Safety Data Sheet Page 1 of 11

Transcription

1 Safety Data Sheet Page 1 of 11 TEROSON VR 4600 AE SDS No. : V001.3 Date of issue: Section 1. Identification of the substance/prepaion and of the company/undertaking Product name: Intended use: TEROSON VR 4600 AE Aerosol Supplier: Henkel Australia Pty Ltd Canterbury Road Kilsyth, Victoria, 3137 Australia Phone: +61 (3) Emergency information: 24 HOUR EMERGENCY CONTACT NUMBER: Classification of the substance or mixture Hazardous according to the criteria of Safe Work Australia. GHS Classification: Section 2. Hazards identification Hazard Class Hazard Category Target organ Flammable aerosols Category 1 Serious eye irritation Category 2A Target Organ Systemic Toxicant - Single exposure Category 3 respiory tract irritation Central Nervous System Acute hazards to the aquatic Category 1 environment Chronic hazards to the aquatic environment Category 1 Hazard pictogram: Signal word: Danger

2 Page 2 of 11 Hazard statement(s): Precautionary Statement(s): Prevention: Response: Storage: Disposal: H222 Extremely flammable aerosol. H319 Causes serious eye irritation. H335 May cause respiory irritation. H336 May cause drowsiness or dizziness. H410 Very toxic to aquatic life with long lasting effects. Repeated exposure may cause skin dryness or cracking. P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. P211 Do not spray on an open flame or other ignition source. P251 Do not pierce or burn, even after use. P261 Avoid breathing dust/fume/gas/mist/vapours/spray. P264 Wash hands thoroughly after handling. P271 Use only outdoors or in a well-ventilated area. P273 Avoid release to the environment. P280 Wear eye protection/face protection. P304+P340+P312 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. Call a POISON CENTER or physician if you feel unwell. P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P337+P313 If eye irritation persists: Get medical advice/attention. P391 Collect spillage. P403+P233 Store in a well-ventilated place. Keep container tightly closed. P405 Store locked up. P410+P412 Protect from sunlight. Do not expose to tempeures exceeding 50 C/122 F. P501 Dispose of contents/container to an appropriate treatment and disposal facility in accordance with applicable laws and regulations. Dangerous Goods information: Classified as Dangerous Goods according to the criteria of the Australian Code for the Transport of Dangerous Goods by Road and Rail (ADG Code). Section 3. Composition / information on ingredients General chemical description: Type of prepaion: Mixture Corrosion inhibitor Coating Identity of ingredients: Chemical ingredients Proportion % % % light arom., <0.1% < 10 % Benzene < 10 % light arom., <0.1% < 5 % Benzene < 3 % non hazardous ingredients~ %

3 Page 3 of 11 Section 4. First aid measures Ingestion: Skin: Eyes: Inhalation: First Aid facilities: Medical attention and special treatment: Do not induce vomiting. Have victim rinse mouth thoroughly with water. Seek medical advice. Remove contaminated clothing and footwear. Wash with soap and water. Seek medical advice. Wash clothing before reuse. Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Seek medical advice. Move to fresh air in case of accidental inhalation of vapours. Seek medical advice. Eye wash and safety shower Normal washroom facilities Treat symptomatically and supportively. Section 5. Fire fighting measures Suitable extinguishing media: Improper extinguishing media: Decomposition products in case of fire:: Particular danger in case of fire:: Special protective equipment for fire-fighters: Additional fire fighting advice: Water spray (fog), foam, dry chemical or carbon dioxide. Water spray jet Thermal decomposition can lead to release of irritating gases and vapors. carbon monoxide Carbon dioxide. Hydrocarbons. WARNING FLAMMABLE! Contents under pressure. Closed containers may rupture (due to build up of pressure) when exposed to extreme heat. Do not puncture or incinee pressurized containers. Use water spray to keep fire exposed containers cool and disperse vapors. Wear self-contained breathing appaus and full protective clothing, such as turn-out gear. In case of fire, keep containers cool with water spray. Collect contaminated fire fighting water sepaely. It must not enter drains. Section 6. Accidental release measures Personal precautions: Environmental precautions: Clean-up methods: Wear protective equipment. Avoid contact with skin and eyes. Danger of slipping on spilled product. Keep unprotected persons away. Do not empty into drains / surface water / ground water. Inform authorities in the event of product spillage to water courses or sewage systems. Remove with liquid-absorbing material (sand, peat, sawdust). Dispose of contaminated material as waste according to Section 13. Section 7. Handling and storage

4 Page 4 of 11 Precautions for safe handling: Conditions for safe storage: Avoid breathing vapors or mists of this product. Avoid contact with eyes, skin and clothing. Keep away from heat, spark and flame. Vapors will accumulate readily and may ignite explosively. Ensure adequate ventilation. Do not handle or store near an open flame, heat or other sources of ignition. Do not puncture, incinee, or expose to tempeures above 48.9 C (120 F). Keep away from heat and direct sunlight. Ensure adequate ventilation. Storage at 15 to 20 C is recommended. Must be stored in the facility for the dangerous goods Section 8. Exposure controls / personal protection National exposure standards: Ingredient [Regulated substance] N-BUTYL ACETATE N-BUTYL ACETATE BUTANE ACETONE ACETONE XYLENE (O-, M-, P- ISOMERS) XYLENE (O-, M-, P- ISOMERS) ZINC OXIDE (FUME) ZINC OXIDE (FUME) ZINC OXIDE (INSPIRABLE DUST) Engineering controls: Eye protection: Skin protection: form of exposure TWA (ppm) TWA (mg/m3) Peak Limit. (ppm) Peak Limit. (mg/m3) STEL (ppm) STEL (mg/m3) , , ,000 2, Fume Fume Inspirable dust Ventilate working rooms thoroughly. Avoid naked flames, sparking and sources of ignition. Switch off electrical devices. Do not smoke, do not weld. Do not empty waste into waste water drains. Wear protective glasses. Wear suitable protective clothing. Use of Butyl or Nitrile Rubber gloves is recommended. Please note that in practice the working life of chemical resistant gloves may be considerably reduced as a result of many influencing factors (e.g. tempeure). Suitable risk assessment should be carried out by the end user. If signs of wear and tear are noticed then the gloves should be replaced. Respiory protection: Use only in well-ventilated areas. If inhalation risk exists, wear a respior or air supplied mask complying with the requirements of AS/NZS 1715 and AS/NZS Section 9. Physical and chemical properties

5 Page 5 of 11 Appearance: aerosol Odor: characteristic Specific gravity: 1.52 Flash point: C (-4 F) Ignition tempeure 365 C (689 F) Lower explosive limit: 1.20 %(V) Upper explosive limit: 13.0 %(V) Vapor pressure: hpa (; 20 C (68 F)) Density: 1.03 g/cm3 Solubility in water: Not miscible or difficult to mix (20 C) VOC content (2004/42/EC) 69.8 % (VOCV VOC regulation CH) Section 10. Stability and reactivity Stability: Conditions to avoid: Incompatible materials: Stable under normal conditions of tempeure and pressure. Keep away from heat, spark and flame. Strong oxidizing agents. Hazardous decomposition products: Thermal decomposition can lead to release of irritating gases and vapors. carbon monoxide carbon dioxide Oxides of nitrogen. Section 11. Toxicological information

6 Page 6 of 11 Health Effects: Ingestion: Skin: Eyes: Inhalation: Chronic effects: Xylene - mixture of isomeres : Not expected under normal conditions of use. May cause mild skin irritation. Repeated exposure may cause skin dryness or cracking. Symptoms may include redness, edema, drying, defatting and cracking of the skin. Causes serious eye irritation. Symptoms may include severe irritation, pain, tearing, blurred vision. This product is irritating to the respiory system. Vapours may cause drowsiness and dizziness. Central nervous system depression, including dizziness, drowsiness, fatigue, nausea, headache, unconsciousness. Unspecific central nervous disorders (e.g. headaches, insomnia), dyspepsia and vegetative dystonia. Acute toxicity: Xylene - mixture of isomeres Solvent naphtha (petroleum), light arom., <0.1% Benzene Value type LD50 LC50 LD50 Value > 8,800 mg/kg > 23.4 mg/l > 14,112 mg/kg Route of application oral inhalation dermal Exposure time 4 h Species LC mg/l 4 h inhalation LD50 5,800 mg/kg oral LC50 76 mg/l inhalation 4 h LD50 > 15,688 mg/kg dermal LD50 3,523 mg/kg oral LC50 11 mg/l inhalation 4 h LD50 > 1,700 mg/kg dermal LD50 > 6,800 mg/kg oral LD50 LC50 > 5,000 mg/kg > 5.7 mg/l oral inhalation 4 h Method BASF Test OECD Guideline 403 (Acute Inhalation Toxicity) OECD Guideline 402 (Acute Dermal Toxicity) Draize Test Not specified Not specified OECD Guideline 401 (Acute Oral Toxicity) OECD Guideline 403 (Acute Inhalation Toxicity) Skin corrosion/irritation: Xylene - mixture of isomeres Result Exposure time Species Method not irritating BASF Test not irritating guinea pig modeely irritating not irritating Serious eye damage/irritation: Xylene - mixture of isomeres Result Exposure time Species Method not irritating BASF Test irritating OECD Guideline 405 (Acute Eye Irritation / Corrosion) slightly irritating OECD Guideline 405 (Acute Eye Irritation / Corrosion) slightly irritating

7 Page 7 of 11 Respiory or skin sensitization: not sensitising not sensitising not sensitising Result Test type Species Method Guinea pig maximisat ion test Guinea pig maximisat ion test Guinea pig maximisat ion test guinea pig guinea pig guinea pig OECD Guideline 406 (Skin Sensitisation) Germ cell mutagenicity: Xylene - mixture of isomeres Repeated dose toxicity: Result Type of study / Route of administion bacterial reverse mutation assay (e.g Ames test) bacterial reverse mutation assay (e.g Ames test) in vitro mammalian chromosome aberion test bacterial reverse mutation assay (e.g Ames test) in vitro mammalian chromosome aberion test mammalian cell gene mutation assay Metabolic activation / Exposure time without Species oral: drinking water mouse bacterial reverse mutation assay (e.g Ames test) bacterial reverse mutation assay (e.g Ames test) Drosophila melanogaster Method Ames Test OECD Guideline 471 (Bacterial Reverse Mutation Assay) OECD Guideline 473 (In vitro Mammalian Chromosome Aberion OECD Guideline 471 (Bacterial Reverse Mutation Assay) OECD Guideline 473 (In vitro Mammalian Chromosome Aberion OECD Guideline 476 (In vitro Mammalian Cell Gene Mutation Result NOAEL=900 mg/kg Route of application inhalation: gas oral: drinking water Exposure time / Frequency of treatment Species Method 28 d OECD Guideline 422 (Combined Repeated Dose Toxicity Study with the Reproduction / Developmental Toxicity Screening 13 wdaily OECD Guideline 408 (Repeated Dose 90-Day Oral Toxicity in Rodents) Section 12. Ecological information

8 Page 8 of 11 General ecological information: Ecotoxicity: Do not empty into drains / surface water / ground water. Very toxic to aquatic life with long lasting effects. Toxicity: Value type Value Acute Toxicity Study Exposure time Species Method LC50 62 mg/l Fish 96 h Leuciscus idus DIN EC mg/l Daphnia 24 h Daphnia magna EC mg/l Algae 72 h Scenedesmus subspicatus (new name: Desmodesmus subspicatus) EC mg/l Algae 72 h Scenedesmus subspicatus (new name: Desmodesmus subspicatus) EC mg/l Bacteria 18 h LC mg/l Fish 96 h EC mg/l Daphnia 48 h EC mg/l Algae 96 h OECD Guideline OECD Guideline LC50 8,120 mg/l Fish 96 h Pimephales promelas OECD Guideline 203 (Fish, Acute Toxicity EC50 8,800 mg/l Daphnia 48 h Daphnia pulex OECD Guideline 202 (Daphnia sp. Acute Immobilisation NOEC 530 mg/l Algae 8 d Microcystis aeruginosa DIN EC10 1,000 mg/l Bacteria 30 min Pseudomonas putida DIN 38412, part 27 (Bacterial oxygen consumption test) LC50 18 mg/l Fish 96 h Oncorhynchus mykiss OECD Guideline 203 (Fish, Acute Toxicity EC mg/l Daphnia 48 h Daphnia magna OECD Guideline 202 (Daphnia sp. Acute Immobilisation EC50 > 1-10 mg/l Algae OECD Guideline LC50 86 mg/l Fish Leuciscus idus OECD Guideline 203 (Fish, Acute Toxicity EC mg/l Daphnia 48 h Daphnia magna OECD Guideline 202 (Daphnia sp. Acute Immobilisation EC50 > 1-10 mg/l Algae Scenedesmus subspicatus (new name: Desmodesmus subspicatus) EC 50 > 1-10 mg/l Bacteria OECD Guideline LC50 18 mg/l Fish 96 h Oncorhynchus mykiss OECD Guideline 203 (Fish, Acute Toxicity EC mg/l Daphnia 48 h Daphnia magna OECD Guideline 202 (Daphnia sp. Acute Immobilisation EC50 > 1-10 mg/l Algae OECD Guideline LC50 > 1,000 mg/l Fish Leuciscus idus OECD Guideline

9 Page 9 of (Fish, Acute Toxicity NOEC mg/l Algae 72 h Selenastrum capricornutum OECD Guideline (new name: Pseudokirchnerella subcapitata) EC mg/l Algae 72 h Selenastrum capricornutum (new name: Pseudokirchnerella subcapitata) NOEC 500 mg/l Bacteria OECD Guideline Persistence and degradability: Result Route of application Degradability Method readily biodegradable aerobic 98 % OECD Guideline 301 D (Ready Biodegradability: Closed Bottle readily biodegradable aerobic % EU Method C.4-E (Determination of the "Ready" BiodegradabilityClosed Bottle readily biodegradable aerobic 78 % OECD Guideline 301 F (Ready Biodegradability: Manometric Respirometry readily biodegradable aerobic > 60 % OECD 301 A - F readily biodegradable aerobic 78 % OECD Guideline 301 F (Ready Biodegradability: Manometric Respirometry Bioaccumulative potential / Mobility in soil: LogKow Bioconcention factor (BCF) Exposure time Species Tempeure Method C OECD Guideline 107 (Partition Coefficient (noctanol / water), Shake Flask Method) OECD Guideline 107 (Partition Coefficient (noctanol / water), Shake Flask Method) > 3 OECD Guideline 107 (Partition Coefficient (noctanol / water), Shake Flask Method) d Oncorhynchus mykiss 3.12 > 3 OECD Guideline 107 (Partition Coefficient (noctanol / water), Shake Flask Method) Section 13. Disposal consideions Waste disposal of product: Disposal for uncleaned package: Dispose of in accordance with local and national regulations. Product waste meets the criteria of National Hazardous Waste Catalogue. Completely empty pressurized gas containers (including propellant gas). Disposal must be made according to official regulations.

10 Page 10 of 11 Section 14. Transport information Road and Rail Transport: Dangerous Goods information: Classified as Dangerous Goods according to the criteria of the Australian Code for the Transport of Dangerous Goods by Road and Rail (ADG Code). UN no.: 1950 Proper shipping name: AEROSOLS Class or division: 2.1 Packing group: Emergency information: Refer to the Dangerous Goods - Initial Emergency Response Guide HB 76. Marine transport IMDG: UN no.: 1950 Proper shipping name: AEROSOLS (Zinc powder) Class or division: 2.1 Packing group: EmS: F-D,S-U Seawater pollutant: Marine pollutant Air transport IATA: UN no.: 1950 Proper shipping name: Aerosols, flammable Class or division: 2.1 Packing group: Packing instructions (passenger) 203 Packing instructions (cargo) 203 Section 15. Regulatory information SUSMP Poisons Schedule AICS: None All components are listed or are exempt from listing on the Australian Inventory of Chemical Substances (AICS). Section 16. Other information Abbreviations/acronyms: ADGC - Australian Dangerous Goods Code IMDG: International Maritime Dangerous Goods code IATA-DGR: International Air Transport Association Dangerous Goods Regulations STEL - Short term exposure limit TWA - Time weighted average Reason for issue: Reviewed SDS. Reissued with new date. involved chapters: 1-16 Date of previous issue: Disclaimer:

11 Page 11 of 11 The percentage weight (% w/w) of ingredients is not to be taken as a specification guaranteed by Henkel Australia Pty. Limited, but only as an approximate guide to the content of hazardous ingredients in the material. The information contained herein does not constitute a guarantee by Henkel Australia Pty. Limited concerning the properties of the material. The information contained in the Safety Data Sheet is offered in good faith and has been developed from what is believed to be accue and reliable sources. The information is offered without warranty, representation, inducement or licence and Henkel Australia Pty. Limited assumes no legal responsibility for reliance upon same. Henkel Australia Pty. Limited disclaims any liability for loss, injury or damage incurred in connection with the use of the material or its associated Safety Data Sheet. This information is not to be construed as a representation that the material is suitable for any particular purpose or use except those conditions and warranties implied by either Commonwealth or State statutes. Customers are encouraged to make their own enquiries as to the material s characteristics and, where appropriate, to conduct their own tests in the specific context of the material s intended use.