Safety Data Sheet according to Regulation (EC) No 1907/2006

Transcription

1 Safety Data Sheet according to Regulation (EC) No 1907/2006 Page 1 of 15 LOCTITE SF 7400 known as LOCTITE ml Blister M/L SDS No. : V007.0 Revision: printing date: Replaces version from: SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier LOCTITE SF 7400 known as LOCTITE ml Blister M/L Contains: 1.2. Relevant identified uses of the substance or mixture and uses advised against Intended use: Coating 1.3. Details of the supplier of the safety data sheet Henkel Limited 2 Bishop Square Business Park AL109EY Herfordshire Hatfield Great Britain Phone: Fax-no.: ua-productsafety.uk@henkel.com 1.4. Emergency telephone number 24 Hours Emergency Tel: +44 (0) Classification of the substance or mixture SECTION 2: Hazards identification Classification (CLP): Flammable liquids Category 2 H225 Highly flammable liquid and vapor. Serious eye irritation Category 2 H319 Causes serious eye irritation. Specific target organ toxicity - single exposure Category 3 H336 May cause drowsiness or dizziness. Target organ: Central Nervous System Specific target organ toxicity - single exposure Category 3 H335 May cause respiratory irritation. Target organ: respiratory tract irritation 2.2. Label elements Label elements (CLP):

2 SDS No.: V007.0 LOCTITE SF 7400 known as LOCTITE ml Blister M/L Page 2 of 15 Hazard pictogram: Signal word: Hazard statement: Supplemental information Precautionary statement: Danger H225 Highly flammable liquid and vapor. H319 Causes serious eye irritation. H335 May cause respiratory irritation. H336 May cause drowsiness or dizziness. EUH066 Repeated exposure may cause skin dryness or cracking. "***" ***For consumer use only: P101 If medical advice is needed, have product container or label at hand. P102 Keep out of reach of children. P501 Dispose of waste and residues in accordance with local authority requirements*** Precautionary statement: Prevention Precautionary statement: Response Precautionary statement: Storage P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. P261 Avoid breathing vapours. P280 Wear protective gloves/protective clothing. P337+P313 If eye irritation persists: Get medical advice/attention. P403+P235 Store in a well-ventilated place. Keep cool Other hazards None if used properly. Not fulfilling Persistent, Bioaccumulative and Toxic (PBT), very Persistent and very Bioaccumulative (vpvb) criteria Mixtures chemical description: Solvent based coating SECTION 3: Composition/information on ingredients Declaration of the ingredients according to CLP (EC) No 1272/2008: Hazardous components 2-Naphthalenol, 1-[[4- (phenylazo)phenyl]azo]-, ar-heptyl ar',ar''- Me derivs EC Number REACH-Reg No content Classification 25- < 50 % Flam. Liq. 3 H226 STOT SE 3 H < 50 % Flam. Liq. 2 H225 Acute Tox. 4; Inhalation H332 Eye Irrit. 2 H319 STOT SE 3 H ,1- < 1 % Carc. 2 H351 Repr. 2 H361 Aquatic Chronic 4 H413 For full text of the H - statements and other abbreviations see section 16 "Other information".

3 SDS No.: V007.0 LOCTITE SF 7400 known as LOCTITE ml Blister M/L Page 3 of 15 Substances without classification may have community workplace exposure limits available Description of first aid measures Inhalation: Move to fresh air. If symptoms persist, seek medical advice. Skin contact: Rinse with running water and soap. Obtain medical attention if irritation persists. SECTION 4: First aid measures Eye contact: Rinse immediately with plenty of running water (for 10 minutes), seek medical attention from a specialist. Ingestion: Rinse mouth, drink 1-2 glasses of water, do not induce vomiting, consult a doctor Most important symptoms and, both acute and delayed RESPIRATORY: Irritation, coughing, shortness of breath, chest tightness. EYE: Irritation, conjunctivitis. Repeated exposure may cause skin dryness or cracking. Vapors may cause drowsiness and dizziness Indication of any immediate medical attention and special treatment needed See section: Description of first aid measures 5.1. Extinguishing media Suitable extinguishing media: Carbon dioxide, foam, powder SECTION 5: Firefighting measures Extinguishing media which must not be used for safety reasons: High pressure waterjet 5.2. Special hazards arising from the substance or mixture In the event of a fire, carbon monoxide (CO), carbon dioxide (CO2) and nitrogen oxides (NOx) can be released Advice for firefighters Wear self-contained breathing apparatus and full protective clothing, such as turn-out gear. Additional information: In case of fire, keep containers cool with water spray. SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures Wear protective equipment. Avoid contact with skin and eyes. Ensure adequate ventilation Environmental precautions Do not empty into drains / surface water / ground water.

4 SDS No.: V007.0 LOCTITE SF 7400 known as LOCTITE ml Blister M/L Page 4 of Methods and material for containment and cleaning up For small spills wipe up with paper towel and place in container for disposal. For large spills absorb onto inert absorbent material and place in sealed container for disposal. Dispose of contaminated material as waste according to Section Reference to other sections See advice in section Precautions for safe handling Use only in well-ventilated areas. Vapours should be extracted to avoid inhalation. Keep away from sources of ignition - no smoking. Avoid skin and eye contact. See advice in section 8 Hygiene measures: Wash hands before work breaks and after finishing work. Do not eat, drink or smoke while working. Good industrial hygiene practices should be observed. SECTION 7: Handling and storage 7.2. Conditions for safe storage, including any incompatibilities Store in a cool, well-ventilated place. Keep away from heat and direct sunlight. Refer to Technical Data Sheet 7.3. Specific end use(s) Coating

5 SDS No.: V007.0 LOCTITE SF 7400 known as LOCTITE ml Blister M/L Page 5 of 15 SECTION 8: Exposure controls/personal protection 8.1. Control parameters Occupational Exposure Limits Valid for Great Britain Ingredient [Regulated substance] ppm mg/m 3 Short term exposure limit category / Remarks Short Term Exposure Limit (STEL): [BUTYL ACETATE] [BUTYL ACETATE] Time Weighted Average (TWA): Short Term Exposure Limit (STEL): Skin designation: Time Weighted Average (TWA): Time Weighted Average (TWA): Short Term Exposure Limit (STEL): Can be absorbed through the skin. Indicative Indicative Regulatory list EH40 WEL EH40 WEL EH40 WEL EH40 WEL EH40 WEL ECTLV ECTLV Occupational Exposure Limits Valid for Ireland Ingredient [Regulated substance] ppm mg/m 3 Short term exposure limit category / Remarks Time Weighted Average (TWA): [BUTYL ACETATE] [BUTYL ACETATE] [METHYL ISOBUTYL KETONE (MIBK)] [METHYL ISOBUTYL KETONE (MIBK)] [METHYL ISOBUTYL KETONE (MIBK)] Short Term Exposure Limit (STEL): Time Weighted Average (TWA): Short Term Exposure Limit (STEL): Skin designation: Time Weighted Average (TWA): Short Term Exposure Limit (STEL): Indicative OELV Indicative OELV Can be absorbed through the skin. Indicative Indicative Regulatory list IR_OEL IR_OEL IR_OEL IR_OEL IR_OEL ECTLV ECTLV

6 SDS No.: V007.0 LOCTITE SF 7400 known as LOCTITE ml Blister M/L Page 6 of 15 Predicted No-Effect Concentration (PNEC): Name on list Environmental Compartment Exposure period mg/l ppm mg/kg others aqua 0,18 mg/l (freshwater) aqua (marine 0,018 mg/l water) aqua 0,36 mg/l (intermittent releases) sewage 35,6 mg/l treatment plant (STP) sediment 0,981 (freshwater) mg/kg sediment 0,0981 (marine water) mg/kg soil 0,0903 mg/kg Air Predator aqua (freshwater) aqua (marine water) sediment (freshwater) sediment (marine water) soil sewage treatment plant (STP) aqua (intermittent releases) 0,6 mg/l 0,06 mg/l 27,5 mg/l 1,5 mg/l 8,27 mg/kg 0,83 mg/kg 1,3 mg/kg Remarks

7 SDS No.: V007.0 LOCTITE SF 7400 known as LOCTITE ml Blister M/L Page 7 of 15 Derived No-Effect Level (DNEL): Name on list Application Area Route of Exposure Health Effect Workers inhalation Long term Workers inhalation Acute/short term Workers inhalation Long term local Workers inhalation Acute/short term local Workers dermal Long term Workers dermal Acute/short term inhalation Long term inhalation inhalation dermal dermal oral oral inhalation Acute/short term Acute/short term local Long term Acute/short term Long term Acute/short term Long term local Workers Inhalation Acute/short term Workers Inhalation Acute/short term local Workers Inhalation Long term Workers Inhalation Long term local Workers dermal Long term Inhalation Inhalation Inhalation Inhalation dermal Acute/short term Acute/short term local Long term Long term local Long term Exposure Time 300 mg/m3 600 mg/m3 300 mg/m3 600 mg/m3 11 mg/kg 11 mg/kg 35,7 mg/m3 300 mg/m3 300 mg/m3 6 mg/kg 6 mg/kg 2 mg/kg 2 mg/kg 35,7 mg/m3 208 mg/m3 208 mg/m3 83 mg/m3 83 mg/m3 11,8 mg/kg 155,2 mg/m3 155,2 mg/m3 14,7 mg/m3 14,7 mg/m3 4,2 mg/kg Remarks

8 SDS No.: V007.0 LOCTITE SF 7400 known as LOCTITE ml Blister M/L Page 8 of 15 oral Long term 4,2 mg/kg Biological Exposure Indices: Ingredient [Regulated substance] Parameters 4- methylpentan -2-one Biological specimen Urine Sampling time Conc. Basis of biol. exposure index Sampling time: End of UKEH40BMG shift. V Remark Additional Information 8.2. Exposure controls: Engineering controls: Ensure good ventilation/extraction. Respiratory protection: Ensure adequate ventilation. An approved mask or respirator fitted with an organic vapour cartridge should be worn if the product is used in a poorly ventilated area Filter : A (EN 14387) Hand protection: Chemical-resistant protective gloves (EN 374). Suitable materials for short-term contact or splashes (recommended: at least protection index 2, corresponding to > 30 minutes permeation time as per EN 374): nitrile rubber (NBR; >= 0.4 mm thickness) Suitable materials for longer, direct contact (recommended: protection index 6, corresponding to > 480 minutes permeation time as per EN 374): nitrile rubber (NBR; >= 0.4 mm thickness) This information is based on literature references and on information provided by glove manufacturers, or is derived by analogy with similar substances. Please note that in practice the working life of chemical-resistant protective gloves may be considerably shorter than the permeation time determined in accordance with EN 374 as a result of the many influencing factors (e.g. temperature). If signs of wear and tear are noticed then the gloves should be replaced. Eye protection: Safety glasses with sideshields or chemical safety goggles should be worn if there is a risk of splashing. Protective eye equipment should conform to EN166. Skin protection: Wear suitable protective clothing. Protective clothing should conform to EN for liquid splashes or to EN for dusts. Advices to personal protection equipment: The information provided on personal protective equipment is for guidance purposes only. A full risk assessment should be conducted prior to using this product to determine the appropriate personal protective equipment to suit local conditions. Personal protective equipment should conform to the relevant EN standard. SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties Appearance liquid red Odor characteristic Odour threshold ph Melting point Solidification temperature Not determined

9 SDS No.: V007.0 LOCTITE SF 7400 known as LOCTITE ml Blister M/L Page 9 of 15 Initial boiling point Flash point Evaporation rate Flammability Explosive limits lower upper Vapour pressure (20 C (68 F)) Relative vapour density: Density (20 C (68 F)) Bulk density Solubility Solubility (qualitative) (Solvent: Water) Partition coefficient: n-octanol/water Auto-ignition temperature Decomposition temperature Viscosity Viscosity (kinematic) Explosive properties Oxidising properties C ( F) 14 C (57.2 F) 1,7 %(V) 10,4 %(V) 10,7 mbar 0,97 g/cm3 Not miscible 9.2. Other information SECTION 10: Stability and reactivity Reactivity Reaction with strong acids. Reacts with strong oxidants Chemical stability Stable under recommended storage conditions Possibility of hazardous reactions See section reactivity Conditions to avoid No decomposition if used according to specifications Incompatible materials See section reactivity Hazardous decomposition products Irritating organic vapours.

10 SDS No.: V007.0 LOCTITE SF 7400 known as LOCTITE ml Blister M/L Page 10 of 15 SECTION 11: Toxicological information toxicological information: Prolonged or repeated contact may cause skin irritation Information on toxicological Acute oral toxicity: 2-Naphthalenol, 1-[[4- (phenylazo)phenyl]azo]-, ar-heptyl ar',ar''-me derivs Species Method LD mg/kg rat OECD Guideline 423 (Acute Oral toxicity) LD mg/kg rat OECD Guideline 401 (Acute Oral Toxicity) LD50 > mg/kg rat Acute dermal toxicity: 2-Naphthalenol, 1-[[4- (phenylazo)phenyl]azo]-, ar-heptyl ar',ar''-me derivs Species Method LD50 > mg/kg rabbit OECD Guideline 402 (Acute Dermal Toxicity) LD50 > mg/kg rat OECD Guideline 402 (Acute Dermal Toxicity) LD50 > mg/kg rabbit not specified Acute inhalative toxicity: Test atmosphere Exposure time Species Method LC50 > 23,4 mg/l mist 4 h rat OECD Guideline 403 (Acute Inhalation Toxicity) Acute 11 mg/l vapour Expert judgement toxicity estimate (ATE) LC50 8,2-16,4 mg/l vapour 4 h rat OECD Guideline 403 (Acute Inhalation Toxicity) Skin corrosion/irritation: Solvent may remove essential oils from the skin making it susceptible to attack from other chemicals. Result Exposure time Species Method not irritating rabbit OECD Guideline 404 (Acute Dermal Irritation / Corrosion) not irritating 4 h rabbit OECD Guideline 404 (Acute Dermal Irritation / Corrosion)

11 SDS No.: V007.0 LOCTITE SF 7400 known as LOCTITE ml Blister M/L Page 11 of 15 Serious eye damage/irritation: Result Exposure Species Method time not irritating rabbit OECD Guideline 405 (Acute Eye Irritation / Corrosion) slightly irritating rabbit OECD Guideline 405 (Acute Eye Irritation / Corrosion) Respiratory or skin sensitization: The mixture is classified based on threshold limits referring to the classified substances present in the mixture. Result Test Species Method not sensitising not sensitising Guinea pig maximisation test Guinea pig maximisation test guinea pig guinea pig not specified OECD Guideline 406 (Skin Sensitisation) Germ cell mutagenicity: The mixture is classified based on threshold limits referring to the classified substances present in the mixture. Result Type of study / Route of administration negative bacterial reverse mutation assay (e.g negative negative Ames test) mammalian cell gene mutation assay bacterial reverse mutation assay (e.g Ames test) Metabolic activation / Exposure time Species Method with and without OECD Guideline 471 (Bacterial Reverse Mutation with and without Assay) OECD Guideline 476 (In vitro Mammalian Cell Gene Mutation Test) with and without OECD Guideline 471 (Bacterial Reverse Mutation Assay) Carcinogenicity No data available. Reproductive toxicity: No data available. STOT-single exposure: No data available. STOT-repeated exposure:: The mixture is classified based on threshold limits referring to the classified substances present in the mixture. Aspiration hazard: No data available. Result / Route of application Exposure time / Frequency of treatment NOAEL 125 mg/kg oral: gavage 6 (interim sacrifice) or 13 w daily Species Method rat EPA OTS (90- Day Oral Toxicity in Rodents)

12 SDS No.: V007.0 LOCTITE SF 7400 known as LOCTITE ml Blister M/L Page 12 of 15 ecological information: Do not empty into drains / surface water / ground water. SECTION 12: Ecological information Toxicity Toxicity (Fish): Exposure time Species Method LC50 18 mg/l 96 h Pimephales promelas OECD Guideline 203 (Fish, Acute Toxicity Test) LC mg/l 96 h Salmo gairdneri (new name: OECD Guideline 203 (Fish, Oncorhynchus mykiss) Acute Toxicity Test) Toxicity (Daphnia): Exposure time Species Method EC50 44 mg/l 48 h Daphnia sp. OECD Guideline 202 (Daphnia sp. Acute Immobilisation Test) EC mg/l 48 h Daphnia magna OECD Guideline 202 (Daphnia sp. Acute Immobilisation Test) Chronic toxicity to aquatic invertebrates Exposure time Species Method NOEC 23,2 mg/l 21 d Daphnia magna OECD 211 (Daphnia magna, Reproduction Test) Toxicity (Algae): Exposure time Species Method EC50 674,7 mg/l 72 h Scenedesmus subspicatus (new name: Desmodesmus subspicatus) EC10 295,5 mg/l 72 h Scenedesmus subspicatus (new name: Desmodesmus subspicatus) EC mg/l 96 h Selenastrum capricornutum (new name: Pseudokirchneriella subcapitata) OECD Guideline 201 (Alga, Growth Inhibition Test) OECD Guideline 201 (Alga, Growth Inhibition Test) OECD Guideline 201 (Alga, Growth Inhibition Test) Toxicity to microorganisms Exposure time Species Method IC mg/l 40 h Ciliate (Tetrahymena other guideline: pyriformis) EC0 275 mg/l 16 h not specified

13 SDS No.: V007.0 LOCTITE SF 7400 known as LOCTITE ml Blister M/L Page 13 of Persistence and degradability The product is not biodegradable. Result Test Degradability Exposure time Method readily biodegradable aerobic 83 % 28 d OECD Guideline 301 D (Ready Biodegradability: Closed Bottle Test) readily biodegradable aerobic 99 % 7 day OECD Guideline 301 E (Ready biodegradability: Modified OECD Screening Test) Bioaccumulative potential No data available. No substance data available Mobility in soil The product evaporates readily. 2-Naphthalenol, 1-[[4- (phenylazo)phenyl]azo]-, arheptyl ar',ar''-me derivs LogPow Temperature Method 2,3 25 C OECD Guideline 117 (Partition Coefficient (n-octanol / water), HPLC Method) 1,31 20 C not specified 5,14 OECD Guideline 107 (Partition Coefficient (n-octanol / water), Shake Flask Method) Results of PBT and vpvb assessment 2-Naphthalenol, 1-[[4-(phenylazo)phenyl]azo]-, ar-heptyl ar',ar''-me derivs PBT / vpvb Not fulfilling Persistent, Bioaccumulative and Toxic (PBT), very Persistent and very Bioaccumulative (vpvb) criteria. Not fulfilling Persistent, Bioaccumulative and Toxic (PBT), very Persistent and very Bioaccumulative (vpvb) criteria. Not fulfilling Persistent, Bioaccumulative and Toxic (PBT), very Persistent and very Bioaccumulative (vpvb) criteria Other adverse No data available. SECTION 13: Disposal considerations Waste treatment methods Product disposal: Dispose of in accordance with local and national regulations. Collection and delivery to recycling enterprise or other registered elimination institution. Disposal of uncleaned packages: Disposal must be made according to official regulations. After use, tubes, cartons and bottles containing residual product should be disposed of as chemically contaminated waste in an authorised legal land fill site or incinerated. Waste code other solvents and solvent mixtures The valid EWC waste code numbers are source-related. The manufacturer is therefore unable to specify EWC waste codes for the articles or products used in the various sectors. The EWC codes listed are intended as a recommendation for users. We will be happy to advise you.

14 SDS No.: V007.0 LOCTITE SF 7400 known as LOCTITE ml Blister M/L Page 14 of 15 SECTION 14: Transport information UN number ADR 1263 RID 1263 ADN 1263 IMDG 1263 IATA UN proper shipping name ADR RID ADN IMDG IATA PAINT PAINT PAINT PAINT Paint Transport hazard class(es) ADR 3 RID 3 ADN 3 IMDG 3 IATA Packing group ADR RID ADN IMDG IATA II II II II II Environmental hazards ADR RID ADN IMDG IATA Special precautions for user ADR RID ADN IMDG IATA Special provision 640D Tunnelcode: (D/E) Special provision 640D Special provision 640D Transport in bulk according to Annex II of Marpol and the IBC Code SECTION 15: Regulatory information Safety, health and environmental regulations/legislation specific for the substance or mixture VOC content 74,7 % (2010/75/EC) Chemical safety assessment A chemical safety assessment has not been carried out.

15 SDS No.: V007.0 LOCTITE SF 7400 known as LOCTITE ml Blister M/L Page 15 of 15 SECTION 16: Other information The labelling of the product is indicated in Section 2. The full text of all abbreviations indicated by codes in this safety data sheet are as follows: H225 Highly flammable liquid and vapor. H226 Flammable liquid and vapor. H319 Causes serious eye irritation. H332 Harmful if inhaled. H335 May cause respiratory irritation. H336 May cause drowsiness or dizziness. H351 Suspected of causing cancer. H361 Suspected of damaging fertility or the unborn child. H413 May cause long lasting harmful to aquatic life. Further information: This information is based on our current level of knowledge and relates to the product in the state in which it is delivered. It is intended to describe our products from the point of view of safety requirements and is not intended to guarantee any particular properties. Relevant changes in this safety data sheet are indicated by vertical lines at the left margin in the body of this document. Corresponding text is displayed in a different color on shadowed fields.