Safety Data Sheet Page 1 of 7

Transcription

1 Safety Data Sheet Page 1 of 7 RESIN SDS No. : V001.3 Date of issue: Section 1. Identification of the substance/preparation and of the company/undertaking Product name: Intended use: RESIN Epoxy resin Supplier: Henkel Australia Pty Ltd Canterbury Road Kilsyth, Victoria, 3137 Australia Phone: +61 (3) Emergency information: 24 HOUR EMERGENCY CONTACT NUMBER: Classification of the substance or mixture Hazardous according to the criteria of Safe Work Australia. GHS Classification: Hazard Class Hazard Category Skin irritation Category 2 Serious eye irritation Category 2A Skin sensitizer Category 1 Chronic hazards to the aquatic Category 3 environment Hazard pictogram: Section 2. Hazards identification Signal word: Warning

2 Page 2 of 7 Hazard statement(s): Precautionary Statement(s): Prevention: Response: Disposal: H315 Causes skin irritation. H317 May cause an allergic skin reaction. H319 Causes serious eye irritation. H412 Harmful to aquatic life with long lasting effects. P261 Avoid breathing dust/fume/gas/mist/vapours/spray. P272 Contaminated work clothing should not be allowed out of the workplace. P273 Avoid release to the environment. P280 Wear eye protection/face protection. P280 Wear protective gloves. P264 Wash hands thoroughly after handling. P302+P352 IF ON SKIN: Wash with plenty of water. P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P333+P313 If skin irritation or rash occurs: Get medical advice/attention. P337+P313 If eye irritation persists: Get medical advice/attention. P362 Take off contaminated clothing. P501 Dispose of contents/container to an appropriate treatment and disposal facility in accordance with applicable laws and regulations. Classification of material Xi - Irritant Risk phrases: R36/38 Irritating to eyes and skin. R43 May cause sensitisation by skin contact. R52/53 Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment. Safety phrases: S24 Avoid contact with skin. S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S28 After contact with skin, wash immediately with plenty of water. S37 Wear suitable gloves. S46 If swallowed, seek medical advice immediately and show this container or label. Dangerous Goods information: Not classified as Dangerous Goods according to the criteria of the Australian Code for the Transport of Dangerous Goods by Road and Rail (ADG Code). Signal word: HAZARDOUS Section 3. Composition / information on ingredients General chemical description: Mixture Identity of ingredients: Chemical ingredients Proportion (epichlorhydrin); 10- < 30 % epoxy molecular weight <= 700) Silicon carbide < 10 % Oxirane, 2,2'-((2,2-dimethyl-1, < 5 % propanediyl)bis(oxymethylene))bisnon hazardous ingredients~ 30- < 70 %

3 Page 3 of 7 Section 4. First aid measures Ingestion: Skin: Eyes: Inhalation: Medical attention and special treatment: Rinse mouth, do not induce vomiting, consult a doctor. Rinse with running water and soap. In case of adverse health effects seek medical advice. Rinse immediately with plenty of running water (for 10 minutes). Seek medical attention if necessary. Move to fresh air. If symptoms persist, seek medical advice. Treat symptomatically and supportively. Section 5. Fire fighting measures Suitable extinguishing media: Improper extinguishing media: Decomposition products in case of fire:: Special protective equipment for fire-fighters: Carbon dioxide, foam, powder High pressure waterjet. Oxides of carbon. Irritating and toxic gases or fumes may be released during a fire. Wear self-contained breathing apparatus and full protective clothing, such as turn-out gear. Section 6. Accidental release measures Personal precautions: Environmental precautions: Clean-up methods: Avoid skin and eye contact. Do not let product enter drains. For small spills wipe up with paper towel and place in container for disposal. For large spills absorb onto inert absorbent material and place in sealed container for disposal. Section 7. Handling and storage Precautions for safe handling: Conditions for safe storage: Use only in well-ventilated areas. Avoid skin and eye contact. Prolonged or repeated skin contact should be avoided to minimise any risk of sensitisation. Store in a cool, well-ventilated place. For optimum shelf life store in original containers under refrigerated conditions at 2-8 C ( F)

4 Page 4 of 7 Section 8. controls / personal protection National exposure standards: Ingredient [Regulated substance] SILICON CARBIDE (INSPIRABLE DUST) form of exposure Inspirable dust. TWA (ppm) TWA (mg/m3) Peak Limit. (ppm) Peak Limit. (mg/m3) STEL (ppm) STEL (mg/m3) Engineering controls: Eye protection: Skin protection: Use general ventilation. Wear protective glasses. Wear suitable protective clothing. The use of chemical resistant gloves such as Nitrile is recommended. Please note that in practice the working life of chemical resistant gloves may be considerably reduced as a result of many influencing factors (e.g. temperature). Suitable risk assessment should be carried out by the end user. If signs of wear and tear are noticed then the gloves should be replaced. Respiratory protection: Use only in well-ventilated areas. If inhalation risk exists, wear a respirator or air supplied mask complying with the requirements of AS/NZS 1715 and AS/NZS Appearance: grey paste Odor: mild Specific gravity: Flash point: > 93 C (> F) Estimated Density: g/cm3 VOC content: < 3.00 % (2010/75/EC) Section 9. Physical and chemical properties Section 10. Stability and reactivity Stability: Conditions to avoid: Incompatible materials: Stable under normal conditions of temperature and pressure. Oxidizing conditions. Avoid heating. Reaction with strong acids. Reacts with strong oxidants. Hazardous decomposition products: Irritating and toxic gases or fumes may be released during a fire.

5 Page 5 of 7 Section 11. Toxicological information Health Effects: Ingestion: Skin: Eyes: Inhalation: Aggrevated med. condition: May cause gastrointestinal tract irritation if swallowed. May cause skin sensitization. This product is irritating to the skin. Itching. Redness. This product is irritating to the eyes. Redness. Excess tearing. May cause irritation to nose and throat. Skin disorders. Skin allergies. Eye disorders. Acute toxicity: Oxirane, 2,2'-((2,2- dimethyl-1,3- propanediyl)bis(oxymethy lene))bis type > 5,000 mg/kg 23,000 mg/kg > 2,000 mg/kg > 2,150 mg/kg Route of application oral dermal oral dermal Species rat rabbit rat rabbit Method Not specified Skin corrosion/irritation: Result Species Method slightly irritating 4 h rabbit OECD Guideline 404 (Acute Dermal Irritation / Corrosion) Serious eye damage/irritation: Result Species Method not irritating rabbit OECD Guideline 405 (Acute Eye Irritation / Corrosion) Respiratory or skin sensitization: sensitising Result Test type Species Method Mouse local lymphnod e assay (LLNA) mouse OECD Guideline 429 (Skin Sensitisation: Local Lymph Node Assay)

6 Page 6 of 7 Germ cell mutagenicity: Result Type of study / Route of administration negative bacterial reverse mutation assay (e.g Ames test) Metabolic activation / Species Method OECD Guideline 472 (Genetic Toxicology: Escherichia coli, Reverse Mutation Assay) Section 12. Ecological information General ecological information: Do not empty into drains / surface water / ground water., Harmful to aquatic organisms., May cause long-term adverse effects in the aquatic environment. Toxicity: bisphenol- A- bisphenol- A- bisphenol- A- type Acute Toxicity Study Species Method LC mg/l Fish 96 h Oncorhynchus mykiss OECD Guideline 203 (Fish, Acute Toxicity Test) EC mg/l Algae 72 h Scenedesmus capricornutum OECD Guideline 201 (Alga, Growth Inhibition Test) NOEC 2.4 mg/l Algae 72 h Scenedesmus capricornutum OECD Guideline 201 (Alga, Growth Inhibition Test) Persistence and degradability: bisphenol- A- Result Route of application Degradability Method aerobic 5 % OECD Guideline 301 F (Ready Biodegradability: Manometric Respirometry Test) Section 13. Disposal considerations Waste disposal of product: Disposal for uncleaned package: Collection and delivery to recycling enterprise or other registered elimination institution. After use, tubes, cartons and bottles containing residual product should be disposed of as chemically contaminated waste in an authorised legal land fill site or incinerated. Disposal must be made according to official regulations. Section 14. Transport information

7 Page 7 of 7 Road and Rail Transport: Dangerous Goods information: Not classified as Dangerous Goods according to the criteria of the Australian Code for the Transport of Dangerous Goods by Road and Rail (ADG Code). General information: Not hazardous according to RID, ADR, ADN, IMDG, IATA-DGR. SUSMP Poisons Schedule 5 Section 15. Regulatory information AICS: All components are listed or are exempt from listing on the Australian Inventory of Chemical Substances (AICS). Section 16. Other information Abbreviations/acronyms: ADGC - Australian Dangerous Goods Code GHS: Globally Harmonized System IATA-DGR: International Air Transport Association Dangerous Goods Regulations IMDG: International Mari Dangerous Goods code STEL - Short term exposure limit TWA - Time weighted average Reason for issue: Reviewed MSDS. Reissued with new date. involved chapters: 2,5,16 Date of previous issue: Disclaimer: The percentage weight (% w/w) of ingredients is not to be taken as a specification guaranteed by Henkel Australia Pty. Limited, but only as an approximate guide to the content of hazardous ingredients in the material. The information contained herein does not constitute a guarantee by Henkel Australia Pty. Limited concerning the properties of the material. The information contained in the Safety Data Sheet is offered in good faith and has been developed from what is believed to be accurate and reliable sources. The information is offered without warranty, representation, inducement or licence and Henkel Australia Pty. Limited assumes no legal responsibility for reliance upon same. Henkel Australia Pty. Limited disclaims any liability for loss, injury or damage incurred in connection with the use of the material or its associated Safety Data Sheet. This information is not to be construed as a representation that the material is suitable for any particular purpose or use except those conditions and warranties implied by either Commonwealth or State statutes. Customers are encouraged to make their own enquiries as to the material s characteristics and, where appropriate, to conduct their own tests in the specific context of the material s intended use.