Cargo Handling Sheet. IPA Isopropyl Alcohol USP Grade. Document date: 16 December 2013 Original Document

Transcription

1 Cargo Handling Sheet IPA Isopropyl Alcohol USP Grade Original Document

2 Product Details: Product Name: IMO Shipping Name: Chemical Family: Product Code: SDS: Isopropyl Alcohol-USP Isopropyl Alcohol Alcohols S Physical Properties: Density: Specific Gravity: deg C. Viscosity: deg C. Vapor Pressure: 4, deg C. Boiling Point: 82 Deg C. Melting Point: -88 Deg C. Flash Point: 12 Deg C. Notes: Transshipments are not permitted unless the responsible Shell Chemical charterer has been consulted and the operation approved by the Regional Marine Technical Advisor. Marpol Details: Marpol Annex: II IMO Ship Type: 3 Shell Chemicals requires a ship type 2 IMO Pollution Category: Oil Like: High Viscosity: Solidifying: Z No No No USCG: USCG compatibility group 20, not compatible with group 12 Isocyanates. 2

3 Cargo Handling Requirements: All shore and ship cargo lines and tanks are to be presented clean (residual free), dry, odor free, and rest free, with good gaskets and pressure tested heating coils. Prepurging of Vessel s Tanks: N2 Blanket Required: Percent Oxygen in Nitrogen Blanket: Loading Temperature Range: Transit Temperature Range: Discharge Temperature Range: Maximum Heating Coil Temperature: No Check charter party <8% if required. Ambient Ambient Ambient Blanked off Adjacent Maximum Cargo Temperature: 30 Deg C. Regional Requirements: None noted at this time. Notes: Tank Acceptance Requirements: Stainless or Coated: Wall Wash Required: Stainless preferred. Coated tanks, to be in very good condition with minimal blistering or breakdown. All blisters to be scraped to hard coating. All defects to be noted by the surveyor. Carrier to verify suitability of coating for product. Pipelines and fittings to be of stainless steel. Yes Wash Notes: Chlorides = 1ug/g(ppm) Color Hydrocarbons Appearance = 5 Max = Pass = Clear and free from suspended matter. 3

4 cgmp Prohibited Adjacent Cargo and Prior Cargo List Isopropanol (IPA) - USP/EP Grade This list applies to USP/EP product shipments in non-dedicated transportation equipment to protect end-users from either adulteration or contamination of the cargo. It is based in part on the NIOP Unacceptable Prior Cargo List, the FOSFA List of Banned Immediate Previous Cargoes, and the Codex Code of Practice for the Storage and Transport of Edible Fats and Oils in Bulk (Codex Alimentarius), and the Chapter 5.3 Criteria of the CEFIC Guidelines for Handling and Distribution of Propylene Glycol USP/EP. In addition, the USP General Chapter 467 for Organic Volatile Impurities (now known as Residual Solvents) is cited, subject to the compositional limits therein. Additional restrictions beyond the Immediate Previous Cargo: Leaded products shall not be carried as the three previous cargoes. Ethylene Dichloride and Styrene monomer shall not be carried as the three previous cargoes in organic coated tanks, or as the last cargo in stainless steel and inorganic coated tanks. Stainless Steel passivated tanks (Clause 5.11 D under the NIOP trading Rules): Ship tanks which have been newly coated, or fully recoated, or passivated stainless steel tanks shall be considered as new buildings. Cargoes carried prior to the date of such coatings or passivation shall not be considered as relevant. Owners are required to provide independent verification when requested. Owners will not withhold prior cargo information if requested. Ship owners should employ a passivation process such as that recommended under the current version of ASTM A 967. NIOP accepts the media for passivation listed under the ASTM guidelines including, but not limited to, Nitric Acid and Citric Acid solutions. PLEASE NOTE: This is not an exhaustive listing; it is intended to be a reference guide. Any prior or adjacent cargo substances not shown on this list which have the potential risk of a hazardous exposure need to be thoroughly reviewed by the consignee or shipper with Shell Chemical prior to presentation of transport equipment for loading to determine any HSSE impact. These restrictions are applicable to 3 (three) cargos prior to loading IPA-USP grade product. SUBSTANCE Acetone cyanohydrin REASON TO BE ON THE LIST Reactive with water. Decomposes to form Hydrogen Cyanide Acetonitrile 4

5 Acrylates such as: Sensitizer; harmful by all routes of exposure butyl acrylate ethyl acrylate ethyl hexyl acrylate methyl acrylate methyl methacrylate monomer Acrylonitrile Carcinogen cat 2 Adiponitrile Aldehydes, e.g.: Acetaldehyde Formaldehyde Gluteraldehyde Allyl compounds, e.g.: Allyl alcohol Toxic by ingestion. Carcinogen cat 3 IARC 2 A carcinogen Toxic by inhalation and if swallowed, sensitizer, high aquatic toxicity Toxic; harmful by all routes of exposure; irritating to eyes, respiratory system, and skin; lacrymator; high aquatic toxicity Allyl chloride Allyl ligands Allyl palladium chloride Amides, e.g. Acrylamide Dimethylformamide (DMF) N,N-dimethylacetamide Carcinogen cat 2, sensitizer Reproductive tox cat 2 N,N-dimethlyformamide Amines, e.g.: Dibutylamine Diethanolamine Harmful by all routes of exposure Form nitrosamines, harmful if swallowed (R 48) Corrosive, sensitizer 5

6 Diethylenetriamine Diisopropylamine Ethanolamine Ethylenediamine n-propylamine Corrosive Corrosive, harmful by all routes of exposure Corrosive, sensitizer Low odor threshold Corrosive hexamethylediamine Animal-origin products including lard, tallow, etc. Non-Kosher BSE/TSE mad cow exposure Aniline Carcinogen and mutagen cat 3, sensitizer Anisol Aromatic Hydrocarbons e.g. Benzene Ethylbenzene Naphthalene Toluene Xylene (mixed isomers and o-, m-, p-) Aromatic Hydrocarbon Solvents (> 8% aromatics) Bisphenol A 1,3-butadiene Caprolactam Chlorinated compounds, e.g.: Carbon tetrachloride Ethylene dichloride Epichlorhydrin Carcinogen cat 1 IARC 2 B Carcinogen cat 3, toxic to aquatic organisms Reprotox cat 3, neurotox effects Harmful by inhalation/skin contact, contains EB Solvents limits; Class 1 Solvents to be Avoided May contain benzene Suspected carcinogens; discussion on hormone disrupting effects Carcinogen cat Harmful by all routes of exposure. Dioxins, PCBs Carcinogen cat 3; toxic by inhalation, Carcinogen cat 2 Carcinogen cat 3, corrosive, sensitizer 6

7 Chlorobenzenes Chloroform Chloroprene 1,2-dichloroethane 1,2-dichloroethene 1,1-dichloroethene 1,1,1- trichloroethane 1,3-dichloropropene ( TELONE ) Methylene chloride Perchloroethylene Trichloroethane Trichlorethylene Harmful by inhalation, aquatic toxicity Carcinogen cat 3, harmful by inhalation Carcinogen cat 2 Toxic; environmental hazard Toxic; environmental hazard Toxic; environmental hazard Toxic; environmental hazard Fumigant, reference NIOP list Carcinogen cat 3 Carcinogen cat 3, aquatic toxicity Harmful by inhalation, ODC properties Carcinogen cat 1 Vinyl chloride monomer Coal tar and coal tar pitch, e.g.: Creosote (coal tar or wood) Cresol (o,m,p and cresylates and cresylic acids) Cyclohexane Di-glycidyl ether of bisphenol A 1,2-dimethoxyethane 1,4-dioxane Divinylbenzene Epoxy resins (uncured) Ethylene dibromide Carcinogen cat 2 Carcinogen cat 2 Corrosive, toxic if contact with skin Di-glycidyl ethers are suspected carcinogens; discussion on hormone disrupting effects Intermediate, associated with styrene Asthmogenic Carcinogen cat 2, environmental toxin 7

8 Ethylene glycols, e.g.: monoethylene glycol MEG diethylene glycol DEG Harmful if swallowed; toxic by ingestion triethylene glycol TEG ethylene glycol-based de-icing fluids ethylene glycol-based antifreeze Ethylene glycol ethers, e.g.: Ethylene glycol ethyl ether (ethoxy ethanol), Ethylene glycol ethyl ether acetate (ethoxy ethyl acetate), Several health hazards including reproductive toxicity Ethylene glycol methyl ether acetate (methoxy ethylacetate), Ethylene glycol methyl ether (methoxy ethanol), Ethylene glycol monobutyl ether (butoxyethanol), Ethylene glycol monoalkyl ether) Ethylene oxide Carcinogen and mutagen cat 2 Furfuryl alcohol Harmful by all routes of exposure; IARC review inadequate data n-hexane Isoprene Isocyanates such as : Carcinogen cat 2, mutagen cat 3, aquatic toxicity Asthmogenic, very reactive Cyanates Methylene diisocyanate (MDI) Methyl isocyanate Diphenyl methane diisocyanate (MDI) Polymethylenene polyphenylisocyanate Toluene diisocyanate (TDI) 8

9 Lecithin Methanol Methyl n-butyl ketone (MBK) Methylcyclohexane Methyl styrene monomer n-methyl Pyrrolidone Morpholine Morpholine ethanol Derived from plant/animal material, non-kosher, BSE/TSE exposure Odor threshold Corrosive, harmful by all routes of exposure, IARC group 3 Reference FOSFA list Nitrobenzene Carcinogen and reproductive toxin cat 3 Nitromethane Nitropropane Noxious cargoes Pesticides- Harmful if swallowed, explosive upon heating Harmful by all routes of exposure Reference NIOP List Reference CEFIC and FOSFA guidelines including biocides, insecticides, fungicides, herbicides, and rodenticides Petroleum Products other than De-aromatized Hydrocarbon Solvents (e.g. ShellSol D-grades) Phenol Phthalates,e.g.: Dioctyl phthalate May contain benzene Mutagen cat 3, toxic by all routes of exposure, corrosive Although some suspect as a human carcinogen; IARC concluded not a human carcinogen (group 3) (effects in lab animals related to peroxisome proliferation) Propylene oxide Carcinogen and mutagen cat 2 9

10 Pygas Pyridine Resins, Curing Agents, Hardeners, Modifiers, and Tackifiers Sulfolane Styrene Monomer Tall Oil and Tall Oil Fatty Acid Tetrahydrofuran Tetralin Toluidine Trichloroacetic acid Trifluoroacetic acid Tricresyl phosphate Vinyl acetate monomer Contains benzene Harmful by all routes of exposure, IARC group 3, low odor threshold; Subject to USP General Chapter 467-Residual Solvents limits; Class 2 Solvents to be Limited Skin irritating and sensitizing properties IARC 2B, tainting, low odor threshold Reference NIOP list Irritating, mutagenic/carcinogenic effects observed in animals IARC 2 B Corrosive Corrosive Under NTP review (carcinogen, reproductive toxin) IARC 2 B Maintenance of heating coils is to be verified in the ship s log. If product is to be heated, heating coils are to be confirmed leak free. If Product is not heated, heating coils are to be drained, dried and blanked off. Safety Information and Incident Reporting. Safety Information: For more detailed information, refer to the SDS or e-sds for reportable spill/release quantities whether in the water, air or ground. Incident Reporting: International Registered Vessels: call Shell International Trading and Shipping in London on (44)

11 Jones Act Vessels: call the Shell 24 hr. incident number at The USA National response center telephone number is For additional marine cargo handling advice or information, contact Captain Eddie Trotter at ( ) Shell Chemical LP PO Box 4407 Houston Texas USA Tel Internet Disclaimer The information contained in this publication is, to the best of our knowledge, true and accurate, but any recommendations or suggestions that may be made are without guarantee, since the conditions of use are beyond our control. Furthermore, nothing contained herein shall be construed as a recommendation to use any product in conflict with existing patents covering any material or its use. Shell Chemicals The expression Shell Chemicals refers to the companies of the Shell Group of companies that are engaged in the chemical businesses. Each of the companies that make up the Shell Group of companies is an independent entity and has its own separate identity. 11