1.4. Emergency telephone number Country Organisation/Company Address Emergency number Comment. Penarth CF64 2XX Cardiff
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1 Date of issue: Version: 1.0 SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier Product form : Mixture Trade name Product code Product group : Coolant NF : PC : Trade product 1.2. Relevant identified uses of the substance or mixture and uses advised against Relevant identified uses Intended for general public Main use category Use of the substance/mixture Uses advised against 1.3. Details of the supplier of the safety data sheet Putoline Oil Dollegoorweg EC Almelo - Netherlands T 0031 (0) vib@putoline.com 1.4. Emergency telephone number : Industrial use,professional use,consumer use : Antifreeze and coolant Country Organisation/Company Address Emergency number Comment United Kingdom National Poisons Information Service (Cardiff Centre) Gwenwyn Ward, Llandough Hospital SECTION 2: Hazards identification 2.1. Classification of the substance or mixture Penarth CF64 2XX Cardiff Classification according to Regulation (EC) No. 1272/2008 [CLP]Mixtures/Substances: SDS EU 2015: According to Regulation (EU) 2015/830 (REACH Annex II) Acute toxicity (oral), Category 4 H302 Specific target organ toxicity Repeated exposure, Category 2 Full text of H statements : see section 16 H373 Adverse physicochemical, human health and environmental effects May cause damage to organs through prolonged or repeated exposure. Harmful if swallowed Label elements Labelling according to Regulation (EC) No. 1272/2008 [CLP]Extra labelling to displayextra classification(s) to display Hazard pictograms (CLP) : Signal word (CLP) Hazardous ingredients Hazard statements (CLP) Precautionary statements (CLP) 2.3. Other hazards GHS07 : Warning GHS08 : ethanediol; ethylene glycol : H302 - Harmful if swallowed. H373 - May cause damage to organs through prolonged or repeated exposure. : P101 - If medical advice is needed, have product container or label at hand. P102 - Keep out of reach of children. P264 - Wash hands, forearms and face thoroughly after handling. P270 - Do not eat, drink or smoke when using this product. P314 - Get medical advice/attention if you feel unwell. P501 - Dispose of contents/container to hazardous or special waste collection point, in accordance with local, regional, national and/or international regulation. SECTION 3: Composition/information on ingredients 3.1. Substances EN (English) 1/7
2 3.2. Mixtures Name Product identifier % Classification according to Regulation (EC) No. 1272/2008 [CLP] ethanediol; ethylene glycol (CAS-No.) (EC-No.) (EC Index-No.) (REACH-no) sodium 2-ethylhexanoate (CAS-No.) (EC-No.) (REACH-no) Full text of H-statements: see section Acute Tox. 4 (Oral), H302 STOT RE 2, H373 0,1-5 Repr. 2, H361d SECTION 4: First aid measures 4.1. Description of first aid measures First-aid measures general First-aid measures after inhalation First-aid measures after skin contact First-aid measures after eye contact First-aid measures after ingestion : Call a poison center or a doctor if you feel unwell. : Remove person to fresh air and keep comfortable for breathing. : Wash skin with plenty of water. : Rinse eyes with water as a precaution. : Rinse mouth. Call a poison center or a doctor if you feel unwell Most important symptoms and effects, both acute and delayed Symptoms/effects after inhalation : Inhalation may affect the nervous system causing headache, possibly dizziness, nausea, weakness, loss of coordination and unconsciousness. Symptoms/effects after ingestion : Ingestion may cause nausea, vomiting and diarrhea Indication of any immediate medical attention and special treatment needed Treat symptomatically. SECTION 5: Firefighting measures 5.1. Extinguishing media Suitable extinguishing media Unsuitable extinguishing media : Water spray. Dry powder. Foam. Carbon dioxide. : Do not use a heavy water stream Special hazards arising from the substance or mixture Hazardous decomposition products in case of fire : Toxic fumes may be released. Incomplete combustion releases dangerous carbon monoxide, carbon dioxide and other toxic gases Advice for firefighters Protection during firefighting SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures : Do not attempt to take action without suitable protective equipment. Self-contained breathing apparatus. Complete protective clothing For non-emergency personnel Emergency procedures : Ventilate spillage area. Do not breathe dust/fume/gas/mist/vapours/spray For emergency responders Protective equipment 6.2. Environmental precautions Avoid release to the environment Methods and material for containment and cleaning up Methods for cleaning up : Take up liquid spill into absorbent material. Other information 6.4. Reference to other sections For further information refer to section 13. SECTION 7: Handling and storage 7.1. Precautions for safe handling Precautions for safe handling Hygiene measures : Do not attempt to take action without suitable protective equipment. For further information refer to section 8: "Exposure controls/personal protection". : Dispose of materials or solid residues at an authorized site Conditions for safe storage, including any incompatibilities Storage conditions : Store in a well-ventilated place. Keep cool. : Ensure good ventilation of the work station. Wear personal protective equipment. Do not breathe dust/fume/gas/mist/vapours/spray. : Do not eat, drink or smoke when using this product. Always wash hands after handling the product (Version: 1.0) EN (English) 2/7
3 7.3. Specific end use(s) SECTION 8: Exposure controls/personal protection 8.1. Control parameters ethanediol; ethylene glycol ( ) EU Local name Ethylene glycol EU IOELV TWA (mg/m³) 52 mg/m³ EU IOELV TWA (ppm) 20 ppm EU IOELV STEL (mg/m³) 104 mg/m³ EU IOELV STEL (ppm) 40 ppm EU Notes Skin EU Regulatory reference COMMISSION DIRECTIVE 2000/39/EC United Kingdom Local name Ethane-1,2-diol United Kingdom WEL TWA (mg/m³) 10 mg/m³ particulate 52 mg/m³ vapour United Kingdom WEL TWA (ppm) 20 ppm vapour United Kingdom WEL STEL (mg/m³) 104 mg/m³ vapour United Kingdom WEL STEL (ppm) 40 ppm vapour United Kingdom Remark (WEL) Sk (Can be absorbed through the skin. The assigned substances are those for which there are concerns that dermal absorption will lead to systemic toxicity) United Kingdom Regulatory reference EH40. HSE 8.2. Exposure controls Appropriate engineering controls: Ensure good ventilation of the work station. Hand protection: Protective gloves Type Material Permeation Thickness (mm) Penetration Standard Reusable gloves Nitrile rubber (NBR), Neoprene rubber (HNBR), Viton II 4 (> 120 minutes), 5 (> 240 minutes), 6 (> 480 minutes) >=0,35 3 (> 0.65) EN 374 Eye protection: Safety glasses Type Use Characteristics Standard Safety glasses Droplet clear EN 166 Skin and body protection: Wear suitable protective clothing Respiratory protection: In case of insufficient ventilation, wear suitable respiratory equipment Personal protective equipment symbol(s): Environmental exposure controls: Avoid release to the environment (Version: 1.0) EN (English) 3/7
4 SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties Physical state : Liquid Colour Odour Odour threshold : Yellow. ph : 8,7 Relative evaporation rate (butylacetate=1) Melting point Freezing point : odourless. : Boiling point : 164 C Flash point Auto-ignition temperature Decomposition temperature Flammability (solid, gas) Vapour pressure Relative vapour density at 20 C Relative density Density Solubility Log Pow Viscosity, kinematic Viscosity, dynamic Explosive properties Oxidising properties : 115 C - ASTM D93 (PM) : : 1823 Pa (20 C) : 1,1 kg/m³ (15 C) - ASTM D4052 : Water: completely miscible Lower explosive limit (LEL) : 3,2 vol % Upper explosive limit (UEL) : 53 vol % 9.2. Other information SECTION 10: Stability and reactivity Reactivity The product is non-reactive under normal conditions of use, storage and transport Chemical stability Stable under normal conditions Possibility of hazardous reactions No dangerous reactions known under normal conditions of use Conditions to avoid None under recommended storage and handling conditions (see section 7) Incompatible materials Hazardous decomposition products Under normal conditions of storage and use, hazardous decomposition products should not be produced. SECTION 11: Toxicological information Information on toxicological effects Acute toxicity (oral) Acute toxicity (dermal) Acute toxicity (inhalation) ATE CLP (oral) Skin corrosion/irritation Serious eye damage/irritation Respiratory or skin sensitisation Germ cell mutagenicity Carcinogenicity Reproductive toxicity STOT-single exposure : Oral: Harmful if swallowed. 625 mg/kg bodyweight ph: 8,7 ph: 8, (Version: 1.0) EN (English) 4/7
5 STOT-repeated exposure Aspiration hazard : May cause damage to organs through prolonged or repeated exposure. SECTION 12: Ecological information Toxicity Ecology - general Acute aquatic toxicity Chronic aquatic toxicity Persistence and degradability Coolant NF Persistence and degradability Bioaccumulative potential Mobility in soil Results of PBT and vpvb assessment Other adverse effects : The product is not considered harmful to aquatic organisms nor to cause long-term adverse effects in the environment. Biodegradable. SECTION 13: Disposal considerations Waste treatment methods Waste treatment methods European List of Waste (LoW) code : Dispose of contents/container in accordance with licensed collector s sorting instructions. : * - antifreeze fluids containing dangerous substances SECTION 14: Transport information In accordance with ADR / RID / IMDG / IATA / ADN UN number ADR IMDG IATA ADN RID UN proper shipping name Transport hazard class(es) Packing group Environmental hazards No supplementary information available Special precautions for user Overland transport Transport by sea Air transport Inland waterway transport Rail transport Transport in bulk according to Annex II of Marpol and the IBC Code (Version: 1.0) EN (English) 5/7
6 SECTION 15: Regulatory information Safety, health and environmental regulations/legislation specific for the substance or mixture EU-Regulations Contains no REACH substances with Annex XVII restrictions Contains no substance on the REACH candidate list Contains no REACH Annex XIV substances Directive 2012/18/EU (SEVESO III) National regulations Chemical safety assessment No chemical safety assessment has been carried out SECTION 16: Other information Abbreviations and acronyms: ADN ADR ATE BCF European Agreement concerning the International Carriage of Dangerous Goods by Inland Waterways European Agreement concerning the International Carriage of Dangerous Goods by Road Acute Toxicity Estimate Bioconcentration factor CLP Classification Labelling Packaging Regulation; Regulation (EC) No 1272/2008 DMEL DNEL EC50 IARC IATA IMDG LD50 LC50 LOAEL NOAEC NOAEL NOEC OECD PBT PNEC Derived Minimal Effect level Derived-No Effect Level Median effective concentration International Agency for Research on Cancer International Air Transport Association International Maritime Dangerous Goods Median lethal dose Median lethal concentration Lowest Observed Adverse Effect Level No-Observed Adverse Effect Concentration No-Observed Adverse Effect Level No-Observed Effect Concentration Organisation for Economic Co-operation and Development Persistent Bioaccumulative Toxic Predicted No-Effect Concentration REACH Registration, Evaluation, Authorisation and Restriction of Chemicals Regulation (EC) No 1907/2006 RID STP TLM SDS vpvb Full text of H- and EUH-statements: Regulations concerning the International Carriage of Dangerous Goods by Rail Sewage treatment plant Median Tolerance Limit Very Persistent and Very Bioaccumulative Acute Tox. 4 (Oral) Acute toxicity (oral), Category 4 Repr. 2 Reproductive toxicity, Category 2 STOT RE 2 Specific target organ toxicity Repeated exposure, Category 2 H302 H361d H373 Harmful if swallowed. Suspected of damaging the unborn child. May cause damage to organs through prolonged or repeated exposure (Version: 1.0) EN (English) 6/7
7 SDS EU (REACH Annex II) This information is based on our current knowledge and is intended to describe the product for the purposes of health, safety and environmental requirements only. It should not therefore be construed as guaranteeing any specific property of the product (Version: 1.0) EN (English) 7/7
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