Material Safety Data Sheet

Transcription

1 Material Safety Data Sheet Issuing Date 30-Apr-2007 MSDS PN: REV. E 1. PRODUCT AND COMPANY IDENTIFICATION Product Name DNA Wash Solution Solution 2 Product Code(s) Trade Name(s) DNA WASH SOLUTION 2 Recommended Use For research use only. Not for use in diagnostic procedures. Supplier Address APPLIED BIOSYSTEMS850 LINCOLN CENTRE DRIVEFOSTER CITY CA USA 94404TELEPHONE: (650) (USA) Emergency Telephone Number CHEMTREC: (INTERNATIONAL) (NORTH AMERICA) 2. HAZARDS IDENTIFICATION WARNING! Emergency Overview FLAMMABLE LIQUID AND VAPOR May be harmful if swallowed, inhaled, or absorbed through skin May cause skin, eye, and respiratory tract irritation May cause drowsiness and dizziness May cause central nervous system depression May cause adverse liver effects May cause adverse kidney effects Appearance Colorless Physical State Liquid Odor Alcohol Potential Health Effects Principle Routes of Exposure Acute Toxicity Eyes Skin Inhalation Ingestion Chronic Effects Inhalation, Skin contact, Eye contact. Irritating to eyes. May be harmful in contact with skin. May cause irritation. May discolor the skin. May be harmful if inhaled. Inhalation of vapors in high concentration may cause irritation of respiratory system. May be harmful if swallowed. Ingestion may cause gastrointestinal irritation, nausea, vomiting and diarrhea. No known effect based on information supplied Page 1 / 8

2 Aggravated Medical Conditions Interactions with Other Chemicals Environmental Hazard Central nervous system. Preexisting eye disorders. Liver disorders. Skin disorders. Kidney disorders. Use of alcoholic beverages may enhance toxic effects. See Section 12 for additional Ecological information. 3. COMPOSITION/INFORMATION ON INGREDIENTS Chemical Name CAS-No Weight % Ethyl alcohol FIRST AID MEASURES General Advice Eye Contact Skin Contact Inhalation Ingestion Notes to Physician Protection of First-aiders In case of injury caused by fire:. Flush with plenty of water immediately. Continue flushing during transport to hospital or medical center. Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. If eye irritation persists, consult a specialist. Wash skin with soap and water. If skin irritation persists, call a physician. Move victim to fresh air. Apply artificial respiration if victim is not breathing. Administer oxygen if breathing is difficult. If symptoms persist, call a physician. Never give anything by mouth to an unconscious person. Clean mouth with water and afterwards drink plenty of water. Do not induce vomiting. If symptoms persist, call a physician. Treat symptomatically. Remove all sources of ignition. Ensure that medical personnel are aware of the material(s) involved, and take precautions to protect themselves. 5. FIRE-FIGHTING MEASURES Flammable Properties Flash Point Suitable Extinguishing Media Unsuitable Extinguishing Media Explosion Data Sensitivity to mechanical impact Sensitivity to static discharge HIGHLY FLAMMABLE: Will be easily ignited by heat, sparks or flames. Containers may explode when heated. Many liquids are lighter than water C Water spray. Foam. Dry powder. Carbon dioxide (CO2). CAUTION: All these products have a very low flash point. Use of water spray when fighting fire may be inefficient. None Yes. Specific Hazards Arising from the Chemical Vapors may form explosive mixtures with air. Vapors may travel to source of ignition and flash back. Most vapors are heavier than air. They will spread along ground and collect in low or confined areas (sewers, basements, tanks). Protective Equipment and Precautions for Firefighters As in any fire, wear self-contained breathing apparatus and full protective gear. Move containers from fire area if you can do it without risk. Page 2 / 8

3 NFPA Health Hazard 2 Flammability 3 Stability 0 Physical and Chemical Hazards - HMIS Health Hazard 2* Flammability 3 Stability 0 Personal Precautions - 6. ACCIDENTAL RELEASE MEASURES Personal Precautions Methods for Containment Methods for Cleaning Up Other Information Ensure adequate ventilation. Remove all sources of ignition. Take precautionary measures against static discharges. Stop leak if you can do it without risk. A vapor suppressing foam may be used to reduce vapors. Absorb or cover with dry earth, sand or other non-combustible material and transfer to containers. Use clean non-sparking tools to collect absorbed material. Dike far ahead of liquid spill for later disposal. Water spray may reduce vapor; but may not prevent ignition in closed spaces. 7. HANDLING AND STORAGE Handling Storage Handle in accordance with good industrial hygiene and safety practice. Wear personal protective equipment. Avoid contact with skin and eyes. Do not breathe vapors or spray mist. Ensure adequate ventilation. Keep away from open flames, hot surfaces and sources of ignition. Take precautionary measures against static discharges. Use only in an area containing flame proof equipment. To avoid ignition of vapors by static electricity discharge, all metal parts of the equipment must be grounded. Keep in a dry, cool and well-ventilated place. Keep in properly labeled containers. Keep away from heat and sources of ignition. 8. EXPOSURE CONTROLS / PERSONAL PROTECTION Exposure Guidelines Chemical Name ACGIH TLV OSHA PEL NIOSH IDLH Ethyl alcohol TWA: 1000 ppm TWA: 1000 ppm TWA: 1900 mg/m 3 TWA: 1000 ppm 3300 ppm NIOSH IDLH: Immediately Dangerous to Life or Health Engineering Measures Personal Protective Equipment Eye/Face Protection Skin and Body Protection Respiratory Protection Hygiene Measures Showers, eyewash stations, and ventilation systems. Safety glasses with side-shields. Protective gloves. In case of inadequate ventilation wear respiratory protection. When using, do not eat, drink or smoke. Regular cleaning of equipment, work area and clothing. Page 3 / 8

4 9. PHYSICAL AND CHEMICAL PROPERTIES Appearance Colorless. Odor Alcohol. Odor Threshold No information available. Physical State Liquid. ph No information available. Flash Point C Autoignition Temperature 363 C / 685 F Decomposition Temperature No information available. Boiling Point/Range No information available. Melting Point/Range No information available. Flammability Limits in Air No information available. Explosion Limits Explosion Limits Upper 19.0 Lower 3.3 Specific Gravity No information available. Water Solubility Soluble in water. Solubility No information available. Evaporation Rate No data available Vapor Pressure 59 Vapor Density 1.6 VOC Content >20% Partition Coefficient (noctanol/water) No information available. 10. STABILITY AND REACTIVITY Stability Incompatible Products Conditions to Avoid Stable under recommended storage conditions. Oxidizing agents. Acids. Bases. Peroxides. Combustible materials. Ammonia. Keep away from open flames, hot surfaces and sources of ignition. Hazardous Decomposition Products Carbon oxides. Hazardous Polymerization Hazardous polymerization does not occur. 11. TOXICOLOGICAL INFORMATION Acute Toxicity Product Information Chronic Toxicity Chemical Name LD50 Oral LD50 Dermal LC50 Inhalation Ethyl alcohol 1501 mg/kg (rat) mg/l ( Rat ) 4 h Target Organ Effects Blood, Central nervous system (CNS), Eyes, Liver, Reproductive System, Respiratory system, Skin. Page 4 / 8

5 Ecotoxicity Ecotoxicity effects of component substances. 12. ECOLOGICAL INFORMATION Chemical Name Toxicity to Algae Toxicity to Fish Microtox Daphnia Magna (Water Flea) Ethyl alcohol LC50= mg/l Oncorhynchus mykiss 96 h LC50= 14.2 mg/l Pimephales promelas 96 h EC50 = mg/l 30 min EC50 = mg/l 5 min EC50 = mg/l 24 h EC50 = 9268 mg/l 48 h Persistence and Degradability No information available. Chemical Name Log Pow Ethyl alcohol DISPOSAL CONSIDERATIONS Waste Disposal Method This material, as supplied, is a hazardous waste according to federal regulations (40 CFR 261). Contaminated Packaging US EPA Waste Number Dispose of in accordance with local regulations. D001 This product contains one or more substances that are listed with the State of California as a hazardous waste. Chemical Name Ethyl alcohol California Hazardous Waste Status Toxic; Ignitable 14. TRANSPORT INFORMATION DOT TDG MEX Proper Shipping Name Ethanol Ethanol,3,,PG Proper Shipping Name Ethanol ETHANOL,3,,PG Proper Shipping Name Etanol Etanol,3, ICAO Page 5 / 8

6 14. TRANSPORT INFORMATION Ethanol solution,3,,pg IATA ERG Code 3L,Ethanol solution,3,pg IMDG/IMO EmS No. F-E, S-D, Ethanol solution,3,pg RID ADR ADN Classification Code F1 Ethanol solution,3,,rid ADR/RID-Labels 3 Classification Code F1 ADR/RID-Labels 3 Proper Shipping Name Ethanol Classification Code F1 Special Provisions 144, 223 Ethanol,3, Hazard Labels 3 Limited Quantity 5 L Page 6 / 8

7 International Inventories 15. REGULATORY INFORMATION TSCA DSL EINECS/ELINCS ENCS CHINA KECL PICCS AICS Listed on inventory. For purposes of 40 CFR , this product is for Research and Development (R&D) Use Only. Complies Does not Comply Does not Comply Complies Does not Comply Complies Complies U.S. Federal Regulations SARA 313 Section 313 of Title of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product does not contain any chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372. SARA 311/312 Hazard Categories Acute Health Hazard Chronic Health Hazard Fire Hazard Sudden Release of Pressure Hazard Reactive Hazard Yes Yes Yes No No Clean Water Act This product does not contain any substances regulated as pollutants pursuant to the Clean Water Act (40 CFR and 40 CFR ) CERCLA This material, as supplied, does not contain any substances regulated as hazardous substances under the Comprehensive Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302) or the Superfund Amendments and Reauthorization Act (SARA) (40 CFR 355). There may be specific reporting requirements at the local, regional, or state level pertaining to releases of this material. U.S. State Regulations California Proposition 65 This product contains the following Proposition 65 chemicals: Chemical Name CAS-No California Prop. 65 Ethyl alcohol Developmental U.S. State Right-to-Know Regulations Chemical Name Massachusetts New Jersey Pennsylvania Illinois Rhode Island Ethyl alcohol X X X X International Regulations Mexico - Grade Serious risk, Grade 3 Chemical Name Carcinogen Status Exposure Limits Ethyl alcohol Mexico: TWA= 1000 ppm Mexico: TWA= 1900 mg/m 3 Page 7 / 8

8 Canada This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations (CPR) and the MSDS contains all the information required by the CPR. WHMIS Hazard Class B2 Flammable liquid D2B Toxic materials 16. OTHER INFORMATION Issuing Date 30-Apr-2007 Revision Note No information available Disclaimer The information provided on this MSDS is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guide for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered as a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other material or in any process, unless specified in the text. End of MSDS Page 8 / 8