Safety Data Sheet according to GB/T Page 1 of 11.
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1 Safety Data Sheet according to GB/T Page 1 of 11. TEROSON EP 4560 known as TEROKAL 4560GB 18kg SDS No. : V001.2 Revision: printing date: Identification of the substance/prepaion and of the company/undertaking Product name: TEROSON EP 4560 known as TEROKAL 4560GB 18kg Company name: Henkel (China) Investment Co. Ltd. No.928 Zhangheng Rd Pudong, Shanghai, P.R. China Germany Phone: Revision date: Emergency information: Emergency telephone: (24h). 2. Hazards identification Classification of the substance or mixture according to GB (General rule for classification and hazard communication of chemicals): Hazard Class Hazard Category Skin corrosion/irritation Category 1C Serious eye damage/eye irritation Category 1 Skin sensitizer Category 1 Acute hazards to the aquatic Category 2 environment Chronic hazards to the aquatic Category 2 environment Label elements according to GB (General rules for prepaion of precautionary label for chemicals): Hazard pictogram: Signal word: Danger
2 Page 2 of 11. Hazard statement: Prevention: Response: Storage: Disposal: H314 Causes severe skin burns and eye damage. H317 May cause an allergic skin reaction. H411 Toxic to aquatic life with long lasting effects. P260 Do not breathe dusts or mists. P264 Wash hands thoroughly after handling. P272 Contaminated work clothing should not be allowed out of the workplace. P273 Avoid release to the environment. P280 Wear protective gloves/protective clothing/eye protection/face protection. P301+P330+P331 IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. P303+P361+P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water [or shower]. P304+P340+P310 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. Immediately call a POISON CENTER or physician. P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P333+P313 If skin irritation or rash occurs: Get medical advice/attention. P362+P364 Take off contaminated clothing and wash it before reuse. P391 Collect spillage. P405 Store locked up. P501 Dispose of contents/container to an appropriate treatment and disposal facility in accordance with applicable laws and regulations, and product characteristics at time of disposal.
3 Page 3 of Composition / information on ingredients General description: Mixture Declaion of the ingredients according to GB : Hazard component Content GHS Classification 30- < 50 % Skin corrosion/irritation 2 H315 Serious eye damage/eye irritation 2A H319 Skin sensitizer 1 H317 Acute hazards to the aquatic environment 2 H401 Chronic hazards to the aquatic environment 2 H411 Cristobalite < 20 % Acute toxicity 5; Oral H303 Acute toxicity 5; Dermal H313 Skin corrosion/irritation 1C H314 Serious eye damage/eye irritation 1 H318 Acute hazards to the aquatic environment 3 H402 Chronic hazards to the aquatic environment 3 H < 10 % Acute toxicity 5; Oral H303 Specific target organ toxicity - repeated exposure 2; Inhalation H373+H < 10 % Toxic to reproduction 2 H361 Acute hazards to the aquatic environment 1 H400 Chronic hazards to the aquatic environment 1 H < 10 % Skin corrosion/irritation 2; Dermal H315 Serious eye damage/eye irritation 1 H318 Specific target organ toxicity - single exposure 3; Inhalation H335 Acute hazards to the aquatic environment 3 H < 1 % Serious eye damage/eye irritation 2A H319 Toxic to reproduction 2 H361 Specific target organ toxicity - single exposure 3 H335 Acute hazards to the aquatic environment 2 H401 Chronic hazards to the aquatic environment 2 H411 Only hazardous ingredients for which a classification according to GB is already available are displayed in this table. For full text of the Hazard statements see section 16 Other information. 4. First aid measures
4 Page 4 of 11. Skin contact: Eye contact: Inhalation: Ingestion: Immediately wash skin thoroughly with soap and water. If symptoms develop and persist, get medical attention. In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. If mist or vapor of this product is inhaled, remove person immediately to fresh air. Seek medical attention if symptoms develop or persist. Get immediate medical attention. Do not induce vomiting. 5. Fire fighting measures Hazardous combustion products: Extinguishing media: Notice and measures for firing fighting: Irritating and/or toxic fumes and gases may be emitted upon the product's decomposition. Upon decomposition, this product emits carbon monoxide, carbon dioxide and/or low molecular weight hydrocarbons. Water spray (fog), foam, dry chemical or carbon dioxide. This product is combustible at high tempeures. Wear full protective clothing. Wear self-contained breathing appaus. 6. Accidental release measures Emergency measures: Clean-up methods: Prevent further leakage or spillage if safe to do so. Wear appropriate protective equipment and clothing during clean-up. Do not allow product to enter sewer or waterways. Remove all sources of ignition. Absorb spill with inert material. Shovel material into appropriate container for disposal. Dispose of according to Federal, State and local governmental regulations. 7. Handling and storage Notice for handling: Avoid contact with eyes, skin and clothing. Wash thoroughly after handling. Avoid breathing fumes if this product is used at high tempeures. Use only with adequate ventilation. Do not take internally. For industrial use only. 8. Exposure controls / personal protection GBZ ACGIH NIOSH OSHA Calcium carbonate 4 mg/m3pc-twa 8 mg/m3pc-twa 0.3 mg/m3pc-twa (SKIN) 2 mg/m3pc-twa 2 mg/m3 TWA Calcium carbonate 4 mg/m3pc-twa 8 mg/m3pc-twa 10 mg/m3 TWA Silica Filler 5 mg/m3pc-twa 6 mg/m3 TWA Engineering controls: Provide local and general exhaust ventilation to effectively remove and prevent buildup of any vapors or mists geneed from the handling of this product.
5 Page 5 of 11. Respiory protection: Eye protection: Body protection: When workplace hazards warrant the use of a respior, appropriate respiors must be used, and a program that follows 29 CFR must be followed. If ventilation is not sufficient to effectively prevent buildup of aerosols, mists or vapors, appropriate NIOSH/MSHA respiory protection must be provided. Wear safety glasses; chemical goggles (if splashing is possible). Wear impervious gloves for prolonged contact. Gloves should be tested to determine suitability for prolonged contact. Suitable glove materials may include: Nitrile gloves. Neoprene gloves. Pictograms for recommended PPE: 9. Physical and chemical properties Physical state: paste Appearance: blue paste Boiling point: Not available. Density: g/cm3 10. Stability and reactivity Stability: Conditions to avoid: Incompatible products: Decomposition products: Stable at normal conditions. Store away from incompatible materials. Excessive heat. Keep away from strong oxidizing agents, strong Lewis or mineral acids. Reacts with water. Avoid contact with amines. Upon decomposition, this product emits carbon monoxide, carbon dioxide and/or low molecular weight hydrocarbons. 11. Toxicological information General toxicological information: No experimental toxicological data on the prepaion as such is available. Oral toxicity: Acute toxicity estimate (ATE) : > 5,000 mg/kg Method: Calculation method Dermal toxicity: Acute toxicity estimate (ATE) : > 5,000 mg/kg Method: Calculation method
6 Page 6 of 11. Acute toxicity: Cristobalite Value type Value > 2,000 mg/kg > 2,000 mg/kg 2,885.3 mg/kg 2,979.7 mg/kg Route of application oral dermal oral dermal Exposure time 3,160 mg/kg oral > 20,000 mg/kg > 10,000 mg/kg > 2,000 mg/kg > 2,500 mg/kg 6,400 mg/kg > 8,000 mg/kg oral dermal oral dermal oral dermal Species New Zealand white rabbit rabbit rabbit Method OECD Guideline 420 (Acute Oral Toxicity) not specified OECD Guideline 401 (Acute Oral Toxicity) OECD Guideline 402 (Acute Dermal Toxicity) EPA OTS (Acute Oral Toxicity) EPA OTS (Acute Dermal Toxicity) OECD Guideline 425 (Acute Oral Toxicity: Up-and-Down Procedure) OECD Guideline 402 (Acute Dermal Toxicity) not specified not specified Skin corrosion/irritation: Result Exposure Species Method time modeely irritating 24 h rabbit Draize Test corrosive 4 h rabbit OECD Guideline 404 (Acute Dermal Irritation / Corrosion) not irritating 24 h rabbit Draize Test Serious eye damage/irritation: Result Exposure time Species Method not irritating rabbit OECD Guideline 405 (Acute Eye Irritation / Corrosion) corrosive rabbit OECD Guideline 405 (Acute Eye Irritation / Corrosion) not irritating rabbit Draize Test
7 Page 7 of 11. Respiory or skin sensitization: sensitising Result Test type Species Method Mouse local lymphnod e assay (LLNA) mouse OECD Guideline 429 (Skin Sensitisation: Local Lymph Node Assay) Germ cell mutagenicity: Result Type of study / Route of administion negative bacterial reverse mutation assay (e.g Ames test) Metabolic activation / Exposure time with and without Species Method negative oral: gavage mouse not specified negative negative bacterial reverse mutation assay (e.g Ames test) in vitro mammalian chromosome aberion test with and without with and without OECD Guideline 472 (Genetic Toxicology: Escherichia coli, Reverse Mutation Assay) not specified not specified Repeated dose toxicity: Result Route of application Exposure time / Frequency of treatment Species Method NOAEL=50 mg/kg oral: gavage 14 wdaily OECD Guideline 408 (Repeated Dose 90-Day Oral Toxicity in Rodents) LOAEL=0,5 % oral: feed 28 daysdaily not specified NOAEL=0,1 % oral: feed 28 daysdaily not specified 12. Ecological information General ecological information: Toxic to aquatic organisms
8 Page 8 of 11. Toxicity: bisphenol- A- bisphenol- A- bisphenol- A- bisphenol- A- bisphenol- A- Cristobalite Value type Value Acute Toxicity Study Exposure time Species Method LC mg/l Fish 96 h Oncorhynchus mykiss OECD Guideline 203 (Fish, Acute Toxicity Test) EC mg/l Daphnia 48 h Daphnia magna OECD Guideline 202 (Daphnia sp. Acute Immobilisation Test) EC50 > 11 mg/l Algae 72 h Scenedesmus capricornutum OECD Guideline 201 (Alga, Growth NOEC 4.2 mg/l Algae 72 h Scenedesmus capricornutum OECD Guideline 201 (Alga, Growth IC50 > 100 mg/l Bacteria 3 h activated sludge, industrial other guideline: LC50 > 100 mg/l Fish 96 h not specified OECD Guideline 203 (Fish, Acute Toxicity Test) EC50 15 mg/l Daphnia 48 h Daphnia magna OECD Guideline 202 (Daphnia sp. Acute Immobilisation Test) IC mg/l Algae 72 h Scenedesmus subspicatus (new name: Desmodesmus subspicatus) OECD Guideline 201 (Alga, Growth EC0 > 1,000 mg/l Bacteria ISO 8192 (Test for Inhibition of Oxygen Consumption by Activated Sludge) LC mg/l Fish 96 h not specified EC mg/l Daphnia 48 h Daphnia magna OECD Guideline 202 (Daphnia sp. Acute Immobilisation Test) LC mg/l Fish 96 h Oncorhynchus mykiss OECD Guideline 203 (Fish, Acute Toxicity Test) EC mg/l Daphnia 48 h Daphnia magna OECD Guideline 202 (Daphnia sp. Acute Immobilisation Test) EC mg/l Algae 72 h Pseudokirchneriella subcapitata OECD Guideline 201 (Alga, Growth NOEC 48 mg/l Algae 72 h Pseudokirchneriella subcapitata OECD Guideline 201 (Alga, Growth EC mg/l Bacteria 3 h activated sludge of a predominantly domestic sewage OECD Guideline 209 (Activated Sludge, Respiion LC mg/l Fish 96 h Oncorhynchus mykiss OECD Guideline
9 Page 9 of (Fish, Acute Toxicity Test) EC mg/l Algae Ankistrodesmus falcatus not specified Persistence and degradability: bisphenol- A- Result Route of application Degradability Method aerobic 5 % OECD Guideline 301 F (Ready Biodegradability: Manometric Respirometry Test) not readily biodegradable. aerobic 0 % OECD 301 A - F aerobic 80 % OECD Guideline 301 C (Ready Biodegradability: Modified MITI Test (I)) not readily biodegradable. aerobic > 0 - < 60 % OECD 301 A - F Bioaccumulative potential / Mobility in soil: bisphenol- A- LogPow Bioconcention factor (BCF) Exposure time Species Tempeure Method C EU Method A.8 (Partition Coefficient) 4.9 not specified 6 not specified not specified 0.98 not specified 13. Disposal consideions Product disposal: If the waste is classified as hazardous waste according to GB (Identification standards for hazardous wastes,general Specifications).Dispose of as hazardous waste in compliance with "Regulation on the Safety Management of Hazardous Chemicals","Law of thepeople's Republic of China on the prevention and control of Environmental Pollution by Solid Waste", "National Catalogue of Hazardous Waste". 14. Transport information
10 Page 10 of 11. Road transport ADR: Class: 8 Packing group: III Classification code: C8 Hazard ident. number: 80 UN no.: 3259 Label: 8 Technical name: AMINES, SOLID, CORROSIVE, N.O.S. (Polyoxy propylene diamine,epoxy resin) Railroad transport RID: Class: 8 Packing group: III Classification code: C8 Hazard ident. number: 80 UN no.: 3259 Label: 8 Technical name: AMINES, SOLID, CORROSIVE, N.O.S. (Polyoxy propylene diamine,epoxy resin) Marine transport IMDG: Class: 8 Packing group: III UN no.: 3259 Label: 8 EmS: F-A,S-B Seawater pollutant: Marine pollutant Proper shipping name: AMINES, SOLID, CORROSIVE, N.O.S. (Polyoxy propylene diamine,epoxy resin) Air transport IATA: Class: 8 Packing group: III Packaging instructions (passenger): 860 Packaging instructions (cargo): 864 UN no.: 3259 Label: 8 Proper shipping name: Amines, solid, corrosive, n.o.s. (Polyoxy propylene diamine) Notice For Transportation: Transport according to local and national regulations. Ensure containers will not leak, collapse, or being damaged when transported. DO NOT transport with incompatible materials. Transportation vehicle should be equipped with right fire-fighting equipment in case of emergency. Avoid solarization, drenched and high tempeure when transported.
11 Page 11 of Regulatory information The following laws and regulations lay down provisions in terms of chemicals safety use, storage, transportation, loading/ unloading, classification as well as symbol. Law of the People's Republic of China on Work Safety (Adopted by the 28th meeting of 9th NPC standing committee on 29th June 2002, revised by 10th meeting of 12nd NPC standing committee on 31st Aug 2014). Law of the People's Republic of China on the Prevention and Treatment of Occupational Diseases (Adopted by the 24th meeting of 9th NPC standing committee on 27th October 2001, revised by 21st meeting of 12nd NPC standing committee on 2nd Jul 2016). Law of the People's Republic of China on environmental protection (Adopted by 11st meeting of 7th NPC standing committee on 26th December 1989, revised by 8th meeting of 12nd NPC standing committee on 24th Apr 2014). Regulation on the Safety Management of Hazardous Chemicals (Adopted by 32nd State Council executive meeting on 4th December 2013). Regulations on License to Work Safety (Adopted by 54th State Council executive meeting on 29th July 2014). 16. Other information Issue date: Issue department: Regulatory Affairs Disclaimer: This information is based on our current level of knowledge and relates to the product in the state in which it is delivered. It is intended to describe our products from the point of view of safety requirements and is not intended to guarantee any particular properties. Others: The full text of all abbreviations indicated by codes in this safety data sheet section 3 are as follows: H303 May be harmful if swallowed. H313 May be harmful in contact with skin. H314 Causes severe skin burns and eye damage. H315 Causes skin irritation. H317 May cause an allergic skin reaction. H318 Causes serious eye damage. H319 Causes serious eye irritation. H335 May cause respiory irritation. H361 Suspected of damaging fertility or the unborn child. H373+H330 May cause damage to organs through prolonged or repeated exposure if inhaled. H400 Very toxic to aquatic life. H401 Toxic to aquatic life. H402 Harmful to aquatic life. H410 Very toxic to aquatic life with long lasting effects. H411 Toxic to aquatic life with long lasting effects. H412 Harmful to aquatic life with long lasting effects.
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