SAFETY DATA SHEET. Creation Date 10-Feb-2011 Revision Date 19-Jan-2018 Revision Number Identification

Transcription

1 SAFETY DATA SHEET Creation Date 10-Feb-2011 Revision Number 4 Product Name Cat No. : 1. Identification Tartrazine AC ; AC ; AC CAS-No Synonyms Acid Yellow 23; C.I Recommended Use Uses advised against Laboratory chemicals. Not for food, drug, pesticide or biocidal product use Details of the supplier of the safety data sheet Company Fisher Scientific One Reagent Lane Fair Lawn, NJ Tel: (201) Acros Organics One Reagent Lane Fair Lawn, NJ Emergency Telephone Number For information US call: ACROS-01 / Europe call: Emergency Number US: / Europe: CHEMTREC Tel. No.US: / Europe: Hazard(s) identification Classification This chemical is considered hazardous by the 2012 OSHA Hazard Communication Standard (29 CFR ) Respiratory Sensitization Category 1 Skin Sensitization Category 1 Label Elements Signal Word Danger Hazard Statements May cause an allergic skin reaction May cause allergy or asthma symptoms or breathing difficulties if inhaled Page 1 / 6

2 Precautionary Statements Prevention Avoid breathing dust/fume/gas/mist/vapors/spray In case of inadequate ventilation wear respiratory protection Contaminated work clothing should not be allowed out of the workplace Wear protective gloves Inhalation IF INHALED: If breathing is difficult, remove to fresh air and keep at rest in a position comfortable for breathing If experiencing respiratory symptoms: Call a POISON CENTER or doctor/physician Skin IF ON SKIN: Wash with plenty of soap and water If skin irritation or rash occurs: Get medical advice/attention Wash contaminated clothing before reuse Disposal Dispose of contents/container to an approved waste disposal plant Hazards not otherwise classified (HNOC) None identified 3. Composition/Information on Ingredients Component CAS-No Weight % FD&C yellow No > First-aid measures General Advice Eye Contact Skin Contact Inhalation Ingestion Most important symptoms and effects Notes to Physician Suitable Extinguishing Media Unsuitable Extinguishing Media Flash Point Method - Autoignition Temperature Explosion Limits Upper Lower If symptoms persist, call a physician. Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Get medical attention. Wash off immediately with plenty of water for at least 15 minutes. If skin irritation persists, call a physician. Move to fresh air. If not breathing, give artificial respiration. Get medical attention if symptoms occur. Clean mouth with water and drink afterwards plenty of water. Get medical attention if symptoms occur. None reasonably foreseeable.. May cause allergy or asthma symptoms or breathing difficulties if inhaled. May cause allergic skin reaction. Symptoms of allergic reaction may include rash, itching, swelling, trouble breathing, tingling of the hands and feet, dizziness, lightheadedness, chest pain, muscle pain or flushing Treat symptomatically 5. Fire-fighting measures Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide. Page 2 / 6

3 Sensitivity to Mechanical Impact Sensitivity to Static Discharge Specific Hazards Arising from the Chemical Keep product and empty container away from heat and sources of ignition. Hazardous Combustion Products Nitrogen oxides (NOx) Carbon monoxide (CO) Carbon dioxide (CO2) Sulfur oxides Protective Equipment and Precautions for Firefighters As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear. NFPA Health 2 Flammability 1 Instability 1 Physical hazards N/A Personal Precautions Environmental Precautions 6. Accidental release measures Ensure adequate ventilation. Use personal protective equipment. Avoid dust formation. Should not be released into the environment. Methods for Containment and Clean Sweep up or vacuum up spillage and collect in suitable container for disposal. Keep in Up suitable, closed containers for disposal. Handling Storage Exposure Guidelines 7. Handling and storage Wear personal protective equipment. Ensure adequate ventilation. Do not get in eyes, on skin, or on clothing. Avoid ingestion and inhalation. Avoid dust formation. Keep in a dry, cool and well-ventilated place. Keep container tightly closed. Keep away from water. 8. Exposure controls / personal protection This product does not contain any hazardous materials with occupational exposure limitsestablished by the region specific regulatory bodies. Engineering Measures Ensure adequate ventilation, especially in confined areas. Ventilation systems. Personal Protective Equipment Eye/face Protection Skin and body protection Respiratory Protection Hygiene Measures Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR or European Standard EN166. Long sleeved clothing. Wear a NIOSH/MSHA or European Standard EN 149 approved full-facepiece airline respirator in the positive pressure mode with emergency escape provisions. Handle in accordance with good industrial hygiene and safety practice. 9. Physical and chemical properties Physical State Powder Solid Appearance Orange Odor Odor Threshold ph g/l aq.sol Page 3 / 6

4 Melting Point/Range > 300 C / 572 F Boiling Point/Range Flash Point Evaporation Rate Flammability (solid,gas) Flammability or explosive limits Upper Lower Vapor Pressure Vapor Density Specific Gravity Solubility Soluble in water Partition coefficient; n-octanol/water Autoignition Temperature Decomposition Temperature > 300 C Viscosity Molecular Formula C16 H9 N4 Na3 O9 S2 Molecular Weight Stability and reactivity Reactive Hazard Stability Conditions to Avoid Incompatible Materials None known, based on information available Hygroscopic. Incompatible products. Exposure to moisture. Strong oxidizing agents Hazardous Decomposition Products Nitrogen oxides (NOx), Carbon monoxide (CO), Carbon dioxide (CO2), Sulfur oxides Hazardous Polymerization Hazardous Reactions Acute Toxicity. None under normal processing. 11. Toxicological information Product Information Oral LD50 Based on ATE data, the classification criteria are not met. ATE > 2000 mg/kg. Component Information Component LD50 Oral LD50 Dermal LC50 Inhalation FD&C yellow No mg/kg (Mouse) Not listed Not listed Toxicologically Synergistic Products Delayed and immediate effects as well as chronic effects from short and long-term exposure Irritation Sensitization Carcinogenicity May cause an allergic skin reaction May cause sensitization by inhalation The table below indicates whether each agency has listed any ingredient as a carcinogen. Component CAS-No IARC NTP ACGIH OSHA Mexico FD&C yellow No Not listed Not listed Not listed Not listed Not listed Mutagenic Effects Reproductive Effects Developmental Effects.. Page 4 / 6

5 Teratogenicity STOT - single exposure STOT - repeated exposure Aspiration hazard. None known None known Symptoms / effects,both acute and delayed Symptoms of allergic reaction may include rash, itching, swelling, trouble breathing, tingling of the hands and feet, dizziness, lightheadedness, chest pain, muscle pain or flushing Endocrine Disruptor Information Other Adverse Effects Ecotoxicity. The toxicological properties have not been fully investigated. 12. Ecological information Component Freshwater Algae Freshwater Fish Microtox Water Flea FD&C yellow No. 5 Not listed LC50: > 1000 ppm/48 h (Oryzias latipes) Not listed Not listed Persistence and Degradability Soluble in water Persistence is unlikely based on information available. Bioaccumulation/ Accumulation Mobility Waste Disposal Methods DOT TDG IATA IMDG/IMO. Will likely be mobile in the environment due to its water solubility. 13. Disposal considerations Chemical waste generators must determine whether a discarded chemical is classified as a hazardous waste. Chemical waste generators must also consult local, regional, and national hazardous waste regulations to ensure complete and accurate classification. 14. Transport information 15. Regulatory information All of the components in the product are on the following Inventory lists: X = listed International Inventories Component TSCA DSL NDSL EINECS ELINCS NLP PICCS ENCS AICS IECSC KECL FD&C yellow No. 5 X X X X X X X Legend: X - Listed E - Indicates a substance that is the subject of a Section 5(e) Consent order under TSCA. F - Indicates a substance that is the subject of a Section 5(f) Rule under TSCA. N - Indicates a polymeric substance containing no free-radical initiator in its inventory name but is considered to cover the designated polymer made with any free-radical initiator regardless of the amount used. P - Indicates a commenced PMN substance R - Indicates a substance that is the subject of a Section 6 risk management rule under TSCA. S - Indicates a substance that is identified in a proposed or final Significant New Use Rule T - Indicates a substance that is the subject of a Section 4 test rule under TSCA. XU - Indicates a substance exempt from reporting under the Inventory Update Rule, i.e. Partial Updating of the TSCA Inventory Data Base Production and Site Reports (40 CFR 710(B). Y1 - Indicates an exempt polymer that has a number-average molecular weight of 1,000 or greater. Page 5 / 6

6 Y2 - Indicates an exempt polymer that is a polyester and is made only from reactants included in a specified list of low concern reactants that comprises one of the eligibility criteria for the exemption rule. U.S. Federal Regulations TSCA 12(b) SARA 313 SARA 311/312 Hazard Categories CWA (Clean Water Act) Clean Air Act See section 2 for more information OSHA Occupational Safety and Health Administration CERCLA California Proposition 65 U.S. State Right-to-Know Regulations This product does not contain any Proposition 65 chemicals U.S. Department of Transportation Reportable Quantity (RQ): DOT Marine Pollutant DOT Severe Marine Pollutant N N N U.S. Department of Homeland Security This product does not contain any DHS chemicals. Other International Regulations Mexico - Grade Prepared By 16. Other information Regulatory Affairs Thermo Fisher Scientific EMSDS.RA@thermofisher.com Creation Date 10-Feb-2011 Revision Date 19-Jan-2018 Print Date 19-Jan-2018 Revision Summary SDS sections updated Disclaimer The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text End of SDS Page 6 / 6