3 M propylbenzene butylbenzene M3-propylbenzene, tert-butyl-2- m Benzene, 1,4-dim tert-butyl-4- m ,2,4-trim pentylbenzene tert-butylbenzene ,3,5-tri m m-cymene p-xylene ppm STEL; 441 mg/m3 STEL 1,2,4-tri Benzene, 1,2-dim ,2,4, tetram 1,2-di ,3-Dim2-50 ppm ; 220 mg/m / Aromatics Mix Page 5 of 12

6 1,3,5-trim Dim5-, ,3- Methylbutylbenzene, France: Chemical Name CAS No. EINEC No. VLCTs-STEL VME- Toluene ppm STEL [VLCT] (restrictive limit); 384 mg/m3 STEL [VLCT] 50 ppm [VME] ; 192 mg/m3 [VME] Benzene ppm [VME] ; 3.25 mg/m3 [VME] Ethylbenzene ppm STEL [VLCT] (restrictive limit); 442 mg/m3 STEL [VLCT] m-xylene ppm STEL [VLCT] (restrictive limit); 442 mg/m3 STEL [VLCT] isobutylbenzene Propylbenzene sec-butylbenzene m o-cymene ppm STEL [VLCT] (restrictive limit); 250 mg/m3 STEL [VLCT] 20 ppm [VME] ; 88.4 mg/m3 [VME] 50 ppm [VME] ; 221 mg/m3 [VME] 50 ppm [VME] ; 221 mg/m3 [VME] 20 ppm [VME] ; 100 mg/m3 [VME] phenylhexane isopropyltoluene (pcumene) t-butyl-3,5- dim o-xylene ppm STEL [VLCT] (restrictive limit); 442 mg/m3 STEL [VLCT] 1,2-Dim3- M2-propylbenzene, isopropylbenzene (cumene) M propylbenzene butylbenzene M3-propylbenzene, tert-butyl-2- m Benzene, 1,4-dim tert-butyl-4- m ,2,4-trim ppm STEL 20 ppm [VME] [VLCT] (restrictive ; 100 limit); 250 mg/m3 mg/m3 [VME] STEL [VLCT] pentylbenzene tert-butylbenzene ,3,5-tri m m-cymene / Aromatics Mix Page 6 of 12

7 p-xylene ppm STEL [VLCT] (restrictive limit); 442 mg/m3 STEL [VLCT] 1,2,4-tri Benzene, 1,2-dim ,2,4, tetram 1,2-di ,3-Dim2-1,3,5-trim Dim5-, ,3- Methylbutylbenzene, ppm [VME] ; 221 mg/m3 [VME] M2-propylbenzene, isopropylbenzene (cumene) ppm AGW (The risk of damage to the BAT values are observed, exposure factor 2.5); 100 mg/m3 AGW (The risk of damage to the BAT values are observed, exposure factor 2.5) Germany: Chemical Name CAS No. EINEC No. VELs Toluene ppm AGW (The risk of damage to the BAT values are observed, exposure factor 4); 190 mg/m3 AGW (The risk of damage to the BAT values are observed, exposure factor 4) Benzene Ethylbenzene ppm AGW (exposure factor 2); 440 mg/m3 AGW (exposure factor 2) phenylhexane isopropyltoluene (pcumene) t-butyl-3,5- dim o-xylene m-xylene isobutylbenzene Propylbenzene sec-butylbenzene m o-cymene ,2-Dim M4-propylbenzene butylbenzene M3-propylbenzene, tert-butyl-2- m Benzene, 1,4-dim tert-butyl-4- m ,2,4-trim ppm AGW (The risk of damage to the BAT values are observed, exposure factor 2); 100 mg/m3 AGW (The risk of damage to the BAT values are observed, exposure factor 2) pentylbenzene tert-butylbenzene / Aromatics Mix Page 7 of 12

8 1,3,5-tri m m-cymene p-xylene ,2,4-tri Benzene, 1,2-dim ,2,4,5-tetram ,2-di ,3-Dim2-1,3,5-trim ppm AGW (The risk of damage to the BAT values are observed, exposure factor 2); 100 mg/m3 AGW (The risk of damage to the BAT values are observed, exposure factor 2) Dim5-, ,3- Methylbutylbenzene, Personal Protection: Engineering Measures: Respiratory Protection: Eye Protection: Skin Protection: Local exhaust ventilation or other engineering controls are normally required when handling or using this product to avoid overexposure. Respiratory protection may be required to avoid overexposure when handling this product. General or local exhaust ventilation is the preferred means of protection. Use a respirator if general room ventilation is not available or sufficient to eliminate symptoms. Wear chemically resistant safety glasses with side shields when handling this product. Wear additional eye protection such as chemical splash goggles and/or face shield when the possibility exists for eye contact with splashing or spraying liquid, or airborne material. Do not wear contact lenses. Have an eye wash station available. Wear protective gloves. Inspect gloves for chemical break-through and replace at regular intervals. Clean protective equipment regularly. Wash hands and other exposed areas with mild soap and water before eating, drinking, and when leaving work IX. PHYSICAL AND CHEMICAL PROPERTIES Appearance, color: Colorless Odor: ModerateAromatic ph: No data available. Flash Point: No data available. Flammability: Highly Flammable Autoignition Temperature: 480 deg C Evaporation Rate: No data available. Odor Threshold: No data available. Solubility: Not determined VOC % by weight: No data available. Molecular Weight: No data available. X. STABILITY AND REACTIVITY: Stability: Materials to Avoid / Chemical Incompatiability: Hazardous Decomposition Products: Stable under normal conditions. Strong oxidizing agents Carbon dioxide Carbon monoxide XI. TOXICOLOGICAL INFORMATION: Component Toxicological Data: NIOSH: / Aromatics Mix Page 8 of 12

9 Chemical Name CAS No. LD50/LC50 Toluene Inhalation LC50 Rat : 49 gm/m3/4h; Inhalation LC50 Mouse : 400 ppm/24h; Oral LD50 Rat : 636 mg/kg; Dermal LD50 Rabbit : ul/kg Benzene Inhalation LC50 Rat ppm 4 h; Oral LD50 Rat 1800 mg/kg Benzene, Oral LD50 Rat : 3500 mg/kg; Dermal LD50 Rabbit : ul/kg p-cymene Oral LD50 Rat 3669 mg/kg o-xylene Inhalation LC50 Rat 2180 ppm 4 h; Oral LD50 Rat 3609 mg/kg m-xylene Oral LD50 Rat 5000 mg/kg; Dermal LD50 Rabbit µl/kg Isobutylbenzene Dermal LD50 Rat >2000 mg/kg Benzene, propyl Oral LD50 Rat 6040 mg/kg Benzene, sec-butyl Oral LD50 Rat 2240 mg/kg; Dermal LD50 Rabbit >16 ml/kg Benzene, m2-(methylethyl) Oral LD50 Rat 2130 mg/kg Cumene Oral LD50 Rat 1400 mg/kg; Inhalation LC50 Rat mg/m3 4 h; Dermal LD50 Rabbit >3160 mg/kg p-ethyltoluene Oral LD50 Rat 4850 mg/kg; Inhalation LC50 Mouse mg/m3 4 h Benzene, 1,2,4-trim Inhalation LC50 Rat 18 g/m3 4 h; Oral LD50 Rat 3400 mg/kg; Dermal LD50 Rabbit >3160 mg/kg tert-butylbenzene Oral LD50 Rat 3045 mg/kg Toluene, o Inhalation LC50 Mouse 54 g/m3 4 h Benzene, m3-(methylethyl) Oral LD50 Rat 2970 mg/kg p-xylene Inhalation LC50 Rat 4550 ppm 4 h; Oral LD50 Rat >3392 mg/kg Component Carcinogenic Data: OSHA: Chemical Name CAS No. Benzene Monograph 29, Supplement 7; 1987; {IARC - Group 1 (carcinogenic to humans)}; Known Carcinogen; {NTP Eighth Report - Known Carcinogens}; 1 ppm ; 5 ppm STEL; 0.5 ppm action limit; Cancer hazard; Flammable (see 29 CFR ); {OSHA - 29 CFR 1910 Specifically Regulated Chemicals} Present Cumene Present ACGIH: Chemical Name CAS No. Toluene A4 - Not Classifiable as a Human Carcinogen Benzene A1 - Confirmed Human Carcinogen Aconfirmed human carcinogen A3 - Confirmed Animal Carcinogen with Unknown Relevance to Humans o-xylene A4 - Not Classifiable as a Human Carcinogen m-xylene A4 - Not Classifiable as a Human Carcinogen p-xylene A4 - Not Classifiable as a Human Carcinogen NIOSH: Chemical Name CAS No. Benzene potential occupational carcinogen NTP: Chemical Name CAS No. Benzene Known Carcinogen IARC: Chemical Name CAS No. Group No. Monograph 29, Supplement 7; Group 1 Group 2A Group 2B Cumene Group 2B / Aromatics Mix Page 9 of 12

10 XII. ECOLOGICAL INFORMATION: Overview: Moderate ecological hazard. This product may be dangerous to plants and/or wildlife. Mobility: No data Persistence: No data Bioaccumulation: No data Degradability: No data Ecological Toxicity Data: 0 XIII. DISPOSAL CONSIDERATIONS: Waste Description of Spent Product: Disposal Methods: Waste Disposal of Packaging: Spent or discarded material is a hazardous waste. Dispose of by incineration following Federal, State, Local, or Provincial regulations. Comply with all Local, State, Federal, and Provincial Environmental Regulations. XIV: TRANSPORTATION INFORMATION: United States: DOT Proper Shipping Name: Flammable liquids, n.o.s. (Toluene, Benzene) UN Number: UN1993 Hazard Class: 3 Packing Group: II International: IATA Proper Shipping Name: Flammable liquids, n.o.s. (Toluene, Benzene) UN Number: UN1993 Hazard Class: 3 Packing Group: II Marine Pollutant: Yes XV. REGULATORY INFORMATION: United States: Chemical Name CAS# CERCLA SARA 313 SARA EHS 313 TSCA Toluene X X - X Benzene X X - X Ethylbenzene X X - X phenylhexane X 4-isopropyltoluene (p-cumene) X t-butyl-3,5-dim o-xylene X X - X m-xylene X X - X isobutylbenzene X Propylbenzene X sec-butylbenzene X 3-m o-cymene X 1,2-Dim X M2-propylbenzene, X isopropylbenzene (cumene) X X - X M4-propylbenzene X butylbenzene X M3-propylbenzene, X tert-butyl-2-m Benzene, 1,4-dim X tert-butyl-4- m X 1,2,4-trim X - X pentylbenzene X tert-butylbenzene X 1,3,5-tri X / Aromatics Mix Page 10 of 12

11 2-m X m-cymene X p-xylene X X - X 1,2,4-tri Benzene, 1,2-dim X 1,2,4,5-tetram X 1,2-di ,3-Dim2-1,3,5-trim X Dim5-, 1, X Methylbutylbenzene, The following chemicals are listed on CA Prop 65: Chemical Name CAS # Regulation Benzene Prop 65 Cancer Prop 65 Cancer Cumene Prop 65 Cancer Toluene Prop 65 Devolop Tox Benzene Prop 65 Devolop Tox Toluene Prop 65 Rep Female Benzene Prop 65 Rep Male State Right To Know Listing: Chemical Name CAS# New Jersey Massachusetts Pennsylvania California Toluene X X X X Benzene X X X X Ethylbenzene X X X X phenylhexane isopropyltoluene (pcumene) X X - t-butyl-3,5- dim o-xylene X X X X m-xylene X X X X isobutylbenzene X X X - Propylbenzene X X X - sec-butylbenzene X X - 3-m o-cymene ,2-Dim M2-propylbenzene, isopropylbenzene X X X X (cumene) M4-propylbenzene butylbenzene X - X - M3-propylbenzene, tert-butyl-2- m Benzene, 1,4-dim tert-butyl-4- m ,2,4-trim X X X - pentylbenzene X - X - tert-butylbenzene X X X - 1,3,5-tri m m-cymene p-xylene X X X X 1,2,4-tri Benzene, 1,2-dim / Aromatics Mix Page 11 of 12

12 1,2,4, tetram 1,2-di X X - 1,3-Dim2-1,3,5-trim X - X Dim5-, ,3- Methylbutylbenzene, EU Directives Classification: Hazard Symbols Risk Phrases: Safety Phrases: Water Hazard Class: R63 - Possible risk of harm to the unborn child R46 - May cause heritable genetic damage R45 - May cause cancer R65 - Harmful: may cause lung damage if swallowed R38 - Irritating to skin R48/20/21/22 - Harmful: danger of serious damage to health by prolonged exposure through inhalation, in contact with skin and if swallowed R10 - Flammable R11 - Highly flammable S16:Keep away from sources of ignition - No smoking S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice S36/37/39:Wear suitable protective clothing, gloves and eye/face protection S53:Avoid exposure - obtain special instruction before use ID Number 5956, hazard class 2 - hazard to waters ID Number 3355, hazard class 3 - severe hazard to waters ID Number 4736, hazard class 2 - hazard to waters ID Number 3925, hazard class 2 - hazard to waters XVI: ADDITIONAL INFORMATION Prior Version Date: 01/02/09 Disclaimer Restek Corporation provides the descriptions, data and information contained herein in good faith but makes no representation as to its comprehensiveness or accuracy. It is provided for your guidance only. Because many factors may affect processing or application/use, Restek Corporation recommends you perform an assessment to determine the suitability of a product for your particular purpose prior to use. No warranties of any kind, either expressed or implied, including fitness for a particular purpose, are made regarding prodcuts described, data or information set forth. In no case shall the descriptions, information, or data provided be considered a part of our terms and conditions of sale. Further, the descriptions, data and information furnished hereunder are given gratis. No obligation or liability for the description, data and information given are assumed. All such being given and accepted at your risk / Aromatics Mix Page 12 of 12