RAILROAD COMMISSION OF TEXAS APPENDIX E SARA TITLE III LISTED CHEMICALS

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1 RAILROAD COMMISSION OF TEXAS APPENDIX E SARA TITLE III LISTED CHEMICALS

2 WASTE MINIMIZATION IN THE OIL FIELD - APPENDIX E NOTES

3 RAILROAD COMMISSION OF TEXAS LIST OF SARA TITLE III CHEMICALS The American Petroleum Institute (API) and Independent Petroleum Association of America (IPAA) have developed a generic report approach for oil and gas operators' use in complying with the requirements of Title III of SARA (Superfund Amendments and Reauthorization Act), also known as the Emergency Planning and Community Right-to- Know Act of API/IPAA developed two generic reports to assist an E&P operator in complying with the reporting requirements. The following Generic List of Hazardous Chemical Categories is provided as Exhibit A in the API/IPAA document of November, 1988, titled: Superfund Amendments and Reauthorization Act of 1986 Emergency Planning and Community Right-to-Know Act Sections 311 and 312 Generic List and Inventory for the Oil and Gas Exploration and Production Industry E-1

4 WASTE MINIMIZATION IN THE OIL FIELD - APPENDIX E NOTES E-2

5 RAILROAD COMMISSION OF TEXAS SARA TITLE III 311 GENERIC LIST OF HAZARDOUS* CHEMICAL CATEGORIES FOR THE OIL AND GAS EXPLORATION AND PRODUCTION INDUSTRY Acids, Inorganic Hydrochloric acid (<30%) (CAS# ) Acids, Inorganic - Hydrofluoric Acid Hydrofluoric acid (<12%) (CAS# ) Acids, Inorganic - Sulfuric Acid Sulfuric Acid (CAS# ) Acids, Organic Acetic acid (CAS# ) Acetic anhydride (CAS# ) Benzoic acid (CAS# ) Citric acid (CAS# ) Formic acid (CAS# ) Acrylamide Monomer (CAS# ) Alkalinity and ph Control Materials Calcium hydroxide (CAS# ) Potassium hydroxide (CAS# ) Soda ash (CAS# ) Sodium bicarbonate (CAS# ) Sodium carbonate (CAS# ) Sodium hydroxide (CAS# ) Biocides Amines Glutaraldehyde (CAS# ) Isopropanol (CAS# ) Thiozolin Biocides - Acrolein Acrolein (CAS# ) Reactivity, Reactivity, Fire, Reactivity,, Delayed (Chronic) Reactivity, Fire,, Delayed (Chronic) Fire, Sudden Release of Pressure, Reactivity, Biocides - Anhydrous Ammonia Anhydrous ammonia Sudden Release of Pressure, Note: The list refers to the chemicals as "hazardous;" however, for the purposes of SARA Title III, "hazardous" indicates any chemical required to have a material data safety sheet (MSDS). All chemicals listed in this appendix are not necessarily hazardous as defined by RCRA. E-3

6 WASTE MINIMIZATION IN THE OIL FIELD - APPENDIX E Biocides - Formaldehyde Formaldehyde Breakers, Emulsion/Gel Ammonium persulfate (CAS# ) Benzoic acid (CAS# ) Enzyme Sodium acetate (CAS# ) Sodium persulfate (CAS# ) Buffers, ph Sodium acetate (CAS# ) Sodium bicarbonate (CAS# ) Sodium carbonate (CAS# ) Sodium diacete Calcium Compounds Calcium bromite (CAS# ) Calcium hypochlorite (CAS# ) Calcium oxide (CAS# ) Gypsum (CAS# ) Lime (CAS# ) Cement (CAS# ) Cement Additives - Accelerators Calcium chloride (CAS# ) Gypsum (CAS# ) Potassium chloride (CAS# ) Sodium chloride (CAS# ) Sodium metasiliate Cement Additives - Fluid Loss Cellulose polymer Latex Cement Additives - Miscellaneous Cellulose flakes (CAS# ) Coated aluminum Gilsonite (CAS# ) Lime (CAS# ) Long chain alcohols Cement Additives - Retarders Cellulose polymer Lignosulfonates Fire,, Delayed (Chronic) Fire, E-4

7 RAILROAD COMMISSION OF TEXAS Cement Additives - Weight Modification Barite (CAS# ) Bentonite Diatomaceous earth (CAS# ) Fly ash Glass beads Hematite (CAS# ) Ilmenite Pozzolans Chlorine Gas Corrosion Inhibitors 2-Butoxyethanol 4-4' Methylene dianiline (CAS# ) Acetylenic alcohols Amine formulations Ammonium bisulfite (CAS# ) Gelatin Ironite sponge (CAS# ) Sodium chromate (CAS# ) Sodium dichromate (CAS# ) Sodium polyacrylate Zinc carbonate (CAS# ) Zinc lignosulfonate Zinc oxide (CAS# ) Crosslinkers (Polymer Linking) Boron compounds Organo-metallic complexes Defoaming Agents Aluminum stearate Fatty acid salt formation Mixed alcohols Silicones Tributylphosphate (CAS# ) Deflocculants Acrylic polymer Calcium lignosulfonate Chrome-free lignosulfonate Chromium lignosulfonate Iron lignosulfonate Quebracho Sodium acid pyrophosphate (SAPP) Sodium hexametaphosphate (CAS# ) Sodium phosphate (oilfos) Sodium tetraphosphate Sodium tripolyphosphate (STP) Styrene, maleic anhydride co-polymer salt Sulfo-methylated tannin Sudden Release of Pressure, Reactivity,, Delayed (Chronic) Fire,, Delayed (Chronic) Fire,, Delayed (Chronic) E-5

8 WASTE MINIMIZATION IN THE OIL FIELD - APPENDIX E Detergents/Foamers Amphoteric surfactant formulation Detergents Ethoxylated phenol Explosives Charged well jet perforating gun, Class C explosives Detonators, Class A explosives Explosive power device, Class B Filtration Control Agents/Flocculants Acrylamide AMPS copolymer Aniline formaldehyde copolymer hydrochlorite Anionic polyacrylamide Causticized leonardite Leonardite Partially hydrolyzed polyacrylamide Polyaklanolamine ester Polyamine acrylate Polyanionic cellulose Potassium lignite Preserved starch Sodium carboxymethyl cellulose (CAS# ) Starch (CAS# ) Sulfomethylated phenol formaldehyde Vinylsulfonate copolymer Fluoride Generating Compounds Ammonium bifluoride (CAS# ) Ammonium fluoride (CAS# ) Friction Reducers Acrylamide methacrylate copolymers Sulfonates Fire, Sudden Release of Pressure Fuels Acetylene gas (CAS# ) Diesel (CAS# ) Fuel oil Gasoline (CAS# ) Kerosene (CAS# ) Propane (CAS# ) Fire, Sudden Release of Pressure, Immediate (Acute), Delayed (Chronic) Gelling Agents Cellulose and guar derivatives Gel Stabilizers Sulfites Thiosulfates Heat Transfer Fluids Ethylene glycol (CAS# ) Freon, Delayed (Chronic) E-6

9 RAILROAD COMMISSION OF TEXAS Herbicides Hydraulic Fluids Hydrogen Sulfide (CAS# ) Inert Gases Carbonate dioxide (CAS# ) Nitrogen (CAS# ) Lost Circulation Materials Cane Fibers Cedar fibers Cellophane fibers Corn cob Cottonseed hulls Mica (CAS# ) Nut Shells Paper Rock wool Sawdust Lubricants, Drilling Mud Additives Graphite (CAS# ) Mineral oil formulations Organo-fatty acid salt Vegetable oil formulations Walnut shells Lubricants, Engine Grease Motor oil Miscellaneous Drilling Additives Diatomaceous earth (CAS# ) Oxalic acid (CAS# ) Potassium acetate (CAS# ) Zinc bromide (CAS# ) Odorants Mercaptans, aliphatic Fire, Fire, Sudden Release of Pressure, Immediate (Acute), Delayed (Chronic) Fire, Oil-Based Mud Additives Amid polymer formulations Amine treated lignite Asphalt Diesel (CAS# ) Gilsonite (CAS# ) Mineral Oil Organophilic clay Organophilic hectorite Petroleum distillate (CAS# ) Polyethylene powder Polymerized organic acids Sulfonate surfactant Fire,, Delayed (Chronic) E-7

10 WASTE MINIMIZATION IN THE OIL FIELD - APPENDIX E Paint and Paint Thinner Pipe Joint Compound Preservatives Dithiocarbamates Isothiazions Paraformaldehyde (CAS# ) Produced Hydrocarbons Condensate Crude oil (CAS# ) Natural gas Proppants Bauxite (CAS# ) Resin coated sand Zirconium proppant Resin and Resin Solutions Melamine resins Phenolic resins Polyglycol resins Salt Solutions Aluminum chloride (CAS# ) Ammonium chloride (CAS# ) Calcium bromide (CAS# ) Calcium chloride (CAS# ) Calcium sulfate (CAS# ) Ferrous sulfate (CAS# ) Potassium chloride (CAS# ) Sodium chloride (CAS# ) Sodium sulfate (CAS# ) Zinc bromide (CAS# ) Zinc chloride (CAS# ) Zinc sulfate Fire, Delayed (Chronic) Delayed (Chronic), Delayed (Chronic) Fire, Sudden Release of Pressure, Immediate (Acute), Delayed (Chronic) Fire, Scale Inhibitors Fire,, Delayed (Chronic) Ethylenediaminetetraacetic acid (EDTA) (CAS# ) Inorganic phosphates Nitrilotriacetic acid (NTA) (CAS# ) Organic phosphates Phosphonates Polyacrylate Polyphosphates Shale Control Additives Hydrolyzed polyacrylamide polymer Organo-aluminum complex Polyacrylate polymer Sulfonated asphaltic residuum E-8

11 RAILROAD COMMISSION OF TEXAS Silica, Delayed (Chronic) Solvents Fire,, Delayed (Chronic) 1,1,1 - Trichloroethane (CAS# ) Acetone (CAS# ) Aliphatic hydrocarbons t-butyl alcohol (CAS# ) Carbon tetrachloride (CAS# ) Chloroform (CAS#67-6-3) Diacetone alcohol (CAS# ) Ethylene glycol monobutyl ether (CAS# ) Kerosene (CAS# ) Isopropanol (CAS# ) Methyl ethyl ketone (MEK)(CAS# ) Methyl isobutyl ketone (MIBK) (CAS# ) Methylene chloride (CAS# ) Methanol (CAS# ) Naphtha (CAS# ) Toluene (CAS# ) Turpentine (CAS# ) Xylene (CAS# ) Spotting Fluids Non-oil base spotting fluid Oil base spotting fluid (diesel oil base) Oil base spotting fluid (mineral oil base) Sulfonated vegetable ester Sulphur Dioxide (CAS# ) Surfactants - Corrosive Alcohol ether sulfates Amines Quaternary polyamine Sulfonic acid Surfactants - Ethylene Diamine Ethylene Diamine (CAS# ) Surfactants - Flammable Amines Ammonium salts Fatty alcohols Isopropanol (CAS# ) Methanol (CAS# ) Oxyalkylated phenols Petroleum naphtha (CAS# ) Sulfonates Surfactants - Miscellaneous Amine salts Glycols Fire,, Delayed (Chronic) Sudden Release of Pressure, Immediate (Acute), Delayed (Chronic), Delayed (Chronic) Fire, Fire,, Delayed (Chronic) E-9

12 WASTE MINIMIZATION IN THE OIL FIELD - APPENDIX E Temporary Blocking Agents Benzoic acid (CAS# ) Naphthalene (CAS# ) Petroleum wax polymers Sodium chloride (CAS# ) Tracers Ammonium nitrate Potassium nitrate Viscosifiers Attapulgite Bentonite Guar gum (CAS# ) Sepiolite Xanthan gum Weight Materials Barite (CAS# ) Calcium carbonate (CAS# ) Galena Hematite (CAS# ) Iron carbonate Siderite Welding Materials Solder Welding Rods Fire E-10

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