Safety Data Sheet Page 1 of 8

Transcription

1 Safety Data Sheet Page 1 of METAL MAGIC STICK SDS No. : V001.1 Date of issue: Section 1. Identification of the substance/preparation and of the company/undertaking Product name: Intended use: METAL MAGIC STICK Epoxy stick Supplier: Henkel Australia Pty Ltd Canterbury Road Kilsyth, Victoria, 3137 Australia Phone: +61 (3) Emergency information: 24 HOUR EMERGENCY CONTACT NUMBER: Classification of the substance or mixture Hazardous according to the criteria of Safe Work Australia. GHS Classification: Hazard Class Hazard Category Skin corrosion/irritation Category 2 Serious Eye Damage/Eye Irritation Category 2 Skin sensitizer Category 1 Chronic hazards to the aquatic Category 3 environment Hazard pictogram: Section 2. Hazards identification Signal word: Warning

2 Page 2 of 8 Hazard statement(s): Precautionary Statement(s): Prevention: Response: Disposal: H315 Causes skin irritation. H317 May cause an allergic skin reaction. H319 Causes serious eye irritation. H412 Harmful to aquatic life with long lasting effects. P261 Avoid breathing vapors, mist, or spray. P264 Wash skin thoroughly after handling. P272 Contaminated work clothing should not be allowed out of the workplace. P273 Avoid release to the environment. P280 Wear protective gloves/protective clothing/eye protection/face protection. P302+P352 IF ON SKIN: Wash with plenty of water. P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P333+P313 If skin irritation or rash occurs: Get medical attention. P337+P313 If eye irritation persists: Get medical advice/attention. P362+P364 Take off contaminated clothing and wash it before reuse. P501 Dispose of contents/container to an appropriate treatment and disposal facility in accordance with applicable laws and regulations, and product characteristics at of disposal. Classification of material Xi - Irritant Risk phrases: R36/38 Irritating to eyes and skin. R43 May cause sensitisation by skin contact. R52/53 Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment. Safety phrases: S24 Avoid contact with skin. S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S28 After contact with skin, wash immediately with plenty of water and soap. S37/39 Wear suitable gloves and eye/face protection. S46 If swallowed, seek medical advice immediately and show this container or label. S61 Avoid release to the environment. Refer to special instructions/safety data sheets. Dangerous Goods information: Not classified as Dangerous Goods according to the criteria of the Australian Code for the Transport of Dangerous Goods by Road and Rail (ADG Code). Signal word: HAZARDOUS Section 3. Composition / information on ingredients General chemical description: Type of preparation: Mixture Epoxy resin Identity of ingredients: Chemical ingredients Proportion bisph-a-(epichlorhydrin); % epoxy molecular weight <= 700) < 10 % non hazardous ingredients~ %

3 Page 3 of 8 Section 4. First aid measures Ingestion: Skin: Eyes: Inhalation: First Aid facilities: Medical attention and special treatment: Rinse mouth, do not induce vomiting, consult a doctor. Immediately wash skin thoroughly with soap and water. Seek medical advice. Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Seek medical advice. Move to fresh air, consult doctor if complaint persists. Eye wash Normal washroom facilities Treat symptomatically. Section 5. Fire fighting measures Suitable extinguishing media: Improper extinguishing media: Decomposition products in case of fire:: Special protective equipment for fire-fighters: Additional fire fighting advice: Water spray (fog), foam, dry chemical or carbon dioxide. High pressure waterjet Thermal decomposition can lead to release of irritating gases and vapors. Oxides of carbon. Oxides of nitrogen. Wear self-contained breathing apparatus and full protective clothing, such as turn-out gear. In case of fire, keep containers cool with water spray. Collect contaminated fire fighting water separately. It must not enter drains. Section 6. Accidental release measures Personal precautions: Environmental precautions: Clean-up methods: Avoid contact with skin and eyes. Wear protective equipment. Use personal protective equipment as described in Section 8. Do not empty into drains / surface water / ground water. Absorb spill with inert material. Shovel material into appropriate container for disposal. Dispose of contaminated material as waste according to Section 13. Section 7. Handling and storage Precautions for safe handling: See advice in section 8 Ensure that workrooms are adequately ventilated. Avoid skin and eye contact. Prolonged or repeated skin contact should be avoided Conditions for safe storage: Store in a cool, dry, well-ventilated area. Do not expose to direct sunlight.

4 Page 4 of 8 Section 8. controls / personal protection National exposure standards: None Engineering controls: Eye protection: Skin protection: Respiratory protection: Ventilation should effectively remove and prevent buildup of any vapor/mist/fume/dust generated from the handling of this product. Wear chemical goggles. Use of protective coveralls and long sleeves is recommended. Suitable protective gloves. Butyl rubber gloves. Please note that in practice the working life of chemical resistant gloves may be considerably reduced as a result of many influencing factors (e.g. temperature). Suitable risk assessment should be carried out by the end user. If signs of wear and tear are noticed then the gloves should be replaced. If inhalation risk exists, wear a respirator or air supplied mask complying with the requirements of AS/NZS 1715 and AS/NZS Section 9. Physical and chemical properties Appearance: grey paste Odor: mild ph: Not applicable Specific gravity: Boiling point: 390 C (734 F) Flash point: > 93.3 C (> F) (Setaflash Closed Cup; ASTM D3828 Method B) Density: 2.25 g/cm3 Solubility in water: Insoluble Section 10. Stability and reactivity Stability: Conditions to avoid: Stable under normal conditions of temperature and pressure. Keep away from heat, ignition sources and incompatible materials. Protect from direct sunlight.

5 Page 5 of 8 Incompatible materials: Reaction with strong acids. Oxidizing agents. Hazardous decomposition products: Hazardous polymerization: Thermal decomposition can lead to release of irritating gases and vapors. Oxides of carbon. Oxides of nitrogen. Will not occur. Section 11. Toxicological information Health Effects: Ingestion: Skin: Eyes: Inhalation: May cause irritation to the gastrointestinal tract, mouth and mucous membranes. Irritating to skin. Symptoms may include redness, edema, drying, defatting and cracking of the skin. May cause an allergic skin reaction. Causes serious eye irritation. Symptoms may include severe irritation, pain, tearing, blurred vision. May cause irritation to nose and throat. Acute toxicity: bisph-a- Tris(dimethylaminomethy l)ph Value type LD50 LD50 Value > 2,000 mg/kg 23,000 mg/kg Route of application oral dermal LD50 1,200 mg/kg oral rat Species rat rabbit Method Skin corrosion/irritation: bisph-a- Tris(dimethylaminomethy l)ph Result Species Method slightly irritating 4 h rabbit OECD Guideline 404 (Acute Dermal Irritation / Corrosion) corrosive 4 h rabbit OECD Guideline 404 (Acute Dermal Irritation / Corrosion) Serious eye damage/irritation: bisph-a- Result Species Method not irritating rabbit OECD Guideline 405 (Acute Eye Irritation / Corrosion)

6 Page 6 of 8 Respiratory or skin sensitization: bisph-a- Tris(dimethylaminomethy l)ph sensitising not sensitising Result Test type Species Method Mouse local lymphnod e assay (LLNA) Buehler test mouse guinea pig OECD Guideline 429 (Skin Sensitisation: Local Lymph Node Assay) OECD Guideline 406 (Skin Sensitisation) Germ cell mutagenicity: bisph-a- Tris(dimethylaminomethy l)ph Result Type of study / Route of administration negative bacterial reverse mutation assay (e.g Ames test) negative negative negative bacterial reverse mutation assay (e.g Ames test) in vitro mammalian chromosome aberration test mammalian cell gene mutation assay Metabolic activation / with and without with and without with and without Species Method OECD Guideline 472 (Genetic Toxicology: Escherichia coli, Reverse Mutation Assay) OECD Guideline 471 (Bacterial Reverse Mutation Assay) OECD Guideline 473 (In vitro Mammalian Chromosome Aberration Test) OECD Guideline 476 (In vitro Mammalian Cell Gene Mutation Test) Section 12. Ecological information

7 Page 7 of 8 General ecological information: Ecotoxicity: Do not empty into drains / surface water / ground water. Harmful to aquatic life with long lasting effects. Toxicity: bisph- A- bisph- A- bisph- A- Value type Value Acute Toxicity Study Species LC mg/l Fish 96 h Oncorhynchus mykiss (reported as Salmo gairdneri) Method OECD Guideline 203 (Fish, Acute Toxicity Test) EC mg/l Algae 72 h Scenedesmus capricornutum OECD Guideline 201 (Alga, Growth Inhibition Test) NOEC 2.4 mg/l Algae 72 h Scenedesmus capricornutum OECD Guideline 201 (Alga, Growth Inhibition Test) LC mg/l Fish 96 h Brachydanio rerio (new name: Danio rerio) EC50 84 mg/l Algae h Scenedesmus subspicatus (new name: Desmodesmus subspicatus) EC0 27 mg/l Bacteria 16 h ISO (Determination of the Acute Lethal Toxicity of Substances to a Freshwater Fish [Brachydanio rerio Hamilton- Buchanan (Teleostei, Cyprinidae)] OECD Guideline 201 (Alga, Growth Inhibition Test) Persistence and degradability: bisph- A- Result Not biodegradable. readily Route of application Degradability Method aerobic 5 % OECD Guideline 301 F (Ready Biodegradability: Manometric Respirometry Test) % OECD Guideline 301 D (Ready Biodegradability: Closed Bottle Test) Bioaccumulative potential / Mobility in soil: LogKow Bioconcentration factor (BCF) Species Temperature Method C EPA OPPTS (Partition Coefficient, n- octanol / H2O, Shake Flask Method)

8 Page 8 of 8 Section 13. Disposal considerations Waste disposal of product: Disposal for uncleaned package: Collection and delivery to recycling enterprise or other registered elimination institution. Packaging that cannot be cleaned are to be disposed of in the same manner as the product. Section 14. Transport information Road and Rail Transport: Dangerous Goods information: Not classified as Dangerous Goods according to the criteria of the Australian Code for the Transport of Dangerous Goods by Road and Rail (ADG Code). General information: Not hazardous according to RID, ADR, ADN, IMDG, IATA-DGR. SUSMP Poisons Schedule 5 Section 15. Regulatory information Section 16. Other information Abbreviations/acronyms: ADGC - Australian Dangerous Goods Code IMDG: International Mari Dangerous Goods code IATA-DGR: International Air Transport Association Dangerous Goods Regulations Reason for issue: Reviewed SDS. Reissued with new date. involved chapters: 1-16 Date of previous issue: Disclaimer: The percentage weight (% w/w) of ingredients is not to be taken as a specification guaranteed by Henkel Australia Pty. Limited, but only as an approximate guide to the content of hazardous ingredients in the material. The information contained herein does not constitute a guarantee by Henkel Australia Pty. Limited concerning the properties of the material. The information contained in the Safety Data Sheet is offered in good faith and has been developed from what is believed to be accurate and reliable sources. The information is offered without warranty, representation, inducement or licence and Henkel Australia Pty. Limited assumes no legal responsibility for reliance upon same. Henkel Australia Pty. Limited disclaims any liability for loss, injury or damage incurred in connection with the use of the material or its associated Safety Data Sheet. This information is not to be construed as a representation that the material is suitable for any particular purpose or use except those conditions and warranties implied by either Commonwealth or State statutes. Customers are encouraged to make their own enquiries as to the material s characteristics and, where appropriate, to conduct their own tests in the specific context of the material s intended use.