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1 Supporting Information IG TRUGPUT DISCVERY F EW FULIG-RESISTAT SURFACES Mingyan Zhou, ongwei Liu, Adith Venkiteshwaran, James Kilduff, Daniel G. Anderson, Robert Langer and Georges Belfort J. Mater. Chem., DI: /c0jm01266a Table S1. ame, structure, and formula weight of monomers employed in this study. otes: Monomers were dissolved in DI water unless designated by superscript a which indicates that 90% ethanol was used as the solvent. Commercial vinyl monomers were purchased from Sigma-Aldrich (Saint Louis, M) and were used as-received without further purification. A. Methacrylates having hydrophobic side chains 1 a Methyl methacrylate 2 a Ethyl methacrylate 3 a Butyl methacrylate a Isobutyl methacrylate a tert-butyl methacrylate a exyl methacrylate a 2-Ethylhexyl methacrylate a Allyl methacrylate a Cyclohexyl methacrylate a Isobornyl methacrylate 28 a Ethylene glycol dicyclopentenyl ether methacrylate
2 B. etero ring group monomers 16 a Glycidyl methacrylate a Tetrahydrofurfuryl methacrylate Acryloylmorpholine (R)-α-Acryloyloxy-β,β-dimethyl-γbutyrolactone a -Vinylcaprolactam C. Aromatic monomers 15 a Phenyl methacrylate a Benzyl methacrylate a Ethylene glycol phenyl ether methacrylate a Styrene
3 D. ydroxy monomers 24 a ydroxypropyl methacrylate [Tris(hydroxymethyl)methyl]acrylamide a 3-Chloro-2-hydroxypropyl methacrylate Cl a 3-(Trimethoxysilyl)propyl methacrylate Si a Caprolactone 2-(methacryloyloxy)ethyl ester 64 a Bis[2-(methacryloyloxy)ethyl] phosphate P a 3-(Acryloyloxy)-2-hydroxypropyl methacrylate
4 E. PEG monomers 8 a 2-(Methylthio)ethyl methacrylate S a 2-Ethoxyethyl methacrylate a 2-Butoxyethyl methacrylate a Ethylene glycol dimethacrylate a Triethylene glycol dimethacrylate 30 a Ethylene glycol methyl ether methacrylate a Di(ethylene glycol) methyl ether methacrylate Poly(ethylene glycol) methyl ether methacrylate Poly(ethylene glycol) methyl ether methacrylate Poly(ethylene glycol) methyl ether methacrylate Poly(ethylene glycol) methyl ether methacrylate
5 F. Strong and weak acid monomers 65 a mono-2-(methacryloyloxy)ethyl maleate 42 a mono-2-(methacryloyloxy)ethyl succinate 43 Acrylic acid 44 2-Acrylamidoglycolic acid 45 Methacrylic acid 50 Itaconic acid 46 3-Sulfopropyl methacrylate potassium salt 47 a Ethylene glycol methacrylate phosphate 48 2-Acrylamido-2-methyl-1-propanesulfonic acid S K P S Styrenesulfonic acid sodium salt S 3 a G. Amine monomers 58 Acrylamide Isopropylacrylamide a -tert-butylacrylamide (Dimethylamino)ethyl methacrylate a 2-(Diethylamino)ethyl methacrylate [3-(Dimethylamino)propyl]methacrylamide
6 . Basic and Zwitterionic monomers [3-(Methacryloylamino)propyl]dimethyl(3- sulfopropyl)ammonium hydroxide inner salt [2-(Methacryloyloxy)ethyl]dimethyl-(3- sulfopropyl)ammonium hydroxide [2-(Methacryloyloxy)ethyl] trimethylammonium chloride [3-(Methacryloylamino)propyl] trimethylammonium chloride [2-(Methacryloyloxy)ethyl] trimethylammonium methyl sulfate S S Cl Cl S I. ther monomers 41 Methacrylonitrile C Vinylformamide a 2,2,2-Trifluoroethyl methacrylate 20 a Trimethylsilyl methacrylate F F F Si a 2-Isocyanatoethyl methacrylate 11 a 2-(Methacryloyloxy)ethyl acetoacetate r (2-Acetoacetoxyethyl methacrylate) 53 Diacetone acrylamide C
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