SAFETY DATA SHEET according to regulation (EC) No. 1907/2006 (REACH), Appendix II

Transcription

1 SAFETY DATA SHEET according to regulation (EC) No. 1907/2006 (REACH), Appendix II SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier Trade name or designation of the mixture Registration number Synonyms Silicone Grease - SDS number 7609 Product code Ford Internal Ref.: Issue date Version number 2.0 Revision date Supersedes date Product use 08-August August August-2014 Public use 1.2. Relevant identified uses of the substance or mixture and uses advised against Identified uses Greases and Lubricants Uses advised against None known Details of the supplier of the safety data sheet Company name Ford Motor Company Ltd. Address Parts Distribution Centre Royal Oak Way South NN11 8NT Daventry, Northants United Kingdom Telephone number Address Ford-Werke GmbH Edsel-Ford-Str Köln Germany Telephone number HSE@rle.de 1.4 Emergency telephone (mo. - fr. 09:00-16:00) number SECTION 2: Hazards identification 2.1. Classification of the substance or mixture The mixture has been assessed and/or tested for its physical, health and environmental hazards and the following classification applies. Classification according to Directive 67/548/EEC or 1999/45/EC as amended This preparation does not meet the criteria for classification according to Directive 1999/45/EC as amended. Classification according to Regulation (EC) No 1272/2008 as amended This mixture does not meet the criteria for classification according to Regulation (EC) 1272/2008 as amended Label elements Label according to Regulation (EC) No. 1272/2008 as amended Hazard pictograms Signal word Hazard statements Precautionary statements Prevention Response Storage Disposal Supplemental label information EUH210 - Safety data sheet available on request Other hazards The product contains Boric Acid with a concentration of < 0.1%. Ford Internal Ref.: Version #: 2.0 Revision date: 08-August-2014 Issue date: 08-August / 6

2 SECTION 3: Composition/information on ingredients 3.2. Mixtures General information Chemical name % CAS-No. / EC No. REACH Registration No. Index No. Notes Boric Acid < Repr. 1B; H360FD: C 5.5%, Repr. Cat. 2; R60-61: C 5,5 % Classification: DSD: CLP: Repr. Cat. 2;R60-61 Repr. 1B;H360FD CLP: Regulation No. 1272/2008. DSD: Directive 67/548/EEC. Composition comments The full text for all R- and H-phrases is displayed in section 16. SECTION 4: First aid measures General information Ensure that medical personnel are aware of the material(s) involved, and take precautions to protect themselves Description of first aid measures Inhalation Move to fresh air. Call a physician if symptoms develop or persist. Skin contact Eye contact Ingestion 4.2. Most important symptoms and effects, both acute and delayed 4.3. Indication of any immediate medical attention and special treatment needed SECTION 5: Firefighting measures General fire hazards 5.1. Extinguishing media Suitable extinguishing media Unsuitable extinguishing media 5.2. Special hazards arising from the substance or mixture 5.3. Advice for firefighters Special protective equipment for firefighters Special fire fighting procedures Specific methods Wash off with soap and water. Get medical attention if irritation develops and persists. Rinse with water. Get medical attention if irritation develops and persists. Rinse mouth. Get medical attention if symptoms occur. Direct contact with eyes may cause temporary irritation. Treat symptomatically. SECTION 6: Accidental release measures No unusual fire or explosion hazards noted. Water fog. Foam. Dry chemical powder. Carbon dioxide (CO2). Do not use water jet as an extinguisher, as this will spread the fire. Carbon monoxide, carbon dioxide and other hydrocarbon fragments. During fire, gases hazardous to health may be formed. Self-contained breathing apparatus and full protective clothing must be worn in case of fire. Use water spray to cool unopened containers. Use standard firefighting procedures and consider the hazards of other involved materials Personal precautions, protective equipment and emergency procedures For non-emergency Keep unnecessary personnel away. For personal protection, see section 8. personnel For emergency responders Keep unnecessary personnel away. Use personal protection recommended in Section 8 of the SDS Environmental precautions Avoid discharge into drains, water courses or onto the ground Methods and material for containment and cleaning up Stop the flow of material, if this is without risk. Following product recovery, flush area with water. Ford Internal Ref.: Version #: 2.0 Revision date: 08-August-2014 Issue date: 08-August / 6

3 6.4. Reference to other sections For personal protection, see section 8. For waste disposal, see section 13 of the SDS. SECTION 7: Handling and storage 7.1. Precautions for safe handling 7.2. Conditions for safe storage, including any incompatibilities 7.3. Specific end use(s) Greases and Lubricants SECTION 8: Exposure controls/personal protection 8.1. Control parameters Occupational exposure limits Biological limit values Recommended monitoring procedures Derived no-effect level (DNEL) Avoid contact with eyes. Ensure adequate ventilation, especially in confined areas. Avoid release to the environment. Observe good industrial hygiene practices. Store in original tightly closed container. Keep out of the reach of children. Use care in handling/storage. No exposure limits noted for ingredient(s). No biological exposure limits noted for the ingredient(s). Follow standard monitoring procedures. Predicted no effect concentrations (PNECs) 8.2. Exposure controls Appropriate engineering controls Good general ventilation (typically 10 air changes per hour) should be used. Ventilation rates should be matched to conditions. If applicable, use process enclosures, local exhaust ventilation, or other engineering controls to maintain airborne levels below recommended exposure limits. If exposure limits have not been established, maintain airborne levels to an acceptable level. Individual protection measures, such as personal protective equipment General information Personal protection equipment should be chosen according to the CEN standards and in discussion with the supplier of the personal protective equipment. Eye/face protection Skin protection - Hand protection Nitrile rubber Wear safety glasses with side shields (or goggles). Glove thickness 0.4 mm. Break through time >= 480 min. Glove recommendation: Camatril Velours 730 (Kächele-Cama GmbH, source of supply see or comparable product. Hand protection in case of splash contact: Nitrile rubber Glove thickness 0.4 mm. Break through time >= 480 min. Glove recommendation: Camatril Velours 730 (Kächele-Cama GmbH, source of supply see or comparable product. The protective gloves to be used must comply with the specification of EU directive 89/686/EC and the resultant standard EN374. The above given information is based on laboratory test in line with EN374. The recommendation is only valid for the supplied product and the stated application. Special working conditions, like heat or mechanical strain, which deviate from the test conditions, can reduce the protective effect provided by the recommended glove. - Other Wear suitable protective clothing. Respiratory protection Thermal hazards Hygiene measures Environmental exposure controls SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties Appearance In case of insufficient ventilation, wear suitable respiratory equipment. Wear appropriate thermal protective clothing, when necessary. Always observe good personal hygiene measures, such as washing after handling the material and before eating, drinking, and/or smoking. Routinely wash work clothing and protective equipment to remove contaminants. Environmental manager must be informed of all major releases. Paste. Ford Internal Ref.: Version #: 2.0 Revision date: 08-August-2014 Issue date: 08-August / 6

4 Odour Physical state Form Colour Odour threshold ph Melting point/freezing point Initial boiling point and boiling range Flash point Evaporation rate Flammability (solid, gas) Liquid. Solid. Translucent White. Odourless. > C (> F) Cleveland closed cup Upper/lower flammability or explosive limits Flammability limit - lower (%) Flammability limit - upper (%) Vapour pressure Vapour density Relative density Solubility(ies) Solubility (water) Solubility (other) Partition coefficient (n-octanol/water) Auto-ignition temperature Decomposition temperature Viscosity Explosive properties Oxidizing properties 9.2. Other information Density 1.10 g/cm3 VOC (EU) < 1 % VOC (CH) < 3 % SECTION 10: Stability and reactivity Reactivity The product is stable and non-reactive under normal conditions of use, storage and transport Chemical stability Material is stable under normal conditions Possibility of hazardous reactions No dangerous reaction known under conditions of normal use Conditions to avoid Contact with incompatible materials Incompatible materials Strong oxidising agents Hazardous decomposition products SECTION 11: Toxicological information General information May form carbon dioxide, carbon monoxide, and formaldehyde when heated to decomposition. Occupational exposure to the substance or mixture may cause adverse effects. Information on likely routes of exposure Inhalation No adverse effects due to inhalation are expected. Skin contact Eye contact Ingestion Symptoms Information on toxicological effects Acute toxicity No adverse effects due to skin contact are expected. Direct contact with eyes may cause temporary irritation. May cause discomfort if swallowed. However, ingestion is not likely to be a primary route of occupational exposure. Exposure may cause temporary irritation, redness, or discomfort. No data available. Ford Internal Ref.: Version #: 2.0 Revision date: 08-August-2014 Issue date: 08-August / 6

5 Skin corrosion/irritation Serious eye damage/eye irritation Respiratory sensitisation Skin sensitisation Germ cell mutagenicity Carcinogenicity Direct contact with eyes may cause temporary irritation. Reproductive toxicity The product contains Boric Acid with a concentration of < 0.1%. Specific target organ toxicity - single exposure Specific target organ toxicity - repeated exposure Aspiration hazard Mixture versus substance information No information available. Other information The product contains Boric Acid with a concentration of < 0.1%. SECTION 12: Ecological information Toxicity The product is not classified as environmentally hazardous. However, this does not exclude the possibility that large or frequent spills can have a harmful or damaging effect on the environment Persistence and degradability Bioaccumulative potential Partition coefficient n-octanol /water (log Kow) Bioconcentration factor (BCF) Mobility in soil No data available Results of PBT and vpvb assessment The mixture contains no substance that fulfils the criteria of a PBT- or vpvb substance Other adverse effects No other adverse environmental effects (e.g. ozone depletion, photochemical ozone creation potential, endocrine disruption, global warming potential) are expected from this component. SECTION 13: Disposal considerations Waste treatment methods Residual waste Contaminated packaging EU waste code Dispose of in accordance with local regulations. Empty containers or liners may retain some product residues. This material and its container must be disposed of in a safe manner (see: Disposal instructions). Empty containers should be taken to an approved waste handling site for recycling or disposal. The Waste code should be assigned in discussion between the user, the producer and the waste disposal company Disposal methods/information Special precautions Collect and reclaim or dispose in sealed containers at licensed waste disposal site. Dispose in accordance with all applicable regulations. SECTION 14: Transport information ADR Not regulated as dangerous goods. IATA Not regulated as dangerous goods. IMDG Not regulated as dangerous goods. SECTION 15: Regulatory information Safety, health and environmental regulations/legislation specific for the substance or mixture EU regulations Ford Internal Ref.: Version #: 2.0 Revision date: 08-August-2014 Issue date: 08-August / 6

6 Regulation (EC) No. 1005/2009 on substances that deplete the ozone layer, Annex I Regulation (EC) No. 1005/2009 on substances that deplete the ozone layer, Annex II Regulation (EC) No. 850/2004 On persistent organic pollutants, Annex I as amended Regulation (EC) No. 689/2008 concerning the export and import of dangerous chemicals, Annex I, part 1 as amended Regulation (EC) No. 689/2008 concerning the export and import of dangerous chemicals, Annex I, part 2 as amended Regulation (EC) No. 689/2008 concerning the export and import of dangerous chemicals, Annex I, part 3 as amended Regulation (EC) No. 689/2008 concerning the export and import of dangerous chemicals, Annex V as amended Regulation (EC) No. 166/2006 Annex II Pollutant Release and Transfer Registry Regulation (EC) No. 1907/2006, REACH Article 59(1) Candidate List as currently published by ECHA Authorisations Regulation (EC) No. 1907/2006, REACH Annex XIV Substances subject to authorization, as amended Restrictions on use Regulation (EC) No. 1907/2006, REACH Annex XVII Substances subject to restriction on marketing and use as amended Directive 2004/37/EC: on the protection of workers from the risks related to exposure to carcinogens and mutagens at work Directive 92/85/EEC: on the safety and health of pregnant workers and workers who have recently given birth or are breastfeeding Other EU regulations Directive 94/33/EC on the protection of young people at work Directive 98/24/EC on the protection of the health and safety of workers from the risks related to chemical agents at work EU Directive 96/82/EC - Control of Major Accident Hazards: Threshold quantities established for the application of Articles 6 and 7 Other regulations National regulations Follow national regulation for work with chemical agents. VOC (EU): < 1 % Chemical safety assessment SECTION 16: Other information List of abbreviations References Information on evaluation method leading to the classification of mixture Full text of any statements or R-phrases and H-statements under Sections 2 to 15 Revision information Training information Disclaimer The product is classified and labelled in accordance with EC directives or respective national laws. This Safety Data Sheet complies with the requirements of Regulation (EC) No 1907/2006. No Chemical Safety Assessment has been carried out. The classification for health and environmental hazards is derived by a combination of calculation methods and test data, if available. R60 May impair fertility. R61 May cause harm to the unborn child. H360FD May damage fertility. May damage the unborn child. Follow training instructions when handling this material. The information in the sheet was written based on the best knowledge and experience currently available. Ford Internal Ref.: Version #: 2.0 Revision date: 08-August-2014 Issue date: 08-August / 6

7 Attachment to the Safety Data Sheet Product Name: Silicone Grease Page: 1/1 Ford Int. Ref. No.: Print Date: Involved Products: Finiscode Part number 2S5J M1C171 AB Container Size: 100 g I / GBEN