SAFETY DATA SHEET. Revision Date 19-Jan-2018 Revision Number Identification

Transcription

1 SAFETY DATA SHEET Revision Number 3 Product Name Cat No. : Synonyms Recommended Use Uses advised against 1. Identification AC ; AC ; AC Laboratory chemicals. Not for food, drug, pesticide or biocidal product use Details of the supplier of the safety data sheet Company Fisher Scientific One Reagent Lane Fair Lawn, NJ Tel: (201) Acros Organics One Reagent Lane Fair Lawn, NJ Emergency Telephone Number For information US call: ACROS-01 / Europe call: Emergency Number US: / Europe: CHEMTREC Tel. No.US: / Europe: Hazard(s) identification Classification This chemical is considered hazardous by the 2012 OSHA Hazard Communication Standard (29 CFR ) Acute oral toxicity Category 4 Acute dermal toxicity Category 4 Acute Inhalation Toxicity - Vapors Category 4 Skin Corrosion/irritation Category 2 Serious Eye Damage/Eye Irritation Category 2 Respiratory Sensitization Category 1 Skin Sensitization Category 1 Specific target organ toxicity (single exposure) Category 3 Target Organs - Respiratory system. Label Elements Signal Word Danger Hazard Statements Harmful if swallowed Harmful in contact with skin Causes skin irritation Causes serious eye irritation May cause an allergic skin reaction Harmful if inhaled Page 1 / 7

2 May cause allergy or asthma symptoms or breathing difficulties if inhaled May cause respiratory irritation Precautionary Statements Prevention Wash face, hands and any exposed skin thoroughly after handling Do not eat, drink or smoke when using this product Wear protective gloves/protective clothing/eye protection/face protection Avoid breathing dust/fume/gas/mist/vapors/spray Use only outdoors or in a well-ventilated area In case of inadequate ventilation wear respiratory protection Contaminated work clothing should not be allowed out of the workplace Inhalation IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing If experiencing respiratory symptoms: Call a POISON CENTER or doctor/physician Skin IF ON SKIN: Wash with plenty of soap and water Call a POISON CENTER or doctor/physician if you feel unwell Take off contaminated clothing and wash before reuse If skin irritation or rash occurs: Get medical advice/attention Eyes IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing If eye irritation persists: Get medical advice/attention Ingestion IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell Rinse mouth Storage Store in a well-ventilated place. Keep container tightly closed Store locked up Disposal Dispose of contents/container to an approved waste disposal plant Hazards not otherwise classified (HNOC) None identified 3. Composition/Information on Ingredients Component CAS-No Weight % First-aid measures Eye Contact Skin Contact Inhalation Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Get medical attention. Wash off immediately with soap and plenty of water while removing all contaminated clothes and shoes. Obtain medical attention. Remove from exposure, lie down. Move to fresh air. If not breathing, give artificial respiration. Obtain medical attention. Page 2 / 7

3 Ingestion Most important symptoms and effects Notes to Physician Suitable Extinguishing Media Unsuitable Extinguishing Media Clean mouth with water. Get medical attention. May cause allergy or asthma symptoms or breathing difficulties if inhaled. May cause allergic skin reaction. Symptoms of allergic reaction may include rash, itching, swelling, trouble breathing, tingling of the hands and feet, dizziness, lightheadedness, chest pain, muscle pain or flushing Treat symptomatically 5. Fire-fighting measures Water spray. Carbon dioxide (CO 2). Dry chemical. Chemical foam. Flash Point > 110 C / > 230 F Method - Autoignition Temperature Explosion Limits Upper Lower Sensitivity to Mechanical Impact Sensitivity to Static Discharge Specific Hazards Arising from the Chemical Keep product and empty container away from heat and sources of ignition. Hazardous Combustion Products Nitrogen oxides (NOx) Carbon monoxide (CO) Carbon dioxide (CO2) Protective Equipment and Precautions for Firefighters As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear. NFPA Health 2 Flammability 1 Instability 0 Physical hazards N/A Personal Precautions Environmental Precautions 6. Accidental release measures Ensure adequate ventilation. Use personal protective equipment. See Section 12 for additional ecological information. Methods for Containment and Clean Soak up with inert absorbent material (e.g. sand, silica gel, acid binder, universal binder, Up sawdust). Keep in suitable, closed containers for disposal. Do not let this chemical enter the environment. Handling Storage Exposure Guidelines 7. Handling and storage Avoid contact with skin and eyes. Do not breathe vapors or spray mist. Do not ingest. Use only in area provided with appropriate exhaust ventilation. Keep in a dry, cool and well-ventilated place. Keep container tightly closed. 8. Exposure controls / personal protection This product does not contain any hazardous materials with occupational exposure limitsestablished by the region specific regulatory bodies. Page 3 / 7

4 Engineering Measures Ensure adequate ventilation, especially in confined areas. Ensure that eyewash stations and safety showers are close to the workstation location. Personal Protective Equipment Eye/face Protection Skin and body protection Respiratory Protection Hygiene Measures Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR or European Standard EN166. Wear appropriate protective gloves and clothing to prevent skin exposure. Follow the OSHA respirator regulations found in 29 CFR or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced. Handle in accordance with good industrial hygiene and safety practice. 9. Physical and chemical properties Physical State Liquid Appearance Colorless Odor Odor Threshold ph Melting Point/Range Boiling Point/Range 115 C / mmhg Flash Point > 110 C / > 230 F Evaporation Rate Flammability (solid,gas) Flammability or explosive limits Upper Lower Vapor Pressure Vapor Density 6.73 Specific Gravity Solubility Partition coefficient; n-octanol/water Autoignition Temperature Decomposition Temperature Viscosity Molecular Formula C13 H9 N O Molecular Weight Stability and reactivity Reactive Hazard Stability Conditions to Avoid Incompatible Materials None known, based on information available Moisture sensitive. Incompatible products. Exposure to moist air or water. Strong oxidizing agents Hazardous Decomposition Products Nitrogen oxides (NOx), Carbon monoxide (CO), Carbon dioxide (CO2) Hazardous Polymerization Hazardous Reactions. None under normal processing. Page 4 / 7

5 Acute Toxicity 11. Toxicological information Product Information Component Information Toxicologically Synergistic Products Delayed and immediate effects as well as chronic effects from short and long-term exposure Irritation Sensitization Carcinogenicity The table below indicates whether each agency has listed any ingredient as a carcinogen. Component CAS-No IARC NTP ACGIH OSHA Mexico 2-Biphenylyl isocyanate Not listed Not listed Not listed Not listed Not listed Mutagenic Effects Reproductive Effects Developmental Effects Teratogenicity STOT - single exposure STOT - repeated exposure Aspiration hazard... Respiratory system None known Symptoms / effects,both acute and delayed Symptoms of allergic reaction may include rash, itching, swelling, trouble breathing, tingling of the hands and feet, dizziness, lightheadedness, chest pain, muscle pain or flushing Endocrine Disruptor Information Other Adverse Effects Ecotoxicity Do not empty into drains. Persistence and Degradability Bioaccumulation/ Accumulation Mobility Waste Disposal Methods The toxicological properties have not been fully investigated. 12. Ecological information Disposal considerations Chemical waste generators must determine whether a discarded chemical is classified as a hazardous waste. Chemical waste generators must also consult local, regional, and national hazardous waste regulations to ensure complete and accurate classification. DOT UN-No UN Transport information Page 5 / 7

6 TDG UN-No UN2206 IATA UN-No 2206 Proper Shipping Name ISOCYANATE SOLUTION, TOXIC, N.O.S.* IMDG/IMO UN-No 2206 Proper Shipping Name ISOCYANATE SOLUTION, TOXIC, N.O.S. International Inventories 15. Regulatory information Legend: X - Listed E - Indicates a substance that is the subject of a Section 5(e) Consent order under TSCA. F - Indicates a substance that is the subject of a Section 5(f) Rule under TSCA. N - Indicates a polymeric substance containing no free-radical initiator in its inventory name but is considered to cover the designated polymer made with any free-radical initiator regardless of the amount used. P - Indicates a commenced PMN substance R - Indicates a substance that is the subject of a Section 6 risk management rule under TSCA. S - Indicates a substance that is identified in a proposed or final Significant New Use Rule T - Indicates a substance that is the subject of a Section 4 test rule under TSCA. XU - Indicates a substance exempt from reporting under the Inventory Update Rule, i.e. Partial Updating of the TSCA Inventory Data Base Production and Site Reports (40 CFR 710(B). Y1 - Indicates an exempt polymer that has a number-average molecular weight of 1,000 or greater. Y2 - Indicates an exempt polymer that is a polyester and is made only from reactants included in a specified list of low concern reactants that comprises one of the eligibility criteria for the exemption rule. U.S. Federal Regulations TSCA 12(b) SARA 313 SARA 311/312 Hazard Categories CWA (Clean Water Act) Clean Air Act See section 2 for more information OSHA Occupational Safety and Health Administration CERCLA California Proposition 65 U.S. State Right-to-Know Regulations This product does not contain any Proposition 65 chemicals U.S. Department of Transportation Reportable Quantity (RQ): DOT Marine Pollutant DOT Severe Marine Pollutant N N N Page 6 / 7

7 U.S. Department of Homeland Security This product does not contain any DHS chemicals. Other International Regulations Mexico - Grade Prepared By Revision Date Print Date Revision Summary 16. Other information Regulatory Affairs Thermo Fisher Scientific EMSDS.RA@thermofisher.com 19-Jan Jan-2018 This document has been updated to comply with the US OSHA HazCom 2012 Standard replacing the current legislation under 29 CFR to align with the Globally Harmonized System of Classification and Labeling of Chemicals (GHS). Disclaimer The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text End of SDS Page 7 / 7