KP010 KP011 KP012 DELETION PEN SUBID: Version 2 Print Date

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1 SECTION 1. PRODUCT AND COMPANY IDENTIFICATION Identification of the substance/preparation Product name : MSDS Number : Use of the : Correction pen Substance/Preparation Product code : KE63V, KE914, KE926, OAXFK, OAXEH Business group : GS Company/Undertaking Identification Agfa Corporation 611 River Drive Center 3 Elmwood Park, NJ U.S.A. Transport Emergency Non-transportation Call CHEMTREC : Health Emergency Phone : International : Agfa Information Phone : SECTION 2. COMPOSITION/INFORMATION ON INGREDIENTS This correction pen mainly consists of a plastic housing enclosing a porous wick, which retains a very small quantity of corrector liquid. When not in use, the pen is closed with a protective cap. Labelling and hazard information in this Safety Data Sheet refers to the pure corrector liquid as retained in the wick. CAS-No. Concentration [%] gamma-butyrolactone >= <= 80.0 Phosphoric acid >= <= 5.0 Polycarboxylic acids >= <= 5.0 Water >= <= 30.0 SECTION 3. HAZARDS IDENTIFICATION The product as a whole has not been tested. This hazard information is for the individual ingredients. Emergency Overview Form : Liquid. Colour : Colourless. Odour : Pungent smell WARNING! REG_NOAM 1/11 EN

2 In normal conditions of storage, transport and use, the pencil will not cause any special health or safety hazard. Use cold water spray to cool fire-exposed containers to minimize the risk of rupture. May cause respiratory tract irritation. Causes skin irritation. Causes eye irritation. Maybe Harmful if swallowed. Potential Health Effects Aggravated Medical Condition : Persons with preexisting eye, skin or respiratory tract disorders may be more susceptible to the effects of this product. Acute health effects Inhalation gamma-butyrolactone : May cause respiratory tract irritation with symptoms of coughing, sore throat and runny nose. May cause central nervous system depression with symptoms of headache, nausea, dullness and dizziness. Phosphoric acid : Is expected to be irritating to the respiratory tract with symptoms of coughing, sore throat, and runny nose. Polycarboxylic acids : May cause respiratory tract irritation with symptoms of coughing, sore throat and runny nose. Skin contact gamma-butyrolactone : May be irritating to the skin with symptoms of reddening and itching. Repeated or prolonged skin contact with the solvent can result in dry, defatted and cracked skin causing increased susceptibility to infection. In addition, dermatitis and skin rash and redness may occur from skin contact. Phosphoric acid : Corrosive with symptoms of reddening, itching, swelling, burning and possible permanent damage. Polycarboxylic acids : May cause irritation resulting in reddening, drying and itching. Repeated or prolonged skin contact with the solvent can result in dry, defatted and cracked skin causing increased susceptibility to infection. In addition, dermatitis and skin rash and redness may occur from skin contact. Eye contact gamma-butyrolactone : May be irritating to the eyes with symptoms of reddening, tearing and stinging. Phosphoric acid : Can be severely irritating and corrosive to the eyes resulting in burning, reddening, swelling of the eye and surrounding tissue and possibly permanent injury to the cornea. Polycarboxylic acids : May be irritating to the eyes with symptoms of reddening, tearing and stinging. Ingestion gamma-butyrolactone : May cause gastrointestinal irritation. May cause nervous system effects which can include symptoms of dizziness, incoordination, headache, numbness, and/or confusion. Moderately toxic by ingestion. REG_NOAM 2/11 EN

3 Phosphoric acid : Swallowing high concentrations may cause severe injury. Chronic health hazards Ingestion gamma-butyrolactone : May cause nervous system damage with symptoms of numbness, incoordination, headache, and confusion. Carcinogenicity The components of this product are not listed by NTP, IARC or regulated as a carcinogen by OSHA. SECTION 4. FIRST AID MEASURES Eye contact : Rinse thoroughly with plenty of water for at least 15 minutes and consult a physician. Skin contact : Wash immediately with plenty of water and soap. Apply calcium gluconate gel on and around the affected area and continuous massage it into the skin until at least 15 minutes after pain is relieved. Cover the area with a dressing soaked in the gel and lightly bandage. Seek medical attention. Ingestion : Rinse mouth with plenty of water. Seek medical advice. Inhalation : Take person to fresh air. If necessary, seek medical advice. SECTION 5. FIRE-FIGHTING MEASURES Suitable extinguishing media : e.g. water, CO2, foam, powder, sand. Specific hazards during fire fighting : Combustion of one pencil will not cause a major problem to health, safety and to the environment. When burning large amounts of pencils, hazardous fumes can be set free. Their composition is depending on the conditions of the combustion process and will not substantially differ from that resulting from merely burning plastic Special protective equipment for fire-fighters housings and caps of such pencils. : Firefighters should be equipped with self-contained breathing apparatus to protect against potentially toxic and irritating fumes. SECTION 6. ACCIDENTAL RELEASE MEASURES Personal precautions : See section : Exposure controls / personel protection. Additional advice : Wash away residues with plenty of water. SECTION 7. HANDLING AND STORAGE Handling REG_NOAM 3/11 EN

4 Advice on protection against : Keep away from heat and sources of ignition. fire and explosion Advice on safe handling : In normal conditions of storage, transport and use, the liquid will not leak from the pencil. SECTION 8. EXPOSURE CONTROLS / PERSONAL PROTECTION Exposure Limit Values (US) Components CAS-No. Values Type Revision Basis Date Phosphoric acid mg/m3 TWA 2002 ACGIH 3 mg/m3 STEL 2002 ACGIH 1 mg/m3 PEL OSHA Z1 1 mg/m3 TWA 1989 OSHA Z1A 3 mg/m3 STEL 1989 OSHA Z1A Tetrafluoroboric acid mg/m3 TWA ACGIH 6 mg/m3 STEL ACGIH 2.5 mg/m3 TWA 2008 ACGIH 2.5 mg/m3 TWA OSHA Z2 2.5 mg/m3 PEL OSHA Z1 2.5 mg/m3 TWA 1989 OSHA Z1A 2.5 mg/m3 REL 2005 NIOSH Exposure Limit Values (CA) Components CAS-No. Values Type Revision Basis Date Phosphoric acid mg/m3 TWA OEL (QUE) 3 mg/m3 STEL OEL (QUE) 1 mg/m3 8 HR ACL CAD SK OEL 3 mg/m3 15 MIN CAD SK OEL ACL 1 mg/m3 TWA CAD MB OEL 3 mg/m3 STEL CAD MB OEL Tetrafluoroboric acid mg/m3 TWA OEL (QUE) 2.5 mg/m3 TWA CAD AB OEL 2.5 mg/m3 TWA CAD BC OEL 2.5 mg/m3 TWAEV CAD ON OEL 2.5 mg/m3 TWA CAD AB OEL 2 mg/m3 TWA CAD MB OEL 6 mg/m3 STEL CAD MB OEL 2.5 mg/m3 8 HR ACL CAD SK OEL 5 mg/m3 15 MIN CAD SK OEL ACL 2.5 mg/m3 TWA CAD MB OEL Exposure controls REG_NOAM 4/11 EN

5 Hygiene measures : Observe normal precautions when handling chemicals. Avoid inhaling vapour. Don't wear the correction pen on your body. Avoid that the tip of the wick comes into contact with the eyes and the skin. Always apply the protective cap to the pen, when the latter is not in use. Unproper handling, such as licking the wick, inhaling the corrector liquid or breaking and opening the pen, so as to set free the wick, is to be avoided. Keep away from foodstuffs, drinks and tobacco. Employees should wash their hands and face before eating, drinking, or using tobacco products. Educate and train employees in the safe use and handling of this product. Emergency showers and eye wash stations should be available. Respiratory protection : Under normal conditions of use, respirator protection is not required. If respirators are used, institute a program in accordance with OSHA standard 29CFR or Canada CSA Standard Z Hand protection : Use chemical resistant gloves. In case of prolonged immersion or frequently repeated contact use gloves made of the materials: butyl rubber (thickness >= 0.36 mm, breakthrough time > 480 min), nitrile rubber (thickness >= 0.38 mm, breakthrough time > 480 min) or neoprene (thickness >= 0.65 mm, breakthrough time > 240 min). For intermittent splash protection corresponding gloves with breakthrough times > 60 min can be used. Avoid gloves made of: natural latex. Eye protection : Safety glasses. SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES Form : Liquid. Colour : Colourless. Odour : Pungent smell ph : Not applicable Melting point/range : < 0 C (< 32 F) Boiling point/range : > 100 C (> 212 F) Relative vapour density : Not applicable VOC content : 63 % VOC content excluding water SECTION 10. STABILITY AND REACTIVITY Stability : The product is stable under normal conditions of storage and use. SECTION 11. TOXICOLOGICAL INFORMATION Toxicity data specific for individual ingredients in their pure state: REG_NOAM 5/11 EN

6 Acute oral toxicity gamma-butyrolactone : LD50 rat 1,540 mg/kg Phosphoric acid : LD50 rat 1,530 mg/kg Polycarboxylic acids : LD50 rat > 2,000 mg/kg Acute inhalation toxicity gamma-butyrolactone : LC50 rat > 5.1 mg/l/ 4 h Phosphoric acid : LC50 rat > 0.2 mg/l/ 4 h Acute dermal toxicity gamma-butyrolactone : LD50 guinea pig > 5,000 mg/kg Phosphoric acid : LD50 rabbit 2,740 mg/kg Acute toxicity (other route) gamma-butyrolactone : No data available Skin irritation gamma-butyrolactone : No skin irritation No skin irritation Literature. Phosphoric acid : rat Corrosive Causes burns. Literature. Exposure quickly causes a strong corrosive action upon all body tissue. Acute dermal irritation/corrosion Eye irritation gamma-butyrolactone : Severe eye irritation. Severe eye irritation. OECD Test Guideline 405 Phosphoric acid : Irritating to eyes. Eye irritation Severe eye irritation. Sensitization gamma-butyrolactone : Did not cause sensitization on laboratory animals. Did not cause sensitization on laboratory animals. Literature. Phosphoric acid : No data available Repeated dose toxicity REG_NOAM 6/11 EN

7 gamma-butyrolactone : No data available Phosphoric acid : Skin contact can cause skin damage with formation of excema.the fluid can cause a dry or cracking skin. Carcinogenicity gamma-butyrolactone : Literature. No carcinogenic effects observed at the doses tested. Phosphoric acid : There was no evidence of cancer in male mice following chronic oral administration. No tumors were reported in mice following longterm dermal application. Toxicity to reproduction gamma-butyrolactone : Has not caused reproductive effects in male or female animals when administered orally at dose levels not causing systemic toxicity Phosphoric acid : Has not caused reproductive effects in male or female animals when administered orally at dose levels not causing systemic toxicity Mutagenicity gamma-butyrolactone : There is no evidence for mutagenicity from studies in animals. Phosphoric acid : There is no evidence for mutagenicity from studies in animals. Teratogenicity gamma-butyrolactone : No data available Phosphoric acid : Has not caused birth defects when administered orally at dose levels not causing systemic toxicity in the mother. Other information Hazard labelling of the corrector liquid: see section 15. SECTION 12. ECOLOGICAL INFORMATION Elimination information (persistence and degradability) Biodegradation gamma-butyrolactone : OECD 302B Biodegradability > 90 % after 28 d According to the results of tests of biodegradability this product is considered as being readily biodegradable. Phosphoric acid No data available Physico-chemical removability REG_NOAM 7/11 EN

8 gamma-butyrolactone : The product can be degraded by abiotic (e.g. chemical or photolytic) processes. Neutralization is normally necessary before waste water is discharged into water treatment plants. Phosphoric acid No data available Bioaccumulation gamma-butyrolactone : Accumulation in aquatic organisms is unlikely. Phosphoric acid No data available Ecotoxicity effects Ecotoxicity data specific for individual ingredients in their pure state: Toxicity to fish gamma-butyrolactone : Species: Leuciscus idus (golden orfe) LC50: > 220 mg/l/ 96 h Phosphoric acid : No data available Polycarboxylic acids : Species: Brachidanio rerio (zebra fish) LC50: > 100 mg/l/ 96 h Toxicity to daphnia gamma-butyrolactone : Species: Daphnia magna EC50: > 500 mg/l/ 48 h Phosphoric acid : Species: Daphnia magna (water flea) EC50: > 100 mg/l/ 96 h Polycarboxylic acids : Species: Daphnia magna (water flea) EC50: > 1,000 mg/l/ 48 h Toxicity to algae gamma-butyrolactone : Species: Scenedesmus subspicatus (algae) EC50: 360 mg/l/ 72 h Phosphoric acid : No data available Toxicity to bacteria gamma-butyrolactone : Species: Pseudomonas putida (bacteria) EC50: > 10,000 mg/l/ 17 h Phosphoric acid : Species: Pseudomonas putida (bacteria) EC50: 270 mg/l/ 16 h SECTION 13. DISPOSAL CONSIDERATIONS Waste disposal methods REG_NOAM 8/11 EN

9 Used correction pencils are considered industrial waste. Refer to local provisions and regulations on disposal of such waste. US. RCRA Hazardous Waste Classification (40 CFR 261) If discarded in its purchased form, this product would not be a hazardous waste either by listing or by characteristic. However, under RCRA, it is the responsibility of the product user to determine at the time of disposal, whether a material containing the product or derived from the product should be classified as a hazardous waste. SECTION 14. TRANSPORT INFORMATION Not classified as dangerous in the meaning of transport regulations. SECTION 15. REGULATORY INFORMATION US. Toxic Substances Control Act (TSCA) All of the components of this product are listed on the TSCA Inventory. US. OSHA Classification This product is hazardous under the criteria of the Federal OSHA Hazard Communication Standard 29 CFR US. SARA 311/312 Hazard Categories Acute Health Hazard. US. EPA CERCLA Hazardous Substances (40 CFR 302) Phosphoric acid : Reportable quantity: 5,000 lbs US. California Prop. 65 This product does not contain any chemicals known to State of California to cause cancer, birth defects or any other harm. State Right-to-Know Information The following chemicals are specifically listed by individual states. Other product specific health and safety data in other sections of the MSDS may also be applicable for state requirements. For details on your regulatory requirements you should contact the appropriate agency in your state. US. Massachusetts Commonwealth's Right-to-Know Law (Appendix A to 105 Code of Massachusetts Regulations Section ) CAS-No. Concentration [%] Phosphoric acid >= <= 5.0 US. New Jersey Worker and Community Right-to-Know Act (New Jersey Statute Annotated Section 34:5A-5) REG_NOAM 9/11 EN

10 CAS-No. Concentration [%] Phosphoric acid >= <= 5.0 US. Pennsylvania Worker and Community Right-to-Know Law (34 Pa. Code Chap ) CAS-No. Concentration [%] Phosphoric acid >= <= 5.0 US. Rhode Island Hazardous Substances Right-to-Know Act (R.I. Gen. Laws Section et. seq.) CAS-No. Concentration [%] Phosphoric acid >= <= 5.0 US. Massachusetts, New Jersey, Pennsylvania or Rhode Island Right to Know Substance Lists : See Section 2. Canadian WHMIS Classification Not regulated. Canadian Environmental Protection Act (CEPA) All components of this product are on the Canadian DSL list. SECTION 16. OTHER INFORMATION US. HMIS Rating Health : 2 Flammability : 1 Reactivity : 0 (0 = Minimal, 1 = Slight, 2 = Moderate, 3 = Serious, 4 = Severe) US. NFPA 704M Rating Health : 2 Flammability : 1 Reactivity : 0 (0 = Insignificant, 1 = Slight, 2 = Moderate, 3 = High, 4 = Extreme) Agfa Corporation's method of hazard communication is comprised of Product Labels and Material Safety Data Sheets. HMIS and NFPA ratings are provided by Agfa Corporation as a customer service. This MSDS is replacing Agfa MSDS number 823G.004 Section(s) changed compared to the previous issue: 1, 8, 16 REG_NOAM 10/11 EN

11 This product is not manufactured by Agfa. The information disclosed in this Safety Data Sheet has been provided by the manufacturer. This information is furnished without warranty, expressed or implied, and is believed to be accurate to the best knowledge of Agfa Corporation. The data on this MSDS relates only to the specific material designated herein. Agfa Corporation assumes no legal responsibility for use or reliance upon these data. REG_NOAM 11/11 EN

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