PRODUCTS FOR PERSONAL CARE, HOUSEHOLD, INDUSTRIAL AND INSTITUTIONAL APPLICATIONS

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1 THE GREEN ISSUE

2 PRODUCTS FOR PERSONAL CARE, HOUSEHOLD, INDUSTRIAL AND INSTITUTIONAL APPLICATIONS

3 THE GREEN ISSUE TABLE OF CONTENT PERLASTAN Sarcosinate Surfactants 6 PERLASTAN Glutamate Surfactants 7 PERLASTAN L-30 Sodium Lauroyl Sarcosinate PERLASTAN SCG 50 Disodium Cocoyl Glutamate PERLASTAN C-30 Sodium Cocoyl Sarcosinate PERLASTAN SCG 50 HC Disodium Cocoyl Glutamate PERLASTAN CH-30 Sodium Cocoyl Sarcosinate PERLASTAN SCG 50 IPF Disodium Cocoyl Glutamate PERLASTAN M-30 Sodium Myristoyl Sarcosinate PERLASTAN SCG 50 ZPF NEW Disodium Cocoyl Glutamate PERLASTAN ON-60V Sodium Oleoyl Sarcosinate PERLASTAN SCG 35 Disodium Cocoyl Glutamate PERLASTAN L PERLASTAN C PERLASTAN CH PERLASTAN M Lauroyl Sarcosine Cocoyl Sarcosine Cocoyl Sarcosine Myristoyl Sarcosine PERLASTAN SCG 35 MS Disodium Cocoyl Glutamate PERLASTAN SLG 38 Sodium Lauroyl Glutamate Sodium Cocoyl Glutamate/ PERLASTAN SC 25 NKW Disodium Cocoyl Glutamate Sodium Cocoyl Glutamate/ PERLASTAN SC 25 NKPF NEW Disodium Cocoyl Glutamate PERLASTAN OCP Oleoyl Sarcosine PERLASTAN SCG 38 CE NEW Disodium Cocoyl Glutamate Amino Acid Based Surfactants 8-11 Applications and Benefits Attributes POLYFIX Zinc Diricinoleate Concentrate POLYFIX ZRC 25 GP NEW POLYFIX ZRC 30 MT 3

4 FROM HUMBLE ROOTS IN LEATHER PROCESSING CHEMICALS SCHILL+SEILACHER S STORY BEGAN IN 1877, WHEN KARL SCHILL AND CHRISTOPH SEILACHER STARTED MANUFACTURING CHEMICALS FOR LEATHER PROCESSING IN HEILBRONN, GERMANY. IN 1925 SCHILL+SEILACHER OPENED A SECOND PRODUCTION SITE 877 Following the Second World War, Schill+Seilacher moved its Heilbronn operation to Böblingen, a suburb of Stuttgart. Although both locations Hamburg and Böblingen are sharing the same name, they are serving different industries and working independently of each other. Schill+Seilacher ventured into the North American market in 1979 with the establishment of Struktol Company of America. SCA is located at the heart of the American tire industry, just outside Akron, Ohio, and majorly supplies the plastic, rubber and tire industries. Schill+Seilacher Chemie GmbH, situated on the banks of the Elbe just south of Dresden was acquired in the early 1990s and serves as both a production and research facility for silicone based chemistry. SNS Nanotech in Hudson, Ohio, specializes in developing complex nanofiber matrices and is the youngest member of the Schill+Seilacher Group. Their proprietary technology enables the fabrication of self-supporting mats that can entrap particles within a nanofiber matrix or encapsulate them within individual 4 nanofibers.

5 WORLDWIDE... TO A GLOBAL PLAYER IN THE PRODUCTION OF INDUSTRIAL PROCESS ADDITIVES. IN HAMBURG TO CATER TO THE EXPANDING NEEDS OF ITS GROWING CUSTOMER BASE AND SECURE BETTER ACCESS TO INTERNATIONAL MARKETS THROUGH THE CITY S BUSTLING PORT. ISO 9001: Our quality guarantee The high quality standard of our products is guaranteed by our certified quality management system (ISO 9001), which integrates our highly qualified application experts, state of the art laboratories and testing equipment, and modern production methods into an effective and continually improving team. ISO 14001: Our commitment to the environment Our commitment to reducing waste and managing energy consumption efficiently has been at the core of our business for many years. By helping us work more efficiently and cost effective, our ISO certification promises better products through environmental responsibility. 5

6 PERLASTAN SARCOSINATE SURFACTANTS PERLASTAN Sarcosinate Surfactants Surfactants based on amino acid N-methyl glycine (sarcosine). Product Name CTFA/INCI Name Active Ingredient Remarks PERLASTAN L-30 Aqua, Sodium Lauroyl Sarcosinate 30 % ECO-Label, Nordic Swan PERLASTAN C-30 Aqua, Sodium Cocoyl Sarcosinate 30 % PERLASTAN CH-30 Aqua, Sodium Cocoyl Sarcosinate 30 % PERLASTAN M-30 Aqua, Sodium Myristoyl Sarcosinate 30 % PERLASTAN ON-60V Aqueous concentrate of Sodium Oleoyl Sarcosinate 60 % ACIDIC FORM Product Name CTFA/INCI Name Active Ingredient Remarks PERLASTAN L Lauroyl Sarcosine 94 % ECO-Label, Nordic Swan PERLASTAN C Cocoyl Sarcosine 94 % PERLASTAN CH Cocoyl Sarcosine 94 % PERLASTAN M Myristoyl Sarcosine 94 % PERLASTAN OCP Oleoyl Sarcosine 90 % 6 ATTRIBUTES n very mild to skin and eyes n lowers irritation potential of severe surfactants n offers buffer capacity at skin ph n provides rich foam and smooth skin feel n resistant to sebum delathering n environmentally friendly n rapid biodegradability n compatible with cationic surfactants n metal corrosion inhibition APPLICATIONS n rinse-off applications for skin care and hair care like body wash, aerosol shampoos, liquid hand soaps, cleansing wipes, shaving gels, surgical scrubs, hair shampoos, hair conditioners n dental and oral hygiene products like toothpastes and mouth washes n eye care products like eye drops, contact lense cleansers

7 PERLASTAN GLUTAMATE SURFACTANTS PERLASTAN Glutamate Surfactants Mild and good foaming surfactants based on amino acid L-glutamic acid. Product Name CTFA/INCI Name Dry Substance Remarks PERLASTAN SCG 50 PERLASTAN SCG 50 HC PERLASTAN SCG 50 IPF Propylene Glycol, Sodium Chloride Isopropyl Alcohol, Sodium Chloride Isopropyl Alcohol, Sodium Chloride 50 %, ph 10 ECO-Label, Nordic Swan 50 %, ph 10 ECO-Label, Nordic Swan 50 %, ph 10 ECO-Label, Nordic Swan PERLASTAN SCG 50 ZPF NEW Propanediol, Sodium Chloride 50 %, ph 10 ECOCERT, NATRUE, ECO-Label, Nordic Swan, ECOGARANTIE PERLASTAN SCG 35 PERLASTAN SCG 35 MS PERLASTAN SLG 38 Propylene Glycol, Sodium Chloride Isopropyl Alcohol, Sodium Chloride Aqua, Disodium Lauroyl Glutamate, Propylene Glycol, Sodium Chloride 35 %, ph 10 ECO-Label, Nordic Swan 35 %, ph 10 ECO-Label, Nordic Swan 38 %, ph 9.5 ECO-Label, Nordic Swan PERLASTAN SC 25 NKW Sodium Cocoyl Glutamate 25 %, ph 6.5 BDIH, ECOCERT, NATRUE, ECO-Label, Nordic Swan, COSMOS, ECOGARANTIE PERLASTAN SC 25 NKPF NEW Sodium Cocoyl Glutamate 25 %, ph 6.5 BDIH, ECOCERT, NATRUE, ECO-Label, Nordic Swan, COSMOS, ECOGARANTIE PERLASTAN SCG 38 CE NEW Sodium Chloride 38 %, ph 10.5 BDIH, ECOCERT, ECO-Label, Nordic Swan, COSMOS ATTRIBUTES n remarkably mild to skin and eyes n lowers irritation potential of severe surfactants n comfortable and soft feeling of the skin during and after use n gentle cleansing n excellent foaming power n offers buffer capacity at skin ph n environmentally friendly n useful for certified natural cosmetics n no tears formulations APPLICATIONS n rinse off products for skin and hair like facial and body cleansers, hair shampoos, baby bath soaps n dermatological products and allergen-controlled medical cleansers 7

8 AMINO ACID BASED SURFACTANTS APPLICATIONS AND BENEFITS LUBRICANTS METAL WORKING FLUIDS ORAL CARE SKIN CARE / HAIR CARE corrosion inhibition under hydrophobic conditions corrosion inhibition under hydrophilic conditions enzyme inhibition effects, neutral taste, BDIH, ECOCERT, NATRUE, COSMOS foam boosting, fine foam texture, mildness, BDIH, ECOCERT, NATRUE, COSMOS, ECO-Label, Nordic Swan INDUSTRIAL PERSONAL CARE LEATHER interaction with metal ions (chromium) AMINO ACID BASED SURFACTANTS PET CARE mildness, foaming, wash off HOUSEHOLD / HOME CARE HARD SURFACE CLEANERS wetting, foaming, withstands alkaline conditions, ECO-Label, Nordic Swan GLASS CLEANERS non-smear, wetting AEROSOL APPLICATIONS corrosion inhibition, wetting CARPET SHAMPOOS non-tacky residues after drying BLEACHING AIDS 8 withstands high ph, compatibility with oxidising agents, thickening effects

9 ATTRIBUTES MILDNESS TO SKIN AND EYES severe mild It was found by cytotoxicity tests that N-acyl amino acids achieve low toxicity for cultured human skin cells. The shorter the fatty acid chain part of amino acid surfactant the milder it behaves to human skin cells. Sodium N-Acyl Glutamate Sodium N-Acyl Sarcosinate Sodium Salt of Fatty Acid C12 C14 C12 C12 C14 Sodium Lauryl Ether Sulfate C12 M. Kanari, Y. Kawasaki and K. Sakamoto J. Soc. Cosmet. Chem., 27, 498 (1993) Sodium Alkyl Sulfate C12 C NR50 (ppm) BUFFER CAPACITY AT PH OF SKIN ph-value Buffer at ph 5.5 Perlastan surfactants generally show at ph of 5 to 6.5 the buffer capacity of an unneutralized carboxylic acid. Especially the ph = 5.5 of the skin is supported during cleansing processes [mmol] acidic or alkaline / [g] active substance Sodium Cocoyl Glutamate (PERLASTAN SC 25 NKW) Sodium Lauroyl Sarcosinate (PERLASTAN L-30) Cocamidopropyl Betaine Sodium Lauryl Sulfate Sodium Laureth-3 Sulfate 9

10 AMINO ACID BASED SURFACTANTS Foam height [cm] Time [min] Sodium Cocoyl Glutamate (PERLASTAN SC 25 NKW) ++ Sodium Lauroyl Sarcosinate (PERLASTAN L-30) ++ Cocamidopropyl Betaine + Sodium Lauryl Sulfate + Sodium Laureth-3 Sulfate Sodium Oleate micro porosity PROMOTES FINE LATHER Foam height and stability is comparable to extremely good foaming surfactants like sulfate and betaine surfactants. Most important factor is that the amino acid based surfactants provides very fine porous, mousse-like foam. Biodegradability BOD/COD 100% 80% 60% 40% 20% 0% > 95% after 28 days > 80% after 10 days Time [days] Sodium Cocoyl Glutamate (PERLASTAN SC 25 NKW) Sodium Lauroyl Sarcosinate (PERLASTAN L-30) Cocamidopropyl Betaine Sodium Lauryl Sulfate Sodium Laureth-3 Sulfate ENVIRONMENTALLY FRIENDLY, HIGHLY AND RAPIDLY BIODEGRADABLE Bacterial decomposition under aerobic (manometric respirometry test; OECD 301F) as well as anaerobic (ISO 11734) conditions takes place faster than with most other types of commercially available anionic surfactants. Sarcosinate and glutamate surfactants reach extremely high degradation values close to 100 %. 10

11 11

12 POLYFIX ZINC DIRICINOLEATE CONCENTRATE ODOUR ABSORBER Aqueous concentrates of zinc ricinoleate activated as its complex with chelating agent. POLYFIX ZRC 25 GP NEW INCI: AQUA, ZINC RICINOLEATE, TETRASODIUM GLUTAMATE DIACETATE, PROPANEDIOL Eco friendly odour absorber concentrate for personal care application. ATTRIBUTES n capable of binding bad odour compounds e.g. thioglycolic acid, isovaleric acid etc. n is readily biodegradable n is water soluble and cold processable n is compatible with non-ionic and anionic surfactants n recommended use level of 1-10 % n will not affect most fragrances n suitable for COSMOS and ECOCERT concepts APPLICATIONS As an additive in odour eliminating cosmetic products where smell originates from perspiration or ingredients. n deodorants roll-on, sprays and sticks n hand sanitizers n foot creams n hair depilatory creams n permanent hair straightening n permanent hair wave 12

13 POLYFIX ZINC DIRICINOLEATE CONCENTRATE POLYFIX ZRC 30 MT Water, Zinc Diricinoleate, Chelating Agent, Alcohol Ethoxylated Broad spectrum odour absorber concentrate for household and I&I use. ATTRIBUTES n eliminates bad odour caused e.g. by amines, mercaptanes, hydrogen sulfides, organic acids, ammonia, thio esters etc. n is readily biodegradable APPLICATIONS Broad application range in homecare and I&I cleaners for eliminating smells caused by urine, excrements, spoiled foods, tabacco etc. n is water soluble and cold processable n is compatible with non-ionic and anionic surfactants n recommended use level of 1-10 % n will not affect most fragrances n active as limescale remover 13

14 SCHILL+SEILACHER AT A GLANCE BÖBLINGEN SPECIALITY CHEMICALS FOR: FIBRES TEXTILES LEATHER PAPER COSMETICS FINE CHEMICALS HAMBURG SPECIALITY CHEMICALS FOR: RUBBER ANTIFOAMS POLYDIS LATEX SILICONES RELEASE AGENTS PIRNA SPECIALITY CHEMICALS FOR: SILICONES PU INDUSTRY PAPER TEXTILES COSMETICS HUDSON / OHIO / USA PRODUCER OF: NANOFIBRE MATRICES STOW / OHIO / USA SPECIALITY CHEMICALS FOR: PLASTICS WOOD COMPOSITES RUBBER LEATHER 14

15

16 Any Questions? Our service team will be pleased to answer any questions and assist you with advice and information. We can also provide you with contact data of our local offices, distributors and agencies. Data sheets and samples of our products are available upon request. For more information please contact: Schill+Seilacher GmbH Schoenaicher Strasse Boeblingen (Germany) Phone: Fax: surfactants@schillseilacher.de Visit also our site: KHM

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