Safety Data Sheet according to Regulation (EC) No1907/2006

Transcription

1 Safety Data Sheet according to Regulation (EC) No1907/2006 LOCTITE EA 9396 AERO PART B 500GR KIT known as EA 9396 PART Page 1 of 13 SDS No. : Revision: printing date: SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier Contains: Triazaundecamethylenediamine Amines, polyethylenepoly- 3,6,9,12-tetraazatetradecamethylenediamine 1.2. Relevant identified uses of the substance or mixture and uses advised against Intended use: Part B of 2-Component Epoxy Adhesive Details of the supplier of the safety data sheet Henkel Limited 2 Bishop Square Business Park AL109EY Herfordshire Hatfield Great Britain Phone: Fax-no.: ua-productsafety.uk@uk.henkel.com 1.4. Emergency telephone number 24 Hours Emergency Tel: +44 (0) Classification of the substance or mixture SECTION 2: Hazards identification Classification (CLP): Acute toxicity Category 4 H302 Harmful if swallowed. Route of Exposure: Oral Skin corrosion Category 1B H314 Causes severe skin burns and eye damage. Skin sensitizer Category 1 H317 May cause an allergic skin reaction. Chronic hazards to the aquatic environment Category 2 H411 Toxic to aquatic life with long lasting effects.

2 Page 2 of 13 Classification (DPD): C - Corrosive R34 Causes burns. Xn - Harmful R21/22 Harmful in contact with skin and if swallowed. Sensitizing R43 May cause sensitisation by skin contact. N - Dangerous for the environment R51/53 Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment Label elements Label elements (CLP): Hazard pictogram: Signal word: Hazard statement: Precautionary statement: Prevention Precautionary statement: Response Danger H302 Harmful if swallowed. H314 Causes severe skin burns and eye damage. H317 May cause an allergic skin reaction. H411 Toxic to aquatic life with long lasting effects. P273 Avoid release to the environment. P280 Wear protective gloves/protective clothing/eye protection/face protection. P303+P361+P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/ shower. P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to remove. Continue rinsing. P310 Immediately call a POISON CENTER or doctor. P333+P313 If skin irritation or rash occurs: Get medical advice/attention.

3 Page 3 of 13 Label elements (DPD): C - Corrosive N - Dangerous for the environment Risk phrases: R21/22 Harmful in contact with skin and if swallowed. R34 Causes burns. R43 May cause sensitisation by skin contact. R51/53 Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. Safety phrases: S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S36/37/39 Wear suitable protective clothing, gloves and eye/face protection. S45 In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). S57 Use appropriate container to avoid environmental contamination. S60 This material and its container must be disposed of as hazardous waste. Contains: Triazaundecamethylenediamine, Amines, polyethylenepoly-, 3,6,9,12-tetraazatetradecamethylenediamine,, Bis(aminopropyl)piperazine 2.3. Other hazards None if used properly. General chemical description: Accelerator for epoxy systems Base substances of preparation: organic amine SECTION 3: Composition/information on ingredients

4 Page 4 of 13 Declaration of the ingredients according to CLP (EC) No 1272/2008: Triazaundecamethylenediamine Bis(aminopropyl)piperazine Amines, polyethylenepoly ,6,9,12-tetraazatetradecamethylenediamine EC Number REACH-Reg No. content Classification >= 40- < 50 % Acute toxicity 4; Dermal H312 Acute toxicity 4; Oral H302 Skin sensitizer 1 H317 Chronic hazards to the aquatic environment 2 H411 Skin corrosion 1B H >= 30- < 40 % Skin corrosion 1B H >= 5- < 10 % Acute toxicity 4; Dermal H312 Skin corrosion 1B H314 Skin sensitizer 1 H317 Acute hazards to the aquatic environment 1 H400 Chronic hazards to the aquatic environment 1 H410 Acute toxicity 4; Oral H >= 5- < 10 % Skin corrosion 1B H314 Skin sensitizer 1 H317 Acute hazards to the aquatic environment 1 H400 Chronic hazards to the aquatic environment 1 H >= 1- < 3 % Acute toxicity 3; Dermal H311 Skin corrosion 1B H314 Skin sensitizer 1 H317 Chronic hazards to the aquatic environment 3 H412 For full text of the H - statements and other abbreviations see section 16 "Other information". Substances without classification may have community workplace exposure limits available.

5 Page 5 of 13 Declaration of ingredients according to DPD (EC) No 1999/45: Triazaundecamethylenediamine Bis(aminopropyl)piperazine Amines, polyethylenepoly ,6,9,12- tetraazatetradecamethylenediamine EC Number REACH-Reg No. content Classification >= 40 - < 50 % Xn - Harmful; R21/22 R43 C - Corrosive; R34 N - Dangerous for the environment; R51/ >= 30 - < 40 % C - Corrosive; R >= 5 - < 10 % N - Dangerous for the environment; R50/53 Xn - Harmful; R21/22 R43 C - Corrosive; R >= 5 - < 10 % C - Corrosive; R34 R N - Dangerous for the environment; R50/53 >= 1 - < 3 % Xn - Harmful; R21 C - Corrosive; R34 R43 R52/53 For full text of the R-Phrases indicated by codes see section 16 'Other Information'. Substances without classification may have community workplace exposure limits available Description of first aid measures SECTION 4: First aid measures Inhalation: Move to fresh air. If symptoms persist, seek medical advice. Skin contact: Rinse with running water and soap. Obtain medical attention if irritation persists. Eye contact: Rinse immediately with plenty of running water (for 10 minutes), seek medical attention from a specialist. Ingestion: Rinse mouth, drink 1-2 glasses of water, do not induce vomiting, consult a doctor Most important symptoms and effects, both acute and delayed Causes burns. INGESTION: Nausea, vomiting, diarrhoea, abdominal pain. SKIN: Rash, Urticaria Indication of any immediate medical attention and special treatment needed See section: Description of first aid measures 5.1. Extinguishing media Suitable extinguishing media: Foam, extinguishing powder, carbon dioxide. Fine water spray SECTION 5: Firefighting measures 5.2. Special hazards arising from the substance or mixture Danger of decomposition if exposed to heat. Formation of toxic gases is possible during heating or in fires. See section 10.

6 Page 6 of Advice for firefighters Wear self-contained breathing apparatus and full protective clothing, such as turn-out gear. Dispose of combustion residues and contaminated fire-fighting water in accordance with statutory regulations. Collect contaminated fire fighting water separately. It must not enter drains. Additional information: In case of fire, keep containers cool with water spray. SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures Avoid contact with skin and eyes. Wear protective equipment. Ensure adequate ventilation Environmental precautions Do not empty into drains / surface water / ground water Methods and material for containment and cleaning up Remove mechanically. For large spills absorb onto inert absorbent material and place in sealed container for disposal. Dispose of contaminated material as waste according to Section 13. Ensure adequate ventilation Reference to other sections See advice in section 8 SECTION 7: Handling and storage 7.1. Precautions for safe handling Ensure good ventilation/suction at the workplace. Extract when the product is heated. See advice in section 8 Avoid skin and eye contact. Do not spray against flames or glowing bodies. Keep away from sources of ignition - no smoking. Hygiene measures: Good industrial hygiene practices should be observed. Wash hands before work breaks and after finishing work. Do not eat, drink or smoke while working Conditions for safe storage, including any incompatibilities Store in sealed original container. Store in a cool, dry place. Ensure that storage and workrooms are adequately ventilated. Must be stored in a room with spill collection facilities. Keep away from heat and direct sunlight Specific end use(s) Part B of 2-Component Epoxy Adhesive. SECTION 8: Exposure controls/personal protection 8.1. Control parameters Occupational Exposure Limits Valid for Great Britain None

7 Page 7 of 13 Biological Exposure Indices: None 8.2. Exposure controls: Engineering controls: Ensure good ventilation/extraction. Respiratory protection: Ensure adequate ventilation. An approved mask or respirator fitted with an organic vapour cartridge should be worn if the product is used in a poorly ventilated area Filter type: A Hand protection: Chemical-resistant protective gloves (EN 374). Suitable materials for short-term contact or splashes (recommended: at least protection index 2, corresponding to > 30 minutes permeation time as per EN 374): nitrile rubber (NBR; >= 0.4 mm thickness) Suitable materials for longer, direct contact (recommended: protection index 6, corresponding to > 480 minutes permeation time as per EN 374): nitrile rubber (NBR; >= 0.4 mm thickness) This information is based on literature references and on information provided by glove manufacturers, or is derived by analogy with similar substances. Please note that in practice the working life of chemical-resistant protective gloves may be considerably shorter than the permeation time determined in accordance with EN 374 as a result of the many influencing factors (e.g. temperature). If signs of wear and tear are noticed then the gloves should be replaced. Eye protection: Safety glasses with sideshields or chemical safety goggles should be worn if there is a risk of splashing. Skin protection: Wear suitable protective clothing. SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties Appearance liquid liquid Orange-red Odor ammoniacal Odour threshold ph (; Solvent: Water) Initial boiling point (1.013 hpa) Flash point Decomposition temperature Vapour pressure Density (20 C (68 F)) Bulk density Viscosity Viscosity (kinematic) Explosive properties Solubility (qualitative) (20 C (68 F); Solvent: Water) Solidification temperature Melting point Flammability Auto-ignition temperature Explosive limits Partition coefficient: n-octanol/water > 7 > 100 C (> 212 F) > 93 C (> F)Estimated > 100 C (> 212 F) 1,0 g/cm3 fully soluble

8 Page 8 of 13 Evaporation rate Vapor density Oxidising properties 9.2. Other information SECTION 10: Stability and reactivity Reactivity Reaction with strong oxidants. Reacts with acids. Reacts violently with peroxides. Will cause some corrosion to copper alloys and aluminum. Do not mix with nitric acid or sodium nitrite. Reaction with some curing agents may produce an exothermic reaction which in large masses could cause runaway polymerization Chemical stability Stable under recommended storage conditions Possibility of hazardous reactions See section reactivity Conditions to avoid Avoid mixing resin (Part A) and curing agent (Part B) unless you plan to use immediately. Failure to observe these precautions may result in excessive heat build-up causing an exotherm. Danger of decomposition if exposed to heat Incompatible materials See section reactivity Hazardous decomposition products Hydrocarbons Nitric acid. Nitrosamines At higher temperature ammonia or amine derivatives may be generated. At higher temperature carbon oxides and nitrogen oxides may be generated. May produce fumes when heated to decomposition. Fumes may contain carbon monoxide and other toxic fumes. See section Information on toxicological effects SECTION 11: Toxicological information General toxicological information: The mixture is classified based on the available hazard information for the ingredients as defined in the classification criteria for mixtures for each hazard class or differentiation in Annex I to Regulation 1272/2008/EC. Relevant available health/ecological information for the substances listed under Section 3 is provided in the following. Oral toxicity: Harmful if swallowed. Inhalative toxicity: May cause irritation to respiratory system. Skin irritation: Causes severe skin burns and eye damage. Eye irritation: Avoid eye contact. Corrosive

9 Page 9 of 13 Sensitizing: May cause an allergic skin reaction. Acute oral toxicity: Value type Value Route of application Exposure time Species LD mg/kg oral rat LD mg/kg rat Method Acute inhalative toxicity: Value type Value Route of application Exposure time Species Method Acute dermal toxicity: Triazaundecamethylenedi amine Value type Value Route of application Exposure time Species LD mg/kg dermal rabbit LD mg/kg dermal rabbit Method Skin corrosion/irritation: Triazaundecamethylenedi amine Result Exposure time Species Method corrosive 4 h rabbit Draize Test corrosive rabbit Respiratory or skin sensitization: Triazaundecamethylenedi amine sensitising sensitising Result Test type Species Method Guinea pig maximisat ion test Guinea pig maximisat ion test guinea pig guinea pig Magnusson and Kligman Method Germ cell mutagenicity: Result Type of study / Route of administration positive bacterial reverse mutation assay (e.g Ames test) Metabolic activation / Exposure time with and without Species Method SECTION 12: Ecological information General ecological information: The mixture is classified based on the available hazard information for the ingredients as defined in the classification criteria for mixtures for each hazard class or differentiation in Annex I to Regulation 1272/2008/EC. Relevant available health/ecological information for the substances listed under Section 3 is provided in the following.

10 Page 10 of Toxicity Ecotoxicity: Toxic to aquatic life with long lasting effects. Do not empty into drains / surface water / ground water. Triazaundecamethylenediamin e Triazaundecamethylenediamin e Triazaundecamethylenediamin e 3,6,9,12- tetraazatetradecamethylenedia mine Value type Value Acute Toxicity Study Exposure time Species Method LC mg/l Fish 96 h Poecilia reticulata OECD Guideline 203 (Fish, Acute Toxicity Test) EC50 24,1 mg/l Daphnia 48 h Daphnia magna OECD Guideline 202 (Daphnia sp. Acute Immobilisation Test) NOEC 0,5 mg/l Algae 72 h Selenastrum capricornutum (new name: Pseudokirchnerella subcapitata) EC50 6,8 mg/l Algae 72 h Selenastrum capricornutum (new name: Pseudokirchnerella subcapitata) LC50 > 100 mg/l Fish 96 h Brachydanio rerio (new name: Danio rerio) OECD Guideline 201 (Alga, Growth Inhibition Test) OECD Guideline 201 (Alga, Growth Inhibition Test) OECD Guideline 203 (Fish, Acute Toxicity Test) LC mg/l Fish 96 h Poecilia reticulata OECD Guideline 203 (Fish, Acute Toxicity Test) EC50 31 mg/l Daphnia 48 h Daphnia magna OECD Guideline 202 (Daphnia sp. Acute Immobilisation EC50 20 mg/l Algae 72 h Selenastrum capricornutum (new name: Pseudokirchnerella subcapitata) EC10 < 2,5 mg/l Algae 72 h Selenastrum capricornutum (new name: Pseudokirchnerella subcapitata) Test) OECD Guideline 201 (Alga, Growth Inhibition Test) OECD Guideline 201 (Alga, Growth Inhibition Test) Persistence and degradability Persistence and Biodegradability: The product is not biodegradable. Triazaundecamethylenediamin e Result under test conditions no biodegradation observed Route of application Degradability Method aerobic 0 % OECD Guideline 301 D (Ready Biodegradability: Closed Bottle Test) aerobic 0 % OECD Guideline 301 D (Ready Biodegradability: Closed Bottle Test) Bioaccumulative potential / Mobility in soil Mobility: Cured adhesives are immobile. Bioaccumulative potential: No data available. LogKow Bioconcentration factor (BCF) Exposure time Species Temperature Method

11 Page 11 of 13 Triazaundecamethylenediamin e 3,6,9,12- tetraazatetradecamethylenedia mine ,16-3,67-2,65 OECD Guideline 107 (Partition Coefficient (noctanol / water), Shake Flask Method) Results of PBT and vpvb assessment PBT/vPvB Not fulfilling Persistent, Bioaccumulative and Toxic (PBT), very Persistent and very Bioaccumulative (vpvb) criteria Other adverse effects No data available. SECTION 13: Disposal considerations Waste treatment methods Product disposal: Special waste incineration with the approval of the responsible local authority. Disposal of uncleaned packages: Disposal must be made according to official regulations. Use packages for recycling only when totally empty. Packaging that cannot be cleaned are to be disposed of in the same manner as the product. Waste code waste adhesives and sealants containing organic solvents and other dangerous substances The valid EWC waste code numbers are source-related. The manufacturer is therefore unable to specify EWC waste codes for the articles or products used in the various sectors. The EWC codes listed are intended as a recommendation for users. We will be happy to advise you.

12 Page 12 of 13 SECTION 14: Transport information UN number ADR 2735 RID 2735 ADNR 2735 IMDG 2735 IATA UN proper shipping name ADR RID ADNR IMDG IATA AMINES, LIQUID, CORROSIVE, N.O.S. (Tetraethylene pentamine,substituted piperazine) AMINES, LIQUID, CORROSIVE, N.O.S. (Tetraethylene pentamine,substituted piperazine) AMINES, LIQUID, CORROSIVE, N.O.S. (Tetraethylene pentamine,substituted piperazine) AMINES, LIQUID, CORROSIVE, N.O.S. (Tetraethylene pentamine,substituted piperazine) Amines, liquid, corrosive, n.o.s. (Tetraethylene pentamine,substituted piperazine) Transport hazard class(es) ADR 8 RID 8 ADNR 8 IMDG 8 IATA Packaging group ADR RID ADNR IMDG IATA III III III III III Environmental hazards ADR RID ADNR IMDG IATA Environmentally Hazardous Environmentally Hazardous Environmentally Hazardous Environmentally Hazardous Special precautions for user ADR RID ADNR IMDG IATA Tunnelcode: (E) Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code SECTION 15: Regulatory information Safety, health and environmental regulations/legislation specific for the substance or mixture VOC content < 3 %

13 Page 13 of 13 (1999/13/EC) Chemical safety assessment A chemical safety assessment has not been carried out. SECTION 16: Other information The labelling of the product is indicated in Section 2. The full text of all abbreviations indicated by codes in this safety data sheet are as follows: R21 Harmful in contact with skin. R21/22 Harmful in contact with skin and if swallowed. R34 Causes burns. R43 May cause sensitisation by skin contact. R50/53 Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. R51/53 Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. R52/53 Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment. H302 Harmful if swallowed. H311 Toxic in contact with skin. H312 Harmful in contact with skin. H314 Causes severe skin burns and eye damage. H317 May cause an allergic skin reaction. H400 Very toxic to aquatic life. H410 Very toxic to aquatic life with long lasting effects. H411 Toxic to aquatic life with long lasting effects. H412 Harmful to aquatic life with long lasting effects. Further information: This information is based on our current level of knowledge and relates to the product in the state in which it is delivered. It is intended to describe our products from the point of view of safety requirements and is not intended to guarantee any particular properties.