Section 2. Composition / information on ingredients % % Section 3. Hazards identification

Transcription

1 Safety Data Sheet NORDBAK Backing Mat. 20KG M/L Page 1 of 8 MSDS-No. : Revision: printing date: Section 1. Identification of the substance/preparation and of the company/undertaking Product name: NORDBAK Backing Mat. 20KG M/L Identification of manufacturer, importer or distributor Importer: Henkel Singapore Pte Ltd 401 Commonwealth Drive, #03-01/02, Haw Par Technocentre, Singapore Phone : Fax : address of person responsible for Safety Data Sheet: ap-ua-psra.sea@henkel.com Section 2. Composition / information on ingredients Declaration of ingredients: Limestone Reaction product: bisphenol-a- (epichlorhydrin); epoxy resin (number average molecular weight <= 700) Quartz (SiO2) EINECS content Classification % % R43 Xi - Irritant; R36/38 N - Dangerous for the environment; R51/ % % Toxic for reproduction - category 3.; R62, R63 Xn - Harmful; R22 C - Corrosive; R34 N - Dangerous for the environment; R50/ % Mutagen category 3.; R68 R10 Xi - Irritant; R37 R43 carcinogenic, category 3; R40 Xn - Harmful; R20/22 R52/ ,1-1 % Section 3. Hazards identification Hazard classification: Xn - Harmful N - Dangerous for the environment

2 Page 2 of 8 Risk phrases: Skin: Eye: Inhalation: Ingestion: Aggrevated med. condition: R36/38 Irritating to e and skin. R40 Limited evidence of a carcinogenic effect. R68 Possible risk of irreversible effects. R43 May cause sensitisation by skin contact. R51/53 Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.. Allergic skin reaction. Moderate skin irritation. Itching. Redness. Moderate eye irritation. Redness. Mild respiratory tract irritation. May cause irritation to nose and throat. May be harmful if swallowed. Eye, skin and respiratory disorders. Skin allergies. Section 4. First aid measures Inhalation: Skin contact: Eye contact: Ingestion: Move to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical attention. Immediately flush skin with plenty of water (using soap, if available). Remove contaminated clothing and footwear. If symptoms develop and persist, get medical attention. Immediately flush e with plenty of water for at least 15 minutes. DO NOT induce vomiting unless directed to do so by medical personnel. Keep individual calm. If symptoms develop and persist, get medical attention. Section 5. Fire fighting measures Suitable extinguishing media: Special protection equipment for firefighters: Particular danger/case of fire: Hazardous combustion products: Water spray (fog), foam, dry chemical or carbon dioxide. Wear self-contained breathing apparatus and full protective clothing, such as turn-out gear. In case of fire, keep containers cool with water spray. Closed containers may rupture (due to build up of pressure) when exposed to extreme heat. Oxides of carbon. Acids. Aldehydes. Phenolics. Irritating organic fragments. Section 6. Accidental release measures Environmental precautions: Do not allow product to enter sewer or waterways.

3 Page 3 of 8 Clean-up methods: Remove all sources of ignition. Immediately contact emergency personnel. Scrape up as much material as possible. Clean residue with soap and water. Store in a closed container until ready for disposal. Section 7. Handling and storage Handling: Storage: Keep away from heat, spark and flame. Prevent contact with e, skin and clothing. Do not breathe vapor and mist. Wash thoroughly after handling. Keep container closed. Store in original container until ready to use. Store in tightly closed containers. In a cool/well-ventilated area. Keep away from heat and direct sunlight. Section 8. controls / personal protection Ingredient Type ppm mg/m 3 Remarks CALCIUM CARBONATE (LIMESTONE, SG PEL Listed. MARBLE) Limestone 10 CALCIUM CARBONATE (LIMESTONE, 10 SG PEL MARBLE) 10 CALCIUM CARBONATE (LIMESTONE, MARBLE) N-BUTYL GLYCIDYL ETHER (BGE) N-BUTYL GLYCIDYL ETHER (BGE) N-BUTYL GLYCIDYL ETHER (BGE) N-BUTYL GLYCIDYL ETHER (BGE) SILICA, CRYSTALLINE - #-QUARTZ, RESPIRABLE FRACTION SILICA-CRYSTALLINE: QUARTZ, RESPIRABLE DUST 10 SG PEL 3 ACGIH SG PEL Skin designation: ACGIH Can be absorbed through the skin. Short Term 0,1 SG PEL Limit (STEL): 0,025 ACGIH 0,1 SG PEL Respiratory protection: Eye protection: Body protection: Engineering controls: Hygienic measures: Use NIOSH approved respirator if there is potential to exceed exposure limit(s). Safety goggles or safety glasses with side shields. Chemical resistant, impermeable gloves. Use local exhaust ventilation if the potential for airborne exposure exists. Wash hands before work breaks and after finishing work. Good industrial hygiene practices should be observed. Section 9. Physical and chemical properties Appearance: Odor: Vapor density: Gray, White paste Mild Heavier than air.

4 Page 4 of 8 Specific gravity: 1,663 Boiling point: > 149 C (> F) Flash point: > 93 C (> F) (Pensky Martens closed cup) Vapor pressure: < 1 mm hg (; 20 C (68 F)) Solubility: Solvent: Water, Insoluble VOC content < 1,0 % (value for resin and hardener together) (estimated) Section 10. Stability and reactivity Conditions to avoid: Materials to avoid: Stable Excessive heat. Store away from incompatible materials. Strong acids. Strong oxidizing agents. Strong Lewis acids. Strong mineral acids. Bases. Amines. Mercaptans. Hazardous decomposition products: Hazardous polymerization: No decomposition if used according to specifications. Will not occur. Section 11. Toxicological information toxicity: Value type LD50 LC0 LD50 LD50 Value Route of application 0,0812 mg/l oral inhalation mg/kg oral > mg/kg dermal 90 min Species rat rat rat rabbit OECD Guideline 420 ( Oral Toxicity OECD Guideline 401 ( Oral Toxicity) Skin corrosion/irritation: Bisphenol-A epichlorhydrin resin MW <= 700 Result Species slightly irritating 4 h rabbit OECD Guideline 404 ( Dermal Irritation / Corrosion) corrosive rabbit OECD Guideline 404 ( Dermal Irritation / Corrosion) Serious eye damage/irritation: Bisphenol-A epichlorhydrin resin MW <= 700 Result Species not irritating rabbit OECD Guideline 405 ( Eye Irritation / Corrosion) irritating rabbit OECD Guideline 405 ( Eye Irritation / Corrosion)

5 Page 5 of 8 Respiratory or skin sensitization: Bisphenol-A epichlorhydrin resin MW <= 700 sensitising not sensitising not sensitising Result Test type Species Mouse local lymphnod e assay (LLNA) Guinea pig maximisat ion test Buehler test mouse guinea pig guinea pig OECD Guideline 429 (Skin Sensitisation: Local Lymph Node Assay) OECD Guideline 406 (Skin Sensitisation) OECD Guideline 406 (Skin Sensitisation) Germ cell mutagenicity: Bisphenol-A epichlorhydrin resin MW <= 700 Result Type of study / Route of administration negative bacterial reverse mutation assay (e.g Ames test) negative bacterial reverse mutation assay (e.g Ames test) Metabolic activation / with and without with and without Species OECD Guideline 472 (Genetic Toxicology: Escherichia coli, Reverse Mutation Assay) Repeated dose toxicity Result NOAEL=100 mg/kg Route of application / Frequency of treatment Species oral: feed 28 days daily rat OECD Guideline 407 (Repeated Dose 28-Day Oral Toxicity in Rodents) Section 12. Ecological information

6 Page 6 of 8 Toxicity: Bisphenol-A epichlorhydrin resin MW <= 700 Quartz (SiO2) Quartz (SiO2) Quartz (SiO2) Value type Value Toxicity Study Species LC50 > mg/l Fish 96 h OECD Guideline EC50 > mg/l Daphnia 48 h Daphnia magna OECD Guideline 202 (Daphnia sp. Immobilisation EC50 > 200 mg/l Algae 72 h OECD Guideline LC50 1, mg/l Fish 96 h Oncorhynchus mykiss OECD Guideline LC50 > mg/l Fish 96 h Gambusia affinis OECD Guideline EC mg/l Daphnia 48 h Daphnia magna OECD Guideline 202 (Daphnia sp. Immobilisation EC mg/l Algae 5 d Nitzschia sp. OECD Guideline LC50 0,23 mg/l Fish 96 h OECD Guideline EC50 0,14 mg/l Daphnia 48 h Daphnia magna OECD Guideline 202 (Daphnia sp. Immobilisation EC50 1,3 mg/l Algae 72 h Scenedesmus subspicatus (new name: Desmodesmus subspicatus) LC50 65 mg/l Fish 96 h Salmo gairdneri (new name: Oncorhynchus mykiss) EC50 35 mg/l Algae 96 h Selenastrum capricornutum (new name: Pseudokirchnerella subcapitata) OECD Guideline OECD Guideline OECD Guideline LC50 > mg/l Fish OECD Guideline EC50 > mg/l Daphnia Daphnia magna OECD Guideline 202 (Daphnia sp. Immobilisation EC50 > mg/l Algae OECD Guideline Persistence and degradability: Result Route of application Degradability

7 Page 7 of 8 aerobic 0 % 25 % OECD Guideline 301 D (Ready Biodegradability: Closed Bottle Bioaccumulative potential / Mobility in soil: LogKow Bioconcentration factor (BCF) -2,12 0,63 Species Temperature Section 13. Disposal considerations Product of disposal: Packaging Disposal for uncleaned package: Dispose of in accordance with local and national regulations. Packaging that cannot be cleaned are to be disposed of in the same manner as the product. Section 14. Transport information Road transport ADR: Classification code: M6 Hazard ident. number: 90 Technical name: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (Bisphenol-A Epichlorhydrin resin) Railroad transport RID: Classification code: M6 Hazard ident. number: 90 Technical name: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (Bisphenol-A Epichlorhydrin resin) Inland water transport ADN: Classification code: M6 Hazard ident. number: Technical name: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (Bisphenol-A Epichlorhydrin resin) Marine transport IMDG:

8 Page 8 of 8 EmS: Seawater pollutant: Proper shipping name: F-A,S-F Marine pollutant ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (Bisphenol-A Epichlorhydrin resin) Air transport IATA: Packaging instructions (passenger) 964 Packaging instructions (cargo) 964 Proper shipping name: Environmentally hazardous substance, liquid, n.o.s. (Bisphenol-A Epichlorhydrin resin) Section 15. Regulations - classification and identification Indication of danger: Risk phrases: Safety phrases: Xn - Harmful, N - Dangerous for the environment R36/38 Irritating to e and skin. R40 Limited evidence of a carcinogenic effect. R68 Possible risk of irreversible effects. R43 May cause sensitisation by skin contact. R51/53 Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. S26 In case of contact with e, rinse immediately with plenty of water and seek medical advice. S36/37 Wear suitable protective clothing and gloves. S57 Use appropriate container to avoid environmental contamination. S60 This material and its container must be disposed of as hazardous waste. Global inventory status: Regulatory list EINECS TSCA AICS DSL NDSL KECI (KR) PICCS (PH) INV (CN) NZIOC Notification Section 16. Other information Issue date: Disclaimer This information is based on our current level of knowledge and relates to the product in the state in which it is delivered. It is intended to describe our products from the point of view of safety requirements and is not intended to guarantee any particular properties. This safety data sheet was prepared in accordance with Council Directive 67/548/EEC and it's subsequent amendments, and Commission Directive 1999/45/EC.