ABLEBOND 84-1LMISR4. Section 2. Composition / information on ingredients. Section 3. Hazards identification.

Transcription

1 Safety Data Sheet Page 1 of 6 MSDS-No. : Revision: printing date: Section 1. Identification of the substance/preparation and of the company/undertaking Product name: Trade name: ABLEBOND 84-1LMISR4 Identification of manufacturer, importer or distributor Importer: Henkel Philippines Inc. LSL Bldg. 2, Diode St., Light Industry and Science Park of the Philippines I, Brgy. Diezmo, Cabuyao, Laguna, Philippines Phone: Fax: ) address of person responsible for Safety Data Sheet: ap-ua-psra.sea@henkel.com Section 2. Composition / information on ingredients General chemical description: Adhesive Declaration of ingredients: Silver >= 99,9 % Ag as powder (< 1 mm) - classified for environment Reaction product: bisphenol-f- (epichlorhydrin); epoxy resin (number average molecular weight <= 700) Dapsone EINECS content Classification % N - Dangerous for the environment; R50/ % Xi - Irritant; R38, R43 N - Dangerous for the environment; R51/ % Xn - Harmful; R20/21 R43 Xi - Irritant; R36/ % Xn - Harmful; R22 Section 3. Hazards identification Hazard classification: Risk phrases: Xi - Irritant R38 Irritating to skin. R43 May cause sensitisation by skin contact. R52/53 Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment. Section 4. First aid measures Inhalation: Should not be a problem as product is of low volatility. However, if feeling unwell remove patient to fresh air.

2 Page 2 of 6 Skin contact: Rinse with running water and soap. Obtain medical attention if irritation persists. Eye contact: Ingestion: Rinse immediately with plenty of running water (for 10 minutes), seek medical attention from a specialist. Rinse mouth, drink 1-2 glasses of water, do not induce vomiting, consult a doctor. Section 5. Fire fighting measures Suitable extinguishing media: Special protection equipment for firefighters: Particular danger/case of fire: water, carbon dioxide, foam, powder Wear self-contained breathing apparatus and full protective clothing, such as turn-out gear. In the event of a fire, carbon monoxide (CO), carbon dioxide (CO2) and nitrogen oxides (NOx) can be released. In case of fire, keep containers cool with water spray. Section 6. Accidental release measures Personal precautions: Environmental precautions: Clean-up methods: Avoid contact with skin and e. Wear protective equipment. Do not empty into drains / surface water / ground water. For small spills wipe up with paper towel and place in container for disposal. For large spills absorb onto inert absorbent material and place in sealed container for disposal. Section 7. Handling and storage Handling: Storage: Avoid skin and eye contact. See advice in section 8 Ensure good ventilation/extraction. Keep container tightly sealed. Keep frozen. Section 8. Exposure controls / personal protection Ingredient Type ppm mg/m 3 Remarks SILVER, METAL, DUST AND FUME Time Weighted Average 0,1 ACGIH (TWA): SILVER, METAL & SOLUBLE CPDS. Time Weighted Average (TWA): 0,01 PH OEL

3 Page 3 of 6 Respiratory protection: Ensure adequate ventilation. An approved mask or respirator fitted with an organic vapour cartridge should be worn if the product is used in a poorly ventilated area Filter type: A Hand protection: Chemical-resistant protective gloves (EN 374). Suitable materials for short-term contact or splashes (recommended: at least protection index 2, corresponding to > 30 minutes permeation time as per EN 374): nitrile rubber (NBR; >= 0.4 mm thickness) Suitable materials for longer, direct contact (recommended: protection index 6, corresponding to > 480 minutes permeation time as per EN 374): nitrile rubber (NBR; >= 0.4 mm thickness) This information is based on literature references and on information provided by glove manufacturers, or is derived by analogy with similar substances. Please note that in practice the working life of chemical-resistant protective gloves may be considerably shorter than the permeation time determined in accordance with EN 374 as a result of the many influencing factors (e.g. temperature). If signs of wear and tear are noticed then the gloves should be replaced. Eye protection: Body protection: Engineering controls: Hygienic measures: Safety glasses with sideshields or chemical safety goggles should be worn if there is a risk of splashing. Wear suitable protective clothing. Ensure good ventilation/extraction. Good industrial hygiene practices should be observed. Wash hands before work breaks and after finishing work. Do not eat, drink or smoke while working. Section 9. Physical and chemical properties Appearance: silver paste Odor: Slight Melting point: Not determined Specific gravity: 3,5 Auto ignition: Not available. Flash point: Not applicable Vapor pressure: Not applicable Density: 3,5 g/cm3 Solubility: Solvent: Water, Insoluble VOC content < 3 % (1999/13/EC) Section 10. Stability and reactivity Conditions to avoid: No decomposition if stored and applied as directed. Stable under recommended storage conditions.

4 Page 4 of 6 Materials to avoid: Reacts with alcohols and amines. Reacts with oxidants, acids and l Reaction with some curing agents may produce an exothermic reaction which in large masses could cause runaway polymerization. Hazardous decomposition products: Hazardous polymerization: Hydrocarbons carbon oxides. nitrogen oxides Rapid polymerization may generate excessive heat and pressure. Section 11. Toxicological information Oral toxicity: Inhalative toxicity: Dermal toxicity: Skin irritation: Sensitizing: May cause irritation to the digestive tract. May cause irritation to respiratory system. Prolonged or repeated skin contact with silver and its salts may cause a blue-gray discoloration of the skin and mucous membranes that is irreversible (Argyria). Causes skin irritation. May cause an allergic skin reaction. Acute toxicity: Silver >= 99,9 % Ag in powder (< 1 mm) Bisphenol-F epichlorhydrin resin; MW<700 type Route of application oralinhalationder mal Exposure time LD50 > mg/kg oral rat Species Method Respiratory or skin sensitization: sensitising Result Test type Species Method Guinea pig maximisat ion test guinea pig OECD Guideline 406 (Skin Sensitisation) Germ cell mutagenicity: Result Type of study / Route of administration positive bacterial reverse mutation assay (e.g Ames test) Metabolic activation / Exposure time with and without Species Method Section 12. Ecological information Mobility: Cured adhesives are immobile. Ecotoxicity: Do not empty into drains / surface water / ground water. : Harmful to aquatic life with long lasting effects.

5 Page 5 of 6 Toxicity: Bisphenol-F epichlorhydrin resin; MW<700 Bisphenol-F epichlorhydrin resin; MW<700 type Acute Toxicity Study Exposure time Species Method EC50 1,6 mg/l Daphnia 48 h Daphnia magna OECD Guideline 202 (Daphnia sp. Acute Immobilisation Test) EC50 1,8 mg/l Algae 72 h OECD Guideline 201 (Alga, Growth Inhibition Test) LC50 24 mg/l Fish 96 h Brachydanio rerio (new name: Danio rerio) OECD Guideline 203 (Fish, Acute Toxicity Test) EC50 75 mg/l Daphnia 24 h Daphnia magna OECD Guideline 202 (Daphnia sp. Acute Immobilisation Test) Persistence and degradability: Bisphenol-F epichlorhydrin resin; MW<700 Result Route of application Degradability Method aerobic 5 % OECD Guideline 301 F (Ready Biodegradability: Manometric Respirometry Test) 37 % OECD Guideline 301 B (Ready Biodegradability: CO2 Evolution Test) Section 13. Disposal considerations Product Method of disposal: Packaging Disposal for uncleaned package: Do not empty into drains / surface water / ground water. Dispose of in accordance with local and national regulations. After use, tubes, cartons and bottles containing residual product should be disposed of as chemically contaminated waste in an authorised legal land fill site or incinerated. Section 14. Transport information General information: Not hazardous according to RID, ADR, ADNR, IMDG, IATA-DGR. Additional information: UN 1845, carbon dioxide, solid, as a coolant (does not apply for Germany, Sweden, France, Belgium, UK) Section 15. Regulations - classification and identification Indication of danger: Risk phrases: Xi - Irritant R38 Irritating to skin. R43 May cause sensitisation by skin contact. R52/53 Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment.

6 Page 6 of 6 Safety phrases: S24 Avoid contact with skin. S26 In case of contact with e, rinse immediately with plenty of water and seek medical advice. S37 Wear suitable gloves. Global inventory status: Regulatory list TSCA NDSL KECI (KR) PICCS (PH) IECSC Notification Section 16. Other information Issue date: Disclaimer This information is based on our current level of knowledge and relates to the product in the state in which it is delivered. It is intended to describe our products from the point of view of safety requirements and is not intended to guarantee any particular properties. This safety data sheet was prepared in accordance with Council Directive 67/548/EEC and it's subsequent amendments, and Commission Directive 1999/45/EC.