Material Safety Data Sheet

Transcription

1 Material Safety Data Sheet Issuing Date 3/30/2014 Revision Number 0 1. PRODUCT AND COMPANY IDENTIFICATION Product Name Product Code(s) Recommended Use Company Emergency Telephone Number DPD 1B 6741 Test kit reagent. Industrial (not for food or food contact use). Laboratory chemicals. LaMotte Company, Inc. 802 Washington Avenue P.O. Box 329 Chestertown, MD USA 24 Hour Emergency Number (CHEM-TEL): USA, Canada, Puerto Rico Outside North American Continent (Call collect) WARNING! Appearance Clear, colorless 2. HAZARDS IDENTIFICATION Emergency Overview Harmful if swallowed Can cause severe irritation to eyes, skin, and respiratory system May cause burns to the eyes Physical State Liquid Odor Odorless Potential Health Effects Principle Routes of Exposure Acute Toxicity Eyes Skin Inhalation Ingestion Skin and eye contact, Ingestion. Contact with eyes causes severe irritation. Causes irritation, redness, and pain. Risk of serious damage to eyes. May be harmful in contact with skin. Causes irritation. Symptoms can include redness, itching, and pain. May be harmful if inhaled. May cause irritation of respiratory tract. May be harmful if swallowed. Chronic Effects Repeated contact may cause allergic reactions in very susceptible persons Main Symptoms Aggravated Medical Conditions Environmental Hazard Symptoms of allergic reaction may include rash, itching, swelling, trouble breathing, tingling of the hands and feet, dizziness, lightheadedness, chest pain, muscle pain, or flushing. None known. No information available. Page 1 / 10

2 3. COMPOSITION/INFORMATION ON INGREDIENTS CAS-No Weight % - < <0.2 N,N-Diethyl-p-phenylenediamine sulfate < Etidronic acid to 100% Ingredients not specifically listed by name are proprietary to the LaMotte Company, registered under the State of New Jersey Trade Secret protection law, assigned the NJTSRN# p, and may be disclosed only in a medical emergency. 4. FIRST AID MEASURES General Advice Eye Contact Skin Contact Inhalation Ingestion Notes to Physician Protection of First-aiders Do not get in eyes, on skin, or on clothing. Immediately flush with plenty of water. After initial flushing, remove any contact lenses and continue flushing for at least 15 minutes. Immediate medical attention is required. Wash off immediately with soap and plenty of water for at least 15 minutes while removing all contaminated clothing and shoes. Call a physician immediately. Move to fresh air. If breathing is difficult, give oxygen. Consult a physician. Drink plenty of water. Clean mouth with water. Never give anything by mouth to an unconscious person. Consult a physician. May cause sensitization of susceptible persons. Use personal protective equipment. See Section 8 for more detail. Do not use mouth-to-mouth method if victim ingested or inhaled the substance; induce artificial respiration with the aid of a pocket mask equipped with a one-way valve or other proper respiratory medical device. 5. FIRE-FIGHTING MEASURES Flammable Properties Flash Point Suitable Extinguishing Media Explosion Data NFPA Health Hazard 1 HMIS Health Hazard 2 Flammability 0 Flammability 0 Not a fire hazard. Not applicable spray, dry chemical, carbon dioxide (CO 2 ), or foam. Stability 0 Stability 0 Physical and Chemical Hazards N/A Page 2 / 10

3 6. ACCIDENTAL RELEASE MEASURES Personal Precautions Methods for Containment Methods for Cleaning Up Evacuate personnel to safe areas. Ensure adequate ventilation. Use personal protective equipment. Refer to Section 8. Absorb/Cover spill with sodium bicarbonate or sodium carbonate to neutralize, then place in a chemical waste container for later disposal. If local regulations permit, dissolve and rinse to drain with excess water. Following product recovery, flush area with water. 7. HANDLING AND STORAGE Handling Storage Handle in accordance with good industrial hygiene and safety practice. Prevent contact with skin, eyes, and clothing. Do not ingest. Do not eat, drink, or smoke when using this product. Store in original container. Keep containers tightly closed in a dry, cool, and well-ventilated place. Keep away from direct sunlight. Keep away from heat. Keep out of the reach of children. 8. EPOSURE CONTROLS / PERSONAL PROTECTION Exposure Guidelines N,N-Diethyl-p-phenylenediamine sulfate ACGIH TLV OSHA PEL NIOSH IDLH Etidronic acid Personal Protective Equipment Eye/Face Protection Skin and Body Protection Respiratory Protection Hygiene Measures Safety glasses with side-shields. Avoid contact with eyes. Wear latex or nitrile gloves. Maintain adequate ventilation. Handle in accordance with good industrial hygiene and safety practice. Avoid contact with skin, eyes and clothing. Wear suitable gloves and eye/face protection. Wash hands and face before breaks and immediately after handling the product. Page 3 / 10

4 9. PHYSICAL AND CHEMICAL PROPERTIES Appearance Physical State Flash Point Freezing Point Clear, colorless Liquid Not applicable No information available Odor ph Boiling Point/Range Odorless > 100 C/212 F Explosion Limits Not applicable Molecular Weight No data available Vapor Pressure <17 20 C Solubility Soluble in water Vapor Density <1(Air = 1) 10. STABILITY AND REACTIVITY Stability Incompatible Products Conditions to Avoid Stable. Alkalis. Metals. Strong oxidizing agents. Excessive heat. Direct sunlight. Hazardous Decomposition Products Hazardous decomposition products formed under fire conditions -. Carbon oxides (COx). Hazardous Polymerization Hazardous polymerization does not occur. 11. TOICOLOGICAL INFORMATION Acute Toxicity Product Information LD50 Oral VALUE (mg/kg) Product does not present an acute toxicity hazard based on known or supplied information. Oral Rat LD50: 195mg/kg for N,N-Diethyl-p-phenylenediamine sulfate LD50 Oral LD50 Dermal LC50 Inhalation 1500 mg/kg ( Rat ) N,N-Diethyl-p-phenylenediamine sulfate 4640 mg/kg ( Rabbit ) 3000 mg/kg ( Rat ) Etidronic acid 2400 mg/kg ( Rat ) 7940 mg/kg ( Rabbit ) 90 ml/kg ( Rat ) Chronic Toxicity Chronic Toxicity Repeated contact may cause allergic reactions in very susceptible persons. ACGIH IARC NTP OSHA N,N-Diethyl-p-phenylenedia mine sulfate Etidronic acid Page 4 / 10

5 DPD 1B Product Code(s) 6741 Endocrine Disruptor Information This product does not contain any known or suspected endocrine disruptors. EU - Endocrine Disrupters EU - Endocrine Disruptors - Japan - Endocrine Disruptor Candidate List Evaluated Substances Information N,N-Diethyl-p-phenylenediamine sulfate Etidronic acid Ecotoxicity Toxicity to Algae Toxicity to Fish Microtox Daphnia Magna ( Flea) LC mg/l Brachydanio rerio 96 h N,N-Diethyl-p-phenylenedia mine sulfate LC50= 1516 mg/l Lepomis EC50 = 14 mg/l 15 min EC50 = 120 mg/l 72 h macrochirus 96 h LC50= 440 mg/l Leuciscus idus 96 h Etidronic acid LC50= 360 mg/l EC50 = 527 mg/l 48 h Oncorhynchus mykiss 96 h LC50= 563 mg/l Lepomis macrochirus 96 h Log Pow N,N-Diethyl-p-phenylenediamine sulfate C Etidronic acid = ECOLOGICAL INFORMATION Page 5 / 10

6 13. DISPOSAL CONSIDERATIONS Waste Disposal Method Dispose of in accordance with local regulations. Contaminated Packaging Dispose of in accordance with local regulations. RCRA - Halogenated RCRA - P Series Wastes RCRA - F Series Wastes RCRA - K Series Wastes Organic Compounds N,N-Diethyl-p-phenylenedia mine sulfate Etidronic acid TRANSPORT INFORMATION DOT Regulated Proper Shipping Name CORROSIVE LIQUID, ACIDIC, ORGANIC, N.O.S (Phosphonic acid) Hazard Class 8 UN-No 3265 Packing Group III IATA UN-No 3265 Proper Shipping Name CORROSIVE LIQUID, ACIDIC, ORGANIC, N.O.S (Phosphonic acid) Hazard Class 8 Packing Group III IMDG/IMO Proper Shipping Name CORROSIVE LIQUID, ACIDIC, ORGANIC, N.O.S (Phosphonic acid) Hazard Class 8 UN-No 3265 Packing Group III Page 6 / 10

7 15. REGULATORY INFORMATION International Inventories Component ( <1 ) ( <0.2 ) N,N-Diethyl-p-phenyle nediamine sulfate ( <1 ) Etidronic acid ( to 100% ) TSCA DSL EINECS/ELIN ENCS IECSC KECL PICCS AICS CS TSCA EINECS/ELIN KECL CS Present KE TSCA DSL KECL Present KE Present KE Present ; KE Present ENCS KE U.S. Federal Regulations SARA 313 Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product does not contain any chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372. CAS-No Weight % SARA Threshold Values % < <0.2 N,N-Diethyl-p-phenylenediamine sulfate < Etidronic acid to 100% SARA 311/312 Hazard Categories Acute Health Hazard Chronic Health Hazard Fire Hazard Sudden Release of Pressure Hazard Reactive Hazard Yes No No No No Clean Act This product does not contain any substances regulated as pollutants pursuant to the Clean Act (40 CFR and 40 CFR ). Component CWA - Reportable CWA - Toxic Pollutants CWA - Priority Pollutants CWA - Hazardous Quantities Substances ( <1 ) ( <0.2 ) N,N-Diethyl-p-phenylenediamine sulfate ( <1 ) Page 7 / 10

8 Etidronic acid ( to 100% ) Clean Air Act, Section 112 Hazardous Air Pollutants (HAPs) (see 40 CFR 61) This product does not contain any substances regulated as hazardous air pollutants (HAPS) under Section 112 of the Clean Air Act Amendments of CAS-No Weight % N,N-Diethyl-p-phenyle nediamine sulfate <1 Class 1 Ozone Depletors Class 2 Ozone Depletors < < Etidronic acid to 100% CERCLA HAPS data VOC Chemicals Hazardous Substances RQs Extremely Hazardous Substances RQs N,N-Diethyl-p-phenylenediamine sulfate Etidronic acid U.S. State Regulations California Proposition 65 This product does not contain any Proposition 65 chemicals CAS-No California Prop N,N-Diethyl-p-phenylenediamine sulfate Etidronic acid U.S. State Right-to-Know Regulations Massachusetts New Jersey Pennsylvania Illinois Rhode Island N,N-Diethyl-p-phenylenedia mine sulfate Etidronic acid Page 8 / 10

9 International Regulations Mexico - Grade Canada Carcinogen Status Exposure Limits N,N-Diethyl-p-phenylenediamine sulfate Etidronic acid Component ( <1 ) ( <0.2 ) N,N-Diethyl-p-phenylenediamine sulfate ( <1 ) Etidronic acid ( to 100% ) WHMIS Hazard Class Uncontrolled product according to WHMIS classification criteria 1 % Not determined Uncontrolled product according to WHMIS classification criteria 1 % E Not determined Uncontrolled product according to WHMIS classification criteria 16. OTHER INFORMATION NFPA HMIS PPE Transport Symbol Prepared By Regulatory Affairs Department Issuing Date 10/11/2011 Revision Date 13-Oct-2011 Page 9 / 10

10 Revision Note Initial Release Disclaimer The information provided on this MSDS is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guide for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered as a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other material or in any process, unless specified in the text. End of MSDS Page 10 / 10