SAFETY DATA SHEET according to regulation EU 1907/2006/EC

Transcription

1 SECTION 1. IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING Product information Trade name : Identification of the article : Use of the Substance/Mixture Industrial paint Company : SOFICOR MÄDER - Etablissement de L'Aigle Z.I. No 1 - Route de Crulai FR L'AIGLE Telephone : Telefax address Emergency telephone number products-safety.mader-france@mader-group.com : Stéphane MELIN +33 (0) (0) ORFILA (INRS) +33 (0) SECTION 2. HAZARDS IDENTIFICATION Risk advice to man and the environment Classification REGULATION (EC) No 1272/2008 Flam. Liq. 3 Flammable liquid and vapour. Water-react. 2 In contact with water releases flammable gases. Skin Irrit. 2 Causes skin irritation. Label elements Hazard pictograms : Flame Exclamation mark Signal word : Danger Hazard statements : H226 Flammable liquid and vapour. H261 In contact with water releases flammable gases. H315 Causes skin irritation. Precautionary statements : Prevention: P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. P231 + P232 Handle under inert gas. Protect from moisture. P280 Wear protective gloves/ eye protection/ face protection. Response: P335 + P334 Brush off loose particles from skin. Immerse in cool water/ wrap in wet bandages. P362 + P364 Take off contaminated clothing and wash it before reuse. P370 + P378 In case of fire: Use dry sand, dry chemical or alcohol-resistant foam to extinguish. Signal word : 2-butanone oxime; ethyl methyl ketoxime; ethyl methyl ketone oxime May produce an allergic reaction. 1/8

2 SECTION3. COMPOSITION/INFORMATION ON INGREDIENTS Chemical nature of the mixture Industrial paint Hazardous components Chemical name CAS-No. Classification REGULATION (EC) No 1272/2008 xylene Flam. Liq. 3 H226 Acute Tox. 4 H332 Acute Tox. 4 H312 Skin Irrit. 2 H315 ethylbenzene Flam. Liq. 2 H225 Acute Tox. 4 H332 STOT RE 2 H373 Asp. Tox. 1 H304 Concentration [%] >= 30,00 - < 50,00 >= 1,00 - < 10,00 2-butanone oxime; ethyl methyl ketoxime; ethyl methyl ketone oxime 2-ethylhexanoic acid, zirconium salt Acute Tox. 4 H312 Eye Dam. 1 H318 Skin Sens. 1 H317 Carc. 2 H Skin Irrit. 2 H315 Repr. 2 H361d >= 0,10 - < 1,00 >= 0,10 - < 0,30 For the full text of the H-Statements mentioned in this Section, see Section 16. SECTION 4. FIRST AID MEASURES General advice : No hazards which require special first aid measures. Inhalation : Move to fresh air in case of accidental inhalation of dust or fumes from overheating or combustion. If symptoms persist, call a physician. Skin contact : Take off contaminated clothing and shoes immediately. Wash off with soap and plenty of water. Eye contact : Flush eyes with water as a precaution. Remove contact lenses. Protect unharmed eye. Keep eye wide open while rinsing. Ingestion : Clean mouth with water and drink afterwards plenty of water. Do not give milk or alcoholic beverages. Never give anything by mouth to an unconscious person. 2/8

3 SECTION 5. FIREFIGHTING MEASURES Suitable extinguishing media Special protective equipment for firefighters : Use extinguishing measures that are appropriate to local circumstances and the surrounding environment. : In the event of fire, wear self-contained breathing apparatus. Further information : Standard procedure for chemical fires. SECTION 6. ACCIDENTAL RELEASE MEASURES Environmental precautions : No special environmental precautions required. Methods for cleaning up : Wipe up with absorbent material (e.g. cloth, fleece). Keep in suitable, closed containers for disposal. SECTION 7. HANDLING AND STORAGE Handling Advice on safe handling : For personal protection see section 8. No special handling advice required. Advice on protection against fire and explosion : Normal measures for preventive fire protection. Storage Requirements for storage : Keep container tightly closed in a dry and well-ventilated place. areas and containers Advice on common storage : No special restrictions on storage with other products. Other data : No decomposition if stored and applied as directed. SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Components with workplace control parameters 3/8

4 CAS-No. Chemical name Control parameters Type: Update Basis xylene 435 mg/m3 870 mg/m aluminium powder (pyrophoric) 3 mg/m Naphtha (petroleum), hydrotreated heavy; Low boiling point thermally cracked naphtha 300 mg/m3 600 mg/m ethylbenzene 220 mg/m mg/m3 220 mg/m3 Ceiling xylene 440 mg/m3 AGW: TRGS aluminium powder (pyrophoric) 10 mg/m3 6 mg/m3 3 mg/m3 AGW: AGW: AGW: TRGS 900 TRGS 900 TRGS ethylbenzene 20 ml/m3 88 mg/m butanone oxime; ethyl methyl ketoxime; ethyl methyl ketone oxime 0,3 ml/m3 1 mg/m xylene 221 mg/m3 442 mg/m3 AGW: TRGS 900 AGW: 07/2013 TRGS 900 VME VLE aluminium powder (pyrophoric) 10 mg/m3 5 mg/m3 5 mg/m3 VME VME VME ethylbenzene 435 mg/m3 VME xylene 220 mg/m3 441 mg/m aluminium powder (pyrophoric) 10 mg/m3 4 mg/m ethylbenzene 441 mg/m3 552 mg/m xylene 221 mg/m3 442 mg/m3 VLA-EC aluminium powder (pyrophoric) 5 mg/m3 10 mg/m3 5 mg/m ethylbenzene 441 mg/m3 551 mg/m3 VLA-EC xylene 221 mg/m3 442 mg/m aluminium powder (pyrophoric) 5 mg/m3 5 mg/m3 10 mg/m3 4/8

5 CAS-No. Chemical name Control parameters Type: Update Basis ethylbenzene 434 mg/m mg/m Personal protective equipment Respiratory protection : No personal respiratory protective equipment normally required. Hand protection : For prolonged or repeated contact use protective gloves. Eye protection : Safety glasses Skin and body protection : Protective suit Hygiene measures : General industrial hygiene practice. SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES Colour Odour Safety data ph : aluminium : solvent-like : Not applicable Boiling point/boiling range : > 36 C Flash point : ca.23 C Vapour pressure Density Water solubility Viscosity, dynamic Viscosity, kinematic : < hpa at 50 C : ca.1,04 g/cm3 at 23 C : Note: immiscible : Note: No data available : > 20,6 mm2/s at 40 C SECTION 10. STABILITY AND REACTIVITY Hazardous reactions : Note: No hazards to be specially mentioned. SECTION 11. TOXICOLOGICAL INFORMATION Acute inhalation toxicity : Acute toxicity estimate 5/8

6 Dose: > 20 mg/l, 4 h Method: Calculation method Acute dermal toxicity : Acute toxicity estimate Dose: > mg/kg Method: Calculation method Acute dermal toxicity xylene : Acute toxicity estimate Dose: mg/kg Method: Converted acute toxicity point estimate 2-butanone oxime; ethyl methyl ketoxime; ethyl methyl ketone oxime : Acute toxicity estimate Dose: mg/kg Method: Converted acute toxicity point estimate Skin irritation : Remarks:According to the classification criteria of the European Union, the product is not considered as being a skin irritant. ethylbenzene : Remarks:According to the classification criteria of the European Union, the product is not considered as being a skin irritant. Eye irritation : Remarks: According to the classification criteria of the European Union, the product is not considered as being an eye irritant. ethylbenzene : Remarks: According to the classification criteria of the European Union, the product is not considered as being an eye irritant. Sensitisation : Remarks: No data available Further information : No data available ethylbenzene : Solvents may degrease the skin. SECTION 12. ECOLOGICAL INFORMATION There is no data available for this product. Any flow in the sewers or the rivers must be avoided Physico-chemical removability Bioaccumulation Ecotoxicity effects Further information on ecology Additional ecological information SECTION 13. DISPOSAL CONSIDERATIONS : There is no data available for this product. Product : Offer surplus and non-recyclable solutions to a licensed 6/8

7 disposal company. Contaminated packaging : - Empty remaining contents. - Empty containers should be taken to an approved waste handling site for recycling or disposal. SECTION 14. TRANSPORT INFORMATION ADR UN Number : 1263 Description of the goods : PAINT Class : 3 Packaging group : III Classification Code : F1 Hazard Identification : 30 Number ADR/RID-Labels : 3 Tunnel restriction code : (D/E) IATA UN Number : 1263 Description of the goods : PAINT Class : 3 Packaging group : III ADR/RID-Labels : 3 Packing instruction (cargo : 366 aircraft) Packing instruction : 355 (passenger aircraft) Packing instruction (passenger aircraft) : Y344 IMDG Substance No. : UN 1263 Description of the goods : PAINT Class : 3 Packaging group : III ADR/RID-Labels : 3 EmS Number : F-E,S-E Marine pollutant : no SECTION 15. REGULATORY INFORMATION VOC Substances Data : : 52,57 % Nomenclature for classified sites (Law 76/663 as modified) Nomenclature for classified sites (Law 76/663 as modified) : 1432 Storage of flammable liquids in industrial tanks 1433 Sites for the blending(mixing) or use of flammable liquids 2940 Application, curing, drying of varnish, paint, finishes, adhesives, coverings etc. Installations classified for the protection of the environment (Environment : 7/8

8 Code R511-9) Occupational Illnesses (R-461-3, France) Table: : 4 bis Gastro intestinal illness caused by benzene, toluene, xylene and all products in which they are contained. Table: : 84 Health effects caused by professional use of liquid organic solvents (indicated in the table). : Not applicable SECTION 16. OTHER INFORMATION Further information Full text of H-Statements referred to under sections 2 and 3.: H225 H226 H304 H312 H315 H317 H318 H332 H351 H361d H373 Highly flammable liquid and vapour. Flammable liquid and vapour. May be fatal if swallowed and enters airways. Harmful in contact with skin. Causes skin irritation. May cause an allergic skin reaction. Causes serious eye damage. Harmful if inhaled. Suspected of causing cancer. Suspected of damaging the unborn child. May cause damage to organs through prolonged or repeated exposure. The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text. 8/8