SAFETY DATA SHEET. SECTION 1: Identification of the substance/mixture and of the company/undertaking

Transcription

1 SAFETY DATA SHEET SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier Trade name or designation of the mixture Registration number - Synonyms None. SDS number SDS-CJ30H; CJ31H Product code CJ30H and CJ31H Issue date 07-March-2014 Version number AA Revision date - Supersedes date Relevant identified uses of the substance or mixture and uses advised against Identified uses Research and development. Uses advised against None known Details of the supplier of the safety data sheet Supplier Company name ProZyme, Inc. Address 3832 Bay Center Place Hayward, CA Division Telephone Contact person 1.4. Emergency telephone number SECTION 2: Hazards identification 2.1. Classification of the substance or mixture The mixture has been assessed and/or tested for its physical, health and environmental hazards and the following classification applies. Classification according to Directive 67/548/EEC or 1999/45/EC as amended Classification R43 The full text for all R-phrases is displayed in section 16. Classification according to Regulation (EC) No 1272/2008 as amended Health hazards Skin sensitisation Category 1 H317 - May cause an allergic skin reaction. Hazard summary Physical hazards Not classified for physical hazards. Health hazards May cause sensitisation by skin contact. Occupational exposure to the substance or mixture may cause adverse health effects. Environmental hazards Not classified for hazards to the environment. Specific hazards Main symptoms Sensitisation Label elements Label according to Regulation (EC) No. 1272/2008 as amended Contains: Version No.: AA Revision date: - Issue date: 07-March / 7

2 Hazard pictograms Signal word Hazard statements Warning H317 - May cause an allergic skin reaction. Precautionary statements Prevention P261 - Avoid breathing mist or vapour. P280 - Wear protective gloves. Response P302 + P352 - IF ON SKIN: Wash with plenty of soap and water. P333 + P313 - If skin irritation or rash occurs: Get medical advice/attention. P363 - Wash contaminated clothing before reuse. Storage Store away from incompatible materials. Disposal P501 - Dispose of contents/container in accordance with local/regional/national/international regulations. Supplemental label information Not applicable Other hazards None known. SECTION 3: Composition/information on ingredients 3.2. Mixtures General information Chemical name % CAS-No. / EC No. REACH Registration No. INDEX No. Notes < 0, Classification: DSD: T;R23-23/24/25, C;R34, R43, N;R50-50/ CLP: Acute Tox. 3;H301, Acute Tox. 4;H302, Acute Tox. 3;H311, Skin Corr. 1B;H314, Skin Sens. 1;H317, Acute Tox. 3;H331, STOT SE 3;H335, Aquatic Acute 1;H400, Aquatic Chronic 1;H410 CLP: Regulation No. 1272/2008. DSD: Directive 67/548/EEC. #: This substance has been assigned Community workplace exposure limit(s). Composition comments The full text for all R- and H-phrases is displayed in section 16. SECTION 4: First aid measures General information Ensure that medical personnel are aware of the material(s) involved, and take precautions to protect themselves. Wash contaminated clothing before reuse. Use personal protection recommended in Section 8 of the SDS Description of first aid measures Inhalation Move to fresh air. Call a physician if symptoms develop or persist. Skin contact Wash off with soap and plenty of water. If skin irritation or rash occurs: Get medical advice/attention. For minor skin contact, avoid spreading material on unaffected skin. Eye contact Rinse with water. Get medical attention if irritation develops and persists. Ingestion Rinse mouth. Get medical attention if symptoms occur Most important symptoms Exposure may cause temporary irritation, redness, or discomfort. May cause allergic skin reaction. and effects, both acute and delayed 4.3. Indication of any Provide general supportive measures and treat symptomatically. immediate medical attention and special treatment needed SECTION 5: Firefighting measures General fire hazards 5.1. Extinguishing media Suitable extinguishing media Unsuitable extinguishing media 5.2. Special hazards arising from the substance or mixture No unusual fire or explosion hazards noted. Water fog. Foam. Dry chemical powder. Carbon dioxide (CO2). None known. During fire, gases hazardous to health may be formed Version No.: AA Revision date: - Issue date: 07-March / 7

3 5.3. Advice for firefighters Special protective equipment for firefighters Special fire fighting procedures Self-contained breathing apparatus and full protective clothing must be worn in case of fire. In case of fire and/or explosion do not breathe fumes. Move containers from fire area if you can do so without risk. SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures For non-emergency Keep unnecessary personnel away. Wear appropriate protective equipment and clothing during personnel clean-up. Local authorities should be advised if significant spillages cannot be contained. For emergency responders Keep unnecessary personnel away. Use personal protection recommended in Section 8 of the SDS Environmental precautions Avoid discharge into drains, water courses or onto the ground Methods and material for containment and cleaning up Stop the flow of material, if this is without risk. Large Spills: Dike the spilled material, where this is possible. Absorb in vermiculite, dry sand or earth and place into containers. Following product recovery, flush area with water. Small Spills: Wipe up with absorbent material (e.g. cloth, fleece). Clean surface thoroughly to remove residual contamination Reference to other sections Never return spills in original containers for re-use. For personal protection, see Section 8 of the SDS. For waste disposal, see Section 13 of the SDS. SECTION 7: Handling and storage 7.1. Precautions for safe handling 7.2. Conditions for safe storage, including any incompatibilities 7.3. Specific end use(s) Research and development. SECTION 8: Exposure controls/personal protection 8.1. Control parameters Occupational exposure limits Austria. MAK List Wear appropriate personal protective equipment. Avoid contact with skin. Observe good industrial hygiene practices. Keep container tightly closed. Store between 2 C and 8 C (36 F and 46 F). Do not freeze. Store away from incompatible materials (see section 10 of the SDS). MAK 0,05 mg/m3 Germany. DFG MAK List (advisory OELs). Commission for the Investigation of Health Hazards of Chemical Compounds in the Work Area (DFG) TWA 0,2 mg/m3 Latvia. OELs. Occupational exposure limit values of chemical substances in work environment Form Inhalable fraction. Sodium chloride (CAS ) TWA 5 mg/m3 Lithuania. OELs. Limit s for Chemical Substances, General Requirements (Hygiene Norm HN 23:2007) Sodium chloride (CAS ) TWA 5 mg/m3 Slovenia. OELs. Regulations concerning protection of workers against risks due to exposure to chemicals while working (Official Gazette of the Republic of Slovenia) TWA 0,05 mg/m Version No.: AA Revision date: - Issue date: 07-March / 7

4 Switzerland. SUVA Grenzwerte am Arbeitsplatz Biological limit values Recommended monitoring procedures Derived no-effect level (DNEL) Predicted no effect concentrations (PNECs) Form STEL 0,4 mg/m3 Inhalable dust. TWA 0,2 mg/m3 Inhalable dust. No biological exposure limits noted for the ingredient(s). Follow standard monitoring procedures Exposure controls Appropriate engineering controls Good general ventilation (typically 10 air changes per hour) should be used. Ventilation rates should be matched to conditions. If applicable, use process enclosures, local exhaust ventilation, or other engineering controls to maintain airborne levels below recommended exposure limits. If exposure limits have not been established, maintain airborne levels to an acceptable level. Individual protection measures, such as personal protective equipment General information Use personal protective equipment as required. Personal protection equipment should be chosen according to the CEN standards and in discussion with the supplier of the personal protective equipment. Eye/face protection If contact is likely, safety glasses with side shields are recommended. Skin protection - Hand protection Wear protective gloves. - Other Wear suitable protective clothing. Respiratory protection In case of insufficient ventilation, wear suitable respiratory equipment. Thermal hazards Wear appropriate thermal protective clothing, when necessary. Hygiene measures Always observe good personal hygiene measures, such as washing after handling the material and before eating, drinking, and/or smoking. Routinely wash work clothing and protective equipment to remove contaminants. Contaminated work clothing should not be allowed out of the workplace. Environmental exposure controls SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties Appearance Physical state Liquid. Form Liquid. Colour Clear amber. Odour Odourless. Odour threshold ph Melting point/freezing point Initial boiling point and boiling range Flash point Not applicable. Evaporation rate Flammability (solid, gas) Upper/lower flammability or explosive limits Flammability limit - lower (%) Flammability limit - upper (%) Vapour pressure Vapour density Relative density Solubility(ies) Completely soluble in water Version No.: AA Revision date: - Issue date: 07-March / 7

5 Partition coefficient (n-octanol/water) Auto-ignition temperature Decomposition temperature Viscosity Explosive properties Oxidizing properties 9.2. Other information No relevant additional information available. SECTION 10: Stability and reactivity Reactivity The product is stable and non-reactive under normal conditions of use, storage and transport Chemical stability Material is stable under normal conditions Possibility of hazardous No dangerous reaction known under conditions of normal use. reactions Conditions to avoid Contact with incompatible materials Incompatible materials Strong oxidising agents Hazardous No hazardous decomposition products are known. decomposition products SECTION 11: Toxicological information General information Occupational exposure to the substance or mixture may cause adverse effects. Information on likely routes of exposure Ingestion Expected to be a low ingestion hazard. Inhalation No adverse effects due to inhalation are expected. Skin contact May cause allergic skin reaction. Eye contact Direct contact with eyes may cause temporary irritation. Symptoms Exposure may cause temporary irritation, redness, or discomfort. Sensitisation Information on toxicological effects Acute toxicity Skin corrosion/irritation Serious eye damage/eye irritation Respiratory sensitisation Skin sensitisation Germ cell mutagenicity Carcinogenicity Reproductive toxicity Specific target organ toxicity - single exposure Specific target organ toxicity - repeated exposure Aspiration hazard Mixture versus substance information Other information Due to lack of data the classification is not possible. May cause an allergic skin reaction. Due to lack of data the classification is not possible. SECTION 12: Ecological information Toxicity Not expected to be harmful to aquatic organisms Persistence and No data is available on the degradability of this product. degradability Bioaccumulative potential No data available for this product. Partition coefficient n-octanol/water (log Kow) Bioconcentration factor (BCF) Mobility in soil Version No.: AA Revision date: - Issue date: 07-March / 7

6 12.5. Results of PBT and vpvb assessment Other adverse effects No other adverse environmental effects (e.g. ozone depletion, photochemical ozone creation potential, endocrine disruption, global warming potential) are expected from this component. SECTION 13: Disposal considerations Waste treatment methods Residual waste Contaminated packaging EU waste code Disposal methods/information Dispose of in accordance with local regulations. Empty containers or liners may retain some product residues. This material and its container must be disposed of in a safe manner (see: Disposal instructions). Since emptied containers may retain product residue, follow label warnings even after container is emptied. The Waste code should be assigned in discussion between the user, the producer and the waste disposal company. Collect and reclaim or dispose in sealed containers at licensed waste disposal site. SECTION 14: Transport information ADR RID ADN IATA IMDG Transport in bulk This substance/mixture is not intended to be transported in bulk. according to Annex II of MARPOL 73/78 and the IBC Code SECTION 15: Regulatory information Safety, health and environmental regulations/legislation specific for the substance or mixture EU regulations Regulation (EC) No. 1005/2009 on substances that deplete the ozone layer, Annex I Regulation (EC) No. 1005/2009 on substances that deplete the ozone layer, Annex II Regulation (EC) No. 850/2004 On persistent organic pollutants, Annex I as amended Regulation (EC) No. 689/2008 concerning the export and import of dangerous chemicals, Annex I, part 1 as amended Regulation (EC) No. 689/2008 concerning the export and import of dangerous chemicals, Annex I, part 2 as amended Regulation (EC) No. 689/2008 concerning the export and import of dangerous chemicals, Annex I, part 3 as amended Regulation (EC) No. 689/2008 concerning the export and import of dangerous chemicals, Annex V as amended Regulation (EC) No. 166/2006 Annex II Pollutant Release and Transfer Registry Regulation (EC) No. 1907/2006, REACH Article 59(1) Candidate List as currently published by ECHA Authorisations Regulation (EC) No. 1907/2006, REACH Annex XIV Substances subject to authorisation, as amended Restrictions on use Regulation (EC) No. 1907/2006, REACH Annex XVII Substances subject to restriction on marketing and use as amended Version No.: AA Revision date: - Issue date: 07-March / 7

7 Directive 2004/37/EC: on the protection of workers from the risks related to exposure to carcinogens and mutagens at work Directive 92/85/EEC: on the safety and health of pregnant workers and workers who have recently given birth or are breastfeeding Other EU regulations Directive 96/82/EC (Seveso II) on the control of major-accident hazards involving dangerous substances Directive 98/24/EC on the protection of the health and safety of workers from the risks related to chemical agents at work Directive 94/33/EC on the protection of young people at work Other regulations The product is classified and labelled in accordance with EC directives or respective national laws. This Safety Data Sheet complies with the requirements of Regulation (EC) No 1907/2006. National regulations Chemical safety No Chemical Safety Assessment has been carried out. assessment SECTION 16: Other information List of abbreviations References Information on evaluation method leading to the classification of mixture Full text of any statements or R-phrases and H-statements under Sections 2 to 15 Training information Disclaimer TWA: Time weighted average. HSDB - Hazardous Substances Data Bank The classification for health and environmental hazards is derived by a combination of calculation methods and test data, if available. R22 Harmful if swallowed. R23 Toxic by inhalation. R23/24/25 Toxic by inhalation, in contact with skin and if swallowed. R34 Causes burns. R43 May cause sensitisation by skin contact. R50 Very toxic to aquatic organisms. R50/53 Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. H301 Toxic if swallowed. H302 Harmful if swallowed. H311 Toxic in contact with skin. H314 Causes severe skin burns and eye damage. H317 May cause an allergic skin reaction. H331 Toxic if inhaled. H335 May cause respiratory irritation. H400 Very toxic to aquatic life. H410 Very toxic to aquatic life with long lasting effects. Follow training instructions when handling this material. The information in this (M)SDS was obtained from sources which we believe are reliable but cannot guarantee. Additionally, your use of this information is beyond our control and may be beyond our knowledge. Therefore, the information is provided without any representation or warranty express or implied. Trademarks ProZyme is a trademark or registered trademark of ProZyme Inc., in the United States and other countries Version No.: AA Revision date: - Issue date: 07-March / 7