1.4. Emergency telephone number Country Organisation/Company Address Emergency number Comment. Penarth CF64 2XX Cardiff
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1 Date of issue: Revision date: Version: 1.0 SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier Product form : Mixture Trade name : Cleansol Bio Product code : Type of product Product group : Detergent : Trade product 1.2. Relevant identified uses of the substance or mixture and uses advised against Relevant identified uses Main use category Use of the substance/mixture Uses advised against 1.3. Details of the supplier of the safety data sheet Kroon Oil BV Dollegoorweg EC Almelo - Netherlands T 0031 (0) vib@kroon_oil.nl 1.4. Emergency telephone number : Industrial use,professional use : Washing and cleaning products (including solvent based products) Country Organisation/Company Address Emergency number Comment United Kingdom National Poisons Information Service (Cardiff Centre) Gwenwyn Ward, Llandough Hospital SECTION 2: Hazards identification 2.1. Classification of the substance or mixture Penarth CF64 2XX Cardiff Classification according to Regulation (EC) No. 1272/2008 [CLP]Mixtures/Substances: SDS EU 2015: According to Regulation (EU) 2015/830 (REACH Annex II) Skin corrosion/irritation, Category 2 H315 Serious eye damage/eye irritation, Category 1 Full text of H statements : see section 16 Adverse physicochemical, human health and environmental effects Causes skin irritation. Causes serious eye damage Label elements H318 Labelling according to Regulation (EC) No. 1272/2008 [CLP]Extra labelling to displayextra classification(s) to display Hazard pictograms (CLP) : Signal word (CLP) Hazardous ingredients Hazard statements (CLP) Precautionary statements (CLP) 2.3. Other hazards GHS05 : Danger : 2-aminoethanol; 2-(2-ethylhexoxy)ethanol : H315 - Causes skin irritation. H318 - Causes serious eye damage. : P280 - Wear protective gloves/protective clothing/eye protection/face protection. P305+P351+P338+P310 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a doctor, a POISON CENTER. P332+P313 - If skin irritation occurs: Get medical advice/attention. P362+P364 - Take off contaminated clothing and wash it before reuse. SECTION 3: Composition/information on ingredients 3.1. Substances EN (English) 1/8
2 3.2. Mixtures Name Product identifier % Classification according to Regulation (EC) No. 1272/2008 [CLP] 2-aminoethanol (CAS-No.) (EC-No.) (EC Index-No.) (REACH-no) (2-butoxyethoxy)ethanol, diethylene glycol monobutyl ether (CAS-No.) (EC-No.) (EC Index-No.) (REACH-no) (2-ethylhexoxy)ethanol (CAS-No.) (EC-No.) Full text of H-statements: see section ,5 Acute Tox. 4 (Oral), H302 Acute Tox. 4 (Dermal), H312 Acute Tox. 4 (Inhalation), H332 Skin Corr. 1B, H314 Eye Dam. 1, H318 STOT SE 3, H335 < 2,5 Eye Irrit. 2, H ,5 Eye Dam. 1, H318 SECTION 4: First aid measures 4.1. Description of first aid measures First-aid measures after inhalation First-aid measures after skin contact First-aid measures after eye contact First-aid measures after ingestion : Remove person to fresh air and keep comfortable for breathing. : Wash skin with plenty of water. Take off contaminated clothing. If skin irritation occurs: Get medical advice/attention. : Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Call a physician immediately. : Call a poison center or a doctor if you feel unwell Most important symptoms and effects, both acute and delayed Symptoms/effects after skin contact : Irritation. Symptoms/effects after eye contact : Serious damage to eyes Indication of any immediate medical attention and special treatment needed Treat symptomatically. SECTION 5: Firefighting measures 5.1. Extinguishing media Suitable extinguishing media : Water spray. Dry powder. Foam. Carbon dioxide Special hazards arising from the substance or mixture Hazardous decomposition products in case of fire : Toxic fumes may be released Advice for firefighters Protection during firefighting SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures : Do not attempt to take action without suitable protective equipment. Self-contained breathing apparatus. Complete protective clothing For non-emergency personnel Emergency procedures : Ventilate spillage area. Avoid contact with skin and eyes For emergency responders Protective equipment 6.2. Environmental precautions Avoid release to the environment Methods and material for containment and cleaning up Methods for cleaning up : Take up liquid spill into absorbent material. Other information 6.4. Reference to other sections For further information refer to section 13. : Do not attempt to take action without suitable protective equipment. For further information refer to section 8: "Exposure controls/personal protection". : Dispose of materials or solid residues at an authorized site. SECTION 7: Handling and storage 7.1. Precautions for safe handling Precautions for safe handling : Ensure good ventilation of the work station. Avoid contact with skin and eyes. Wear personal protective equipment. EN (English) 2/8
3 Hygiene measures : Wash contaminated clothing before reuse. Do not eat, drink or smoke when using this product. Always wash hands after handling the product Conditions for safe storage, including any incompatibilities Storage conditions : Store in a well-ventilated place. Keep cool Specific end use(s) SECTION 8: Exposure controls/personal protection 8.1. Control parameters 2-aminoethanol ( ) EU Local name 2-Aminoethanol EU IOELV TWA (mg/m³) 2,5 mg/m³ EU IOELV TWA (ppm) 1 ppm EU IOELV STEL (mg/m³) 7,6 mg/m³ EU IOELV STEL (ppm) 3 ppm EU Notes skin EU Regulatory reference COMMISSION DIRECTIVE 2006/15/EC United Kingdom Local name 2-Aminoethanol United Kingdom WEL TWA (mg/m³) 2,5 mg/m³ United Kingdom WEL TWA (ppm) 1 ppm United Kingdom WEL STEL (mg/m³) 7,6 mg/m³ United Kingdom WEL STEL (ppm) 3 ppm United Kingdom Remark (WEL) Sk (Can be absorbed through the skin. The assigned substances are those for which there are concerns that dermal absorption will lead to systemic toxicity) United Kingdom Regulatory reference EH40/2005 (Third edition, 2018). HSE EU Local name 2-(2-Butoxyethoxy)ethanol EU IOELV TWA (mg/m³) 67,5 mg/m³ EU IOELV TWA (ppm) 10 ppm EU IOELV STEL (mg/m³) 101,2 mg/m³ EU IOELV STEL (ppm) 15 ppm EU Regulatory reference COMMISSION DIRECTIVE 2006/15/EC United Kingdom Local name 2-(2-Butoxyethoxy)ethanol United Kingdom WEL TWA (mg/m³) 67,5 mg/m³ United Kingdom WEL TWA (ppm) 10 ppm United Kingdom WEL STEL (mg/m³) 101,2 mg/m³ United Kingdom WEL STEL (ppm) 15 ppm United Kingdom Regulatory reference EH40/2005 (Third edition, 2018). HSE 8.2. Exposure controls Appropriate engineering controls: Ensure good ventilation of the work station. Hand protection: Protective gloves Type Material Permeation Thickness (mm) Penetration Standard Reusable gloves Nitrile rubber (NBR), Neoprene rubber (HNBR) 5 (> 240 minutes), 6 (> 480 minutes) >=0,35 EN 374 EN (English) 3/8
4 Eye protection: Safety glasses Type Use Characteristics Standard Safety glasses Droplet clear EN 166 Skin and body protection: Wear suitable protective clothing Respiratory protection: In case of insufficient ventilation, wear suitable respiratory equipment Personal protective equipment symbol(s): Environmental exposure controls: Avoid release to the environment. SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties Physical state : Liquid Colour Odour Odour threshold ph : 11 Relative evaporation rate (butylacetate=1) Melting point Freezing point : light brown. : alcohol odour. : Boiling point : > 100 C Flash point Auto-ignition temperature Decomposition temperature Flammability (solid, gas) Vapour pressure Relative vapour density at 20 C Relative density Density Solubility Log Pow : < 3 Viscosity, kinematic Viscosity, dynamic Explosive properties Oxidising properties Explosive limits 9.2. Other information : : 1,02 g/cm³ (20 C) : Water: completely soluble : < 9,804 mm²/s : < 10 mpa s (20 C) SECTION 10: Stability and reactivity Reactivity The product is non-reactive under normal conditions of use, storage and transport Chemical stability Stable under normal conditions Possibility of hazardous reactions No dangerous reactions known under normal conditions of use Conditions to avoid None under recommended storage and handling conditions (see section 7). EN (English) 4/8
5 10.5. Incompatible materials Hazardous decomposition products Under normal conditions of storage and use, hazardous decomposition products should not be produced. SECTION 11: Toxicological information Information on toxicological effects Acute toxicity (oral) Acute toxicity (dermal) Acute toxicity (inhalation) LD50 oral rat LD50 dermal rabbit Skin corrosion/irritation Serious eye damage/irritation Respiratory or skin sensitisation Germ cell mutagenicity Carcinogenicity Reproductive toxicity STOT-single exposure STOT-repeated exposure Aspiration hazard 3384 mg/kg 2700 mg/kg : Causes skin irritation. ph: 11 : Causes serious eye damage. ph: 11 Cleansol Bio Viscosity, kinematic < 9,804 mm²/s SECTION 12: Ecological information Toxicity Ecology - general Acute aquatic toxicity Chronic aquatic toxicity : The product is not considered harmful to aquatic organisms nor to cause long-term adverse effects in the environment. LC50 fish mg/l Lepomis macrochirus; 96 h LC50 fish mg/l Leuciscus idus melanotus; 48 h (DIN 38412) EC50 Daphnia 1 EC50 96h algae (1) > 101 mg/l > 101 mg/l NOEC (acute) > 100 mg/l Desmodesmus subspicatus (green algae); 96 h (OCDE Guideline 201) Persistence and degradability Persistence and degradability Readily biodegradable. Biodegradation 76 % (28 d) [OECD 301 D] Bioaccumulative potential Cleansol Bio Log Pow < 3 Log Kow 0, Mobility in soil Results of PBT and vpvb assessment EN (English) 5/8
6 12.6. Other adverse effects SECTION 13: Disposal considerations Waste treatment methods Waste treatment methods : Dispose of contents/container in accordance with licensed collector s sorting instructions. SECTION 14: Transport information In accordance with ADR / RID / IMDG / IATA / ADN UN number ADR IMDG IATA ADN RID UN proper shipping name Transport hazard class(es) Packing group Environmental hazards No supplementary information available Special precautions for user Overland transport Transport by sea Air transport Inland waterway transport Rail transport Transport in bulk according to Annex II of Marpol and the IBC Code SECTION 15: Regulatory information Safety, health and environmental regulations/legislation specific for the substance or mixture EU-Regulations Contains no REACH substances with Annex XVII restrictions Contains no substance on the REACH candidate list Contains no REACH Annex XIV substances Detergent Regulation : Labelling of contents (648/2004/EC): Component % amphoteric surfactants, non-ionic surfactants <5% Directive 2012/18/EU (SEVESO III) National regulations Chemical safety assessment No chemical safety assessment has been carried out EN (English) 6/8
7 SECTION 16: Other information Abbreviations and acronyms: ADN ADR ATE BCF European Agreement concerning the International Carriage of Dangerous Goods by Inland Waterways European Agreement concerning the International Carriage of Dangerous Goods by Road Acute Toxicity Estimate Bioconcentration factor CLP Classification Labelling Packaging Regulation; Regulation (EC) No 1272/2008 DMEL DNEL EC50 IARC IATA IMDG LC50 LD50 LOAEL NOAEC NOAEL NOEC OECD PNEC PBT Derived Minimal Effect level Derived-No Effect Level Median effective concentration International Agency for Research on Cancer International Air Transport Association International Maritime Dangerous Goods Median lethal concentration Median lethal dose Lowest Observed Adverse Effect Level No-Observed Adverse Effect Concentration No-Observed Adverse Effect Level No-Observed Effect Concentration Organisation for Economic Co-operation and Development Predicted No-Effect Concentration Persistent Bioaccumulative Toxic REACH Registration, Evaluation, Authorisation and Restriction of Chemicals Regulation (EC) No 1907/2006 RID STP TLM SDS vpvb Full text of H- and EUH-statements: Regulations concerning the International Carriage of Dangerous Goods by Rail Sewage treatment plant Median Tolerance Limit Very Persistent and Very Bioaccumulative Acute Tox. 4 (Dermal) Acute toxicity (dermal), Category 4 Acute Tox. 4 (Inhalation) Acute toxicity (inhal.), Category 4 Acute Tox. 4 (Oral) Acute toxicity (oral), Category 4 Eye Dam. 1 Serious eye damage/eye irritation, Category 1 Eye Irrit. 2 Serious eye damage/eye irritation, Category 2 Skin Corr. 1B STOT SE 3 H302 H312 H314 H315 H318 H319 H332 H335 Skin corrosion/irritation, Category 1B Specific target organ toxicity Single exposure, Category 3, Respiratory tract irritation Harmful if swallowed. Harmful in contact with skin. Causes severe skin burns and eye damage. Causes skin irritation. Causes serious eye damage. Causes serious eye irritation. Harmful if inhaled. May cause respiratory irritation. EN (English) 7/8
8 SDS EU (REACH Annex II) This information is based on our current knowledge and is intended to describe the product for the purposes of health, safety and environmental requirements only. It should not therefore be construed as guaranteeing any specific property of the product EN (English) 8/8
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