Safety Data Sheet Page 1 of 9

Transcription

1 Safety Data Sheet Page 1 of 9 SF-TEROSON PU 6700 COMP. A EX SDS No. : V001.6 Revision: printing date: Section 1. Identification of the substance/prepaion and of the company/undertaking Product name: SF-TEROSON PU 6700 COMP. A EX Other means of identification: SF-TEROSON PU 6700 COMP. A EX Product code: IDH Recommended use of the chemical and restrictions on use Intended use: Part A for 2-K-Polyurethane adhesive and sealant Identification of manufacturer, importer or distributor Manufacturer: Henkel AG & Co. KGaA, Heidelberg, Henkel Teroson Straße 57, Heidelberg, Germany. Phone: Fax: Importer: Henkel Thailand Ltd The Offices at Centralworld, 35th Floor, 999/9 Rama 1 Rd, Kwang Patumwan, Khet Patumwan, Bangkok 10330, Thailand. Phone : Fax : address of person responsible for Safety Data Sheet: ap-ua-psra.sea@henkel.com Emergency information: FOR EMERGENCIES ONLY (Spill, major leak, Fire, Exposure, or Accident). Call CHEMTREC: GHS Classification: Hazard Class Hazard Category Serious eye damage/eye irritation Category 2 GHS label elements: Hazard pictogram: Section 2. Hazards identification Signal word: Warning

2 Page 2 of 9 Precaution: Hazard statement: H319 Causes serious eye irritation. Prevention: P264 Wash hands thoroughly after handling. P280 Wear eye protection/face protection. Response: P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P337+P313 If eye irritation persists: Get medical advice/attention. Substance or Mixture: Mixture Declaion of hazardous chemical: Section 3. Composition / information on ingredients Hazard component CAS-No. Content GHS Classification % Polyether polyol based on ethylenediamine and propyleneoxide~ % Serious eye damage/eye irritation 2A H % Inhalation: Move to fresh air, consult doctor if complaint persists. Section 4. First aid measures Skin contact: Rinse with running water and soap. Apply replenishing cream. Change all contaminated clothing. Eye contact: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Ingestion: Rinse mouth, drink 1-2 glasses of water, do not induce vomiting, consult a doctor. Indication of immediate medical attention and special treatment needed: See section: Description of first aid measures Suitable extinguishing media: Section 5. Fire fighting measures

3 Page 3 of 9 All common extinguishing agents are suitable. Improper extinguishing media: High pressure waterjet Specific hazards arising from the chemical: In case of fire toxic gases can be released. Special protection equipment and precautions for firefighters: Wear protective equipment. Wear self-contained breathing appaus. Personal precautions: Wear protective equipment. Avoid contact with skin and e. Keep unprotected persons away. Environmental precautions: Do not empty into drains / surface water / ground water. Section 6. Accidental release measures Clean-up methods: Remove with liquid-absorbing material (sand, peat, sawdust). Dispose of contaminated material as waste according to Section 13. Handling: Ensure good ventilation/suction at the workplace. Avoid skin and eye contact. See advice in section 8 Section 7. Handling and storage Storage: Ensure good ventilation/extraction. Store in a cool, dry place. Tempeures between + 10 C and + 25 C Protect from direct sun-light and tempeure above 50 C in any case.

4 Page 4 of 9 Components with specific control parameters for workplace: Section 8. Exposure controls / personal protection Time Weighted Average (TWA): mg/m 3 10 Time Weighted Average (TWA): mg/m 3 10 Respiory protection: In case of dust formation, we recommend wearing of appropriate respiory protection equipment with particle filter P (EN 14387). This recommendation should be matched to local conditions. Hand protection: Chemical-resistant protective gloves (EN 374). Suitable materials for short-term contact or splashes (recommended: at least protection index 2, corresponding to > 30 minutes permeation time as per EN 374): Polychloroprene (CR; >= 1 mm thickness) or natural rubber (NR; >=1 mm thickness) Suitable materials for longer, direct contact (recommended: protection index 6, corresponding to > 480 minutes permeation time as per EN 374): Polychloroprene (CR; >= 1 mm thickness) or natural rubber (NR; >=1 mm thickness) This information is based on liteure references and on information provided by glove manufacturers, or is derived by analogy with similar substances. Please note that in practice the working life of chemical-resistant protective gloves may be considerably shorter than the permeation time determined in accordance with EN 374 as a result of the many influencing factors (e.g. tempeure). If signs of wear and tear are noticed then the gloves should be replaced. Eye protection: Goggles which can be tightly sealed. Protective eye equipment should conform to EN166. Body protection: Wear protective equipment. Protective clothing that covers arms and legs. Protective clothing should conform to EN for liquid splashes or to EN for dusts. Engineering controls: Ensure good ventilation/extraction. Hygienic measures: Do not eat, drink or smoke while working. Wash hands before work breaks and after finishing work. Appearance: light grey pasty, paste Odor: odourless Odor threshold (CA): ph: Melting point / freezing point: Specific gravity: Boiling point: Flash point: > 110 C (> 230 F) (no method) Evapoion e: Flammability (solid, gas): Lower explosive limit: Upper explosive limit: Vapor pressure: Vapor density: Section 9. Physical and chemical properties

5 Page 5 of 9 Density: Solubility: Partition coefficient: n- octanol/water: Auto ignition: Decomposition tempeure: Viscosity: (Brookfield; 20 C (68 F); : no method) VOC content: 1.43 g/cm pa.s Reactivity/Incompatible materials: None if used for intended purpose. Chemical stability: Stable under recommended storage conditions. Conditions to avoid: None if used for intended purpose. Hazardous decomposition products: No decomposition if used according to specifications. Section 10. Stability and reactivity Section 11. Toxicological information Health Effects: E: Symptoms of Overexposure: Causes serious eye irritation. EYE: Irritation, conjunctivitis. Acute oral toxicity: Polyether polyol based on ethylenediamine and propyleneoxide~ > 2,000 mg/kg OECD Guideline 420 (Acute Oral Toxicity) > 2,000 mg/kg > 5,000 mg/kg

6 Page 6 of 9 Acute inhalative toxicity: Acute toxicity estimate (ATE) 5.1 mg/l Expert judgement LC mg/l 90 min Acute dermal toxicity: Polyether polyol based on ethylenediamine and propyleneoxide~ Skin corrosion/irritation: Serious eye damage/irritation: > 2,000 mg/kg OECD Guideline 402 (Acute Dermal Toxicity) > 2,000 mg/kg > 5,000 mg/kg not irritating 4 h OECD Guideline 404 (Acute Dermal Irritation / Corrosion) not irritating 4 h OECD Guideline 404 (Acute Dermal Irritation / Corrosion) not irritating OECD Guideline 405 (Acute Eye Irritation / Corrosion) not irritating OECD Guideline 405 (Acute Eye Irritation / Corrosion) Respiory or skin sensitization: Test type Test type not sensitising Mouse local lymphnode assay (LLNA) mouse OECD Guideline 429 (Skin Sensitisation: Local Lymph Node Assay) not sensitising Mouse local lymphnode assay (LLNA) mouse OECD Guideline 429 (Skin Sensitisation: Local Lymph Node Assay)

7 Page 7 of 9 Germ cell mutagenicity: Repeated dose toxicity: Type of study / Route of administion Metabolic activation / Type of study / Route of administion Metabolic activation / Type of study / Route of administion Metabolic activation / Type of study / Route of administion Metabolic activation / Type of study / Route of administion Metabolic activation / Type of study / Route of administion Metabolic activation / Route of application / Frequency of treatment Route of application / Frequency of treatment bacterial reverse mutation assay (e.g Ames test) OECD Guideline 471 (Bacterial Reverse Mutation Assay) in vitro mammalian chromosome aberion test OECD Guideline 473 (In vitro Mammalian Chromosome Aberion Test) mammalian cell gene mutation assay OECD Guideline 476 (In vitro Mammalian Cell Gene Mutation Test) bacterial reverse mutation assay (e.g Ames test) OECD Guideline 471 (Bacterial Reverse Mutation Assay) in vitro mammalian chromosome aberion test OECD Guideline 473 (In vitro Mammalian Chromosome Aberion Test) mammalian cell gene mutation assay OECD Guideline 476 (In vitro Mammalian Cell Gene Mutation Test) NOAEL=1,000 mg/kg oral: gavage 48 ddaily OECD Guideline 422 (Combined Repeated Dose Toxicity Study with the Reproduction / Developmental Toxicity Screening Test) NOAEL=1,000 mg/kg oral: gavage 48 ddaily OECD Guideline 422 (Combined Repeated Dose Toxicity Study with the Reproduction / Developmental Toxicity Screening Test) Section 12. Ecological information General ecological information: Do not empty into drains, soil or bodies of water. Toxicity: Polyether polyol based on ethylenediamine and propyleneoxide~ NOEC 14 mg/l Algae 72 h Desmodesmus subspicatus OECD Guideline 201 (Alga, Growth Inhibition Test) LC50 4,500 mg/l Fish 48 h Leuciscus idus OECD Guideline 203 (Fish, Acute Toxicity Test) LC50 > 10,000 mg/l

8 Page 8 of 9 Fish 96 h OECD Guideline 203 (Fish, Acute Toxicity Test) EC50 > 1,000 mg/l Daphnia 48 h Daphnia magna OECD Guideline 202 (Daphnia sp. Acute Immobilisation Test) EC50 > 200 mg/l Algae 72 h OECD Guideline 201 (Alga, Growth Inhibition Test) EC50 > 1,000 mg/l Bacteria 3 h activated sludge of a predominantly domestic sewage OECD Guideline 209 (Activated Sludge, Respiion Inhibition Test) Bioaccumulative potential / Mobility in soil: LogPow Tempeure QSAR (Quantitative Structure Activity Relationship) Section 13. Disposal consideions Product Packaging of disposal: In consultation with the responsible local authority, must be subjected to special treatment. Disposal of uncleaned packages: Packaging that cannot be cleaned are to be disposed of in the same manner as the product. Section 14. Transport information General information: Not hazardous according to RID, ADR, ADN, IMDG, IATA-DGR.

9 Page 9 of 9 Section 15. Regulatory information Regulatory Information: Ministry of Industry Notice. The system to classify and communicate the hazard of hazardous material, BE Global inventory status: Regulatory list EINECS TSCA AICS DSL ENCS (JP) KECI (KR) PICCS (PH) IECSC ISHL (JP) NZIOC Notification Section 16. Other information Disclaimer: This information is based on our current level of knowledge and relates to the product in the state in which it is delivered. It is intended to describe our products from the point of view of safety requirements and is not intended to guarantee any particular properties.