Material Safety Data Sheet NANOPLAS, Inc.

Transcription

1 Material Safety Data Sheet NANOPLAS, Inc Godfrey Ave., SW Grand Rapids, MI Tiny Solutions to Large Problems Issuing date 03-Apr-2014 Revision Date 24-Apr-2014 Version PRODUCT AND COMPANY IDENTIFICATION Product name Product Type Recommended Use MB-200 MOLD BRITE CLEANER Extremely flammable aerosol MOLD CLEANER & DEGREASER Manufacturer: Nanoplas Inc Godfrey Ave. SW Grand Rapids, MI Chemical Emergency Phone Number Chemtrec ID 1195 OSHA Regulatory Status This material is considered hazardous by the OSHA Hazard Communication Standard (29 CFR ) Potential Health Effects 2. HAZARDS IDENTIFICATION Emergency Overview Extremely flammable aerosol Contents under pressure Irritating to respiratory system Irritating to skin Irritating to eyes Intentional misuse by deliberately concentrating and inhaling contents may be harmful or fatal Appearance Clear Physical state Aerosol Odor Solvent Principle Routes of Exposure Acute toxicity Eyes Skin Inhalation Ingestion Chronic Effects Aggravated Medical Conditions Environmental hazard Eye contact. Skin contact. Inhalation. Irritating to eyes. Irritating to skin. Prolonged skin contact may defat the skin and produce dermatitis. May cause frostbite. Irritating to respiratory system. Avoid breathing vapors or mists. Symptoms of overexposure are dizziness, headache, tiredness, nausea, unconsciousness, cessation of breathing. Not an expected route of exposure. Potential for aspiration if swallowed. Ingestion may cause gastrointestinal irritation, nausea, vomiting and diarrhea. No information available. Preexisting eye disorders. Skin disorders. Respiratory disorders. Central Vascular System (CVS). See Section 12 for additional Ecological Information. Page 1 / 6

2 3. COMPOSITION/INFORMATION ON INGREDIENTS This product is considered hazardous by the OSHA Hazard Communication Standard (29 CFR ). Chemical Name CAS-No Weight %* HEPTANE ISOPROPYL ALCOHOL CARBON DIOXIDE DIETHYL PHTHALATE FIRST AID MEASURES General advice Eye contact Skin contact Inhalation Ingestion Notes to physician Avoid contact with skin,eyes, and clothing.avoid breathing, vapors,mist,or gas. Rinse with plenty of water. Consult a physician if irritation persists. Rinse with plenty of water.consult a physician if irritation persists. Move to fresh air. Get medical attention immediately if symptoms occur. Do NOT induce vomiting. Call a physician immediately. Treat symptomatically. 5. FIRE-FIGHTING MEASURES Flammable Properties Extremely flammable aerosol. Flash point 16 F / -9 C Method Based on lowest flashpoint of the products constituent. Suitable Extinguishing Media Hazardous Combustion Products Foam. Dry chemical. Alcohol-resistant foam. Carbon dioxide (CO2). Carbon oxides. Explosion Data Sensitivity to Static Discharge Specific hazards arising from the chemical Protective Equipment and Precautions for Firefighters no. Extremely flammable As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear. NFPA Health Hazard 2 Flammability 4 Stability 0 Physical and chemical hazards - HMIS Health Hazard 2 Flammability 4 Physical Hazard 0 Personal protection B 6. ACCIDENTAL RELEASE MEASURES Personal precautions Environmental precautions Methods for Containment Methods for cleaning up Use personal protective equipment. Remove all sources of ignition. Do not flush into surface water or sanitary sewer system. Prevent further leakage or spillage if safe to do so. Soak up with inert absorbent material. Page 2 / 6

3 Advice on safe handling Technical measures/storage conditions Avoid contact with eyes. Avoid breathing vapors or mists. Contents under pressure. Do not puncture or incinerate cans. Do not stick pin or any other sharp object into opening on top of can. Keep away from heat and sources of ignition. Aerosol Level 3 Exposure Guidelines Chemical Name ACGIH TLV OSHA PEL NIOSH IDLH ISOPROPYL ALCOHOL STEL: 400 ppm TWA: 200 ppm CARBON DIOXIDE DIETHYL PHTHALATE EXPOSURE CONTROLS/PERSONAL PROTECTION STEL: ppm TWA: 5000 ppm TWA: 400 ppm TWA: 980 mg/m 3 (vacated) TWA: 400 ppm (vacated) TWA: 980 mg/m 3 (vacated) STEL: 500 ppm (vacated) STEL: 1225 mg/m 3 TWA: 5000 ppm TWA: 9000 mg/m 3 (vacated) TWA: ppm (vacated) TWA: mg/m 3 (vacated) STEL: ppm (vacated) STEL: mg/m 3 IDLH: 2000 ppm TWA: 400 ppm TWA: 980 mg/m 3 STEL: 500 ppm STEL: 1225 mg/m 3 IDLH: ppm TWA: 5000 ppm TWA: 9000 mg/m 3 STEL: ppm STEL: mg/m 3 TWA: 5 mg/m 3 (vacated) TWA: 5 mg/m 3 TWA: 5 mg/m 3 Other Exposure Guidelines Vacated limits revoked by the Court of Appeals decision in AFL-CIO v. OSHA, 965 F.2d 962 (11th Cir., 1992). Engineering Measures Ensure adequate ventilation. Personal Protective Equipment Eye/Face Protection Skin and body protection Respiratory protection Hygiene measures Safety glasses with side-shields. Protective clothing is recommended but not required. If exposure limits are exceeded or irritation is experienced, NIOSH/MSHA approved respiratory protection should be worn. Do not eat, drink or smoke when using this product. General industrial hygiene practice. Avoid contact with skin, eyes and clothing. Wash hands and face before breaks and immediately after handling the product. Avoid breathing vapors, mist or gas. 9. PHYSICAL AND CHEMICAL PROPERTIES Physical state Aerosol Appearance Clear Odor Solvent Color amber Property Values ph Not applicable Boiling point/boiling range Flash Point -9 C / 16 F Flammability Limits in Air upper flammability limit lower flammability limit Vapor pressure Remarks Methods No information available Based on lowest flashpoint of the products constituent. No data available Not Determined Page 3 / 6

4 Vapor density Specific Gravity Water solubility Viscosity, kinematic Heavier than air No information available No information available No information available Other information VOC Content(%) STABILITY AND REACTIVITY Stability Incompatible products Conditions to Avoid Stable under recommended storage conditions. Strong oxidizing agents. Strong oxidizing agents. Strong bases. Hazardous Decomposition Products Carbon oxides. Fumes. Hazardous Reactions Hazardous Polymerization No information available. Hazardous polymerization does not occur. 11. TOXICOLOGICAL INFORMATION Acute toxicity Product Information Causes skin, eye and respiratory tract irritation. May be harmful if swallowed. Component Information Chemical Name LD50 Oral LD50 Dermal LC50 Inhalation HEPTANE > 5000 mg/kg ( Rat ) > 3160 mg/kg ( Rabbit ) ppm ( Rat ) 4 h ISOPROPYL ALCOHOL = 4396 mg/kg ( Rat ) = mg/kg ( Rabbit ) ppm ( Rat ) 8 h DIETHYL PHTHALATE > mg/kg ( Rat ) Chronic toxicity Carcinogenicity The table below indicates whether each agency has evaluated a listed ingredient as a carcinogen. Chemical Name ACGIH IARC NTP OSHA ISOPROPYL ALCOHOL Group 1 Group 3 X IARC: (International Agency for Research on Cancer) Group 1 - Carcinogenic to Humans Group 3 - Not Classifiable as to Carcinogenicity in Humans OSHA: (Occupational Safety & Health Administration) X - Present Target Organ Effects Central Vascular System (CVS). Eyes. Respiratory system. Skin. 12. ECOLOGICAL INFORMATION Ecotoxicity The environmental impact of this product has not been fully investigated. 13. DISPOSAL CONSIDERATIONS Page 4 / 6

5 Waste Disposal Methods Contaminated packaging Dispose of in accordance with federal, state, and local regulations. Do not re-use empty containers. 14. TRANSPORT INFORMATION DOT Ground IATA IMDG CONSUMER COMMODITY ORM-D or LIMITED QUANTITY UN1950, AEROSOLS, FLAMMABLE, 2.1, LTD. QTY. UN1950, AEROSOLS, 2.1, LTD. QTY. International Inventories TSCA - DSL/NDSL - EINECS/ELINCS - ENCS - IECSC - KECL - PICCS - AICS REGULATORY INFORMATION Chemical Name TSCA DSL/NDSL EINECS/ELI NCS ENCS IECSC KECL PICCS AICS HEPTANE X X X X X X X X ISOPROPYL X X X X X X X X ALCOHOL CARBON DIOXIDE X X X X X X X X DIETHYL PHTHALATE X X X X X X X X TSCA - United States Toxic Substances Control Act Section 8(b) Inventory DSL/NDSL - Canadian Domestic Substances List/Non-Domestic Substances List EINECS/ELINCS - European Inventory of Existing Commercial Chemical Substances/EU List of Notified Chemical Substances ENCS - Japan Existing and New Chemical Substances CHINA - China Inventory of Existing Chemical Substances KECL - Korean Existing and Evaluated Chemical Substances PICCS - Philippines Inventory of Chemicals and Chemical Substances AICS - Australian Inventory of Chemical Substances U.S. Federal Regulations SARA 313 Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product contains a chemical or chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372: Chemical Name SARA Threshold Values % ISOPROPYL ALCOHOL 1.0 SARA 311/312 Hazard Categories Acute Health Hazard Chronic Health Hazard Yes Yes Page 5 / 6

6 Fire Hazard Sudden Release of Pressure Hazard Reactive Hazard Yes no no U.S. State Regulations California Proposition 65 This product does not contain any known Proposition 65 chemicals. U.S. State Right-to-Know Regulations Chemical Name Massachusetts New Jersey Pennsylvania Illinois Rhode Island ISOPROPYL ALCOHOL X X X CARBON DIOXIDE X X X DIETHYL PHTHALATE X X X International Regulations Canada Chemical Name Carcinogen Status Exposure Limits ISOPROPYL ALCOHOL Mexico: TWA 400 ppm Mexico: TWA 980 mg/m 3 Mexico: STEL 500 ppm Mexico: STEL 1225 mg/m 3 CARBON DIOXIDE Mexico: TWA 5000 ppm Mexico: TWA 9000 mg/m 3 Mexico: STEL ppm Mexico: STEL mg/m 3 DIETHYL PHTHALATE Mexico: TWA 5 mg/m 3 Mexico: STEL 10 mg/m 3 This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations (CPR) and the MSDS contains all the information required by the CPR. 16. OTHER INFORMATION Prepared By Nanoplas, Inc Godfrey Ave. Grand Rapids, MI Tel Issuing date 03-Apr-2014 Revision Date 03-Apr-2014 Revision Note No information available. Disclaimer The information provided on this MSDS is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guide for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered as a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other material or in any process, unless specified in the text. End of Material Safety Data Sheet Page 6 / 6