Choice of hydrotrope

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1 Akzo Nobel Surface Chemistry AB Technical information Choice of hydrotrope The key to efficient water based cleaning products Complies with the European Detergent Regulation EC 648/24 Oct 9 (8) 1

2 In order to formulate a clear, stable, liquid cleaning product, containing nonionic surfactants, chelating agents and other electrolytes, a hydrotrope is often required. Many hydrotropes are well-known, however, by choosing the right multifunctional hydrotrope, it is possible to have hydrotropic properties and also improved cleaning efficiency on different kinds of soil, corrosion protection, low foam etc. Selecting the right nonionic surfactant is the first important choice. Choosing the wrong hydrotrope could lead to the selected properties of the nonionic surfactant being destroyed, whereas with the correct combination it is possible to produce extremely efficient water based cleaning product. Hydrotropic effect % Berol 26 TKPP Metasilicate 15% SXS 7% SCS 7% YCE The requisite amount of hydrotrope depends on the amount and cloud point of the nonionic, but also on the amount and types of builders. Oct 9 (8) 2

3 Hydrotropic effect in high concentrated liquid cleaners % Berol 26 X% Na 3 NTA (93%) Y% Hydrotrope* YCE Na 3 NTA, % and AG 622 are the most efficient hydrotropes for high concentrated liquid cleaners. Foaming in Vindan Temp: 2 o C Conc: 5 g/l Water hardness: 4 o dh 8 4 5% Berol 26 TKPP Metasilicate 7% YCE YJH-4 and give low foam when combined with a low foaming nonionic surfactant. If extremely low foam is required, Berol 84 can be used instead of Berol 26 in the formulation. Oct 9 (8) 3

4 Degreasing Black box test % Berol 26 Complexing agent 4 2 SCS Cleaning 1:4 Cleaning 1:6 Cloud point, Soil removal, % typical value SXS A special cationic hydrotrope, such as, is strongly recommended if a good degreasing effect is desired. Corrosion of cast iron Corrosion (-9) % Berol 26 TKPP Metasilicate 4 2 Dilution 1:1 ph ~12,5 Meta + Water 7% YCE YJH-4 Dilution 1:1 ph ~11,5 YCE and give the best corrosion protection on iron at dilution 1:1. * The amount of hydrotrope needed to reach a clarity interval of - ~45 o C. Amount of hydrotrope = product as such, not calculated as active matter Oct 9 (8) 4

5 Disinfectant cleaner By choosing a cationic hydrotrope, such as, it is possible to add a cationic biocide like Arquad 2.1 to the cleaning product. Choice of hydrotrope for liquid cleaners Low foam Hard surfaces Foam boosters YCE XCE YCE Corrosion inhibition High conc formulations Oil/Fat/ Pigment Type of soil Pigment/ Dust Protein Nonionic surfactant Berol 26 C EO Narrow range Hydrotropes XCE YCE SCS SXS Alkyl glucoside Complex coco imino glycinate Complex coco imino dipropionate Octyl imino dipropionate Phosphate ester, K-salt Quaternary fatty methyl amine ethoxylate Sodium Cumene Sulphonate Sodium Xylene Sulphonate Complexing agents TKPP Tetra potassium pyrophosphate Na 3 NTA Trisodium nitrilotriacetatic acid (93%) AG Arquad and Berol are registered trademarks in many countries. All information concerning these products and/or all suggestions for handling and use contained herein are offered in good faith and believed to be reliable. Akzo Nobel Surface Chemistry AB and its affiliates, however, make no warranty as to the accuracy and/or sufficiency of such information and/or suggestions, as to the products merchantability or fitness for any particular purpose, or that any suggested use will not infringe any patent. Nothing contained herein shall be construed as granting or extending any license under any patent. Buyer must determine for himself, by preliminary tests or otherwise, the suitability of these products for his purposes. The information contained herein supersedes all previously issued bulletins on the subject matter covered. The user may forward, distribute and/or photocopy this document only if unaltered and complete, including all of its headers and footers, and should refrain from any unauthorized use. You may not copy this document to a website. Oct 9 (8) 5

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