SPECIFIC POLYMERS OVERVIEW:

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MMERS ATALG 2018 SPEIFI PLYMERS VERVIEW: SPEIFI PLYMERS is a company specialized in the synthesis of polymer additives bearing heteroelements; mainly phosphorus, silicon and fluorine.

1 MMERS ATALG 2018 SPEIFI PLYMERS VERVIEW: SPEIFI PLYMERS is a company specialized in the synthesis of polymer additives bearing heteroelements; mainly phosphorus, silicon and fluorine. ur products are intended for research laboratories in surface modifications (glass, metals, metal oxides, nanoparticles, plastics, etc.) for applications in pharmaceuticals, cosmetics, water treatment, metal extraction, concrete, adhesion, anticorrosion, etc. Using our expertise in the field of polymer chemistry, especially in the chemistry of phosphorus, silicon and phosphorus, we propose novel polymers which are often supplied exclusively by our company. These polymers present physico-chemical properties such as: Adhesion onto metal, anticorrosion, complexation of heavy metals, fire-proofing, etc. ydrophoby leophoby hemical inertness Thermal stability, etc. ur services including also custom synthesis and research contract provide our specific expertise on functional polymers to support Research programs.

2 IDEX ALKYL MMERS... 3 SP-3-9 ALKYL MALEIMIDE... 3 EPXYDES... 5 SP-3-15 EPXY PSPI... 5 SP-3-25 ALKYL ALXYSILAE EPXY... 6 FUTIAL (MET)ARYLATES / (META)RYLAMIDES... 7 SP-4-9 ARYLATE - METARYLATE AZIDE - PRPARGYL... 7 SP-40 ARYLATE - METARYLATE ARBXYLI/ESTER/ARBATE... 7 SP-41 PSPI (MET)ARYLATE - (MET)ARYLAMIDE... 9 SP-42-(MET)ARYLATE - (MET)ARYLAMIDE - ALXYSILAE SP-42-0-(MET)ARYLATE - (MET)ARYLAMIDE - URETAE ALXYSILAE SP-43-0-ALKYL/ARYL (MET)ARYLATE - (MET)ARYLAMIDE SP-43-3-ALKXY ARYLATE METARYLATE - (MET)ARYLAMIDE SP-45-EPXY - (MET)ARYLATE - (MET)ARYLAMIDE SP-46-ALLYL/VIYL - METARYLATE - METARYLAMIDE SP-49-TER FUTIAL ARYLATE - METARYLATE FUTIAL STYREE SP-51 PSPI STYREE SP-53 STYREE ALL-ETER SP-55 STYREE EPXY SP-59 TER FUTIAL STYREE VIYL / ALLYL MMERS SP-60 VIYL/ALLYL ARBXYLI/ESTER/ARBATE SP FLUR ALLYL/VIYL/(MET)ARYL SP FLUR ALLYL AMIE SP-61 VIYL/ALLYL PSPI SP-62 0 VIYL/ALLYL ALXYSILAE SP-63 VIYL/ALLYL ARYL SP-69 VIYL/ALLYL AZIDE VARIUS FUTIAL BUIDIG BLKS SP-99- TILATE MALEIMIDE >2 on request

3 ALKYL MMERS SP-3-9 ALKYL MALEIMIDE SP SP SP Maleimide [ ] Mw= Maleimide [not identified] Mw= Maleimide [ ] Mw= SP Allyl Maleimide [ ] 772 Mw= SP Tertbutyl Maleimide [ ] 8112 Mw= SP Maleimide [ ] 792 Mw= >2 on request

4 SP Benzoyl hloride Maleimide [ot Identified] 116l3 Mw= SP Benzoic Acid Maleimide [ot Identified] 1174 Mw= SP Methyl Maleimide Benzoate [ ] >2 on request

5 EPXYDES SP-3-15 EPXY PSPI SP Epoxy Methyl Dimethylphosphonate [ ] 6134P Mw= P( 3 ) 2 SP Epoxy Methyl Diethylphosphonate [ ] 8144P Mw= P( 2 5 ) 2 SP Epoxy Dimethylphosphonate [ ] 5114P Mw= P( 3 ) 2 SP Epoxy 3 Dimethylphosphonate [ ] 8175P Mw= P( 3 ) 2 SP Epoxy 3 Diethylphosphonate [ ] 10215P Mw= P( 2 5 ) 2 SP Epoxy Diethylphosphonate [not identified] 7154P Mw= P( 2 5 ) >2 on request

6 SP-3-25 ALKYL ALXYSILAE EPXY SP EPXY PRPYL URETAE TRIETXYSILAE [ ] 13276Si Mw= Si >2 on request

7 FUTIAL (MET)ARYLATES / (META)RYLAMIDES SP-4-9 ARYLATE - METARYLATE AZIDE - PRPARGYL SP Methacrylate Azide [ ] 6923 Mw= SP Propargyl Methacrylate [ ] 782 Mw= < SP-40 ARYLATE - METARYLATE ARBXYLI/ESTER/ARBATE SP Glycerol carbonate methacrylate [ ] 8105 Mw= SP SP Diethyl Methylene Malonate [ ] 8124 Mw= Di-Undecyl Fumarate [ ] Mw= >2 on request

8 SP (Methacryloyloxy)ethyl phthalate monoester [ ] 4146 Mw= SP Ethyl α-acetoxyacrylate [ ] 7104 Mw= SP (Acryloyloxy)Ethyl Methacrylate [ ] SP Ethyl Acetoxy Acrylate [ ] 8 2 >2 on request

9 SP-41 PSPI (MET)ARYLATE - (MET)ARYLAMIDE SP MATBAE dimethylphosphonate [ ] 13265P Mw= P(3)2 SP MATBAE diethylphosphonate [ ] 15305P Mw= P(25)2 SP MAP1 ME [ ] 7135P Mw= P( 3 ) 2 SP MAP1 ME EMIYDRLYSED [ ] 6115P Mw= P()( 3 ) SP Maleic Acid Dimethylphosphonate [ ] 7117P Mw= P( 3 ) 2 SP MAP1 ET [ ] 9175P Mw= P( 2 5 ) 2 SP MAP1 Acid [ ] 595P Mw= P() 2 SP Methacrylamide Phosphonate ET [ ] 10204P Mw= P( 2 5 ) >2 on request

10 SP MAP1 SIL [ ] 11255PSi2 Mw= Si( 3 ) 3 2 P Si( 3 ) 3 SP AAP1 ME [ot identified] 6115P Mw= P( 3 ) 2 SP AAP1 SIL [ ] 10235PSi2 Mw= Si( - 3 ) 3 2 P Si( 3 ) 3 SP MAP2 ME [ ] 8155P Mw= P( 3 ) 2 SP Maleic Acid 2 Dimethylphosphonate [ ] 8137P Mw= P( 3 ) 2 SP MAP3 ME [ ] 9175P Mw= P( 3 ) 2 SP MAP3 AID [ ] 9198P2 Mw= P() 2 P() 2 SP MAP2 AID [ ] 6115P Mw= P() >2 on request

11 SP Acrylamide 2 Phosphonate ET [ ] 9184P Mw= P( 2 5 ) 2 SP AAP1 Phosphonic Acid [ ] 475P Mw= P() 2 SP MAP3 ET [ ] 17358P2 Mw= P( 2 5 ) 2 P( 2 5 ) 2 SP Maleic Acid Diethylphosphonate [ot Identified] 9157P Mw= P( 2 5 ) 2 SP Acrylamide 2 Phosphonic acid [ ] 5104P Mw= SP MAP3 Acid [ ] 7135P Mw= SP MAP2 ET [ ] P 11 2 >2 on request

12 SP MAP11 ME [ ] P SP SP MAP11 ET [ ] MAP-11 EMIESTER ME [ ] P P SP MAP-11 AID [ ] P SP-42-(MET)ARYLATE - (MET)ARYLAMIDE - ALXYSILAE SP n-[3-trimethoxysilyl)propyl] acrylamide [ ] Si SP n-[3-triethoxysilyl)propyl] acrylamide [ ] Si SP-42-0-(MET)ARYLATE - (MET)ARYLAMIDE - URETAE ALXYSILAE SP Acrylate 2 Propyl Urethane Triethoxysilane [ ] Si SP Methacrylate 2 Propyl Urethane Triethoxysilane [ ] Si( 2 5 ) >2 on request

13 SP-43-0-ALKYL/ARYL (MET)ARYLATE - (MET)ARYLAMIDE SP TYL METARYLATE [ ] Mw= SP PRPYL ARYLAMIDE [ ] 611 Mw= SP PRPYL METARYLAMIDE [ ] 713 Mw= SP DIBUTYL ARYLAMIDE [ ] 1121 Mw= SP METALATRAEE METARYLATE [ ] Mw= >2 on request

14 SP (4-ARBXY)PEYL METARYLATE [ ] Mw= SP (4-ARBXY-3- METYL)PEYL METARYLATE [ot Identified] Mw= (4-FRMYL)PEYL METARYLATE [ ] SP Mw= (4-FRMYL-3- METYL)PEYL METARYLATE [ot Identified] SP Mw= QUILIYL METAYLATE [ ] SP Mw= >2 on request

15 SP (4-METYL)UMARI-7-YL METARYLATE [ ] Mw= SP (3-LR-4- METYL)UMARI-7-YL METARYLATE [ot Identified] 1411l4 Mw= l SP PEAYL METARYLATE [ ] Mw= SP (4-LR-3- METYL)PEYL METARYLATE [ ] 1111l2 Mw= l SP (4-EPTYL)PEYL METARYLATE [ot Identified] Mw= SP IAMYL METARYLATE [ ] Mw= >2 on request

16 SP-43-3-ALKXY ARYLATE METARYLATE - (MET)ARYLAMIDE SP Methoxyethyl-2-methacrylate [ ] 7123 Mw= SP PEG-methacrylate [ ] Mw=on demand n SP EMA-blocked-Mesylate [ ] 7125S Mw= S 3 SP ydroxypropyl beta cyclodextrin methacrylate [ot identified] Mw=1430 SP PEG-acrylate [ ] Mw=on demand n 16 2 >2 on request

17 SP Acetonide Protected Tmp Methacrylate [ ] SP Trimethylolpropane Monomethacrylate [ ] SP DPAMIE METARYLAMIDE [ ] Mw= SP BUTXYETYL METARYLATE [ ] Mw= SP (2- METXYETYL)ARYLAMIDE [ ] 6112 Mw= SP ,-BIS-(2- METXYETYL)ARYLAMIDE [ ] 9173 Mw= >2 on request

18 SP-45-EPXY - (MET)ARYLATE - (MET)ARYLAMIDE SP (3-Methyloxiran-2-Yl)Methyl 2-Methacrylate [ ] SP ,4-Epoxycyclohexylmethyl methacrylate [ ] SP DIMETYLGLYIDYL METARYLATE [ ] SP ,3-EPXYBUTYL METARYLATE [ ] SP-46-ALLYL/VIYL - METARYLATE - METARYLAMIDE SP , Diallyl Methacrylamide [ ] 1015 Mw= SP , Diallyl acrylamide [ ] 913 Mw= SP Allyloxyethoxyethyl Methacrylate [ ] Mw= >2 on request

19 SP Allyloxyethyl Methacrylate [ ] 9144 Mw= SP Vinyloxy-butyl Methacrylate [ ] Mw= SP Butenyl Methacrylate [ ] SP Allyloxyethyl Acrylate [ ] SP Vinyloxybutyl Acrylate [ ] SP-49-TER FUTIAL ARYLATE - METARYLATE SP TRILRETYL METARYLATE 2 [ ] 672l3 Mw= l 3 SP PETABRMPEL METARYLATE [ ] Mw= SP PETALRPEL METARYLATE [ ] 1052l5 Mw= l l l l l SP ARYLXY SUIIMIDE S ARYLATE 2 [ ] 774 Mw= >2 on request

20 SP SP SP METARYLXYSUIIMIDE 3 S METARYLATE 2 [ ] 894 Mw= PETABRMPEL ARYLATE [ ] 9325 Mw= Tridecafluorooctyl Acrylate 2 [ ] F F132 Mw= SP METARYLATE UREA IMIDAZLE [ ] Mw= SP METARYLAMIDE PRPYL IMIDAZLE [ ] Mw= SP (METARYLYLXY)ETYL 2,3,5-TRIIDBEZATE [ ] 1344I3 Mw= SP SP TRIBRMETYLMETARYLATE [ ] 6732 Mw= PETAERYTRITL TRIBRMIDE METARYLATE [ ] Mw= >2 on request

21 SP BRI AID ARYLAMIDE [ ] 910B3 Mw= B SP [DIMETYL-1,3,2-DIXABRIA-2- YL)XY]ETYL METARYLATE [ ] 1119B5 Mw= B SP TERPIEL ARYLATE [ ] Mw= SP (AETYLTI)ETYLMETARYLATE (ASEMA) [ ] 8123S Mw= S SP TEMP METARYLATE [ ] Mw= SP TIYLARBATE METARYLATE [ ] 8103S2 Mw= S S SP BRMUDEYL METARYLATE [ ] Mw= >2 on request

22 SP (LRSULFYL)PRPYL METARYLATE [ ] Mw= SP (2,3,5-TRIIDBEZYLXY)ETY ARYLATE AETIB [ ] 129I34 Mw= I I I SP MTFSiLi [ ] 811F3Li6S2 Mw= SP DL-omocysteine Thiolactone Acrylam [ ] 792S Mw= S SP DL-omocysteine Thiolactone Methacrylamide [ ] 8112S Mw= S SP Thiolactone Acrylate S 9123S Mw= SP Thiolactone Methacrylate 10143S Mw= S 22 2 >2 on request

23 FUTIAL STYREE SP-51 PSPI STYREE SP Styrene Dimethylphosphonate [ ] 11153P Mw= P( 3 ) 2 SP Styrene Diethylphosphonate [ ] 13193P Mw= P( 2 5 ) 2 SP Styrene Phosphonic Acid [ ] 9113P Mw= P() 2 SP Styrene Methylphosphonic Acid [ ] 10133P Mw= >2 on request

24 SP Styrene Ethylphosphonic Acid [ ] 11153P Mw= SP Styrene Butylphosphonic Acid [ot Identified] 13183P Mw= P()( 4 8 ) SP Styrene Dibutylphosphonic Ester [ ] 17253P Mw= P( 4 8 ) 2 SP-53 STYREE ALL-ETER SP Styrene PEG [ ] n on demand n SP Vinylphenol solution, 50%wt in Ethanol [ ] 24 2 >2 on request

25 SP-55 STYREE EPXY SP Styrene Glycidyl Ether [ ] SP VIYLPEYL GLYIDYL ETER [ ] SP-59 TER FUTIAL STYREE SP Styrene Azide [ ] 993 Mw= SP p-iodo Styrene [ ] 87I Mw= I SP p-trifluoroethoxy-metyl Styrene [ ] 1111F3 Mw= SP ot Available 25 2 >2 on request

26 Styrene Imidazole [ ] SP Mw= SP Styrene arbonate [ ] Mw= SP (tert-butylamino) methystyrene (TBAMS) [ ] 1319 Mw= SP VIYLPEYL YLARBATE [ ] 1319 Mw= >2 on request

27 SP VIYLBEZYL 4- FRMYLBEZATE [ot Identified] Mw= SP S-(4-VIYLBEZYL)TIAETATE [ ] 1112S Mw= S STFSiLi [ ] 97F3Li4S2 Mw= SP >2 on request

28 VIYL / ALLYL MMERS SP-60 VIYL/ALLYL ARBXYLI/ESTER/ARBATE SP Allyl Glycerol carbonate [ ] Mw= SP Allyl Amino Maleic Acid [ ] 793 Mw= SP Methoxy Maleic Acid [ ] 5644 Mw= SP Allyloxy ME-ET yclocarbonate 6 [ ] Mw= SP Diallyl Adipate [ ] Mw= SP Furfuryl yclocarbonate Ether [ ] 9105 Mw= SP Diallyl xalate [ ] 8104 Mw= >2 on request

29 SP FLUR ALLYL/VIYL/(MET)ARYL SP Bis Allyloxy Dodecafluorooctane [ ] F F122 Mw= SP Bis Acrylate Dodecafluorooctane [ ] 1410F124 Mw= F SP Allyloxy Tridecafluorooctane [ ] 119F13 Mw= SP FLUR ALLYL AMIE SP Fluoro 6 Diallyl Amine [ ] 1414F13 Mw= F >2 on request

30 SP-61 VIYL/ALLYL PSPI SP Dimethyl Allylphosphonate [ ] 5113P Mw= P( 3 ) 2 SP Diethyl Allylphosphonate [ ] 7153P Mw= P( 2 5 ) 2 SP Undecenyl Phosphonic Acid [ ] 11233P Mw= P() 2 9 SP Undececenyl Diethyl Phosphonate [ ] 15313P Mw= P( 2 5 ) 2 9 SP Undececenyl Dimethyl Phosphonate [ ] 13273P Mw= P( 3 ) 2 9 SP Allyl Phosphonic Acid [ ] 373P Mw= P() 2 SP Ethyl Vinyl Ether Diethylphosphonate [ ] 8174P Mw= P( 2 5 ) >2 on request

31 SP-62 0 VIYL/ALLYL ALXYSILAE SP Vinyl ether c4 propyl urethane trimethoxysilane [ot Registred] Si( 3 ) 3 SP Vinyl ether c4 propyl urethane triethoxysilane [ot Registred] Si( 2 5 ) 3 SP-63 VIYL/ALLYL ARYL SP Resorcinol bis Allyl [ ] Mw= SP-69 VIYL/ALLYL AZIDE SP Undecenyl Azide [ ] Mw= >2 on request

32 VARIUS FUTIAL BUIDIG BLKS SP-99- TILATE MALEIMIDE SP Thiolactone maleimide [ot Identified] 873S Mw= S 32 2 >2 on request

Supporting Information

Supporting Information IG TRUGPUT DISCVERY F EW FULIG-RESISTAT SURFACES Mingyan Zhou, ongwei Liu, Adith Venkiteshwaran, James Kilduff, Daniel G. Anderson, Robert Langer and Georges Belfort J. Mater. Chem.,