HYSOL UF3537 BULK MSDS-No. : V001.2 Revision: printing date: HYSOL UF3537 BULK.

Transcription

1 Safety Data Sheet Page 1 of 6 HYSOL UF3537 BULK MSDS-No. : Revision: printing date: Section 1. Identification of the substance/preparation and of the company/undertaking Product name: HYSOL UF3537 BULK Identification of manufacturer, importer or distributor Importer: Henkel Malaysia Sdn Bhd 46th Floor, Menara TM, Jalan Pantai Baharu, Kuala Lumpur, Malaysia. Phone : Fax : address of person responsible for Safety Data Sheet: ap-ua-psra.sea@henkel.com Section 2. Composition / information on ingredients Declaration of ingredients: 7-Oxabicyclo[4.1.0]hept-3-ylmethyl 7- oxabicyclo[4.1.0]heptane-3- Reaction product: bisphenol-f- (epichlorhydrin); epoxy resin (number average molecular weight <= 700) Trimethylolpropane triglycidyl ether EINECS content Classification % Xi - Irritant; R % Xi - Irritant; R36/38 Xi - Irritant; R43 N - Dangerous for the environment; R51/ % Xi - Irritant; R36/38, R43 R52/ % % Section 3. Hazards identification Hazard classification: Risk phrases: Xi - Irritant R36/38 Irritating to eyes and skin. R43 May cause sensitisation by skin contact. R52/53 Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment. Section 4. First aid measures Inhalation: Move to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical attention.

2 Skin contact: Eye contact: Ingestion: HYSOL UF3537 BULK Page 2 of 6 Immediately flush skin with plenty of water (using soap, if available). Remove contaminated clothing and footwear. If symptoms develop and persist, get medical attention. Wash clothing before reuse. Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Get medical attention. Do not induce vomiting. Never give anything by mouth to an unconscious person. Get medical attention. Section 5. Fire fighting measures Suitable extinguishing media: Special protection equipment for firefighters: Particular danger/case of fire: Water spray (fog), foam, dry chemical or carbon dioxide. Do not use high volume water jet. Wear self-contained breathing apparatus and full protective clothing, such as turn-out gear. In case of fire, keep containers cool with water spray. Uncontrolled polymerization may occur at high temperatures resulting in explosions or rupture of storage containers. Hazardous combustion products: Oxides of carbon. Oxides of nitrogen. Phenolics. Toxic and irritating vapors. Section 6. Accidental release measures Environmental precautions: Clean-up methods: Do not allow product to enter sewer or waterways. Ensure adequate ventilation. Soak up with inert absorbent material (e.g. sand, silica gel, acid binder, universal binder, sawdust). Store in a closed container until ready for disposal. Section 7. Handling and storage Handling: Storage: Use only with adequate ventilation. Keep away from heat, spark and flame. Prevent contact with eyes, skin and clothing. Do not breathe vapor and mist. Wash thoroughly after handling. Keep in a cool, well ventilated area away from heat, sparks and open flame. Keep container tightly closed until ready for use. For optimum shelf life store in original containers under refrigerated conditions at 2-8 C ( F)

3 HYSOL UF3537 BULK Page 3 of 6 Section 8. controls / personal protection Ingredient Type ppm mg/m 3 Remarks SILICA AMORPHOUS, SILICA GEL Time Weighted Average 10 MY OEL SILICA AMORPHOUS, PRECIPITATED SILICA Time Weighted Average 6 SILICA AMORPHOUS, SILICA GEL SILICA AMORPHOUS, PRECIPITATED SILICA Time Weighted Average Time Weighted Average 10 MY OEL 6 Respiratory protection: Eye protection: Body protection: Engineering controls: Use NIOSH approved respirator if there is potential to exceed exposure limit(s). Safety goggles or safety glasses with side shields. Full face protection should be used if the potential for splashing or spraying of product exists. Safety showers and eye wash stations should be available. Use chemical resistant, impermeable clothing including gloves and either an apron or body suit to prevent skin contact. Provide adequate local exhaust ventilation to maintain worker exposure below exposure limits. Section 9. Physical and chemical properties Appearance: Yellow paste, Liquid Odor: None Specific gravity: 1,4 Flash point: > 100 C (> 212 F) Density: 1,4 g/cm3 Solubility: Solvent: Water, Not miscible or difficult to mix VOC content 0 % (calculated) Section 10. Stability and reactivity Conditions to avoid: Materials to avoid: Heat, flames, sparks and other sources of ignition. Store away from incompatible materials. High temperatures. Strong oxidizing agents. Strong acids. Strong alkalis. Amines. Water. Hazardous decomposition products: Hazardous polymerization: Oxides of carbon. Phenolics. Aldehydes. Irritating organic vapours. None under normal processing. Polymerization may occur at elevated temperature or in the presence of incompatible materials.

4 HYSOL UF3537 BULK Page 4 of 6 Section 11. Toxicological information toxicity: Trimethylolpropane triglycidyl ether Value Value Route of type application LD50 > mg/kg oral LD0 > mg/kg oral rat OECD Guideline 401 ( Oral Toxicity) LD0 > mg/kg oral rat OECD Guideline 401 ( Oral Toxicity) Skin corrosion/irritation: not irritating rabbit OECD Guideline 404 ( Dermal Irritation / Corrosion) not irritating rabbit OECD Guideline 404 ( Dermal Irritation / Corrosion) Serious eye damage/irritation: not irritating rabbit OECD Guideline 405 ( Eye Irritation / Corrosion) not irritating rabbit OECD Guideline 405 ( Eye Irritation / Corrosion) Germ cell mutagenicity: Type of study / Route of administration negative bacterial reverse mutation assay (e.g Ames test) negative bacterial reverse mutation assay (e.g Ames test) Metabolic activation / with and without with and without Repeated dose toxicity Route of application / Frequency of treatment NOAEL=< 0,046 inhalation 14 days 6 hours/day, 5 days/week NOAEL=< 0,046 inhalation 14 days 6 hours/day, 5 days/week rat rat Section 12. Ecological information

5 HYSOL UF3537 BULK Page 5 of 6 Toxicity: Value type Value Toxicity Study LC50 24 mg/l Fish Oncorhynchus mykiss OECD Guideline 203 (Fish, Toxicity EC50 40 mg/l Daphnia Daphnia magna OECD Guideline 202 (Daphnia sp. Immobilisation EC50 90 mg/l Algae Selenastrum capricornutum (new name: Pseudokirchnerella subcapitata) LC50 > mg/l Fish 96 h Brachydanio rerio (new name: Danio rerio) OECD Guideline 201 (Alga, Growth Inhibition OECD Guideline 203 (Fish, Toxicity EC50 > mg/l Daphnia 24 h Daphnia magna OECD Guideline 202 (Daphnia sp. Immobilisation EC mg/l Algae 72 h Selenastrum capricornutum (new name: Pseudokirchnerella subcapitata) LC50 > mg/l Fish 96 h Brachydanio rerio (new name: Danio rerio) ISO 8692 (Water Quality OECD Guideline 203 (Fish, Toxicity EC50 > mg/l Daphnia 24 h Daphnia magna OECD Guideline 202 (Daphnia sp. Immobilisation EC mg/l Algae 72 h Selenastrum capricornutum (new name: Pseudokirchnerella subcapitata) ISO 8692 (Water Quality Persistence and degradability: Route of application Degradability 71 % OECD Guideline 301 B (Ready Biodegradability: CO2 Evolution Bioaccumulative potential / Mobility in soil: LogKow Bioconcentration factor (BCF) 1,34 Temperature Section 13. Disposal considerations Product of disposal: Packaging Disposal for uncleaned package: Dispose of in accordance with local and national regulations. Packaging that cannot be cleaned are to be disposed of in the same manner as the product.

6 HYSOL UF3537 BULK Page 6 of 6 Section 14. Transport information General information: Not hazardous according to RID, ADR, ADNR, IMDG, IATA-DGR. Section 15. Regulations - classification and identification Indication of danger: Risk phrases: Safety phrases: Xi - Irritant R36/38 Irritating to eyes and skin. R43 May cause sensitisation by skin contact. R52/53 Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment. S24 Avoid contact with skin. S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S37 Wear suitable gloves. S60 This material and its container must be disposed of as hazardous waste. Section 16. Other information Issue date: Disclaimer This information is based on our current level of knowledge and relates to the product in the state in which it is delivered. It is intended to describe our products from the point of view of safety requirements and is not intended to guarantee any particular properties. This safety data sheet was prepared in accordance with Council Directive 67/548/EEC and it's subsequent amendments, and Commission Directive 1999/45/EC.