Safety Data Sheet according to Regulation (EC) No 1907/2006

Transcription

1 Safety Data Sheet according to Regulation (EC) No 1907/2006 LOCTITE ABLESTIK 8008HT known as ABLECOAT 8008HT, Page 1 of 14 sds no. : Revision: printing date: SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier LOCTITE ABLESTIK 8008HT known as ABLECOAT 8008HT, 1.2. Relevant identified uses of the substance or mixture and uses advised against Intended use: Epoxy adhesive 1.3. Details of the supplier of the safety data sheet Henkel Limited 2 Bishop Square Business Park AL109EY Herfordshire Hatfield Great Britain Phone: Fax-no.: ua-productsafety.uk@uk.henkel.com 1.4. Emergency telephone number 24 Hours Emergency Tel: +44 (0) Classification of the substance or mixture SECTION 2: Hazards identification Classification (DPD): Sensitizing R43 May cause sensitisation by skin contact. Xi - Irritant R36 Irritating to eyes. N - Dangerous for the environment R51/53 Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment Label elements

2 LOCTITE ABLESTIK 8008HT known as ABLECOAT 8008HT, Page 2 of 14 Label elements (DPD): Xi - Irritant N - Dangerous for the environment Risk phrases: R36 Irritating to eyes. R43 May cause sensitisation by skin contact. R51/53 Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. Safety phrases: S24 Avoid contact with skin. S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S37 Wear suitable gloves. S61 Avoid release to the environment. Refer to special instructions/safety data sheets. Additional labeling: Contains epoxy constituents. See information supplied by the manufacturer. Contains: Butadiene, acrylonitrile polymer, carboxy-terminated, polymer with bisphenol A and epichlorohydrin, 1,1'-(methylenedi-p-phenylene)bismaleimide 2.3. Other hazards None if used properly. General chemical description: Adhesive Base substances of preparation: Epoxy resin SECTION 3: Composition/information on ingredients

3 LOCTITE ABLESTIK 8008HT known as ABLECOAT 8008HT, Page 3 of 14 Declaration of the ingredients according to CLP (EC) No 1272/2008: Silver EC Number content REACH-Reg No >= 50- <= 100 % Classification >= 1- < 10 % Serious eye irritation 2 H319 Carbinol acetate Butadiene, acrylonitrile polymer, carboxyterminated, polymer with bisphenol A and epichlorohydrin ,6-Diglycidyl phenyl allyl ether oligomer Methylhydroquinone >= 1- < 10 % Serious eye irritation 2 H319 >= 1- < 5 % Skin irritation 2 H315 Serious eye irritation 2 H319 Skin sensitizer 1 H317 Chronic hazards to the aquatic environment 2 H >= 1- < 3 % Acute toxicity 3; Inhalation H331 Skin irritation 2; Dermal H315 Serious eye irritation 2 H319 Skin sensitizer 1; Dermal H317 Specific target organ toxicity - single exposure 3; Inhalation H335 Acute hazards to the aquatic environment 1 H400 Chronic hazards to the aquatic environment 1 H410 >= 0,1- < 1 % Skin sensitizer 1 H317 Germ cell mutagenicity 2 H >= 0,1- < 0,25 % Organic peroxides E H242 Acute toxicity 3; Inhalation H331 Acute toxicity 4; Dermal H312 Acute toxicity 4; Oral H302 Specific target organ toxicity - repeated exposure 2 H373 Chronic hazards to the aquatic environment 2 H411 Skin corrosion 1B H < 0,25 % Acute toxicity 4; Oral H302 Skin irritation 2; Dermal H315 Serious eye irritation 2 H319 Acute hazards to the aquatic environment 1 H400 For full text of the H - statements and other abbreviations see section 16 "Other information". Substances without classification may have community workplace exposure limits available.

4 LOCTITE ABLESTIK 8008HT known as ABLECOAT 8008HT, Page 4 of 14 Declaration of ingredients according to DPD (EC) No 1999/45: Silver Carbinol acetate Butadiene, acrylonitrile polymer, carboxy-terminated, polymer with bisphenol A and epichlorohydrin ,6-Diglycidyl phenyl allyl ether oligomer 2-Methylhydroquinone EC Number content REACH-Reg No >= 50 - <= 100 % Classification >= 1 - < 10 % Xi - Irritant; R >= 1 - < 10 % Xi - Irritant; R36 >= 1 - < 5 % Xi - Irritant; R36/38, R43 N - Dangerous for the environment; R51/ >= 1 - < 3 % T - Toxic; R23 Xi - Irritant; R36/37/38, R43 N - Dangerous for the environment; R50/ >= 0,1 - < 1 % Mutagen category 3.; Xn - Harmful; R68 Xi - Irritant; R >= 0,1 - < 0,25 % T - Toxic; R23 Xn - Harmful; R21/22, R48/20/22 O - Oxidizing; R7 C - Corrosive; R34 N - Dangerous for the environment; R51/ < 0,25 % Xn - Harmful; R22 Xi - Irritant; R36/38 N - Dangerous for the environment; R50 For full text of the R-Phrases indicated by codes see section 16 'Other Information'. Substances without classification may have community workplace exposure limits available Description of first aid measures SECTION 4: First aid measures Inhalation: Should not be a problem as product is of low volatility. However, if feeling unwell remove patient to fresh air. Skin contact: Rinse with running water and soap. Obtain medical attention if irritation persists. Eye contact: Rinse immediately with plenty of running water (for 10 minutes), seek medical attention from a specialist. Ingestion: Rinse mouth, drink 1-2 glasses of water, do not induce vomiting, consult a doctor Most important symptoms and effects, both acute and delayed SKIN: Rash, Urticaria. EYE: Irritation, conjunctivitis. Prolonged or repeated skin contact with silver and its salts may cause a blue-gray discoloration of the skin and mucous membranes that is irreversible (Argyria) Indication of any immediate medical attention and special treatment needed See section: Description of first aid measures 5.1. Extinguishing media Suitable extinguishing media: water, carbon dioxide, foam, powder SECTION 5: Firefighting measures

5 LOCTITE ABLESTIK 8008HT known as ABLECOAT 8008HT, Page 5 of 14 Extinguishing media which must not be used for safety reasons: High pressure waterjet 5.2. Special hazards arising from the substance or mixture In the event of a fire, carbon monoxide (CO), carbon dioxide (CO2) and nitrogen oxides (NOx) can be released. In case of fire, keep containers cool with water spray Advice for firefighters Wear self-contained breathing apparatus and full protective clothing, such as turn-out gear. SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures Avoid contact with skin and eyes. Wear protective equipment. Ensure adequate ventilation. Remove sources of ignition Environmental precautions Do not empty into drains / surface water / ground water Methods and material for containment and cleaning up For small spills wipe up with paper towel and place in container for disposal. For large spills absorb onto inert absorbent material and place in sealed container for disposal Reference to other sections See advice in chapter Precautions for safe handling Avoid skin and eye contact. See advice in chapter 8 Hygiene measures: Good industrial hygiene practices should be observed. Wash hands before work breaks and after finishing work. Do not eat, drink or smoke while working. SECTION 7: Handling and storage 7.2. Conditions for safe storage, including any incompatibilities Ensure good ventilation/extraction. Keep container tightly sealed. Keep frozen Specific end use(s) Epoxy adhesive SECTION 8: controls/personal protection 8.1. Control parameters Occupational Limits Valid for Great Britain Ingredient ppm mg/m 3 Type Category Remarks SILVER (METALLIC) 0,1 Time Weighted Average EH40 WEL (TWA): SILVER, METALLIC ,1 Time Weighted Average (TWA): Indicative ECTLV

6 LOCTITE ABLESTIK 8008HT known as ABLECOAT 8008HT, Page 6 of 14 Predicted No-Effect Concentration (PNEC): Name on list Environmental Compartment aqua (marine water) aqua (freshwater) STP aqua (intermittent releases) soil period Value mg/l ppm mg/kg others 0,09 mg/l 0,9 mg/l 7400 mg/l 9 mg/l 0,81 mg/kg Remarks Derived No-Effect Level (DNEL): Name on list Application Area Route of Health Effect worker Dermal Long term exposure - systemic effects worker inhalation Long term exposure - local effects worker inhalation Long term exposure - systemic effects general Dermal Long term population exposure - systemic effects general population general population general population inhalation oral inhalation Long term exposure - systemic effects Long term exposure - systemic effects Long term exposure - local effects Time Value 50 mg/kg bw/day 20 mg/m3 176 mg/m3 25 mg/kg bw/day 43,5 mg/m3 25 mg/kg bw/day 10 mg/m3 Remarks Biological Indices: None 8.2. controls: Engineering controls: Ensure good ventilation/extraction. Respiratory protection: Ensure adequate ventilation. An approved mask or respirator fitted with an organic vapour cartridge should be worn if the product is used in a poorly ventilated area Filter type: A

7 LOCTITE ABLESTIK 8008HT known as ABLECOAT 8008HT, Page 7 of 14 Hand protection: Chemical-resistant protective gloves (EN 374). Suitable materials for short-term contact or splashes (recommended: at least protection index 2, corresponding to > 30 minutes permeation time as per EN 374): nitrile rubber (NBR; >= 0.4 mm thickness) Suitable materials for longer, direct contact (recommended: protection index 6, corresponding to > 480 minutes permeation time as per EN 374): nitrile rubber (NBR; >= 0.4 mm thickness) This information is based on literature references and on information provided by glove manufacturers, or is derived by analogy with similar substances. Please note that in practice the working life of chemical-resistant protective gloves may be considerably shorter than the permeation time determined in accordance with EN 374 as a result of the many influencing factors (e.g. temperature). If signs of wear and tear are noticed then the gloves should be replaced. Eye protection: Safety glasses with sideshields or chemical safety goggles should be worn if there is a risk of splashing. Skin protection: Wear suitable protective clothing. SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties Appearance paste silver Odor Mild Odour threshold ph Initial boiling point Flash point Decomposition temperature Vapour pressure Density Bulk density Viscosity Viscosity (kinematic) Explosive properties Solubility (qualitative) (Solvent: Water) Solidification temperature Melting point Flammability Auto-ignition temperature Explosive limits Partition coefficient: n-octanol/water Evaporation rate Vapor density Oxidising properties > 107 C (> F) Not applicable Insoluble 9.2. Other information SECTION 10: Stability and reactivity Reactivity Reacts with alcohols and amines. Reacts with oxidants, acids and lyes Reaction with some curing agents may produce an exothermic reaction which in large masses could cause runaway polymerization Chemical stability Stable under recommended storage conditions.

8 LOCTITE ABLESTIK 8008HT known as ABLECOAT 8008HT, Page 8 of Possibility of hazardous reactions See section reactivity Conditions to avoid No decomposition if stored and applied as directed Incompatible materials See section reactivity Hazardous decomposition products Hydrocarbons carbon oxides. nitrogen oxides Rapid polymerisation may generate excessive heat and pressure Information on toxicological effects SECTION 11: Toxicological information General toxicological information: The preparation is classified based on the conventional method outlined in Article 6(1)(a) of Directive 1999/45/EC. Relevant available health/ecological information for the substances listed under Section 3 is provided in the following. Inhalative toxicity: May cause irritation to respiratory system. Dermal toxicity: Prolonged or repeated skin contact with silver and its salts may cause a blue-gray discoloration of the skin and mucous membranes that is irreversible (Argyria). Skin irritation: Prolonged or repeated contact may cause skin irritation. Eye irritation: Irritating to eyes. Sensitizing: May cause sensitization by skin contact. Acute oral toxicity: Silver Value type Value Route of application time Species Method LD50 > mg/kg oral rat OECD Guideline 401 (Acute Oral Toxicity) LD50 > mg/kg oral rat LD50 > mg/kg rat LD mg/kg oral rat LD mg/kg rat Acute dermal toxicity: Value type Value Route of application time Species LD50 > mg/kg dermal rabbit LD50 > mg/kg rabbit Method

9 LOCTITE ABLESTIK 8008HT known as ABLECOAT 8008HT, Page 9 of 14 Skin corrosion/irritation: Result time Species Method slightly irritating rabbit OECD Guideline 404 (Acute Dermal Irritation / Corrosion) slightly irritating rabbit OECD Guideline 404 (Acute Dermal Irritation / Corrosion) slightly irritating rabbit OECD Guideline 404 (Acute Dermal Irritation / Corrosion) irritating irritating corrosive rabbit corrosive rabbit Serious eye damage/irritation: Silver Carbinol acetate Carbinol acetate Silver Carbinol acetate Carbinol acetate Result time Species Method slightly irritating rabbit OECD Guideline 405 (Acute Eye Irritation / Corrosion) irritating rabbit OECD Guideline 405 (Acute Eye Irritation / Corrosion) irritating rabbit OECD Guideline 405 (Acute Eye Irritation / Corrosion) irritating irritating Respiratory or skin sensitization: sensitising sensitising Result Test type Species Method

10 LOCTITE ABLESTIK 8008HT known as ABLECOAT 8008HT, Page 10 of 14 Germ cell mutagenicity: 2,6-Diglycidyl phenyl allyl ether oligomer 2,6-Diglycidyl phenyl allyl ether oligomer Result Type of study / Route of administration negative bacterial reverse mutation assay (e.g negative Ames test) bacterial reverse mutation assay (e.g Ames test) Metabolic activation / time with and without with and without Species negative intraperitoneal mouse Method negative intraperitoneal mouse positive bacterial reverse with and without other guideline: mutation assay (e.g Ames test) positive with bacterial reverse metabolic mutation assay (e.g activation Ames test) positive with bacterial reverse metabolic mutation assay (e.g activation Ames test) positive intraperitoneal mouse other guideline: positive intraperitoneal positive intraperitoneal positive bacterial reverse mutation assay (e.g Ames test) positive bacterial reverse mutation assay (e.g Ames test) negative dermal mouse negative dermal mouse without OECD Guideline 471 (Bacterial Reverse Mutation Assay) without OECD Guideline 471 (Bacterial Reverse Mutation Assay) Repeated dose toxicity Result NOAEL=5.000 mg/kg Route of application time / Frequency of treatment Species Method oral: gavage 90 days 5 days/week rat OECD Guideline 408 (Repeated Dose 90-Day Oral Toxicity in Rodents) NOAEL=0,1 mg/l inhalation 14 weeks (93 days) 6 hours/ day ; 5 days/week NOAEL=0,1 mg/l inhalation 14 weeks (93 days) 6 hours/ day ; 5 days/week NOAEL=5.000 mg/kg rat rat other guideline: other guideline: oral: gavage 90 days 5 days/week rat OECD Guideline 408 (Repeated Dose 90-Day Oral Toxicity in Rodents) SECTION 12: Ecological information General ecological information: The preparation is classified based on the conventional method outlined in Article 6(1)(a) of Directive 1999/45/EC. Relevant available health/ecological information for the substances listed under Section 3 is provided in the following Toxicity Ecotoxicity: Toxic to aquatic organisms May cause long-term adverse effects in the aquatic environment. Do not empty into drains / surface water / ground water.

11 2-Methylhydroquinone Methylhydroquinone Methylhydroquinone LOCTITE ABLESTIK 8008HT known as ABLECOAT 8008HT, Page 11 of 14 Value type Value Acute Toxicity Study time Species LC mg/l Fish 96 h Leuciscus idus Method LC mg/l Fish 96 h Leuciscus idus EC50 > 500 mg/l Daphnia 48 h Daphnia magna OECD Guideline 202 (Daphnia sp. Acute Immobilisation EC50 > 500 mg/l Daphnia 48 h Daphnia magna OECD Guideline 202 (Daphnia sp. Acute Immobilisation EC50 > 900 mg/l Algae 72 h Scenedesmus subspicatus (new OECD Guideline name: Desmodesmus 201 (Alga, Growth subspicatus) NOEC 900 mg/l Algae 72 h Scenedesmus subspicatus (new name: Desmodesmus subspicatus) EC50 > 900 mg/l Algae 72 h Scenedesmus subspicatus (new name: Desmodesmus subspicatus) NOEC 900 mg/l Algae 72 h Scenedesmus subspicatus (new name: Desmodesmus subspicatus) OECD Guideline 201 (Alga, Growth OECD Guideline 201 (Alga, Growth OECD Guideline 201 (Alga, Growth LC50 0,91 mg/l Fish 96 h Carassius sp. OECD Guideline 203 (Fish, Acute Toxicity LC50 0,91 mg/l Fish 96 h Carassius sp. OECD Guideline 203 (Fish, Acute Toxicity LC50 3,9 mg/l Fish 96 h Oncorhynchus mykiss OECD Guideline 203 (Fish, Acute Toxicity LC50 3,9 mg/l Fish 96 h Oncorhynchus mykiss OECD Guideline 203 (Fish, Acute Toxicity EC50 18 mg/l Daphnia 48 h Daphnia magna OECD Guideline 202 (Daphnia sp. Acute Immobilisation EC50 18 mg/l Daphnia 48 h Daphnia magna OECD Guideline 202 (Daphnia sp. Acute Immobilisation ErC50 3,1 mg/l Algae 72 h Pseudokirchnerella subcapitata OECD Guideline 201 (Alga, Growth ErC50 3,1 mg/l Algae 72 h Pseudokirchnerella subcapitata OECD Guideline 201 (Alga, Growth LC50 0,09 mg/l Fish 96 h Pimephales promelas OECD Guideline 203 (Fish, Acute Toxicity LC50 0,09 mg/l Fish 96 h Pimephales promelas OECD Guideline 203 (Fish, Acute Toxicity EC50 0,19 mg/l Daphnia 48 h Daphnia magna OECD Guideline 202 (Daphnia sp. Acute Immobilisation EC50 0,19 mg/l Daphnia 48 h Daphnia magna OECD Guideline 202 (Daphnia sp. Acute Immobilisation EC50 0,335 mg/l Algae 3 d Selenastrum capricornutum (new name: Pseudokirchnerella subcapitata) EC50 0,335 mg/l Algae 3 d Selenastrum capricornutum (new name: Pseudokirchnerella subcapitata) OECD Guideline 201 (Alga, Growth OECD Guideline 201 (Alga, Growth

12 LOCTITE ABLESTIK 8008HT known as ABLECOAT 8008HT, Page 12 of Persistence and degradability Persistence and Biodegradability: The product is not biodegradable. 2-Methylhydroquinone Result Route of application Degradability Method aerobic 98 % OECD Guideline 301 E (Ready biodegradability: Modified OECD Screening aerobic 98 % OECD Guideline 301 E (Ready biodegradability: Modified OECD Screening aerobic 0 % aerobic 0 % 18 % OECD Guideline 301 E (Ready biodegradability: Modified OECD Screening 18 % OECD Guideline 301 E (Ready biodegradability: Modified OECD Screening readily biodegradable aerobic % EU Method C.4-E (Determination of the "Ready" BiodegradabilityClosed Bottle readily biodegradable aerobic % EU Method C.4-E (Determination of the "Ready" BiodegradabilityClosed Bottle Bioaccumulative potential / Mobility in soil Mobility: Cured adhesives are immobile. Bioaccumulative potential: No data available. 2-Methylhydroquinone LogKow Bioconcentration factor (BCF) -0,41-0,41 2,16 2,16 0,91 0,91 time Species Temperature Method 9,1 calculation OECD Guideline 305 (Bioconcentration: Flowthrough Fish 9,1 calculation OECD Guideline 305 (Bioconcentration: Flowthrough Fish Results of PBT and vpvb assessment PBT/vPvB Not fulfilling Persistent, Bioaccumulative and Toxic (PBT), very Persistent and very Bioaccumulative (vpvb) criteria Other adverse effects No data available.

13 LOCTITE ABLESTIK 8008HT known as ABLECOAT 8008HT, Page 13 of 14 SECTION 13: Disposal considerations Waste treatment methods Product disposal: Do not empty into drains / surface water / ground water. Dispose of in accordance with local and national regulations. Disposal of uncleaned packages: After use, tubes, cartons and bottles containing residual product should be disposed of as chemically contaminated waste in an authorised legal land fill site or incinerated. Waste code waste adhesives and sealants containing organic solvents and other dangerous substances The valid EWC waste code numbers are source-related. The manufacturer is therefore unable to specify EWC waste codes for the articles or products used in the various sectors. The EWC codes listed are intended as a recommendation for users. We will be happy to advise you. SECTION 14: Transport information UN number Not hazardous according to RID, ADR, ADNR, IMDG, IATA-DGR UN proper shipping name Not hazardous according to RID, ADR, ADNR, IMDG, IATA-DGR Transport hazard class(es) Not hazardous according to RID, ADR, ADNR, IMDG, IATA-DGR Packaging group Not hazardous according to RID, ADR, ADNR, IMDG, IATA-DGR Environmental hazards Not hazardous according to RID, ADR, ADNR, IMDG, IATA-DGR Special precautions for user Not hazardous according to RID, ADR, ADNR, IMDG, IATA-DGR Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code not applicable SECTION 15: Regulatory information Safety, health and environmental regulations/legislation specific for the substance or mixture VOC content < 10 % (1999/13/EC) Chemical safety assessment A chemical safety assessment has not been carried out.

14 LOCTITE ABLESTIK 8008HT known as ABLECOAT 8008HT, Page 14 of 14 SECTION 16: Other information The labelling of the product is indicated in Section 2. The full text of all abbreviations indicated by codes in this safety data sheet are as follows: R21/22 Harmful in contact with skin and if swallowed. R22 Harmful if swallowed. R23 Toxic by inhalation. R34 Causes burns. R36 Irritating to eyes. R36/37/38 Irritating to eyes, respiratory system and skin. R36/38 Irritating to eyes and skin. R43 May cause sensitisation by skin contact. R48/20/22 Harmful: danger of serious damage to health by prolonged exposure through inhalation and if swallowed. R50 Very toxic to aquatic organisms. R50/53 Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. R51/53 Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. R68 Possible risk of irreversible effects. R7 May cause fire. H242 Heating may cause a fire. H302 Harmful if swallowed. H312 Harmful in contact with skin. H314 Causes severe skin burns and eye damage. H315 Causes skin irritation. H317 May cause an allergic skin reaction. H319 Causes serious eye irritation. H331 Toxic if inhaled. H335 May cause respiratory irritation. H341 Suspected of causing genetic defects. H373 May cause damage to organs through prolonged or repeated exposure. H400 Very toxic to aquatic life. H410 Very toxic to aquatic life with long lasting effects. H411 Toxic to aquatic life with long lasting effects. Further information: This information is based on our current level of knowledge and relates to the product in the state in which it is delivered. It is intended to describe our products from the point of view of safety requirements and is not intended to guarantee any particular properties.